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At least 721 records · Page 40

Non-isothermal effects on SO2 absorption by water droplets. I - Model development. II - Results and discussion

An analytic model of SO2 absorption in a falling water droplet is developed and a simulation of SO2 washout is performed. Nonisothermic effects on drop growth, droplet physical parameters, reaction rates, and multicomponent diffusion are treated in the model. The gas-liquid interface is assumed to be at equilibrium, and interfacial resistance is negligible. Raindrops are simulated as falling from a 2 km height through an atmospheric region containing SO2. The droplets decrease in size from evaporation and cooling, and their slightly basic pH aids SO2 absorption. The simulation indicates higher SO2 absorption at higher altitudes, and desorption may occur at ground level. Isothermal effects are concluded to be significant, and quantification of effects will depend on further modelling.

Reda, M.↗

Mesoscale simulations of the November 25-26 and December 5-6 cirrus cases using the RAMS model

The Regional Atmospheric Modeling System (RAMS), developed at Colorado State University, was used during the First ISCCP (International Satellite Cloud Climatology Project) Regional Experiment (FIRE) 2 (13 Nov. through 6 Dec. 1991) to provide real time forecasts of cirrus clouds. Forecasts were run once a day, initializing with the 0000 UTC dataset provided by NOAA (Forecast Systems Laboratory (FSL) Mesoscale Analysis and Prediction System (MAPS)). In order to obtain better agreement with observations, a second set of simulations were done for the FIRE 2 cases that occurred on 25-26 Nov. and 5-6 Dec. In this set of simulations, a more complex radiation scheme was used, the Chen/Cotton radiation scheme, along with the nucleation of ice occurring at ice supersaturations as opposed to nucleation occurring at water supersaturations that was done in the actual forecast version. The runs using these more complex schemes took longer wall clock time (7-9 hours for the actual forecasts as compared to 12-14 hrs for the runs using the more complex schemes) however, the final results of the simulations were definitely improved upon. Comparisons between these two sets of simulations are given. Now underway are simulations of these cases using a closed analytical solution for the auto-conversion of ice from a pristine ice class (sizes less than about 50 microns in effective diameter) to a snow class (effective diameters on the order of several hundred microns). This solution is employed along with a new scheme for the nucleation of ice crystals due to Meyers et al and Demott et al. The scheme is derived assuming complete gamma distributions for both the pristine and snow classes. The time rate of change of the number concentration and mass mixing-ratio of each distribution is found by calculating either the flux of crystals that grow beyond a certain critical diameter by vapor deposition in an ice supersaturated regime or by calculating the flux of crystals that evaporate to sizes below that same critical effective diameter.

Harrington, J. L.↗

Miniature Heat Transport System for Spacecraft Thermal Control

Loop heat pipes (LHP) are efficient devices for heat transfer and use the basic principle of a closed evaporation-condensation cycle. The advantage of using a loop heat pipe over other conventional methods is that large quantities of heat can be transported through a small cross-sectional area over a considerable distance with no additional power input to the system. By using LHPs, it seems possible to meet the growing demand for high-power cooling devices. Although they are somewhat similar to conventional heat pipes, LHPs have a whole set of unique properties, such as low pressure drops and flexible lines between condenser and evaporator, that make them rather promising. LHPs are capable of providing a means of transporting heat over long distances with no input power other than the heat being transported because of the specially designed evaporator and the separation of liquid and vapor lines. For LHP design and fabrication, preliminary analysis on the basis of dimensionless criteria is necessary because of certain complicated phenomena that take place in the heat pipe. Modeling the performance of the LHP and miniaturizing its size are tasks and objectives of current research. In the course of h s work, the LHP and its components, including the evaporator (the most critical and complex part of the LHP), were modeled with the corresponding dimensionless groups also being investigated. Next, analysis of heat and mass transfer processes in the LHP, selection of the most weighted criteria from known dimensionless groups (thermal-fluid sciences), heat transfer rate limits, (heat pipe theory), and experimental ratios which are unique to a given heat pipe class are discussed. In the third part of the report, two-phase flow heat and mass transfer performances inside the LHP condenser are analyzed and calculated for Earth-normal gravity and microgravity conditions. On the basis of recent models and experimental databanks, an analysis for condensing two-phase flow regimes, pressure gradients, and local heat transfer coefficients using ammonia, propylene, and R134, are carried out.

Ochterbeck, Jay M.↗

Prebiotic Membranes and Micelles Do Not Inhibit Peptide Formation During Dehydration

Abstract Cycles of dehydration and rehydration could have enabled formation of peptides and RNA in otherwise unfavorable conditions on the early Earth. Development of the first protocells would have hinged upon colocalization of these biopolymers with fatty acid membranes. Using atomic force microscopy, we find that a prebiotic fatty acid (decanoic acid) forms stacks of membranes after dehydration. Using LC‐MS‐MS (liquid chromatography‐tandem mass spectrometry) with isotope internal standards, we measure the rate of formation of serine dipeptides. We find that dipeptides form during dehydration at moderate temperatures (55 °C) at least as fast in the presence of decanoic acid membranes as in the absence of membranes. Our results are consistent with the hypothesis that protocells could have formed within evaporating environments on the early Earth.

Cohen, Zachary R.↗

Kinetics, Products, and Brown Carbon Formation by Aqueous-Phase Reactions of Glycolaldehyde with Atmospheric Amines and Ammonium Sulfate

Glycolaldehyde (GAld) is a C 2 water-soluble aldehyde produced during the atmospheric oxidation of isoprene and many other species and is commonly found in cloudwater. Previous work has established that glycolaldehyde evaporates more readily from drying aerosol droplets containing ammonium sulfate (AS) than does glyoxal, methylglyoxal, or hydroxyacetone, which implies that it does not oligomerize as quickly as these other species. Here, we report NMR measurements of glycolaldehyde’s aqueous-phase reactions with AS, methylamine, and glycine. Reaction rate constants are smaller than those of respective glyoxal and methylglyoxal reactions in the pH range of 3–6. In follow-up cloud chamber experiments, deliquesced glycine and AS seed particles were found to take up glycolaldehyde and methylamine and form brown carbon. At very high relative humidity, these changes were more than 2 orders of magnitude faster than predicted by our bulk liquid NMR kinetics measurements, suggesting that reactions involving surface-active species at crowded air–water interfaces may play an important role. The high-resolution liquid chromatography–electrospray ionization–mass spectrometric analysis of filter extracts of unprocessed AS + GAld seed particles identified sugar-like C 6 and C 12 GAld oligomers, including proposed product 3-deoxyglucosone, with and without modification by reactions with ammonia to diimine and imidazole forms. Chamber exposure to methylamine gas, cloud processing, and simulated sunlight increased the incorporation of both ammonia and methylamine into oligomers. Many C 4 –C 16 imidazole derivatives were detected in an extract of chamber-exposed aerosol along with a predominance of N-derivatized C 6 and C 12 glycolaldehyde oligomers, suggesting that GAld is capable of forming brown carbon SOA.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Graded-porosity heat-pipe wicks

To maximize the capacity of a nonarterial heat pipe, a wick is considered whose porosity is allowed to vary axially along its length. At every axial location the porosity is set no lower than required to maintain the wick in a nearly saturated state under the maximum heat-transport rate. The result is a wick whose permeability is everywhere as high as possible. The differential equation that governs the optimum porosity variation is solved numerically between a condenser-end boundary condition that just prevents a liquid slug or puddle in the vapor spaces and an evaporator-end boundary condition that just prevents circumferential groove dry-up. Experimental performance measurements for an ammonia heat pipe are presented.

Eninger, J. E.↗

Performance of a Hybrid HVAC-Integrated Thermal Storage Device

Thermal equipment in buildings is a primary contributor to peak loads on the electrical grid. Thermal energy storage is a cost-effective strategy to decouple electric use from thermal loads, thus reducing grid peak costs for building owners. One method for storing thermal energy in a building is to integrate a phase change material (PCM) directly into the heating, ventilation, and air conditioning system. These systems often require additional glycol loops, pumps, valves, and heat exchangers to couple the storage to the cooling system and building space, which increases the complexity and cost. This work will discuss an alternate approach where the storage is added directly into the heat pump evaporator. A detailed two-dimensional finite difference heat transfer model of a PCM-refrigerant-glycol heat exchanger was developed to simulate the performance of this component. The fluid stream was discretized along the flow direction to capture changes in the fluid properties and local heat transfer rates, and the phase change material was discretized in both the x and y directions to capture the movement of the melt front. The model was used to understand the impact of different material and geometric properties on the charge and discharge characteristics of the device. Finally, a Ragone framework analogous to that used for electrochemical batteries was used to maximize the energy density and round-trip efficiency of the device while supplying loads appropriate for space cooling in buildings.

buildings↗

Can cloud-top entrainment promote cloud growth?

The primary significance of Cloud Deepening through Entrainment (CDE) is that it can prevent the cloud top entrainment instability from destroying a cloud deck. Without suppressing the instability, CDE transforms it from a cloud destroyer to a cloud builder. The analysis does not depend on an entrainment hypothesis. Moreover, it is not restricted to PBL stratocumulus sheets. Stratiform clouds in the free atmosphere can be subject to CDE we need only reinterpret Ps as the pressure at the base of an elevated turbulent mixed layer. Modest departures from well mixedness will alter the results quantitatively but not qualitatively. Processes other than entrainment, such as surface evaporation, radiative cooling, and advection will often work with CDE to build a cloud layer; but of course they can also oppose CDE by reducing the relative humidity. If we make the weak assumption that the deepening of a cloud layer favors an increase in the cloud top entrainment rate (without specifying any particular functional relationship) we are led to speculate that CDE can cause runaway cloud growth, even in the absence of cloud top entrainment instability. through CDE entrainment leads to a deeper cloud, which leads to stronger entrainment.

Randall, D. A.↗

Thermoneutral zone and scaling of metabolic rate on body mass in small mammals

A 4-species animal model suitable for experimental study of the effect of change in gravitational loading on the scale relationship between metabolic rate and total body mass is used to study the effect of temperature on metabolic rate in six male animals, 8-10 months of age, of each of the four species in the ambient temperature range 20-36 C. The measurements taken permitted partitioning of total body heat output into sensible heat loss by radiation, conduction and convection, and into latent heat loss by evaporation of water from the body surface. It is shown that the condition of thermoneutrality is important for metabolic scale effect studies, and that the thermoneutral zone for the species considered here is a narrow one.

Pace, N.↗

Vertical variation of turbulent entrainment mixing processes in marine stratocumulus clouds using high-resolution digital holography

Marine stratocumulus clouds contribute signi?cantly to the Earth’s radiation budget due to their extensive coverage and high albedo. Yet, subgrid variability in cloud properties such as aerosol concentration, droplet number and precipitation rates lead to considerable errors in global climate models. While these clouds usually have small vertical ex-tent, turbulent entrainment-mixing and precipitation can generate signi?cant variations in droplet number, size and relative dispersion with altitude. In this paper, we analyze turbulent entrainment-mixing processes and the variability in cloud microphysical properties as a function of height within a warm marine stratocumulus cloud layer over the Eastern North Atlantic. We use high resolution airborne holographic measurements and compare them with local turbulence measurements. We ?nd that entrainment-mixing is primarily inhomogeneous near cloud top leading to larger droplet sizes and homogeneous near cloud base leading to smaller droplet sizes. Further analysis of Damk¨ohler number measurements are able to explain the mixing mechanisms at di?erent cloud heights, reinforcing the importance of turbulent mixing and microphysical time scales in deter-mining cloud microphysics.

Desai, Neel↗

Water desalination through the dewpoint evaporative system

This paper presents the first numerical analysis of a novel Dew Point Desalination unit (DPD), which utilizes the phenomenon of the evaporative cooling process to minimize energy consumption. The proposed solution is based on a modular structure, which allows it to obtain any required water production capacity. The analyses for various operational parameters and various climatic conditions are based on the numerical simulations conducted using a validated mathematical model. The system performance was described with different factors, including specific energy consumption (SEC) and daily water production rate respected to 1 m^3*s^-1 of passing air stream (DWP). It is shown that the DPD system can operate in almost every climate zone, and the desalinated water production consumes less than 1.5 kWh*m^-3 of electric energy It is noted the best performance of the DPD system is achieved in the semi-arid, desert and subtropical climate zones. In these climate zones, the 2-stage DPD system allows the production of desalinated water with an electric energy consumption SEC lower than 0.5 kWh*m^-3. The additional benefit of the DPD system is its modularity. The presented DPD system stands as a module, that can be multiplied as needed to achieve the desired size of the desalination plant.

Desalination↗

Intensified Warming and Aridity Accelerate Terminal Lake Desiccation in the Great Basin of the Western United States

Terminal lakes in the Great Basin (GB) of the western US host critical wildlife habitat and food for migrating birds and can be associated with serious human health and economic consequences when they desiccate. Water levels have declined dramatically in the last 100+ years due to diversion of inflows, drought and climate change. Satellite-derived environmental science data records (ESDRs) from the MODerate-resolution Imaging Spectroradiometer (MODIS) (snow cover, evapotranspiration (ET) and land surface temperature (LST)), enable a unique approach to evaluate the effects of aridification on terminal lakes and to study their individual vulnerabilities. Surface and air temperatures in the GB are rising dramatically, with a sharp rise in the rate of increase observed beginning around 2011, while the number of days of snow cover is declining especially in the western mountainous part of the GB as exemplified in Mono Basin, California. Rising temperatures coincide with fewer days of snow cover, a decrease of inflow to the lakes and greater evaporation of water from the lakes. MODIS ESDRs show strong and statistically significant increasing surface temperature (LST) in the GB, a reduction in the number of days of snow cover, and mixed results in ET. ET declined slightly in the more arid parts of the GB due to greater moisture restrictions to evaporation from extended drought, while ET increased in the more-vegetated, wetter, mountainous northeastern parts as temperatures have risen. Severe and costly ecological, human health and economic consequences are expected if the lakes continue to decline as predicted.

land surface temperature↗

Experimental and computational investigation of the influence of iso -butanol on autoignition of n -decane and n -heptane in non-premixed flows

Experimental and computational investigation is carried out to elucidate the influence of iso-butanol on critical conditions of autoignition of n-decane and n-heptane. The counterflow configuration is employed. In this configuration an axisymmetric stream of air is directed over the surface of an evaporating pool of a liquid fuel. A stagnation plane is established. The temperature of the air is increased until autoignition is achieved in the mixing layer in the vicinity of the stagnation plane. The temperature of the air stream at autoignition, T ig , is measured at various values of the strain rate, which is defined as the axial gradient of the axial component of the flow velocity at the stagnation plane. Fuels tested are n-decane, n-heptane, iso-butanol and various mixtures of n-decane/iso-butanol and n-heptane/iso-butanol. Kinetic modeling is carried out using the recently updated version of the comprehensive CRECK chemical-kinetic mechanism. Critical conditions of autoignition are predicted for all fuels and fuel mixtures and the results are compared with the measurements. Computations show that low-temperature chemistry plays a significant role in promoting autoignition of n-decane and n-heptane, and the influence of low-temperature chemistry decreases with increasing strain rates because there is insufficient residence for the low-temperature reactions to take place. Experimental data and numerical simulations show that addition of even small amounts of iso-butanol to n-decane or n-heptane increases the value of T ig at low strain rates indicating that iso-butanol strongly inhibits the low-temperature chemistry of n-decane and n-heptane. Furthermore, the simulations show that when iso-butanol is present in the liquid fuel, only a small amount of n-decane is available in the gas phase and its low concentration cannot effectively sustain the low temperature degenerate branching oxidation process. Here, predicted flame structures show that the peak values of mole fraction of ketohydroperoxide are significantly reduced when iso-butanol is added to n-decane indicating that the kinetic pathway to low temperature ignition is blocked. This observation is confirmed from sensitivity analysis.

42 ENGINEERING↗

Assessing hybrid vigour using the thermal sensitivity of physiological trade-offs in tiger salamanders

Hybridization between species affects biodiversity and population sustainability in numerous ways, many of which depend on the fitness of the hybrid relative to the parental species. Hybrids can exhibit fitter phenotypes compared to the parental lineages, and this ‘hybrid vigour’ can then lead to the extinction of one or both parental lines. In this study, we analysed the relationship between water loss and gas exchange to compare physiological performance among three tiger salamander genotypes—the native California tiger salamander (CTS), the invasive barred tiger salamanders (BTS) and CTS × BTS hybrids across multiple temperatures (13.5°C, 20.5°C and 23.5°C). We developed a new index of performance, the water-gas exchange ratio (WGER), which we define as the ratio of gas exchange to evaporative water loss (μL V O 2 /μL H 2 O). The ratio describes the ability of an organism to support energetically costly activities with high levels of gas exchange while simultaneously limiting water loss to lower desiccation risk. We used flow through respirometry to measure the thermal sensitivity of metabolic rate and resistance to water loss of each salamander genotype to compare indices of physiological performance. We found that temperature had a significant effect on metabolic rate and resistance to water loss, with both traits increasing as temperatures warmed. Across genotypes, we found that hybrids have a higher WGER than the native CTS, owing to a higher metabolic rate despite having a lower resistance to water loss. These results provide a greater insight into the physiological mechanisms driving hybrid vigour and offer a potential explanation for the rapid spread of salamander hybrids. More broadly, our introduction of the WGER may allow for species- or lineage-wide comparisons of physiological performance across changing environmental conditions, highlighting the insight that can be gleaned from multitrait analysis of organism performance.

59 BASIC BIOLOGICAL SCIENCES↗

A disk about PSR 1957+20?

Although the PSR 1957+20 binary system displays a large orbital period derivative, radio observations of the ablated wind from the companion reveal a low free electron density. If the orbital period derivative provides a true indication of the mass loss rate, then the ablated material must be overwhelmingly neutral or largely confined to a narrow region about the orbital plane. However, the companion's high orbital velocity, the observed turbulence in the eclipsing wind, and the energy density of the pulsar's spin-down radiation conspire to make a neutral evaporate unlikely. Radio, optical and infrared observations are shown to suggest that the companion to PSR 1957+20 is bloated, perhaps approaching the size of its Roche lobe. The wind off the companion is most probably a low velocity flow which does not travel far from the orbital plane.

Fruchter, A. S.↗

Treatability Study of Pentaborane(9)

Procedures for the safe destruction of liquid pentaborane(9), B5H9, by solvolysis were investigated. The objective of the study was to establish the optimum conditions for a pilot plant operation that would use water, or alcohol, or water-alcohol mixtures as the solvolysis reagent. Small amounts of B5H9 sprayed from a syringe will not necessarily enflame, nor will a small pool on a spot plate. Therefore, a procedure was developed to reproducibly demonstrate the flammability of B5H9. In these tests every sample of neat B5H9 ignited and burned with a very sooty flame till the sample was consumed. The spontaneous self-ignition of B5H9 was quenched by the addition of small concentrations of ethers THF (tetrahydrofuran) or DME (1,2-dimethoxy ethane). It was found that ten percent (volume) of either provided total quenching with a large margin of safety. When these stabilized solutions were exposed to air, they decomposed and evaporated leaving a residue that was identified by nuclear magnetic resonance (NMR) analysis as boric acid. Most of the laboratory solvolysis experiments used the 90 percent B5H9, 10 percent THF solution. This mixture was safer to handle and its solvolysis reactivity was virtually identical to that of 100 percent B5H9. Reaction rates were analyzed by measurement of hydrogen evolved during the solvolysis reactions. In terms of the minimum overall complete reaction time, the data indicate that 50/50 alcohol/water is the optimum solvolysis reagent. This reaction produced a mixture of boric acid, B(OH)3, and triethoxyborane, B(OEt)3[Et = C2H5], and mixed exchange derivatives thereof.

McDonald, Joseph K.↗

Modelling the development of capillary pressure in freshly 3D-printed concrete elements

3D concrete printing is a promising technology recently developed to automate construction. Since no formwork is used in this technology to support and protect fresh concrete, there are two aspects which considerably accelerate the development of capillary pressure in 3D-printed concrete in comparison to conventionally placed concrete: i) high stiffness of 3D-printed needed to provide sufficient buildability, and ii) very early and fast evaporation of pore water. Accelerated development of capillary pressure may lead to severe plastic shrinkage cracking in 3D-printed elements and, hence, need to be mitigated. This investigation aims at providing a poromechanical model for capillary pressure development in 3D-printed elements. To simulate the development of capillary pressure and plastic shrinkage, environmental factors, material properties, and element geometry need to be considered as a whole. The model inputs – coefficient of permeability, static bulk modulus, air entry pressure and chemical shrinkage rate – were determined experimentally. The model was validated for two fine-grained concretes. Both 3D-printed materials yielded faster capillary pressure increase in comparison to cast concrete, while partial substitution of cement with silica fume further accelerated the capillary pressure development. Furthermore, due to the lower permeability of the mixture containing silica fume, the gradient of capillary pressure between 3D-printed layers increased, as did the gradient of plastic shrinkage.

36 MATERIALS SCIENCE↗

Aggregation‐Induced Stimulated Emission of 100% Dye Microspheres

Dyes with aggregation-induced emission (AIE) properties have gained interest due to their bright luminescence in solid-state aggregates. While fluorescence from AIE dyes is widely exploited, relatively little is known about aggregation-induced stimulated emission. Here, stimulated emission of tetraphenylethene (TPE)-based organoboron AIE dyes, TPEQBN, in thin films and in microcavity lasers is investigated. Using femtosecond pump–probe spectroscopy, gain coefficients up to 230 cm -1 at 500 nm are measured. Using rate equations, concentration- and pump-dependent gain dynamics as well as laser build-up dynamics are analyzed. During laser oscillation, radiative stimulated emission allows high instantaneous quantum yield greater than 90% to be achieved. Solid-state microspheres made of 100% AIE dyes are fabricated via microfluidic emulsion and solvent evaporation method. Coupled with high gain and high refractive index of 1.76, microspheres as small as 2 µm in diameter show lasing by nanosecond pumping with a threshold of ≈10 pJ µm –2 . Polymer coated, but not bare, microspheres are internalized by live cells and generate narrowband cavity-mode emission from within the cytoplasm. This work shows the potential of AIE dyes as laser materials.

36 MATERIALS SCIENCE↗