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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 721 records · Page 40
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Structural relaxation of water during rapid cooling from ambient temperatures

Experiments investigating the properties of deeply supercooled liquid water are needed to develop a comprehensive understanding of water’s anomalous properties. One approach involves transiently heating nanoscale water films into the supercooled region for several nanoseconds at a time and then interrogating the water films after they have quenched to cryogenic temperatures. To relate the results obtained with this approach to other experiments and simulations on supercooled water, it is important to understand how closely the quenched structure tracks the (metastable) equilibrium structure of water as a function of the transient heating temperature. A key step involves quantifying the extent to which water that is transiently heated to ambient temperatures [hyperquenched water (HQW)] subsequently relaxes toward the structure of low-density amorphous (LDA) ice as it cools. We analyzed the infrared reflection–absorption spectra of LDA, HQW, and crystalline ice films to determine their complex indices of refraction. With this information, we estimate that HQW retains ~50%–60% of a structural motif characteristic of water at high temperatures with the balance comprised of a low-temperature motif. This result, along with results from x-ray diffraction experiments on water and amorphous ices, allows one to quantify the fraction of the high-temperature motif at approximately zero pressure as a function of temperature from 150 to 350 K.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Gain Stability of Hamamatsu R5912-MOD Photo-Multipliers at Low Temperature

The Photon Detection System is a crucial component of the ICARUS detector in the Short Baseline Neutrino (SBN) Program at Fermi National Accelerator Laboratory (FNAL). It consists of 360 Photo Multiplier Tubes (PMTs) 8” Hamamatsu R5912-MOD and, since June 2020, it has been operated at the liquid Argon cryogenic temperature. During these years, the PMTs have shown gain losses as an aging effect. Using a climatic chamber at the INFN Sezione di Catania, we confirmed a stable gain for a single PMT 8” Hamamatsu 5912-MOD when operated at room temperature, and a persistent gain loss at temperatures around -70°C, although far from the liquid Argon one. No gain recovery was obtained bringing the PMT back to room temperature. We suspect that dynode deterioration due to temperature gradient plays a significant role in this phenomenon. During our test, the PMT was illuminated by a 520 nm laser source and operated in current mode. The laser beam was split into two optical fibers, the first one transmitting light through Neutral Density filters and then diffusing it over the surface of the PMT photocathode. The other optical fiber was used for an independent reference measurement of the injected light via a bolometric photodetector. In this presentation, the main technical characteristics of the measurement system are shown together with preliminary results which need further investigation to elucidate the underlying mechanisms driving the gain loss and to propose new mitigation strategies.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1993

Collecting cometary soil samples? Development of the ROSETTA sample acquisition system

In the reference scenario of the ROSETTA CNRS mission, the Sample Acquisition System is mounted on the Comet Lander. Its tasks are to acquire three kinds of cometary samples and to transfer them to the Earth Return Capsule. Operations are to be performed in vacuum and microgravity, on a probably rough and dusty surface, in a largely unknown material, at temperatures in the order of 100 K. The concept and operation of the Sample Acquisition System are presented. The design of the prototype corer and surface sampling tool, and of the equipment for testing them at cryogenic temperatures in ambient conditions and in vacuum in various materials representing cometary soil, are described. Results of recent preliminary tests performed in low temperature thermal vacuum in a cometary analog ice-dust mixture are provided.

Coste, P. A.↗
DOE OSTI2020

Using Additives to Control the Decomposition Temperature of Sodium Borohydride

Hydrogen (H 2 ) shows great promise as zero-carbon emission fuel, but there are several challenges to overcome in regards to storage and transportation to make it a more universal energy solution. Gaseous hydrogen requires high pressures and large volume tanks while storage of liquid hydrogen requires cryogenic temperatures; neither option is ideal due to cost and the hazards involved. Storage in the solid state presents an attractive alternative, and can meet the U.S. Department of Energy (DOE) constraints to find materials containing > 7 % H 2 (gravimetric weight) with a maximum H 2 release under 125 °C. While there are many candidate hydrogen storage materials, the vast majority are metal hydrides. Of the hydrides, this review focuses solely on sodium borohydride (NaBH 4 ), which is often not covered in other hydride reviews. However, as it contains 10.6% (by weight) H 2 that can release at 133 ± 3 JK -1 mol -1 , this inexpensive material has received renewed attention. NaBH 4 should decompose to H 2 (g), Na(s), and B(s), and could be recycled into its original form. Unfortunately, metal to ligand charge transfer in NaBH 4 induces high thermodynamic stability, creating a high decomposition temperature of 530 °C. In an effort make H 2 more accessible at lower temperatures, researchers have incorporated additives to destabilize the structure. This review highlights metal additives that have successfully reduced the decomposition temperature of NaBH 4 , with temperatures ranging from 522 °C (titanium (IV) fluoride) to 379 °C (niobium (V) fluoride). We describe synthetic methods employed, chemical pathways taken, and the challenges of boron derivative formation on H 2 cycling. Though no trends can be found across all additives, it is our hope that compiling the data here will enable researchers to gain a better understanding of the additives’ influence and to determine how a new system might be designed to make NaBH 4 a more viable H 2 fuel source.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1989

Safety and cryogenic wind tunnels

The Langley 0.3-Meter Transonic Cryogenic Tunnel (0.3-m TCT) was placed in operation at NASA's Langley Research Center in 1973 as the world's first cryogenic pressure tunnel. The 0.3-m TCT can operate from ambient to cryogenic temperatures over an absolute pressure range from about 1 to 6 atmospheres. Three major test section concepts were developed and refined in this unique facility. The 0.3-m TCT is a leader in the development of various cryogenic pressure wind tunnel experimental techniques, instrumentation, control, model technology and safety standards. The safety experience gained is examined. During this period of advanced research, new operating techniques, training policies, and procedures had to be established. The paper deals with the Do's and Don'ts of cryogenic wind tunnel testing. Hazards and safety requirements which are unique to cryogenic testing are discussed. Highlights of experience and lessons learned with the 0.3-m TCT are reviewed.

Ray, Edward J.↗
NASA NTRS2003

Theoretical Studies of the Extra-terrestrial Chemistry of Biogenic Elements and Compounds

Results are presented on the following:(A) Ab initio quantum chemical studies of reactions in astrophysical ices.Theoretical electronic structure calculations were used to investigate reactions between formaldehyde (H2CO) and both hydrogen cyanide (HCN) and isocyanide (HNC) in search of other favorable reactions such as ammonia-formaldehyde addition, which was found in a recent theoretical study to be strongly enhanced when it occurs within cold ices.The present study examines further reactions between this product and H2CO in ices.(B) Heterogeneous hydrogenation of CO and H2CO on icy grain mantles.Formaldehyde (H2CO) and methanol (CH30H) are thought to be produced in the interstellar medium by the successive hydrogenation of carbon monoxide (CO) on grain surfaces. In the gas phase, the steps in which H adds to CO and H2CO possess modest barriers and are too inefficient to account for the observed abundances. Recent laboratory work has confirmed that formaldehyde and methanol are formed when H atoms are deposited on CO ice at 12 K. The present study employed ab initio quantum chemical calculations to investigate the impact of water ice on the sequential hydrogenation of CO.(C) Ice-bound condensed-phase reactions involving formic acid (HCOOH), methylenimine (CH2NH), hydrogen cyanide (HCN), hydrogen isocyanide (HNC), and ammonia ( 3) were investigated in order to characterize possible pathways to larger organic species that are efficient at the cold temperatures prevalent in cometary nuclei and the interstellar medium. (D) Pathways to glycine and other amino acids in ultraviolet-irradiated ices determined via quantum chemical modeling.(E) Photoionization in ultraviolet processing of astrophysical ice analogs at cryogenic temperatures.

Woon, David E.↗
DOE OSTI2023

Optimization of a Packed Particle Magnetocaloric Refrigerator: A Combined Experimental and Theoretical Study

Magnetocaloric refrigeration has strong potential towards achieving high efficiency hydrogen liquefaction. Optimising parameters such as particle size and operating cycles can have a significant impact on liquefaction performance. Here, this work reports on a room temperature magnetocaloric refrigeration prototype designed with helium as the heat transfer fluid and packed particle Gd 0.8875 Ce 0.1025 Si 0.84 Cr 0.19 as the refrigerant. The temperature spans and cooling power with three different particle sizes at two different operating cycles were measured. A maximum temperature span of 16.7 K and a maximum cooling power of 8.6 W·kg –1 were obtained. Reduction of performance in the faster cycle was observed in larger particles due to insufficient thermal diffusion time and its implications for cryogenic temperatures are discussed. A numerical model was developed based on the experimentally observed variation of the temperature span and cooling power with particle size and cycle duration. This model was then used to study the competing effects of viscous dissipation and thermal diffusion for different particle sizes and cycle durations.

08 HYDROGEN↗
DOE OSTI2022

Thermal conductivity of RHIC superconducting magnet insulation materials at low temperatures

The Electron-Ion Collider (EIC) is planned to be built upon the Relativistic Heavy Ion Collider (RHIC), which vacuum chamber will need to be upgraded to host the EIC hadron beams. For the beam pipe section running through the RHIC superconducting (SC) magnets, the baseline is to insert a screen that will get cooled by thermal contact to the 4.55 K beam pipe of RHIC. Knowing the material properties of the cold mass is thus crucial to understand which is the final temperature that the screen and the superconducting coils in the magnets will reach during the passage of the EIC beams. The thermal conductivities of two insulation materials in the RHIC superconducting magnets and a reference material were measured at cryogenic temperatures at the Magnet Science and Technology division of the National High Magnetic Field Laboratory (NHMFL). The measurements were performed in a Quantum Design physical property measurement system. This report explains the motivation behind this work and summarizes the measurement method and results.

43 PARTICLE ACCELERATORS↗
NASA NTRS2008

Cryogenic Moisture Uptake in Foam Insulation for Space Launch Vehicles

Rigid polyurethane foams and rigid polyisocyanurate foams (spray-on foam insulation), like those flown on Shuttle, Delta IV, and will be flown on Ares-I and Ares-V, can gain an extraordinary amount of water when under cryogenic conditions for several hours. These foams, when exposed for eight hours to launch pad environments on one side and cryogenic temperature on the other, increase their weight from 35 to 80 percent depending on the duration of weathering or aging. This effect translates into several thousand pounds of additional weight for space vehicles at lift-off. A new cryogenic moisture uptake apparatus was designed to determine the amount of water/ice taken into the specimen under actual-use propellant loading conditions. This experimental study included the measurement of the amount of moisture uptake within different foam materials. Results of testing using both aged specimens and weathered specimens are presented. To better understand cryogenic foam insulation performance, cryogenic moisture testing is shown to be essential. The implications for future launch vehicle thermal protection system design and flight performance are discussed.

Fesmire, James E.↗
NASA NTRS1982

Some characteristics of polymers in composite materials and as electrical conductors

The characteristics of carbon fibers (CF) made from polyacrylonitrile (PAN) materials are discussed, together with research on conducting polymers. CF materials have better mechanical properties, chemical inertness, and higher stiffness than metallic materials but are subject to environmental instability, flammability, and delamination fatigue. Polymerization procedures for the monopolymer PAN are described, noting the use of SEM and X-ray diffraction techniques for studying the fiber structure. High modulus and strength of CF are caused by covalent sp(2) bonds in hexagonal carbon rings, which are stronger than the same links in diamonds. Details of the molecular chain structures and macroformations, stress-strain as a function of temperature, and thermosetting and glass transition temperatures of polymers are provided. Computational quantum chemistry techniques are being applied to studying electrical conductance in polymers, mainly to discover ways to stabilize the materials. Doped CH(x) has exhibited photovoltaic properties and other polymers have become superconductors at cryogenic temperatures.

Hansen, C. F.↗
NASA NTRS1987

Support of the eight-foot high-temperature tunnel modifications project

An ultrasonic level sensor was developed to measure the liquid level in a storage vessel under high pressures, namely up to 6000 psi. The sensor is described. A prototype sensor was installed in the cooling-water storage vessel of the Eight-Foot High-Temperature Tunnel. Plans are being made to install the readout instrument in the control room, so that tunnel operators can monitor the water level during the course of a tunnel run. It was discovered that the sensor will operate at cryogenic temperatures. Consequently, a sensor will be installed in the modified Eight-Foot High-Temperature Tunnel to measure the sound speed of liquid oxygen (LOX) as it is transferred from a storage vessel to the tunnel combustor at pressure of about 3000 psi. The sound speed is known to be a reliable indicator of contamination of LOX by pressurized gaseous nitrogen, which will be used to effect the transfer. Subjecting the sensor to a temperature cycle from room temperature to liquid nitrogen temperature and back again several times revealed no deterioration in sensor performance. The method using this sensor is superior to the original method, which was to bleed samples of LOX from the storage vessel to an independent chamber for measurement of the sound speed.

Hodges, Donald Y.↗
NASA NTRS1988

Investigation of energy transfer in the ignition mechanism of a NASA standard initiator

The principal objective of the proposed research was to construct a detailed computer model of the NASA Standard Initiator (NSI). The NSI plays a critical role in initiating various pyrotechnic events in the National Space Transportation System and is also used in Shuttle payload applications. Several initiators failed when being tested at very low temperatures (4 to 20 K). During subsequent investigation an unacceptable high failure rate was found even at higher temperatures (100 to 150 K) but the precise cause of failure was not determined. The modelling work was undertaken to investigate reasons for failure and to predict the performance of alternate firing schemes. The work has shown that the most likely cause of failure at low temperature is poor thermal contact between the electrically heated bridgewire and the pyrotechnic charge. This problem may be masked if there is good thermal contact between the bridgewire and the alumina charge cup. The high thermal conductivity of alumina at cryogenic temperatures was overlooked in previous analyses, which assumed that the charge cup acted as a thermal insulator.

Varghese, Philip L.↗
NASA NTRS2012

Cryogenic Applications of Commercial Electronic Components

We have developed a range of techniques useful for constructing analog and digital circuits for operation in a liquid Helium environment (4.2K), using commercially available low power components. The challenges encountered in designing cryogenic electronics include finding components that can function usefully in the cold and possess low enough power dissipation so as not to heat the systems they are designed to measure. From design, test, and integration perspectives it is useful for components to operate similarly at room and cryogenic temperatures; however this is not a necessity. Some of the circuits presented here have been used successfully in the MUSTANG and in the GISMO camera to build a complete digital to analog multiplexer (which will be referred to as the Cryogenic Address Driver board). Many of the circuit elements described are of a more general nature rather than specific to the Cryogenic Address Driver board, and were studied as a part of a more comprehensive approach to addressing a larger set of cryogenic electronic needs.

Buchanan, Ernest D.↗
NASA NTRS1973

Design and development of liquid hydrogen mixer unit

A dc brushless motor driven mixer unit (a vaneaxial fan) was designed and evaluated for use in cryogenic fluids (liquids and gases). It was found to operate well in all fluids in which it was tested. The test fluids were liquid and gaseous helium, hydrogen in the liquid phase gas phase and mixtures of the two phases, and liquid nitrogen. It operated for over 100 hr at cryogenic temperatures without damage to the bearings and at the conclusion of testing the condition of the bearings was such that an operational life of 5000 hr appeared possible. The unit demonstrated that (with the brushless dc motor principle) useful pumping of cryogenic fluids could be accomplished with very small power inputs to the mixer motor. During test, the motor input power varied from approximately 0.5 W to 2.5 W, depending on fluid density. The high power input produced a mixer efficiency of over 49 percent. In an earlier program (see NASA Report CR-72365), a mixer using an ac induction motor demonstrated an efficiency of 17.7 percent under the same conditions, illustrating the advantage of the dc brushless motor driven unit. The mixer also demonstrated its ability to automatically vary speed as a function of the density of the fluid being pumped. This causes the unit to deliver higher volumetric flow rates as fluid density decreases.

Morgan, R. W.↗
NASA NTRSDate not supplied

Mastering the Cryogenic Frontier: Predicting Sloshing in Cryogenic Propellant Tanks

In recent years, NASA has undertaken the development and validation of computation fluid dynamic (CFD) models for predicting cryogenic two-phase sloshing within propellant tanks. These models have been rigorously anchored against cryogenic ground tests that induce sloshing, as well as limited microgravity tests. The primary focus of these models is to accurately predict the two-phase condensation and, at times, evaporation within the cryogenic propellant. This approach is important for estimating the required autogenous and/or helium pressurant for completing propulsion system burns or ensuring adequate pressure for in-space propellant transfers. Unlike in hypergolic propulsion systems, where the propellant is stored at room temperature, cryogenic propellant is highly volatile. Therefore, ensuring the accurate estimation of pressurant necessitates the precise modeling of two-phase interfacial heat and mass transfer processes. This paper aims to provide an overview of NASA’s continuing efforts in developing and validating these CFD models, with particular emphasis on benchmark cases with sloshing that enhances phase change, tracing their historical development, and demonstrating their predictive accuracy when compared to test results.

low-gravity fluid modeling↗
DOE OSTI2023

Determining biomolecular structures near room temperature using X-ray crystallography: concepts, methods and future optimization

For roughly two decades, cryocrystallography has been the overwhelmingly dominant method for determining high-resolution biomolecular structures. Competition from single-particle cryo-electron microscopy and micro-electron diffraction, increased interest in functionally relevant information that may be missing or corrupted in structures determined at cryogenic temperature, and interest in time-resolved studies of the biomolecular response to chemical and optical stimuli have driven renewed interest in data collection at room temperature and, more generally, at temperatures from the protein–solvent glass transition near 200 K to ∼350 K. Fischer has recently reviewed practical methods for room-temperature data collection and analysis [Fischer (2021), Q. Rev. Biophys. 54 , e1]. Here, the key advantages and physical principles of, and methods for, crystallographic data collection at noncryogenic temperatures and some factors relevant to interpreting the resulting data are discussed. For room-temperature data collection to realize its potential within the structural biology toolkit, streamlined and standardized methods for delivering crystals prepared in the home laboratory to the synchrotron and for automated handling and data collection, similar to those for cryocrystallography, should be implemented.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS2008

High Performance COPVs for In-Space Storage of High Pressure Cryogenic Fuels

Polymeric composite overwrapped pressure vessels (COPVs) provide an attractive material system to support developing commercial launch business and alternate fuel ventures. However to be able to design with these materials, the mechanical behavior of the materials must be understood with regards to processing, performance, damage tolerance, and environment. For the storage of cryogenic propellants, it is important to evaluate the materials performance and impact damage resistance at cryogenic temperatures in order to minimize weight and to ensure safety and reliability. As part of this study, material tests of candidate fiber and resin systems were used as the basis for the selection of the material combinations for evaluation in a COPV at cryogenic conditions. This comprehensive approach has also been expanded to address issues with impact damage tolerance and material degradation due to environmental factors. KEY WORDS: Cryogenic testing, evaluation and applications for pressure vessels, COPVs, tanks, or storage vessels.

Schneider, Judy↗