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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 721 records · Page 40

Satellite Sounder Observations of Contrasting Tropospheric Moisture Transport Regimes: Saharan Air Layers, Hadley Cells, and Atmospheric Rivers

This paper examines the performance of satellite sounder atmospheric vertical moisture proles (AVMP) under tropospheric conditions encompassing moisture contrasts driven by convection and advection transport mechanisms, specifically Atlantic Ocean Saharan air layers (SALs) and Pacific Ocean moisture conveyer belts (MCBs) commonly referred to as atmospheric rivers (ARs), both of these being mesoscale to synoptic meteorological phenomena within the vicinity of subtropical Hadley subsidence zones. Operational AVMP environmental data records retrieved from the Suomi National Polar-orbiting Partnership (SNPP) NOAA-Unique Combined Atmospheric Processing System (NUCAPS) are collocated with dedicated radiosonde observations (RAOBs) obtained from ocean-based intensive field campaigns; these RAOBs provide uniquely independent correlative truth data not assimilated into numerical weather prediction models for satellite sounder validation over open ocean. Using these marine-based data, we empirically assess the performance of the operational NUCAPS AVMP product for detecting and resolving these tropospheric moisture features over otherwise RAOB-sparse regions.

54 ENVIRONMENTAL SCIENCES↗

Assessing Tropical Cyclones’ Contribution to Precipitation over the Eastern United States and Sensitivity to the Variable-Resolution Domain Extent

Tropical cyclones (TCs) can subject an area to heavy precipitation for many hours, or even days, worsening the risk of flooding, which creates dangerous conditions for residents of the U.S. East and Gulf Coasts. To study the representation of TC-related precipitation over the eastern United States in current-generation global climate models, a novel analysis methodology is developed to track TCs and extract their associated precipitation using an estimate of their dynamical outer size. This methodology is applied to three variable-resolution (VR) configurations of the Community Atmosphere Model, version 5 (CAM5), with high-resolution domains over the North Atlantic and one low-resolution conventional configuration, as well as to a combination of reanalysis and observational precipitation data. Metrics and diagnostics such as TC counts, intensities, outer storm sizes, and annual mean total and extreme precipitation are compared between the CAM5 simulations and reanalysis/observations. The high-resolution VR configurations outperform the global low-resolution configuration for all variables in the North Atlantic. Realistic TC intensities are produced by the VR configurations. The total North Atlantic TC counts are lower than observations but better than reanalysis.

54 ENVIRONMENTAL SCIENCES↗

Synthesis and structural characterization of the vividly colored first row transition metal-containing oxyfluoride antiperovskites Sr3-xMnxMO4F and Sr3-xMnxMO4-αF1-δ (M = Al, Ga)

Highlights: • Substitution of Mn{sup 2+} demonstrates Sr{sub 3-x}A{sub x}MO{sub 4}F can tolerate divalent first row transition metals. • The colors of these materials vary from green to purple depending on anion stoichiometry. • Intense colors are likely due to small amounts of Mn{sup 3+} on the tetrahedral Al site. • Structural data is consistent with preferential occupation of eight-coordinate Sr(2) site by Mn{sup 2+}. • Large off-center displacements are observed on the underbonded ten-coordinate Sr(1) site. - Abstract: Incorporation of dopant amounts of the divalent transition metal cation Mn{sup 2+} into the oxyfluoride material Sr{sub 3-x}Mn{sub x}MO{sub 4}F (M = Al, Ga; 0 ≤ x ≤ 0.1) yields green powders which vary in hue depending on the identity of M. Treatment of these phases with post-synthesis annealing under reducing conditions produces anion deficient phases according to Sr{sub 3-x}Mn{sub x}MO{sub 4-α}F{sub 1-δ} displaying vivid purple coloration. Intense colors are likely due to small amounts of Mn{sup 3+} on the tetrahedral M site. Full structural characterization based upon powder X-ray diffraction (PXRD), neutron powder diffraction (NPD), and thermogravimetric analysis (TGA) data are presented herein, demonstrating that the Sr{sub 3-x}A{sub x}MO{sub 4}F (A = Ca, Sr, Ba; M = Al, Ga) anti-perovskite structure can readily accommodate first row transition metals.

36 MATERIALS SCIENCE↗

Life-cycle mediated effects of urbanization on parasite communities in the estuarine fish, Fundulus heteroclitus

This study examined the relationship between urbanization and parasite community structure in the estuarine fish, Fundulus heteroclitus. We measured landscape and physicochemical factors associated with urbanization at 6 sites from 4 collection periods. Concurrently, we quantified the metazoan parasite community in F. heteroclitus collected at those sites, with 105 fish studied per site during the 4 collection periods. Parasite community composition differed among sites. Host size was the most important variable for direct life-cycle parasite assemblages and indirect life-cycle parasites at the individual fish level, while landscape and physicochemical factors determined the structure of indirect life-cycle parasite assemblages at the population scale. Variation in the prevalence and intensity of infection of two indirect life-cycle parasites, Lasiocotus minutus and Glossocercus caribaensis, were the primary parasites that drove differences across sites. Variation in the presence/absence of these indirect life-cycle parasite species was associated with sediment Ni concentrations, patch density, and marsh size. Our data support the hypothesis that urbanization, acting at both landscape and physicochemical scales, can have a significant impact on parasite community structure. This, however, varied by parasite life history: there was little effect of urbanization on the prevalence and intensity of direct life-cycle parasites, but significant variation was detected for indirect life-cycle parasites. This study demonstrates how anthropogenically driven landscape change influences fine-scale population dynamics of parasites.

54 ENVIRONMENTAL SCIENCES↗

Defect identification in simulated Bragg coherent diffraction imaging by automated AI

X-ray Bragg coherent diffraction imaging is a powerful technique for operando and in situ materials characterization and provides a unique means of quantifying the influence of one-dimensional (1D) and two-dimensional (2D) material defects on material response. However, obtaining full images from raw x-ray diffraction data is nontrivial and computationally intensive, precluding real-time experimental feedback. Here, we present a machine learning approach to identify the presence of crystalline line defects (edge and screw) in samples from the raw, 2D, coherent diffraction data without the need for image reconstruction through iterative phase retrieval. Further, we compare different approaches to designing neural networks for this application and demonstrate the potential of automated ML (autoML) approaches.

36 MATERIALS SCIENCE↗

Evaluating downscaled products with expected hydroclimatic co-variances

Abstract. There has been widespread adoption of downscaled products amongst practitioners and stakeholders to ascertain risk from climate hazards at the local scale (e.g., ∼ 5 km resolution). Such products must nevertheless be consistent with physical laws to be credible and of value to users. Here we evaluate statistically and dynamically downscaled products by examining local co-evolution of downscaled temperature and precipitation during convective and frontal precipitation events (two mechanisms testable with just temperature and precipitation). We find that two widely used statistical downscaling techniques (Localized Constructed Analogs version 2, LOCA2, and Seasonal Trends and Analysis of Residuals Empirical Statistical Downscaling Model, STAR-ESDM) generally preserve expected co-variances during convective precipitation events over the historical and future projected intervals as compared to European Centre for Medium-Range Weather Forecasts Reanalysis v5 (ERA5) and two observation-based data products (Livneh and nClimGrid-Daily). However, both techniques dampen future intensification of frontal precipitation that is otherwise robustly captured in global climate models (i.e., prior to downscaling) and with process-based dynamical downscaling across five different regional climate models. In the case of LOCA2, this leads to appreciable underestimation of future frontal precipitation event intensity. This study is one of the first to quantify a likely ramification of the stationarity assumption underlying statistical downscaling methods and identify a phenomenon where projections of future change diverge depending on data production method employed. Finally, our work proposes expected co-variances during convective and frontal precipitation as useful evaluation diagnostics that can be universally applied to a wide range of statistically downscaled products.

54 ENVIRONMENTAL SCIENCES↗

Public Communication of Technical Issues in Today's Changing Visual Language - 12436

Communication regarding the management of radioactive materials is a well-established challenge. Residents and consumers have suspected for years that companies and governments place short-term economic concerns ahead of health and safety. This skepticism is compounded with increased attention to safety issues at nuclear power plants everywhere after Fukushima. Nonetheless, today's environment presents unexpected opportunities to transform public fear into teachable moments that bring knowledge and facts to discussions on nuclear energy. In the weeks following Japan's crisis, the lack of reliable information on radiation levels saw citizens taking to the streets with dosimeters and Geiger counters in crowd-sourced radiation monitoring efforts. Efforts, based mainly online, represent a growing set of examples of how internet and cell-phone technology are being put to use in emergency situations. The maps, graphs and tables created to meet public interest also exemplify some of the psychological priorities of audiences and present learning tools that can improve future education efforts in non-emergency situations. Industry outreach efforts often consist of technical details and quantitative data that are difficult for lay audiences to interpret. The intense attention to nuclear energy issues since last March has produced a wide array of visual samples. Citizen monitors, news organizations, government agencies and others have displayed quantitative information in innovative ways. Their efforts offer new perspective on what charts, maps and info graphics do - or need to do - to illustrate requirements, record assessments and promote understanding of nuclear-waste issues. Surveying the best examples, nuclear communicators can improve their offerings of easy-to-use, evidence-based visuals to inform stakeholders. Familiar to most communications professionals in the nuclear industry, risk communication is a science-based approach with over three decades of research evidence informing the discipline. Risk communication principles address the fact that often perception is reality. Scientific evidence for decision making must be approached differently in situations where stakeholders have high levels of concern and low levels of trust. Visual communications must take this into account to be successful. (author)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Design of the radiation shielding for the time of flight enhanced diagnostics neutron spectrometer at Experimental Advanced Superconducting Tokamak

A radiation shielding has been designed to reduce scattered neutrons and background gamma-rays for the new double-ring Time Of Flight Enhanced Diagnostics (TOFED). The shielding was designed based on simulation with the Monte Carlo code MCNP5. Dedicated model of the EAST tokamak has been developed together with the emission neutron source profile and spectrum; the latter were simulated with the Nubeam and GENESIS codes. Significant reduction of background radiation at the detector can be achieved and this satisfies the requirement of TOFED. The intensities of the scattered and direct neutrons in the line of sight of the TOFED neutron spectrometer at EAST are studied for future data interpretation.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Evaluating crystallographic likelihood functions using numerical quadratures

Intensity-based likelihood functions in crystallographic applications have the potential to enhance the quality of structures derived from marginal diffraction data. Their usage, however, is complicated by the ability to efficiently compute these target functions. Here, a numerical quadrature is developed that allows the rapid evaluation of intensity-based likelihood functions in crystallographic applications. By using a sequence of change-of-variable transformations, including a nonlinear domain-compression operation, an accurate, robust and efficient quadrature is constructed. The approach is flexible and can incorporate different noise models with relative ease.

59 BASIC BIOLOGICAL SCIENCES↗

Effects of Light and Temperature on Fatty Acid Production in Nannochloropsis Salina

Accurate prediction of algal biofuel yield will require empirical determination of physiological responses to the climate, particularly light and temperature. One strain of interest, Nannochloropsis salina, was subjected to ranges of light intensity (5-850 {mu}mol m{sup -2} s{sup -1}) and temperature (13-40 C); exponential growth rate, total fatty acids (TFA) and fatty acid composition were measured. The maximum acclimated growth rate was 1.3 day{sup -1} at 23 C and 250 {mu}mol m{sup -2} s{sup -1}. Fatty acids were detected by gas chromatography with flame ionization detection (GC-FID) after transesterification to corresponding fatty acid methyl esters (FAME). A sharp increase in TFA containing elevated palmitic acid (C16:0) and palmitoleic acid (C16:1) during exponential growth at high light was observed, indicating likely triacylglycerol accumulation due to photo-oxidative stress. Lower light resulted in increases in the relative abundance of unsaturated fatty acids; in thin cultures, increases were observed in palmitoleic and eicosapentaenoeic acids (C20:5{omega}3). As cultures aged and the effective light intensity per cell converged to very low levels, fatty acid profiles became more similar and there was a notable increase of oleic acid (C18:1{omega}9). The amount of unsaturated fatty acids was inversely proportional to temperature, demonstrating physiological adaptations to increase membrane fluidity. This data will improve prediction of fatty acid characteristics and yields relevant to biofuel production.

59 BASIC BIOLOGICAL SCIENCES↗

Submillimeter, millimeter, and microwave spectral line catalogue, revision 3

A computer-accessible catalog of submillimeter, millimeter, and microwave spectral lines in the frequency range between 0 and 10,000 GHz (i.e., wavelengths longer than 30 micrometers) is described. The catalog can be used as a planning or as an aid in the identification and analysis of observed spectral lines. The information listed for each spectral line includes the frequency and its estimated error, the intensity, the lower state energy, and the quantum number assignment. This edition of the catalog has information on 206 atomic and molecular species and includes a total of 630,924 lines. The catalog was constructed by using theoretical least square fits of published spectral lines to accepted molecular models. The associated predictions and their estimated errors are based upon the resultant fitted parameters and their covariances. Future versions of this catalog will add more atoms and molecules and update the present listings as new data appear. The catalog is available as a magnetic data tape recorded in card images, with one card image per spectral line, from the National Space Science Data Center, located at Goddard Space Flight Center.

Pickett, H. M.↗

Scientist-Guided Autonomy for Self-Reliant Rovers

Although Mars rover missions have been highly successful in accomplishing scientific objectives, mission productivity is limited by challenges stemming from the need for commanding ground-based targeted observations under communication constraints imposed by the large distance between Earth and Mars. With an aging fleet of sun-synchronous relay orbiters, the opportunities for regular communication with rovers may become even more limited. In addition to on-board planning, robust navigation, and health assessment, there are strategies to make future rovers more self-reliant by enabling them to perform autonomous scientific characterizations of new areas during periods without an opportunity for ground-based targeted observations. In particular, we have studied how a ”walkabout” strategy, in which an initial high-level characterization of a region is used to informed subsequent passes with specific targeted observations, was used successfully during the investigation of Pahrump Hills by the Mars Science Laboratory. Inspired by this approach, we have identified several capabilities that could allow a rover to autonomously perform some of these initial high-level characterization steps. In this paper, we describe technologies for identifying specific geologic units, regions, or features of interest, identifying areas of contact between two adjacent units, detecting and determining the orientation of layering within rock units, identifying novel and interesting features, and planning observations of regions with different sampling strategies using remote sensing instruments. The observations acquired with these approaches are driven by scientists’ guidance and can provide scientists with data to help inform their decisions about where to make more resource-intensive targeted observations.

Doran, Gary↗

Developing Intensity-Duration-Frequency (IDF) Curves From Satellite-Based Precipitation: Methodology and Evaluation

Given the continuous advancement in the retrieval of precipitation from satellites, it is important to develop methods that incorporate satellite-based precipitation data sets in the design and planning of infrastructure. This is because in many regions around the world, in situ rainfall observations are sparse and have insufficient record length. A handful of studies examined the use of satellite-based precipitation to develop intensity-duration-frequency (IDF) curves; however, they have mostly focused on small spatial domains and relied on combining satellite-based with ground-based precipitation data sets. In this study, we explore this issue by providing a methodological framework with the potential to be applied in ungauged regions. This framework is based on accounting for the characteristics of satellite-based precipitation products, namely, adjustment of bias and transformation of areal to point rainfall. The latter method is based on previous studies on the reverse transformation (point to areal) commonly used to obtain catchment-scale IDF curves. The paper proceeds by applying this framework to develop IDF curves over the contiguous United States (CONUS); the data set used is Precipitation Estimation from Remotely Sensed Information Using Artificial Neural Networks – Climate Data Record (PERSIANN-CDR). IDFs are then evaluated against National Oceanic and Atmospheric Administration (NOAA) Atlas 14 to provide a quantitative estimate of their accuracy. Results of this work show that median errors are in the range of (17–22%), (6–12%), and (3–8%) for one-day, two-day and three-day IDFs, respectively, and return periods in the range (2–100) years. Furthermore, a considerable percentage of satellite-based IDFs lie within the confidence interval of NOAA Atlas 14.

54 ENVIRONMENTAL SCIENCES↗

Sustainable biofuel contributions to carbon mitigation and energy independence

The growing interest in US biofuels has been motivated by two primary national policy goals, (1) to reduce carbon emissions and (2) to achieve energy independence. However, the current low cost of fossil fuels is a key barrier to investments in woody biofuel production capacity. The effectiveness of wood derived biofuels must consider not only the feedstock competition with low cost fossil fuels but also the wide range of wood products uses that displace different fossil intensive products. Alternative uses of wood result in substantially different unit processes and carbon impacts over product life cycles. We developed life cycle data for new bioprocessing and feedstock collection models in order to make life cycle comparisons of effectiveness when biofuels displace gasoline and wood products displace fossil intensive building materials. Wood products and biofuels can be joint products from the same forestland. Furthermore, substantial differences in effectiveness measures are revealed as well as difficulties in valuing tradeoffs between carbon mitigation and energy independence.

09 BIOMASS FUELS↗

TRACER Radar b1 Data Processing: Corrections, Calibrations, and Processing Report

The U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) user facility deployed the first ARM Mobile Facility (AMF1) to Houston, Texas for the Tracking Aerosol Convection Interactions Experiment (TRACER) field campaign. The TRACER campaign was conducted from October 1, 2021 to September 30, 2022, with an intensive operational period (IOP) from June 1 to September 30, 2022.

54 ENVIRONMENTAL SCIENCES↗

From Chaos to Clarity: Autonomous Materials Discovery for Extreme Environments [Slides]

The pursuit of advanced functional materials for energy applications demands an understanding of their behavior under the most challenging conditions. Extreme environments, characterized by intense radiation, high temperatures, and corrosive chemistries, push materials to their limits, often revealing unexpected behaviors and degradation pathways. Traditional materials research approaches, relying on trial-and-error experimentation, are often slow and resource-intensive, ill-suited to the complexities of extreme environments. This talk will explore the transformative potential of autonomous materials science in revolutionizing our understanding of materials synthesis and degradation in extreme environments. By integrating advanced microscopy techniques, artificial intelligence, and robotic experimentation, we can accelerate the discovery and design of resilient materials for a sustainable future. The presentation will highlight recent breakthroughs in autonomous microscopy, computer vision, and machine learning, showcasing their ability to unravel complex material transformations at the atomic scale. The talk will also delve into the challenges and opportunities associated with deploying autonomous systems to probe extreme environments, emphasizing the importance of robust algorithms, real-time data analysis, and adaptive experimentation. The ultimate goal is to empower scientists with unprecedented capabilities to explore, understand, and engineer materials that can withstand the harshest conditions, paving the way for innovations in energy, aerospace, and beyond.

14 SOLAR ENERGY↗

From Chaos to Clarity: Autonomous Materials Discovery for Extreme Environments

The pursuit of advanced functional materials for energy applications demands an understanding of their behavior under the most challenging conditions. Extreme environments, characterized by intense radiation, high temperatures, and corrosive chemistries, push materials to their limits, often revealing unexpected behaviors and degradation pathways. Traditional materials research approaches, relying on trial-and-error experimentation, are often slow and resource-intensive, ill-suited to the complexities of extreme environments. This talk will explore the transformative potential of autonomous materials science in revolutionizing our understanding of materials synthesis and degradation in extreme environments. By integrating advanced microscopy techniques, artificial intelligence, and robotic experimentation, we can accelerate the discovery and design of resilient materials for a sustainable future. The presentation will highlight recent breakthroughs in autonomous microscopy, computer vision, and machine learning, showcasing their ability to unravel complex material transformations at the atomic scale. The talk will also delve into the challenges and opportunities associated with deploying autonomous systems to probe extreme environments, emphasizing the importance of robust algorithms, real-time data analysis, and adaptive experimentation. Our ultimate goal is to empower scientists with unprecedented capabilities to explore, understand, and engineer materials that can withstand the harshest conditions, paving the way for innovations in energy, aerospace, and beyond.

artificial intelligence↗