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At least 721 records · Page 40

Integration of genome-scale metabolic model with biorefinery process model reveals market-competitive carbon-negative sustainable aviation fuel utilizing microbial cell mass lipids and biogenic CO 2

Producing scalable, economically viable, low-carbon biofuels or biochemicals hinges on more efficient bioconversion processes. While microbial conversion can offer robust solutions, the native microbial growth process often redirects a large fraction of carbon to CO 2 and cell mass. By integrating genome-scale metabolic models with techno-economic and life cycle assessment models, this study analyzes the effects of converting cell mass lipids to hydrocarbon fuels, and CO 2 to methanol on the facility’s costs and life-cycle carbon footprint. Results show that upgrading microbial lipids or both microbial lipids and CO 2 using renewable hydrogen produces carbon-negative bisabolene. Additionally, on-site electrolytic hydrogen production offers a supply of pure oxygen to use in place of air for bioconversion and fuel combustion in the boiler. To reach cost parity with conventional jet fuel, renewable hydrogen needs to be produced at less than $\$2.2$ to $\$3.1$/kg, with a bisabolene yield of 80% of the theoretical yield, along with cell mass and CO 2 yields of 22 wt% and 54 wt%, respectively. The economic combination of cell mass, CO 2 , and bisabolene yields demonstrated in this study provides practical insights for prioritizing research, selecting suitable hosts, and determining necessary engineered production levels.

09 BIOMASS FUELS↗

Competitive docking model for prediction of the human nicotinic acetylcholine receptor α7 binding of tobacco constituents

The detrimental health effects associated with tobacco use constitute a major public health concern. The addiction associated with nicotine found in tobacco products has led to difficulty in quitting among users. Nicotinic acetylcholine receptors (nAChRs) are the targets of nicotine and are responsible for addiction to tobacco products. However, it is unknown if the other >8000 tobacco constituents are addictive. Since it is time-consuming and costly to experimentally assess addictive potential of such larger number of chemicals, computationally predicting human nAChRs binding is important for in silico evaluation of addiction potential of tobacco constituents and needs structures of human nAChRs. Therefore, we constructed three dimensional structures of the ligand binding domain of human nAChR α7 subtype and then developed a predictive model based on the constructed structures to predict human nAChR α7 binding activity of tobacco constituents. The predictive model correctly predicted 11 out of 12 test compounds to be binders of nAChR α7. The model is a useful tool for high-throughput screening of potential addictive tobacco constituents. These results could inform regulatory science research by providing a new validated predictive tool using cutting-edge computational methodology to high throughput screen tobacco additives and constituents for their binding interaction with the human α7 nicotinic receptor. The tool represents a prediction model capable of screening thousands of chemicals found in tobacco products for addiction potential, which improves the understanding of the potential effects of additives.

60 APPLIED LIFE SCIENCES↗

Extending The Realm of Optimization for Complex Systems: Uncertainty, Competition, And Dynamics

Research reported addressed these topics: the development of analytical and algorithmic tools for distributed computation of Nash equilibria; synchronization in mean-field oscillator games, with an emphasis on learning and efficiency analysis; questions that combine learning and computation; questions including stochastic and mean-field games; modeling and control in the context of power markets.

97 MATHEMATICS AND COMPUTING↗

Basin-Scale Leakage Risks from Geologic Carbon Sequestration: Impact on Carbon Capture and Storage Energy Market Competitiveness

This three-year project, performed by Princeton University in partnership with the University of Minnesota and Brookhaven National Laboratory, examined geologic carbon sequestration in regard to CO 2 leakage and potential subsurface liabilities. The research resulted in basin-scale analyses of CO 2 and brine leakage in light of uncertainties in the characteristics of leakage processes, and generated frameworks to monetize the risks of leakage interference with competing subsurface resources. The geographic focus was the Michigan sedimentary basin, for which a 3D topographical model was constructed to represent the hydrostratigraphy. Specifically for Ottawa County, a statistical analysis of the hydraulic properties of underlying sedimentary formations was conducted. For plausible scenarios of injection into the Mt. Simon sandstone, leakage rates were estimated and fluxes into shallow drinking-water aquifers were found to be less than natural analogs of CO 2 fluxes. We developed the Leakage Impact Valuation (LIV) model in which we identified stakeholders and estimated costs associated with leakage events. It was found that costs could be incurred even in the absence of legal action or other subsurface interference because there are substantial costs of finding and fixing the leak and from injection interruption. We developed a model framework called RISCS, which can be used to predict monetized risk of interference with subsurface resources by combining basin-scale leakage predictions with the LIV method. The project has also developed a cost calculator called the Economic and Policy Drivers Module (EPDM), which comprehensively calculates the costs of carbon sequestration and leakage, and can be used to examine major drivers for subsurface leakage liabilities in relation to specific injection scenarios and leakage events. Finally, we examined the competiveness of CCS in the energy market. This analysis, though qualitative, shows that financial incentives, such as a carbon tax, are needed for coal combustion with CCS to gain market share. In another part of the project we studied the role of geochemical reactions in affecting the probability of CO 2 leakage. A basin-scale simulation tool was modified to account for changes in leakage rates due to permeability alterations, based on simplified mathematical rules for the important geochemical reactions between acidified brines and caprock minerals. In studies of reactive flows in fractured caprocks, we examined the potential for permeability increases, and the extent to which existing reactive transport models would or would not be able to predict it. Using caprock specimens from the Eau Claire and Amherstburg, we found that substantial increases in permeability are possible for caprocks that have significant carbonate content, but minimal alteration is expected otherwise. We also found that while the permeability increase may be substantial, it is much less than what would be predicted from hydrodynamic models based on mechanical aperture alone because the roughness that is generated tends to inhibit flow.

54 ENVIRONMENTAL SCIENCES↗

Report on the Joint EU-US Workshop on Microbial Community Dynamics: Cooperation and Competition

The European Commission (EC)-United States (US) Task Force on Biotechnology Research has a longstanding joint Working Group on Biotechnology for the Environment whose mission is to foster collaborations between researchers in the European Union (EU) and US in the field of environmental biotechnology. A special focus of the Working Group is to increase scientific interchange between early career scientists in the US and EU. Such interactions initiate a foundation of respect and trust needed to develop long-term collaborations. In order to realize the full potential for the application of modern technologies to obtain a sustainable biosphere, it is vital to create conduits for knowledge exchange among scientists worldwide engaged in environmental microbial biotechnology research. Since its formation in 1994, the Working Group has organized many activities for early career scientists designed to promote this scientific exchange, including two week courses with hands-on research experience, intensive workshops of two or three days, and research scholar exchanges of one to six months. These interactions are focused on environmental problems that respect no international boundaries.

09 BIOMASS FUELS↗

Transport Studies Enabling Efficiency Optimization of Cost-Competitive Fuel Cell Stacks (aka AURORA: Areal Use and Reactant Optimization at Rated Amperage)

Hydrogen fuel cells are recognized as one of the most viable solutions for mobility in the 21st century; however, there are technical challenges that must be addressed before the technology can become available for mass production. One of the most demanding aspects is the costs of present-day fuel cells which are prohibitively high for the majority of envisioned markets. The fuel cell community recognizes two major drivers to an effective cost reduction: (1) decreasing the noble metals content, and (2) increasing the power density in order to reduce the number of cells needed to achieve a specified power level. To date, the majority of development work aimed at increasing the value metric (i.e. W/mg-Pt) has focused on the reduction of precious metal loadings, and this important work continues. Efforts to increase power density have been limited by two main factors: (1) performance limitations associated with mass transport barriers, and (2) the historical prioritization of efficiency over cost. This program is driven by commercialization imperatives, and challenges both of these factors. The premise of this Program, supported by proprietary cost modeling by Nuvera, is that DOE 2015 cost targets can be met by simultaneously exceeding DOE 2015 targets for Platinum loadings (using materials with less than 0.2 mg-Pt/cm 2 ) and MEA power density (operating at higher than 1.0 Watt/cm 2 ). The approach of this program is to combine Nuvera’s stack technology, which has demonstrated the ability to operate stably at high current densities (> 1.5 A/cm 2 ), with low Platinum loading MEAs developed by Johnson Matthey in order to maximize Pt specific power density and reduce stack cost. A predictive performance model developed by PSU/UTK is central to the program allowing the team to study the physics and optimize materials/conditions specific to low Pt loading electrodes and ultra-high current density and operation.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Final Report “Physiological, demographic, competitive and biogeochemical controls on the response of California’s ecosystems to environmental change”

The Loma Ridge Global Change Experiment is a large, well-replicated water and nitrogen input manipulation in the Santa Ana Mountain foothills that operated with DOE support from 2006 to 2015. The experiment considers the effects of increased and decreased water input and increased N input on two adjacent ecosystem types: California Annual Grassland (GL), which is dominated by exotic, Eurasian grasses and forbs, and Coastal Sage Shrubland (CSS), which is dominated by native, drought deciduous, perennial shrubs. The experiment proceeded in two phases: "Phase I Severe treatment", and "Phase II Return to ambient". Phase I showed very rapid change in species composition or ANPP with altered water or N input (low resistance), whereas Phase II showed a very rapid return to initial conditions once ambient water or N input were restored (high resilience). The severe drought treatment killed most of the shrubs in the dry plots and opened the canopy to herbaceous species, but this damage was ephemeral, and the shrubland community is recovering through the mechanisms and patterns that more typically mediate recovery from crown fire. The pattern of low resistance and high resilience carries implications for other "global change experiments", which have often also seen large and rapid treatment effects (low resistance), but have less frequently considered the subsequent recovery or resilience of the system.

54 ENVIRONMENTAL SCIENCES↗

Final Report Extreme Computing and U.S. Competitiveness DOE Award. DE-FG02-11ER26087/DE-SC0008764

The Council has acted on each of the grant deliverables during the funding period. The deliverables are: (1) convening the Council’s High Performance Computing Advisory Committee (HPCAC) on a bi-annual basis; (2) broadening public awareness of high performance computing (HPC) and exascale developments; (3) assessing the industrial applications of extreme computing; and (4) establishing a policy and business case for an exascale economy.

97 MATHEMATICS AND COMPUTING↗

Global Carbon Fiber Composites. Supply Chain Competitiveness Analysis

The objective of this study is to identify key opportunities in the carbon fiber (CF) supply chain where resources and investments can help advance the clean energy economy. The report focuses on four application areas—wind energy, aerospace, automotive, and pressure vessels—that top the list of industries using CF and carbon fiber reinforced polymers (CFRP) and are particularly relevant to the mission of U.S. Department of Energy’s Office of Energy Efficiency and Renewable Energy (DOE EERE). For each of the four application areas, the report addresses the supply and demand trends within that sector, supply chain, and costs of carbon fiber and components.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

The New Solar System: China’s Evolving Solar Industry and Its Implications for Competitive Solar Power in the United States and the World

Solar power is undergoing a revolution. Over the past decade, an energy source as old as the planet and theoretically all but limitless has plummeted in cost and begun in some places to be harnessed in large volume. This dynamic is disrupting the modern energy system and, as energy disruptions always do, rattling the geopolitical order. In the process, the industry that produces the equipment to convert sunlight into electricity is simultaneously reeling, consolidating, and surging. These twin transformations—one of the global energy system, one of the global solar industry—carry profound implications for national economies and for the planet. At the center of both transformations sits China. The New Solar System illuminates key and little- understood changes that are remaking the solar enterprise—in China and thus in the world. Based on this analysis, it recommends changes in U.S. solar policy—particularly timely with a new U.S. administration and Congress—that would put solar power on a more economically sensible path toward environmentally significant growth. The New Solar System does not seek to enable any country to beat another in the global solar industry. It seeks instead to help all countries find their most effective places. By better understanding and playing to their comparative strengths in the solar business, countries would achieve two key objectives. They would reduce the cost for the world of scaling up solar power. And they would be better positioned to fashion policies that maximized the long-term benefit to their own economies from solar’s global growth.

14 SOLAR ENERGY↗

Interactions between ammonia and nitrite oxidizing bacteria in co-cultures: Is there evidence for mutualism, commensalism, or competition?

Nitrification is a two-step environmental microbial process in the nitrogen cycle in which ammonia is oxidized to nitrate. Ammonia-oxidizing bacteria and archaea oxidize ammonia to nitrite and nitrite is oxidized to nitrate by nitrite-oxidizing bacteria. These microorganisms, which likely act in concert in a microbial community, play critical roles in the movement of inorganic N in soils, sediments and waters and are essential to the balance of the nitrogen cycle. Anthropogenic activity has altered the balance of the nitrogen cycle through agriculture practices and organic waste byproducts. Through their influence on available N for plant growth, nitrifying microorganisms influence plant productivity for food and fiber production and the associated carbon sequestration. N Fertilizer production, primarily as ammonia, requires large inputs of natural gas and hydrogen. In croplands fertilized with ammonia-based fertilizers, nitrifiers contribute to the mobilization of this N by producing nitrate (NO3-), wasting the energy used in the production and application of ammonia-based fertilizer. The resulting nitrate is readily leached from these soils, oxidized to gaseous N oxides (greenhouse gases), and denitrified to N2 (which is no longer available as a plant N source). Still, ammonia oxidizers are beneficial in the treatment of wastewater and they also show potential to contribute to microbial bioremediation strategies for clean up of environments contaminated with chlorinated hydrocarbons. Mitigation of the negative effects and exploitation of the beneficial effects of nitrifiers will be facilitated by a systems-level understanding of the interactions of ammonia-oxidizing bacteria and nitrite-oxidizing bacteria with the environment and with each other.

54 ENVIRONMENTAL SCIENCES↗

Development of Cost-Competitive Advanced Thermoelectric Generators for Direct Conversion of Vehicle Waste Heat into Useful Electrical Power

General Motors LLC (GM) proposed a project to develop a cost-effective thermoelectric generator (TEG) that is fully integrated into a GM production light-duty vehicle. The project goal was to reduce automotive energy consumption and CO 2 emissions by generating usable electricity from exhaust gas waste heat. The project objectives were to overcome the major obstacles to TEG commercialization and demonstrate 5% fuel economy improvement over the US06 drive cycle. We investigated electrical and thermal management strategies that included: (1) reducing electrical accessory load on the alternator using thermoelectric (TE) generated power; (2) shifting engine-driven accessories to electrical drive to raise the electrical accessory load consumption; (3) attempting to use the excess electrical power for something other than the vehicle electrical load e.g., propulsion (optimal for hybrids); and (4) implementing fast engine/transmission warm-up during cold-start. We developed a TEG system and all vehicle controls and electrical systems for full vehicle integration. The TEG system was modeled and analyzed for performance and cost. Heat exchangers and thermal interfaces between heat exchangers and TE modules were optimized for TE performance. Other objectives of the project were to (1) further optimize compositions and processing parameters for TE materials, (2) develop suitable diffusion barriers, interfaces electrical interconnections, and thermal contacts within TE modules, (3) implement adequate protection of TE materials and modules from degradation during operation, and (4) develop manufacturing and assembly processes for large scale production of TE materials and components that include scale-up plans for the production of 100,000 TEG units per year.

33 ADVANCED PROPULSION SYSTEMS↗

Strengthening Deterrence for 21st Century Strategic Conflicts and Competition: Accelerating Adaptation and Integration - Annotated Bibliography

This was the fourth in a series of annual events convened at Livermore to exploring the emerging place of the “new domains” in U.S. deterrence strategies. The purposes of the series are to facilitate the emergence of a community of interest that cuts across the policy, military, and technical communities and to inform laboratory strategic planning. U.S. allies have also been drawn into the conversation, as U.S. deterrence strategies are in part about their protection. Discussion in these workshops is on a not-for-attribution basis. It is also makes no use of classified information. On this occasion, there were nearly 100 participants from a dozen countries.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

DEFE0023863 Final Report, Technology for GHG Emission Reduction and Cost-Competitive Mil-Spec Jet Fuel Production using CTL

Ceramatec Inc, in collaboration with IntraMicron (IM), the Energy & Environmental Research Center (EERC) and Sustainable Energy Solutions, LLC (SES), have completed a three-year research project integrating their respective proprietary technologies in key areas to demonstrate production of a jet fuel from coal and biomass sources. The project goals and objectives were to demonstrate technology capable of producing a “commercially-viable quantity” of jet fuel and make significant progress toward compliance with Section 526 of the Energy Independence and Security Act of 2007 (EISA 2007 §526) lifecycle greenhouse gas (GHG) emissions requirements. The Ceramatec led team completed the demonstration of nominal 2 bbl/day Fischer-Tropsch (FT) synthesis pilot plant design, capable of producing a nominal 1 bbl/day in the Jet-A/JP-8 fraction. This production rate would have a capacity of 1,000 gallons of jet fuel per month and provide the design basis of a 100 bbl/day module producing over 2,000 gallons of jet fuel per day. Co-gasification of coal-biomass blends enables a reduction of lifecycle greenhouse gas emissions from equivalent conventional petroleum derived fuel basis. Due to limits of biomass availability within an economic transportation range, implementation of a significant biomass feed fraction will require smaller plants than current world scale CTL and GTL FT plants. Hence a down-scaleable design is essential. The pilot plant design leverages Intramicron’s MicroFiber Entrapped Catalyst (MFEC) support which increases the catalyst bed thermal conductivity two orders of magnitude, allowing thermal management of the FT reaction exotherm in much larger reactor tubes. In this project, single tube reactors having 4.5 inch outer diameter and multi-tube reactors having 4 inch outer diameters were operated, with productivities as high as 1.5 gallons per day per linear foot of reactor tube. A significant reduction in tube count results from the use of large diameter reactor tubes, with an associated reduction in reactor cost. The pilot plant was designed with provisions for product collection capable of operating with conventional wax producing FT catalysts but was operated with a Chevron hybrid wax-free FT catalyst. Process simplification enabled by elimination of the wax hydrocracking process unit provides economic advantages in scaling to biomass capable plant sizes. Intramicron also provided a sulfur capture system based on their Oxidative Sulfur Removal (OSR) catalyst process. The integrated sulfur removal and FT systems were operated with syngas produced by the Transport Reactor Development Unit (TRDU) gasifier at the University of North Dakota EERC. SES performed modeling of their cryogenic carbon capture process on the energy, cost and CO2 emissions impact of the Coal-biomass synthetic fuel process.

01 COAL, LIGNITE, AND PEAT↗

Entrepreneurial Community Feedback on the National Laboratory Accelerator Pitch Competition

Twelve DOE National Labs came together for a Pitch Event as the culmination of the National Lab Accelerator Program. The event was a showcase of Department of Energy innovation where National Laboratory scientists pitched to seasoned investors in an exciting completion. Approximately 60 people attended the September 25th event, bringing together National Lab researchers, technology transfer professionals and the business investment community for a day of technology and business model evaluation and valuable networking.

99 GENERAL AND MISCELLANEOUS↗

Understanding Structures of Cyber Competition in an Era of Major Power Rivalry

Over the past two decades, the cyber domain has emerged and evolved into a key strategic domain for nations across the globe. Security strategies are espoused by heads of state that focus on how to manage the increasingly enormous, crosscutting impact that the cyber domain has on national security across economic, military, intelligence, intellectual property, and countless other facets. These strategies frequently evolve, and even change entirely, as leaders adapt to new technologies and administrations change. Even if these strategies did not change at all, they would take inordinate amounts of time to effectively implement within the organizational structures of government. The time required to go from setting department and agency-level goals, to the time small teams have well-oiled processes and expertise to accomplish tactical objectives that meet the strategic vision is lengthy. With near certainty, by the time objectives and vision are implemented, the landscape, strategy, or both has changed entirely. While this churn will likely never cease due to the rapidly changing nature of the cyber domain, this problem raises an important question: can governmental structures be organized to rapidly adapt to changing cyber strategies? As offices responsible for particular missions in cyberspace shuffle about within the bureaucracy, are technical capabilities enabled or enhanced? No matter how advanced a particular technical capability is or how adept the staff is at solving problems, they will be ineffective if placed haphazardly within the organization: the right authorities may not exist for their office, the correct lines of interpersonal communication may not be established properly, or insufficient resources have not been allocated to effectively deploy a brilliant technical solution. This concept of organizational agility in the context of national cyber capabilities is important when taking into account the National Defense Strategy’s emphasis on cyber capability and the ability of the United States to compete and rapidly adapt to new challenges posed by rivals. As a nation, we are at a point where technology evolves rapidly enough to warrant thoughtful and nimble changes to the bureaucratic structures that support how cyber operations are carried out. Taking these questions and cross-comparing them to the organizational structures across China, Russia, and the United States provides for an interesting thought experiment. As non-democratic regimes, China and Russia have differing priorities and internal power dynamics than the United States and thus organize their governments differently. By combining known and broadcasted strategies of these nations with the observed technical capabilities demonstrated in the public domain, we can begin to see how organizational structures map to strategic goals and directly enable technical capabilities. Insight can be gained by introducing organizational structures into traditional analysis focusing solely around strategies and capabilities; additionally, otherwise unknown capabilities or intents might be discovered or inferred by analyzing organizational structures alone. Analyzing cyber operations from this oft-overlooked perspective could potentially provide useful insight and more concrete actions that can be undertaken to realize the National Defense Strategy’s goals.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Getting Innovation Right in the Strategy for Long-Term Competition (Workshop Summary)

On April 16 and 17, the Center for Global Security Research (CGSR) at Lawrence Livermore National Laboratory (LLNL) hosted a workshop to better understand the relationship between defense strategy and emerging innovation. A primary objective of the workshop was to uncover which processes foster innovation that can help the United States outcompete adversaries and bolster national security. The workshop brought together 63 participants from across the policy, military, and technical communities. Panelists addressed U.S. innovation strategy and inter-departmental initiatives, adversaries and innovation, drivers of technology strategy, private-public collaboration, and ally innovation. The conversation shifted to identify obstacles standing in the way of effective innovative policy, and how any long-term strategy must adjust accordingly to ensure innovative might.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Space Strategy at a Crossroads: Opportunities and Challenges for 21st Century Competition

In its November 2018 report to Congress, the bipartisan National Defense Strategy Commission applauded the main themes of the Trump administration’s 2017 National Defense Strategy. But it was also deeply critical of the strategic thought so far done by the U.S. defense community about the requirements, operational and otherwise, of securing U.S. and allied interests in the types of conflicts we now face. Indeed, it assessed these shortfalls as crippling to the exercise of American power and as dangerous in crisis and war. Is the U.S. military space community exempt from such criticism? Should it be?

29 ENERGY PLANNING, POLICY, AND ECONOMY↗