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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Experimental and Theoretical Study of the Electronic Structures of Lanthanide Indium Perovskites LnInO 3

Ternary lanthanide indium oxides LnInO 3 (Ln = La, Pr, Nd, Sm) were synthesized by high-temperature solid-state reaction and characterized by Xray powder diffraction. Rietveld refinement of the powder patterns showed the LnInO 3 materials to be orthorhombic perovskites belonging to the space group Pnma, based on almost-regular InO 6 octahedra and highly distorted LnO 12 polyhedra. Experimental structural data were compared with results from density functional theory (DFT) calculations employing a hybrid Hamiltonian. Valence region X-ray photoelectron and K-shell X-ray emission and absorption spectra of the LnInO 3 compounds were simulated with the aid of the DFT calculations. Photoionization of lanthanide 4f orbitals gives rise to a complex final-state multiplet structure in the valence region for the 4f n compounds PrInO 3 , NdInO 3 , and SmInO 3 , and the overall photoemission spectral profiles were shown to be a superposition of final-state 4f n-1 terms onto the cross-section weighted partial densities of states from the other orbitals. The occupied 4f states are stabilized in moving across the series Pr-Nd-Sm. Band gaps were measured using diffuse reflectance spectroscopy. These results demonstrated that the band gap of LaInO 3 is 4.32 eV, in agreement with DFT calculations. This is significantly larger than a band gap of 2.2 eV first proposed in 1967 and based on the idea that In 4d states lie above the top of the O 2p valence band. However, both DFT and X-ray spectroscopy show that In 4d is a shallow core level located well below the bottom of the valence band. Band gaps greater than 4 eV were observed for NdInO 3 and SmInO 3 , but a lower gap of 3.6 eV for PrInO 3 was shown to arise from the occupied Pr 4f states lying above the main O 2p valence band.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Machine Learning Prediction of Tritium‐Helium Groundwater Ages in the Central Valley, California, USA

Abstract Groundwater ages provides insight into recharge rates, flow velocities, and vulnerability to contaminants. The ability to predict groundwater ages based on more accessible parameters via Machine Learning (ML) would advance our ability to guide sustainable management of groundwater resources. In this study, ML models were trained and tested on a large data set of tritium concentrations and tritium‐helium groundwater ages from the California Central Valley, a large groundwater basin with complex land use, irrigation, and water management practices. The ML models were trained on 63 features, including location, well construction information, landscape characteristics, and climate variables, water chemistry, and stable isotopes. The Bagging regressor method can accurately classify (F1‐score = 0.91) groundwater samples as either modern or pre‐modern whereas the accuracy of the ML prediction of continuous tritium‐helium groundwater ages is limited and explains only of the variability in this data set. In general, ML groundwater age prediction relies mostly on features related to (a) the source of groundwater recharge, (b) contaminant history, (c) aquifer materials, (d) well construction, and (e) geochemical reactions along flow paths.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Ground Water Age Predictor

Machine Learning script to predict groundwater ages based on auxiliary features in a publicly available dataset, based on publicly available software libraries. Code applied to data from the Groundwater Ambient Monitoring and Assessment (GAMA) program in California, including well location and construction information, chemical constituents and isotopic tracers, and land use metrics.

Chakraborty, Indrasis↗
DOE OSTI2024

Inferring the Focal Depths of Small Earthquakes in Southern California Using Physics-Based Waveform Features

Determining the depths of small crustal earthquakes is challenging in many regions of the world, because most seismic networks are too sparse to resolve trade-offs between depth and origin time with conventional arrival-time methods. Precise and accurate depth estimation is important, because it can help seismologists discriminate between earthquakes and explosions, which is relevant to monitoring nuclear test ban treaties and producing earthquake catalogs that are uncontaminated by mining blasts. Here, we examine the depth sensitivity of several physics-based waveform features for ~8000 earthquakes in southern California that have well-resolved depths from arrival-time inversion. We focus on small earthquakes (2 < M L < 4) recorded at local distances (<150 km), for which depth estimation is especially challenging. We find that differential magnitudes (M w /M L –M c ) are positively correlated with focal depth, implying that coda wave excitation decreases with focal depth. We analyze a simple proxy for relative frequency content, Φ≡log 10 (M 0 )+3log 10 (f c ), and find that source spectra are preferentially enriched in high frequencies, or “blue-shifted,” as focal depth increases. Here, we also find that two spectral amplitude ratios Rg 0.5–2 Hz/Sg 0.5–8 Hz and Pg/Sg at 3–8 Hz decrease as focal depth increases. Using multilinear regression with these features as predictor variables, we develop models that can explain 11%–59% of the variance in depths within 10 subregions and 25% of the depth variance across southern California as a whole. We suggest that incorporating these features into a machine learning workflow could help resolve focal depths in regions that are poorly instrumented and lack large databases of well-located events. Some of the waveform features we evaluate in this study have previously been used as source discriminants, and our results imply that their effectiveness in discrimination is partially because explosions generally occur at shallower depths than earthquakes.

58 GEOSCIENCES↗
DOE OSTI2026

Limited Dynamic Earthquake Triggering in Nevada

Dynamic triggering occurs when seismic waves from distant large earthquakes temporarily alter stress conditions along faults, potentially triggering new earthquakes hundreds to thousands of kilometers away from the source. Previous studies have linked triggered seismicity to anthropogenic activities such as geothermal, oil, and gas production. Although these activities are present in Nevada, little work has been conducted to explore dynamically triggered seismicity in Nevada. Here, we analyze a newly published, high-resolution earthquake catalog for Nevada to identify local seismicity dynamically triggered by teleseismic events (Mw≥7) from 2008 to 2023. We identify 94 dynamically triggered earthquakes concentrated in four distinct regions, which qualitatively show a modest positive correlation with geothermal well locations. Triggered seismicity in Nevada is predominantly delayed, with some instantaneously triggered by Rayleigh waves. The prevalence of delayed triggering indicates that pore fluid interactions may play a critical role in controlling dynamic triggering susceptibility in Nevada. Our results demonstrate that dynamic triggering can provide valuable insight to help identify critically stressed regions.

58 GEOSCIENCES↗
DOE OSTI2024

Rittenhouse et al. 1960s Historical Archived Produced Water Dataset

Around 1960, a private company entered into a research agreement to analyze for dissolved solids in water produced from >800 fields in the U.S. and Canada.. The elemental compositions provided were measured spectrochemically by Rittenhouse et al. The information has been made available to the public as a public service, but the names off of the companies and exact well locations have been removed. The samples are now located at the University of Texas in Austin. More details can be found in the following reference: Gordon Rittenhouse, Robert B. Fulton, Robert J. Grabowski, Joseph L. Bernard, Minor elements in oil-field waters, Chemical Geology, Volume 4, Issues 1–2, 1969, Pages 189-209, ISSN 0009-2541, https://doi.org/10.1016/0009-2541(69)90045-X.

Geochemists Workbench,INORGANIC GEOCHEMISTRY,NEWTS↗
DOE OSTI2020

Prestack Waveform Inversion at GC 955: Trials and sensitivity of PWI to high-resolution seismic data (Data Report)

Understanding the spatial extent and variability of hydrate deposits has important implications for potential economic production, climate change, and assessing natural hazards risks. Seismic reflection techniques are capable of determining the extent of gas hydrate deposits and can shed light on hydrate concentrations and properties. Using high resolution prestack time migrated seismic data collected during a 2013 US Geological Survey expedition and prestack waveform inversion (PWI) techniques, we produce highly resolved velocity models and compare them to co-located well logs. Coupling our PWI results with velocity-porosity relationships and nearby well control, we compare hydrate properties at site 955 in the Green Canyon and site 313 at Walker Ridge.

03 NATURAL GAS↗
DOE OSTI2020

Underground Test Area (UGTA) Sampling Plan for Corrective Action Units 101 and 102: Central and Western Pahute Mesa, Nevada National Security Site, Nevada

The purpose of this groundwater sampling plan (referred to herein as “the Plan”) is to describe the approach for collecting and analyzing groundwater samples to meet the objectives of the U.S. Department of Energy (DOE), Environmental Management (EM) Nevada Program’s Underground Test Area (UGTA) Activity. The Plan is focused on the Central and Western Pahute Mesa corrective action units (CAUs 101 and 102). The remaining UGTA CAUs are in the final stage of the UGTA strategy (Closure Report [CR] stage), and monitoring requirements for these CAUs are described in their respective CRs. The Plan supersedes the Nevada National Security Site Integrated Groundwater Sampling Plan and its ensuing Record of Technical Change (ROTC) (DOE/EMNV, 2019b). The Plan is designed to ensure compliance with the UGTA Quality Assurance Plan (QAP) and its ensuing ROTC (DOE/EMNV, 2018), and the Federal Facility Agreement and Consent Order (FFACO) (1996, as amended). The Plan is implemented by the Environmental Program Services (EPS) contractor. Implementation of the Plan provides data to complete corrective actions prescribed by the FFACO to protect the public from groundwater contaminated by historical underground nuclear testing. The Plan’s scope comprises sample collection and analysis requirements for assessing the extent of groundwater contamination from underground nuclear testing. Sampling wells located in the communities surrounding the Nevada National Security Site (NNSS) is performed by other organizations (e.g., management and operating [M&O] contractor) and is therefore not included within the Plan. The results of the community sampling are presented in the annual NNSS environmental reports.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Spindown of Pulsars Interacting with Companion Winds: The Impact of Magnetospheric Compression

Pulsars in binary systems with strong companion winds can have the magnetopause separating their magnetosphere from the wind located well within their light cylinder. This bow-like enclosure effectively creates a waveguide that confines the pulsar's electromagnetic fields and can significantly alter its spindown. In this paper, we study the spindown of compressed pulsar magnetospheres in such systems. We parameterize the confinement as the ratio between the equatorial position of the magnetopause (or standoff distance) R m and the pulsar's light cylinder R LC . Using particle-in-cell simulations, we quantify the pulsar spindown for a range of compressions, R m /R LC = 1/3–1, and inclination angles, χ = 0°...90°, between magnetic and rotation axes. Our strongly confined models (R m /R LC = 1/3) show two distinct limits. For χ = 0°, the spindown of a compressed pulsar magnetosphere is enhanced by approximately a factor of three compared to an isolated pulsar due to the increased number of open magnetic field lines. Conversely, for χ = 90°, the compressed pulsar spins down at less than 40% of the rate of an isolated reference pulsar due to the mismatch between the pulsar wind stripe wavelength and the waveguide size. We apply our analysis to the 2.77 s oblique rotator (χ = 60°) in the double-pulsar system PSR J0737-3039. With the numerically derived spindown estimate, we constrain its surface magnetic field to B* ≈ (7.3 ± 0.2) × 10 11 G. We discuss the time modulation of its period derivative, the effects of compression on its braking index, and implications for the radio eclipse in PSR J0737-3039.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1971

The lunar laser ranging experiment

With data from two or more well-located observing stations, the lunar range can be corrected accurately for the effects of polar motion and fluctuations in the earth's rotation rate. Very accurate corrections can be made for the earth tides at each station. It appears that the use of lasers giving roughly 0.1-msec pulse lengths is highly desirable. With them, single-shot ranging accuracies of about 3 cm are expected. The actual lunar range results will be analyzed by fitting a numerical integration for the lunar motion to the data. A mathematical model for lunar range is given. Tests of the theory of gravitation are considered.

Bender, P. L.↗
NASA NTRS1975

Investigation of remote sensing to detect near-surface groundwater on irrigated lands

The application of remote sensing techniques was studied for detecting areas with high water tables in irrigated agricultural lands. Aerial data were collected by the LANDSAT-1 satellite and aircraft over the Kansas/Bostwick Irrigation District in Republic and Jewell Counties, Kansas. LANDSAT-1 data for May 12 and August 10, 1973, and aircraft flights (midday and predawn) on August 10 and 11, 1973, and June 25 and 26, 1974, were obtained. Surface and water table contour maps and active observation well hydrographs were obtained from the Bureau of Reclamation for use in the analysis. Results of the study reveal that LANDSAT-1 data (May MSS band 6 and August MSS band 7) correlate significantly (0.01 level) with water table depth for 144 active observation wells located throughout the Kansas/Bostwick Irrigation District. However, a map of water table depths of less than 1.83 meters prepared from the LANDSAT-1 data did not compare favorably with a map of seeped lands of less than 1.22 m (4 feet) to the water table. Field evaluation of the map is necessary for a complete analysis. Analysis of three fields on a within or single-field basis for the 1973 LANDSAT-1 data also showed significant correlation results.

Ryland, D. W.↗
NASA NTRS1976

Characteristics procedure for supersonic flows including consideration of viscous contributions to flow rotationality

A characteristics procedure has been developed which includes viscous and conductive transport terms normal to streamlines. By introducing the transport terms as corrections, the equations retain their hyperbolic character. The solutions have been developed using an inverse grid scheme in a streamline-normal network. Inclusion of the transport terms enables tracing of shock waves through the supersonic portion of the boundary layer so that shock reflections are well-located. Excellent agreement is obtained with the results of other characteristics procedures and with the experimental pressure distributions for the waisted body of Winter, Smith and Rotta.

Anderson, B. H.↗
NASA NTRS1977

Wind-tunnel and flight evaluation of spoilers as trailing-vortex hazard alleviation devices

This paper presents the results of ground-based and flight investigations that have been performed at NASA for the purpose of development of spoilers as trailing-vortex hazard alleviation devices. Based on the results obtained in these investigations, it was found that the induced rolling moment on a trailing model can be reduced by spoilers located near the mid-semispan of a vortex-generating wing. Substantial reductions in induced rolling moment occur when the spoiler vortex attenuator is located well forward on both unswept and swept wing models. In addition, it was found by ground-based model tests and verified by full-scale flight tests that the existing flight spoilers on the B-747 aircraft are effective as trailing vortex attenuators. Based on the results of wind-tunnel investigations of the DC-10-30 and L-1011 aircraft models, the existing flight spoilers on both the DC-10-30 and L-1011 aircraft may also be effective trailing vortex attenuators.

Croom, D. R.↗
NASA NTRS1977

The development and use of spoilers as vortex attenuators

Results are presented of groundbased and flight investigations performed to develop spoilers as trailing vortex alleviation devices. Based on the results obtained in these investigations, it was found that the induced rolling moment on a trailing model can be reduced by spoilers located near the midsemispan of a vortex generating wing. Substantial reductions in induced rolling moment occur when the spoiler vortex attenuator is located well forward on both unswept and swept wing models. In addition, it was found that existing flight spoilers on the jumbo-jet transport aircraft can be effective as trailing vortex attenuators.

Croom, D. R.↗
NASA NTRS1977

Quaternary geologic map of Minnesota

The Quaternary Geologic Map of Minnesota is a compilation based both on the unique characteristics of satellite imagery and on the results of previous field investigations, both published and unpublished. The use of satellite imagery has made possible the timely and economical construction of this map. LANDSAT imagery interpretation proved more useful than expected. Most of the geologic units could be identified by extrapolating from specific sites where the geology had been investigated into areas where little was known. The excellent geographic registry coupled with the multi-spectral record of these images served to identify places where the geologic materials responded to their ecological environment and where the ecology responded to the geologic materials. Units were well located on the map at the scale selected for the study. Contacts between till units could be placed with reasonable accuracy. The reference points that were used to project delineations between units (rivers, lakes, hills, roads and other features), which had not been accurately located on early maps, could be accurately located with the help of the imagery. The tonal and color contrasts, the patterns reflecting geologic change and the resolution of the images permitted focusing attention on features which could be represented at the final scale of the map without distraction by other interesting but site-specific details.

Goebel, J. E.↗
NASA NTRS1975

The system anorthite-forsterite-fayalite-silica to 2 kbar with lunar petrologic applications

Near-liquidus phase relations in the magnesium-rich portion of the system anorthite-forsterite-fayalite-silica have been determined from synthesis experiments at 1 atm and 2 kbar at oxygen fugacities near the iron-wuestite buffer. The major-element chemistries of KREEP basalts are similar to peritectic liquids, L/ol,px,an/, produced experimentally. The reaction L/ol,px,an/ is well-located at low pressures. It intersects the join anorthite-enstatite-ferrosilite at Fe/(Fe+Mg) equals 0.45 (atomic ratio), and is peritectic only for Fe/(Fe+Mg) not greater than 0.45. Although positions of the equilibria, L/an,ol/ and L/ol,px/, differ significantly at 1 atm from their positions at 2 kbar, the position of the piercing point, L/ol,px,an/, on the anorthite-enstatite-ferrosilite join is not sensitive to pressure. The composition of liquids produced by partial melting of troctolites and pyroxenites in the lunar crustal environment will be affected by pressure, whereas liquids derived from gabbroic assemblages will not.

Merrill, R. B.↗
NASA NTRS1975

Energy, frequency, and distance of moonquakes at the Apollo 17 site

'Thermal' moonquakes have been detected at the Apollo 17 site. A typical event releases about 1 to 10 million ergs of energy. The annual seismic energy release for the events observed in the Taurus-Littrow Valley is estimated at 100 billion ergs. Such small events would not cause impossibly rapid erosion on either the North Massif or within the craters of the Central Cluster. Seismic events become increasingly frequent after sunrise and reach a maximum at sunset. The largest events, however, occur most commonly near lunar noon. Rise times of the seismic signals, after being calibrated by the well-located Lunar Seismic Profiling Experiment (LSPE) seismic sources, were used to estimate distances to the seismic events. Most seismic events (about 90%) appear to occur within 2.5 km of the seismometer array.

Cooper, M. R.↗
NASA NTRS1981

Optical studies of the regions of the gamma-ray bursts of 19 November, 1978 and 5 March, 1979

Optical studies were made of two well-located gamma-ray burst regions in the Southern Hemisphere using the 1.5 m telescope at the Cerro Tololo Inter-American Observatory in Chile. Multi-filter image tube plates and UBV photometry surveys were made of both regions. The field of the 19 November, 1978 gamma-ray burst shows no early star or star with unusual colors out to several diameters of the nominal error box. The region of the 5 March, 1979 gamma-ray burst, which includes N49, contains several blue giants in the LMC, two of which deserve further study.

Fishman, G. J.↗