Results for “vapor” — Page 4

DOE OSTI2020

Whose Gas is it anyway? Differentiating the Source of a Large Soil Vapor Plume beneath Two Adjacent Waste Sites - 20487

DOE contractor CH2M Hill Plateau Remediation Company is currently responsible for conducting groundwater contamination monitoring at several RCRA treatment, storage, and disposal units located on the Hanford Site in Richland, Washington State. The Nonradioactive Dangerous Waste Landfill treatment, storage, and disposal unit presents a distinct groundwater monitoring problem because of a large multi-contaminant soil vapor plume beneath it that is a likely source of low-level volatile organic compound groundwater contamination. Adjacent to Nonradioactive Dangerous Waste Landfill is the Solid Waste Landfill. Volatile organic compounds are inventory components of both the Nonradioactive Dangerous Waste Landfill and the Solid Waste Landfill. Therefore, it is possible that both sites could be contributing to the soil vapor plume. For regulatory purposes, it is important to differentiate which site is the primary contributor of volatile organic compounds to the plume. An approach was developed to identify the primary volatile organic compound source of the soil vapor plume beneath Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill. The site conceptual model hypothesis of vapor-phase volatile organic compound transport to the dissolved phase in groundwater was tested by a simple mathematical model of vapor/liquid equilibrium concentrations at the groundwater/air interface. Once it was shown that vapor-phase volatile organic compound transport to groundwater was a valid conceptual model for Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill, spatial and statistical methods were used to determine the primary site contributing to the majority of volatile organic compounds to the soil vapor plume. Average groundwater chloroform, tetrachloroethene, and trichloroethene concentrations from Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill monitoring network wells were plotted on maps of the facilities and immediate vicinities and compared to soil vapor sampling probe locations. Principal component analysis and mixing ratios were used to identify source contributions of each treatment, storage, and disposal unit to the plume. Results of the vapor/liquid equilibrium concentrations mathematical model showed that transport phenomena outweigh steady-state equilibria. Estimated vapor/liquid equilibrium concentrations were considerably lower than soil vapor measurements. The results indicate that dynamic vadose zone and groundwater factors such as decreased vapor concentrations with depth, vapor dilution from dispersion in the vadose zone, and advective and diffusional volatile organic compound dilution in groundwater result in groundwater volatile organic compound concentrations much less than would be measured under steady-state equilibrium conditions. Site source contribution differentiation by principal component analysis and mixing ratios was inconclusive using actual soil gas data because of the similarity in concentration values in both datasets for Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill. Similar data populations suggest mixing of the vapor contributions from both sites by dispersion through the soil matrix pore spaces. However, when groundwater volatile organic compound data were compared between the Nonradioactive Dangerous Waste Landfill and Solid Waste Landfill monitoring networks, Solid Waste Landfill mean concentrations were higher, suggesting more vapor-phase volatile organic compound transport to groundwater at those locations. Simulated volatile organic compound soil vapor and groundwater datasets created to test the methods developed for this study show that the method can be successful in source differentiation when significantly different datasets are compared. This paper will describe a method of testing a conceptual model for vapor-phase contaminant transport to groundwater and for differentiating site sources of contaminants comprising a mixed-constituent soil vapor plume. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2022

Next Generation Solvent Vapor Pressure Testing

Previous work by Savannah River National Laboratory (SRNL) indicated that the actual Next Generation Solvent vapor pressure would be higher than the Original Caustic Side Solvent Extraction (CSSX) solvent vapor pressure, but below a bounding vapor pressure using Raoult’s Law. Since solvent vapor pressure has a significant impact on Composite Lower Flammability Limits (CLFL) and attendant accident analyses, obtaining an additional margin from the bounding NGS vapor pressure would be valuable. In order to quantify how much margin might be gained from the NGS bounding solvent, SRNL researchers were requested to perform vapor pressure testing with the Next Generation Solvent (NGS) by Savannah River Mission Completion (SRMC). The vapor pressure curve for the NGS formulation set to be deployed at the Salt Waste Processing Facility (SWPF) has been determined by SRNL up to 55°C (131°F) using headspace Gas Chromatography (GC). It was expected that NGS would have a higher vapor pressure than the Original CSSX solvent; however, experimental results indicate a lower vapor pressure. At this time, it is uncertain if this difference is due to the 7x increase in concentration of the large calixarene in the solvent (0.007M BOBCalix in Original CSSX solvent vs. 0.05M MaxCalix in NGS) or to minor batch-to-batch variations in Isopar-L constituents. The NGS and the Original CSSX solvent vapor pressure data were fitted to the Antoine Equation. The Antoine equation gives a more accurate representation of the expected vapor pressure of the solvents outside of the temperature range tested. The Antoine equation fitting for NGS is given below: $P=10^{6.364⁻\frac{1788.4}{T+219.3}}$. Where, p is the vapor pressure (partial pressure) of NGS in mmHg and T is the temperature in °C. It is recommended that SRMC either continue using the more conservative Isopar-L vapor pressure calculations at SWPF with the equation developed for the Original CSSX solvent, or the equation presented above for the NGS solvent. Additionally, it is recommended to study the variability in Isopar-L vapor pressure between lots.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

NASA NTRS1997

A High Temperature Vapor Phase Lubrication Study Utilizing a Thioether Liquid Lubricant

Much of the experimental work on vapor phase lubrication has employed certain organo phosphorous compounds as the vapor phase lubricant. Graham and Klaus, for instance, used tricresyl phosphate (TCP) and tributyl phosphate to vapor phase lubricate a four-ball wear tester using M50 steel balls at 370 C. Makki and Graham were able to vapor phase lubricate a reciprocating pin on plate tribometer using 1018 steel at 280 C with TCP vapor. Although a few organo phosphorous compounds, such as TCP, have been successfully used as vapor phase lubricants in many laboratory experiments, many problems remain unsolved. Two areas of concern relate to the 'durability' of phosphate deposited films and to the ability of the lubricating system to "self-recover" when vapor phase lubricated with an organo phosphorous compound. Durability refers to the ability of the deposited film to provide effective lubrication, for a period of time, after the vapor flow to the lubricating surfaces has been interrupted. Vapor phase lubrication tests, conducted at Cleveland State University with their high temperature tribometer, revealed that when TCP vapor flow to the lubricating surfaces was interrupted the frictional coefficient of the system rapidly increased from a value less than 0.1 to a value of 0.3 which was selected as our failure point. Self-recovery means the ability of the vapor phase lubricant to reduce the frictional coefficient of the lubricating system back down to value less than 0.1 after startup of the interrupted vapor flow. Lubrication tests conducted at Cleveland State University revealed that the high temperature tribometer could not self-recover after startup of the interrupted TCP vapor flow.

Morales, Wilfredo↗

NASA NTRS1980

Method and apparatus for vapor detection

The method disclosed herein may be practiced by passing the vapors to be sampled along a path with halogen vapor, preferably chlorine vapor, heating the mixed vapors to halogenate those of the sampled vapors subject to halogenation, removing unreacted halogen vapor, and then sensing the vapors for organic halogenated compounds. The apparatus disclosed herein comprises means for flowing the vapors, both sample and halogen vapors, into a common path, means for heating the mixed vapors to effect the halogenation reaction, means for removing unreacted halogen vapor, and a sensing device for sensing halogenated compounds. By such a method and means, the vapors of low molecular weight hydrocarbons, ketones and alcohols, when present, such as methane, ethane, acetone, ethanol, and the like are converted, at least in part, to halogenated compounds, then the excess halogen removed or trapped, and the resultant vapors of the halogenated compounds sensed or detected. The system is highly sensitive. For example, acetone in a concentration of 30 parts per billion (volume) is readily detected.

Lerner, Melvin↗

DOE OSTI2021

Vaporization behavior of Ir 4 (CO) 12 and Re 2 (CO) 10 measured by torsion effusion gravimetric method

Metal carbonyls are of great importance in chemical vapor deposition (CVD), composite materials fabrication, and other near-net shape technologies. Carbonyl CVD is used for deposition of high-purity metallic and alloy coatings for which vapor pressure data is essential. In this study, we report vapor pressures of solid Ir 4 (CO) 12 and Re 2 (CO) 10 carbonyls measured by using the Knudsen Cell methodology using a torsion effusion thermogravimetric system. The vapor pressure of the Ir 4 (CO) 12 exhibited incongruent vaporization, as the molecular weight (MW) of the effusing species was determined as 128 g/mol as compared to the theoretical MW of 1105 g/mol. It is proposed that the Ir 4 (CO) 12 (s) partially decomposed (~66%) to Ir 4 (CO) 12 (g), Ir(s), and CO(g). The Re 2 (CO) 10 on the other hand, showed congruent behavior with Re 2 (CO) 10 (s) vaporizing to Re 2 (CO) 10 (g) in the measured temperature range. The raw data for vapor pressures was measured using two sets of Knudsen cells with different orifice sizes, and the equilibrium vapor pressures were calculated using Whitman-Motzfeldt methodology. The equilibrium vapor pressures of these carbonyls, partial pressures of gaseous species in case of decomposition, average molecular weights of the effusing gasses were determined. The vapor pressures and Gibbs energies of vaporization reactions of the two above mentioned carbonyls, as well as comparison of vaporization thermodynamics these two carbonyls with other carbonyls from Group VIB to VIIIB are presented in this work.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1998

Upper tropospheric water vapor: A field campaign of two Raman lidars, Airborne hygrometers, and Radiosondes

Water vapor in the atmosphere plays an important role in radiative transfer and the process of radiative balance so critical for understanding global change. It is the principal ingredient in cloud formation, one of the most difficult atmospheric processes to model, and the most variable component of the Earth-atmosphere albedo. And as a free molecule, it is the most active infrared absorber and emitter, thus, the most important greenhouse gas. The radiative impact of water vapor is important at all levels of the atmosphere. Even though moisture decreases by several orders-of-magnitude from the Earth's surface to the tropopause, recent research has shown that, from a radiative standpoint, a small percentage change in water vapor at any level is nearly equivalent. Therefore accurate and precise measurements of this important atmospheric constituent are needed at all levels to evaluate the full radiative impact. The need for improved measurements in the upper troposphere is particularly important because of the generally hostile (very dry and cold) conditions encountered. Because of the importance of water vapor to the understanding of radiative transfer, the Department of Energy's Atmospheric Radiation Measurements (ARM) program initiated a series of measurement campaigns at the Cloud And Radiation Testbed (CART) site in Oklahoma, especially focused on atmospheric water vapor. Three water vapor intensive observation period (water vapor IOP) campaigns were planned. Two of the water vapor IOP campaigns have been completed: the first IOP was held during the fall of 1996 with a focus on boundary layer water vapor measurements, and the second was conducted during the fall of 1997 with a focus on both boundary layer moisture e and moisture in the upper troposphere. This paper presents a review of the intercomparisons of water vapor measurements in the upper troposphere aquired during the second water vapor IOP. Data to be presented include water vapor measurements ements from: two Raman Lidars, the NASA Goddard Scanning Raman Lidar (SRL) and the CART Raman Lidar (CARL), a number of Vaisala radiosondes launched during the IOP campaign, and a dew point hygrometer flown on the University of North Dakota Cessna Citation Aircraft.

Melfi, S. Harvey↗

NASA NTRS1993

Possible near-IR channels for remote sensing precipitable water vapor from geostationary satellite platforms

Remote sensing of troposheric water vapor profiles from current geostationary weather satellites is made using a few broadband infrared (IR) channels in the 6-13 micron region. Uncertainties greater than 20% exist in derived water vapor values just above the surface from the IR emission measurements. In this paper, we propose three near-IR channels, one within the 0.94-micron water vapor band absorption region, and the other two in nearby atmospheric windows, for remote sensing of precipitable water vapor over land areas, excluding lakes and rivers, during daytime from future geostationary satellite platforms. The physical principles are as follows. The reflectance of most surface targets varies approximately linearly with wavelength near 1 micron. The solar radiation on the sun-surface-sensor ray path is attenuated by atmospheric water vapor. The ratio of the radiance from the absorption channel with the radiances from the two window channels removes the surface reflectance effects and yields approximately the mean atmospheric water vapor transmittance of the absorption channel. The integrated water vapor amount from ground to space can be obtained with a precision of better than 5% from the mean transmittance. Because surface reflectances vary slowly with time, temporal variation of precipitable water vapor can be determined reliably. High spatial resolution, precipitable water vapor images are derived from spectral data collected by the Airborne Visable-Infrared Imaging Spectrometer, which measures solar radiation reflected by the surface in the 0.4-2.5 micron region in 10-nm channels and has a ground instantaneous field of view of 20 m from its platform on an ER-2 aircraft at 20 km. The proposed near-IR reflectance technique would complement the IR emission techniques for remote sensing of water vapor profiles from geostationary satellite platforms, especially in the boundary layer where most of the water vapor is located.

Gao, B.-C.↗

NASA NTRS1995

Imaging spectrometer measurement of water vapor in the 400 to 2500 nm spectral region

The Airborne Visible-Infrared Imaging Spectrometer (AVIRIS) measures the total upwelling spectral radiance from 400 to 2500 nm sampled at 10 nm intervals. The instrument acquires spectral data at an altitude of 20 km above sea level, as images of 11 by up to 100 km at 17x17 meter spatial sampling. We have developed a nonlinear spectral fitting algorithm coupled with a radiative transfer code to derive the total path water vapor from the spectrum, measured for each spatial element in an AVIRIS image. The algorithm compensates for variation in the surface spectral reflectance and atmospheric aerosols. It uses water vapor absorption bands centered at 940 nm, 1040 nm, and 1380 nm. We analyze data sets with water vapor abundances ranging from 1 to 40 perceptible millimeters. In one data set, the total path water vapor varies from 7 to 21 mm over a distance of less than 10 km. We have analyzed a time series of five images acquired at 12 minute intervals; these show spatially heterogeneous changes of advocated water vapor of 25 percent over 1 hour. The algorithm determines water vapor for images with a range of ground covers, including bare rock and soil, sparse to dense vegetation, snow and ice, open water, and clouds. The precision of the water vapor determination approaches one percent. However, the precision is sensitive to the absolute abundance and the absorption strength of the atmospheric water vapor band analyzed. We have evaluated the accuracy of the algorithm by comparing several surface-based determinations of water vapor at the time of the AVIRIS data acquisition. The agreement between the AVIRIS measured water vapor and the in situ surface radiometer and surface interferometer measured water vapor is 5 to 10 percent.

Green, Robert O.↗

NASA NTRS1998

A Satellite-Derived Upper-Tropospheric Water Vapor Transport Index for Climate Studies

A new approach is presented to quantify upper-level moisture transport from geostationary satellite data. Daily time sequences of GOES-7 water vapor imagery were used to produce estimates of winds and water vapor mixing ratio in the upper-troposphere sensed by the 6.7-microns water vapor channel. The winds and mixing ratio values were gridded and then combined to produce a parameter called the Water Vapor Transport Index (WVTI) which represents the magnitude of the two dimensional transport of water vapor in the upper troposphere. Daily grids of WVTI, meridional moisture transport, mixing ratio, pressure and other associated parameters were averaged to produce monthly fields for June, July and August of 1987 and 1988 over the Americas and surrounding oceanic regions. The WVTI was used to compare upper-tropospheric moisture transport between the summers of 1987 and 1988, contrasting the latter part of the 1986/87 El Nino event and the La Nina period of 1988. A similar product derived from the NCEP reanalysis was used to help validate the index and understand interannual variability of moisture transport from the modeling perspective. Both datasets showed large upper-level water vapor transport associated with synoptic features over the Americas and with outflow from tropical convective systems. Minimal transport occurred over tropical and subtropical high pressure regions where winds were light. Index values from NCEP were 2-3 times larger than that determined from the GOES satellite This difference resulted from an over estimate of the zonal winds and upper-tropospheric moisture in the reanalysis model. A comparison of the satellite-derived monthly values between the summers of 1987 and 1988 provided some insight into the impact of the ENSO event on upper-level moisture and its transport during the period. During July 1987, a large portion of the tropics in the eastern Pacific Ocean and Caribbean Sea was dominated by strong vapor transport in excess of 5 g/kg/ms with relatively small amounts in the other months. In contrast, JJA 1988 showed an opposite trend with July 1988 being less dominated by tropical water vapor transport. The meridional transport of upper-level water vapor indicated significant poleward transport from the tropics to the higher latitudes. This transport favored the Southern Hemisphere with large transport occurring south of the ITCZ which extended across the eastern Pacific and northern South America. Zonally-averaged monthly transport values were shown to provide a simple way to quantify the monthly and interannual changes in water vapor transport. Zonally-averaged WVTI values peaked in the Southern Hemisphere subtropics during both Austral winters. In the tropics a single more pronounced peak located over the equator and south latitudes occurred in 1988 as opposed to a dual peak in 1987. The second peak around 20 deg.N latitude is consistent with findings of others where upper-tropospheric winds were noted to be stronger in this region during warm ENSO events. Zonally-averaged meridional transport was southward for all summer months and stronger in 1988. The asymmetric nature of the zonally-averaged meridional transport (more southerly water vapor transport) was enhanced during JJA 1998 thus indicating a stronger upper-level branch of the Hadley circulation during this notable strong La Nina period.

Jedlovec, Gary J.↗

NASA NTRS1998

A Satellite-Derived Upper-Tropospheric Water Vapor Transport Index for Climate Studies

A new approach is presented to quantify upper-level moisture transport from geostationary satellite data. Daily time sequences of Geostationary Operational Environmental Satellite GOES-7 water vapor imagery were used to produce estimates of winds and water vapor mixing ratio in the cloud-free region of the upper troposphere sensed by the 6.7- microns water vapor channel. The winds and mixing ratio values were gridded and then combined to produce a parameter called the water vapor transport index (WVTI), which represents the magnitude of the two-dimensional transport of water vapor in the upper troposphere. Daily grids of WVTI, meridional moisture transport, mixing ratio, pressure, and other associated parameters were averaged to produce monthly fields for June, July, and August (JJA) of 1987 and 1988 over the Americas and surrounding oceanic regions, The WVTI was used to compare upper-tropospheric moisture transport between the summers of 1987 and 1988, contrasting the latter part of the 1986/87 El Nino event and the La Nina period of 1988. A similar product derived from the National Centers for Environmental Prediction (NCEP)-National Center for Atmospheric Research (NCAR) 40-Year Reanalysis Project was used to help to validate the index. Although the goal of this research was to describe the formulation and utility of the WVTI, considerable insight was obtained into the interannual variability of upper-level water vapor transport. Both datasets showed large upper-level water vapor transport associated with synoptic features over the Americas and with outflow from tropical convective systems. Minimal transport occurred over tropical and subtropical high pressure regions where winds were light. Index values from NCEP-NCAR were 2-3 times larger than that determined from GOES. This difference resulted from large zonal wind differences and an apparent overestimate of upper-tropospheric moisture in the reanalysis model. A comparison of the satellite-derived monthly values between the summers of 1987 and 1988 provided some insight into the impact of the ENSO event on upper-level moisture and its transport during the period. During July 1987, a large portion of the Tropics in the eastern Pacific Ocean and Caribbean Sea was dominated by strong vapor transport in excess of 4.0 g/kg m/s, with relatively small amounts in the other months. JJA 1988 transport values reached similar magnitude and showed similar patterns for all three months. The meridional transport of upper-level water vapor indicated large poleward transport from the Tropics to the higher latitudes. This transport favored the Southern Hemisphere, with large transport occurring south of the ITCZ, which extended across the eastern Pacific and northern South America. Zonally averaged monthly transport values were shown to provide a simple way to quantify the monthly and interannual changes in water vapor transport. Zonally averaged WVTI values peaked in the Southern Hemisphere subtropics during both austral winters. In the Tropics, a single, more- pronounced peak located over the equator and south latitudes occurred in 1988 as opposed to a dual peak in 1987. The second peak around 20'N latitude is consistent with findings of others in which upper-tropospheric winds were noted to be stronger in this region during warm ENSO events. Zonally averaged meridional transport was southward for all summer months and was stronger in 1988. The asymmetric nature of the zonally averaged meridional transport (more southerly water vapor transport) was enhanced during JJA 1988, thus indicating a stronger upper- level branch of the Hadley circulation during this notably strong La Nina period.

Jedlovec, Gray J.↗

NASA NTRS2007

Electrification in Hurricanes over the Tropical Americas: Implication for Stratospheric Water Vapor

This study explores the relation between lightning activity and water vapor in the Tropical Tropopause Layer (TTL) over hurricane systems in the Tropical Americas. The hypothesis herein is that hurricanes that exhibit enhanced lightning activity are associated with stronger updrafts that can transport more moisture directly into the TTL (and subsequently into the tropical stratosphere) or even directly into the tropical stratosphere over this region. The TTL over the Tropical Americas, which includes the Caribbean and Gulf of Mexico, is of particular interest, because summertime cold point tropopause is the lowest in height and thus the warmest in temperature over the tropics. The latter condition implies higher saturation values and thus potential for more water vapor to enter the stratosphere. Climate forecast is very sensitive to stratospheric water vapor abundance, because of the key role that water vapor plays in regulating the chemical and radiative properties of the stratosphere. Given the potential for increases in hurricane intensity and frequency under predicted warmer conditions, it becomes essential to understand the effect of hurricanes on stratospheric water vapor. In this study, we use a combination of ground and space-borne observations as well as trajectory calculations. The observations include: cloud-to-ground (CG) lightning data from the U.S. National Lightning Detection Network (NLDN), geostationary infrared observations from the National Climatic Data Center Hurricane Satellite (HURSAT) data set, cloud properties from Aqua-MODIS, and water vapor from Aura-MLS. We analyze hurricanes from the 2005 season when Aura-MLS data are available, namely: Dennis, Emily, Katrina, Rita, and Wilma. Our analysis consists of examining CG lightning, cloud-top properties, and TTL water vapor (i.e., 100 and 147 mb) over the hurricane while it remains over water in the Tropical Americas region. We investigate daily as well as diurnal statistical properties. The hurricanes analyzed in this study showed that lightning activity is negatively correlated with minimum infrared brightness temperature and positively correlated with 100-mb water vapor. An examination of the maxima in water vapor observed over the hurricane not only shows larger magnitudes, but also larger differences between water vapor averages and water vapor maxima over the hurricane as lightning activity increases. Trajectory calculations are performed using the Flextra model in order to investigate the fate of the moister air masses found in the TTL.

Pittman, Jasna V.↗

NASA NTRS2003

The Use of Sage Water Vapor Data for Investigating Climate Change Issues

SAGE water vapor data has proven valuable for addressing several of the important issues in climate change research. It has been used to investigate how the upper troposphere water vapor responds to warming and convection, a key question in understanding the water vapor feedback to anthropogenic global warming. In the case of summer versus winter differences, SAGE results showed that the upper tropospheric relative humidity remained approximately constant; this result was in general agreement with how a GCM handled the seasonal difference, and gave credence to the argument that the GCM was not overestimating the water vapor feedback associated with convection. In addition, the convection-water vapor relationship was investigated further using SAGE water vapor and ISCCP cloud data. The results showed that upper tropospheric drying did appear to occur simultaneously with deep convective events in the tropics, only to be replaced by moistening a few hours later, associated (most likely) with the reevaporation of moisture from anvil clouds. The total effect was, again, a moistening of the upper troposphere associated with convection. Calculation of the actual trends in upper tropospheric moisture is a potential goal for SAGE data usage; trends calculated with radiosonde data, or instruments calibrated with radiosonde data have the problem of the effect of changing radiosonde instruments. SAGE data have in effect been used to compare different radiosondes through comparisons, and could continue to do so. SAGE 3 should also help clarify the absolute accuracy of SAGE retrievals in the troposphere. and its consequences. Model results show that water vapor increases can help explain the observations of stratospheric cooling, along with increasing C02 and ozone reduction. SAGE has been shown to provide trends similar to those of some other satellite and in situ retrievals, with increasing water vapor over time. However, SAGE is impacted by aerosol contamination which must be removed from the data; approaches used in the past will be reviewed. The SAGE water vapor errors, if taken literally, would make it hard to justify using SAGE data for such trends, and the error bars must be investigated. Stratospheric water vapor increases, like tropospheric increases, would lead to noticeable warming at the surface, and their changes must be quantified.

Rind, D.↗

NASA NTRSDate not supplied

GEOS Constituent Data Assimilation beyond Aura MLS: Assimilating NASA SAGE III/ISS profiles of stratospheric water vapor

Water vapor in the lower stratosphere is an important trace gas for atmospheric chemistry and radiative budget with direct impact on climate. During the last quarter of the 20th century, the Stratospheric Aerosol and Gas Experiment (SAGE) missions were crucial in monitoring the stratospheric ozone loss and the subsequent recovery as well as trends in water vapor linked to surface temperature trends. The SAGE III instrument aboard the International Space Station (ISS) continues the SAGE mission record, with high vertical resolution profiles of water vapor (and other constituents) since mid-2017. The NASA GEOS Earth system model has the capability to assimilate multi-constituents from ground and space-based instruments using the GEOS Constituent Data Assimilation System (CoDAS). Reanalysis products of stratospheric water vapor without data constraints are historically poor, and two recent reanalyses which assimilated stratospheric constituents observed by the Microwave Limb Sounder (MLS) improve the representation of stratospheric composition, including water vapor, when compared against independent observations. The MLS instrument is on NASA's Aura satellite which is expected to be decommissioned in the coming years. Here we demonstrate that while the number of solar occultation observations a day from SAGE III/ISS is about 1 % of the total number of profiles observed globally by MLS, the chemical timescales of water vapor in the lower stratosphere are long enough that the SAGE III/ISS data can provide a useful constraint on the assimilated product. Analyzed water vapor fields from assimilating only SAGE III/ISS water vapor profiles agree well with independent stratospheric observations, including when compared against the frost-point hygrometers at the three NOAA stations. Over the five-year period from 2017 through 2022, the analyzed water vapor using SAGE III/ISS captures many of the features seen with the assimilation of MLS observations. Note, this ability is reduced over regions where the SAGE III/ISS instrument provides infrequent or no observations (associated with the orbit of the ISS), as highlighted in the case study period following the eruption of the tropical underwater volcano Hunga Tonga in early 2022. Nevertheless, there is a clear benefit to the assimilation of stratospheric water vapor from SAGE III/ISS observations, allowing us to continue to monitor stratospheric composition for climate assessments following the impending loss of Aura.

K. Emma Knowland↗

NASA NTRSDate not supplied

GEOS Constituent Data Assimilation Beyond Aura MLS: Assimilating NASA SAGE III/ISS Profiles of Stratospheric Water Vapor

Water vapor in the lower stratosphere is an important trace gas for atmospheric chemistry and radiative budget with direct impact on climate. During the last quarter of the 20th century, the Stratospheric Aerosol and Gas Experiment (SAGE) missions were crucial in monitoring the stratospheric ozone loss and the subsequent recovery as well as trends in water vapor linked to surface temperature trends. The SAGE III instrument aboard the International Space Station (ISS) continues the SAGE mission record, with high vertical resolution profiles of water vapor (and other constituents) since mid-2017. The NASA GEOS Earth system model has the capability to assimilate multi-constituents from ground and space-based instruments using the GEOS Constituent Data Assimilation System (CoDAS). Reanalysis products of stratospheric water vapor without data constraints are historically poor, and two recent reanalyses which assimilated stratospheric constituents observed by the Microwave Limb Sounder (MLS) improve the representation of stratospheric composition, including water vapor, when compared against independent observations. The MLS instrument is on NASA's Aura satellite which is expected to be decommissioned in the coming years. Here we demonstrate that while the number of solar occultation observations a day from SAGE III/ISS is about 1 % of the total number of profiles observed globally by MLS, the chemical timescales of water vapor in the lower stratosphere are long enough that the SAGE III/ISS data can provide a useful constraint on the assimilated product. Analyzed water vapor fields from assimilating only SAGE III/ISS water vapor profiles agree well with independent stratospheric observations, including when compared against the frost-point hygrometers at the three NOAA stations. Over the five-year period from 2017 through 2022, the analyzed water vapor using SAGE III/ISS captures many of the features seen with the assimilation of MLS observations. Note, this ability is reduced over regions where the SAGE III/ISS instrument provides infrequent or no observations (associated with the orbit of the ISS), as highlighted in the case study period following the eruption of the tropical underwater volcano Hunga Tonga in early 2022. Nevertheless, there is a clear benefit to the assimilation of stratospheric water vapor from SAGE III/ISS observations, allowing us to continue to monitor stratospheric composition for climate assessments following the impending loss of Aura.

K. Emma Knowland↗

NASA NTRSDate not supplied

GEOS Constituent Data Assimilation Beyond Aura MLS: Assimilating NASA SAGE III/ISS Profiles of Stratospheric Water Vapor

Water vapor in the lower stratosphere is an important trace gas for atmospheric chemistry and radiative budget with direct impact on climate. During the last quarter of the 20th century, the Stratospheric Aerosol and Gas Experiment (SAGE) missions were crucial in monitoring the stratospheric ozone loss and the subsequent recovery as well as trends in water vapor linked to surface temperature trends. The SAGE III instrument aboard the International Space Station (ISS) continues the SAGE mission record, with high vertical resolution profiles of water vapor (and other constituents) since mid-2017. The NASA GEOS Earth system model has the capability to assimilate multi-constituents from ground and space-based instruments using the GEOS Constituent Data Assimilation System (CoDAS). Reanalysis products of stratospheric water vapor without data constraints are historically poor, and two recent reanalyses which assimilated stratospheric constituents observed by the Microwave Limb Sounder (MLS) improve the representation of stratospheric composition, including water vapor, when compared against independent observations. The MLS instrument is on NASA's Aura satellite which is expected to be decommissioned in the coming years. Here we demonstrate that while the number of solar occultation observations a day from SAGE III/ISS is about 1 % of the total number of profiles observed globally by MLS, the chemical timescales of water vapor in the lower stratosphere are long enough that the SAGE III/ISS data can provide a useful constraint on the assimilated product. Analyzed water vapor fields from assimilating only SAGE III/ISS water vapor profiles agree well with independent stratospheric observations, including when compared against the frost-point hygrometers at the three NOAA stations. Over the five-year period from 2017 through 2022, the analyzed water vapor using SAGE III/ISS captures many of the features seen with the assimilation of MLS observations. Note, this ability is reduced over regions where the SAGE III/ISS instrument provides infrequent or no observations (associated with the orbit of the ISS), as highlighted in the case study period following the eruption of the tropical underwater volcano Hunga Tonga in early 2022. Nevertheless, there is a clear benefit to the assimilation of stratospheric water vapor from SAGE III/ISS observations, allowing us to continue to monitor stratospheric composition for climate assessments following the impending loss of Aura.

K. Emma Knowland↗

DOE OSTI2021

Suggestions on the Vapor Pressure Determination of Molten Salts

The knowledge of the thermophysical properties of coolant and fuel in molten salts nuclear reactors (MSRs), such as thermal stability and vapor pressure, are of remarkable interest, particularly for simulating safe reactor operations. Molten salt reactorsMSRs use molten salt mixtures as the primary coolant and/or fuel and are expected to operate up to 800 °C. With the revival of interest in deploying MSRs, complete thermophysical and thermochemical characterization of these materials is of interest to industry, regulators, and researchers. Vapor pressure data for molten salts are scarce in the literature, both for pure salts but especially for eutectic mixtures. This report describes the effusion method, which consist of measuring the rate of escape of vapor molecules through a small orifice for the determination of the vapor pressure of compounds and may be useful on compounds such as molten salts. Thermogravimetric analysis records the mass loss as a function of time and temperature. There are two equations that can be used to relate the mass loss rate with the vapor pressure: (1) the Knudsen equation and (2) the Langmuir equation. To apply these equations, the system needs to reach a pseudo (or near) equilibrium condition. Therefore, the experimental conditions must be such that allow the condensed and the vapor/gas phases to be in equilibrium. In order to accomplish equilibrium like conditions, the sample must be in an almost-sealed cell except for a small orifice, from where the vapor escapes. In the Knudsen method vacuum is applied to eliminate the effect that the presence of other gas molecules could have on the evaporation rate of the sample. However, Langmuir alleged that in certain conditions, such as at low temperatures and/or when the vapor pressure is low, the rate of evaporation of a substance is independent of the presence of vapor around it. For that reason, some researchers, when measuring the mass loss of a substance with a predictable low vapor pressure, do not apply vacuum when using the Langmuir equation. However, they use a standard substance to parameterize the experimental setup. The use of one equation or the other will depend on the characteristics of the sample and the availability of an appropriate standard. Some important aspects related to the nature of the samples and vapor pressure measurements are described for future consideration.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2023

Standoff trace explosives vapor detection at meter distances

Vapor detection is a noncontact sampling method, which is a less invasive means of explosives screening than physical swiping. Explosive vapor detection is a challenge due to the low levels of vapors available for detection. This study demonstrates that the parts-per-quadrillion sensitivity of atmospheric flow tube-mass spectrometry (AFT-MS) combined with a high-volume air sampler enables standoff detection of trace explosives vapor at distances of centimeters to meters. Standoff detection of explosives vapor was possible both upstream and downstream of the vapor source relative to room air currents. RDX vapor from a saturated source was detected at up to 2.5 m. Vapors from RDX residue and nitroglycerin residue were detected at distances up to 0.5 m. The sampling can be optimized by accounting for air movement in the room or environment, which could further extend standoff detection distances. In conclusion, using AFT-MS with a high-volume sampler could also be effective for standoff vapor detection of drugs and additional chemical threats and could be useful for security screening applications such as at mail facilities, border crossings, and security checkpoints.

47 OTHER INSTRUMENTATION↗

NASA NTRS2014

Mars' Water Vapor Mapping by the SPICAM IR Spectrometer: Five Martian Years of Observations

The SPICAM IR instrument on the Mars Express mission continuously observes the water vapor in the martian atmosphere starting from 2004 in the 1.38-micrometer spectral band. The water vapor column abundance is retrieved from nadir observations to characterize its spatial, seasonal and interannual variations. A reference set of SPICAM water vapor column abundances (zonally averaged) covering the time period from 2004 to 2013 (martian years 27-31) is available for a grid of 2 deg Ls 2 latitude, along with an average reference map of water vapor abundance combining all the martian years of Mars Express observations. Compared to the previous data retrieval by Fedorova et al. (Fedorova, A., Korablev, O., Bertaux, J.L., Rodin, A., Kiselev, A., Perrier, S. [2006]. J. Geophys. Res. 111, E09S08) the new processing algorithm includes many improvements concerning the calibration and assumed parameters. A major improvement is the account for aerosol scattering based on dust and water ice cloud optical depths measured by THEMIS/Mars Odyssey (Smith, M.D. [2009]. Icarus 202, 444-452). The account for multiple scattering by aerosol particles increases the retrieved water vapor amount by approximately 10% in polar areas during summer, and up to 60-70% for large solar zenith angles. The sensitivity of the results to aerosol properties, surface albedo, solar spectrum, and water vapor vertical distribution has also been studied. The retrieved water vapor reveals nominal annual cycle with maximum abundance of about 60-70 pr. lm for the Northern summer and approximately 20 pr. lm for the Southern summer. The annual average amount of water has been estimated to be of 10-20 pr. micrometers, in agreement with other measurements. From year to year the seasonal cycle of water vapor abundance is very stable. An observed decrease during the MY 28 global dust storm cannot be fully attributed to the masking effect of dust, and indicates a real decrease of water amount near or above the surface. No evidence of diurnal variation of column water vapor amount was found, even though the 1.38-micrometer measurements are sensitive to the few lowermost kilometers above the surface.

Mars water vapor↗