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Spin Rectification and Electrically Controlled Spin Transport in Molecular-Ferroelectrics-Based Spin Valves

We report a spin-rectification effect in a spin-valve structure consisting of ferroelectric croconic acid (C 5 H 2 O 5 ) sandwiched between ferromagnetic electrodes La 0.7 Sr 0.3 MnO 3 and Co, which can be switched between a high-resistance (off ) and a low-resistance (on) state by a poling voltage. In the off state, the magnetoresistance (MR) sign reverses with the measurement voltage with a 0.1-V offset, suggesting a spin-rectification behavior, while in the on state the MR remains negative. These observations can be understood in terms of electrically controlled interfacial energy-band alignment either from the electrostatic effect or from the interfacial redox process. In conclusion, the observed spin-rectification effect suggests thepossibility of diodelike devices for spin-polarized current.

36 MATERIALS SCIENCE↗

Current-driven transverse domain wall oscillations in perpendicular spin-valve structures

Spin-transfer-driven oscillations of a transverse domain wall confined to a perpendicular spin-valve structure are investigated using a one-dimensional model. The stack consists of a polarizer, nonmagnetic spacer, soft free layer, and pinned magnetic layer. It is found that the domain-wall oscillation frequency is a nonmonotonic, highly asymmetrical function of applied electric current, showing a strong dependence on the current direction and the relative strengths of the interfacial and bulk spin-transfer torques. Micromagnetic analysis reveals that the surprising and atypical oscillator response is due to an interplay between the interfacial spin-transfer torque, the bulk spin-transfer torque, the exchange torque, and the damping torque. The underlying physical and material responses are examined, including the important role of the domain-wall twist. The competitions between the involved torques under different operating conditions suggest that the oscillator could serve as a model system to investigate magnetic and spintronic phenomena at the nanoscale. Finally, the observed current-dependent twisting of the free-layer magnetization about the axis of precession may further be found interesting for investigations of the interaction between spin-polarized current and chiral spin structures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Familial Associations of Prevalence and Cause-Specific Mortality for Thoracic Aortic Disease and Bicuspid Aortic Valve in a Large-Population Database

Thoracic aortic disease and bicuspid aortic valve (BAV) likely have a heritable component, but large population-based studies are lacking. This study characterizes familial associations of thoracic aortic disease and BAV, as well as cardiovascular and aortic-specific mortality, among relatives of these individuals in a large-population database. In this observational case-control study of the Utah Population Database, we identified probands with a diagnosis of BAV, thoracic aortic aneurysm, or thoracic aortic dissection. Age- and sex-matched controls (10:1 ratio) were identified for each proband. First-degree relatives, second-degree relatives, and first cousins of probands and controls were identified through linked genealogical information. Cox proportional hazard models were used to quantify the familial associations for each diagnosis. We used a competing-risk model to determine the risk of cardiovascular-specific and aortic-specific mortality for relatives of probands. The study population included 3,812,588 unique individuals. Familial hazard risk of a concordant diagnosis was elevated in the following populations compared with controls: first-degree relatives of patients with BAV (hazard ratio [HR], 6.88 [95% CI, 5.62–8.43]); first-degree relatives of patients with thoracic aortic aneurysm (HR, 5.09 [95% CI, 3.80–6.82]); and first-degree relatives of patients with thoracic aortic dissection (HR, 4.15 [95% CI, 3.25–5.31]). In addition, the risk of aortic dissection was higher in first-degree relatives of patients with BAV (HR, 3.63 [95% CI, 2.68–4.91]) and in first-degree relatives of patients with thoracic aneurysm (HR, 3.89 [95% CI, 2.93–5.18]) compared with controls. Dissection risk was highest in first-degree relatives of patients who carried a diagnosis of both BAV and aneurysm (HR, 6.13 [95% CI, 2.82–13.33]). First-degree relatives of patients with BAV, thoracic aneurysm, or aortic dissection had a higher risk of aortic-specific mortality (HR, 2.83 [95% CI, 2.44–3.29]) compared with controls. Our results indicate that BAV and thoracic aortic disease carry a significant familial association for concordant disease and aortic dissection. The pattern of familiality is consistent with a genetic cause of disease. Furthermore, we observed higher risk of aortic-specific mortality in relatives of individuals with these diagnoses. In conclusion, this study provides supportive evidence for screening in relatives of patients with BAV, thoracic aneurysm, or dissection.

60 APPLIED LIFE SCIENCES↗

Enhanced Component Performance Study: Air-Operated Valves 1998–2020

This report presents an enhanced performance evaluation of air-operated valves (AOVs) at U.S. commercial nuclear power plants. The data used in this study are based on the operating experience failure reports from calendar year 1998 through 2020 as reported in the Institute of Nuclear Power Operations (INPO) Industry Reporting and Information System (IRIS). The AOV failure modes considered are failure-to-open/close (FTOC), failure to operate or control (FTOP), and spurious operation (SO). The component reliability estimates and the reliability data are trended for the most recent 10-year period while yearly estimates for reliability are provided for the entire study period. The following trends were identified for the most recent 10-year period: o Extremely statistically significant increasing trend for the frequency of FTOC demands (demands per reactor year) for low-demand (= 20 demands per year) AOVs o Extremely statistically significant increasing trend for the frequency of FTOC demands for high-demand (> 20 demands per year) AOVs o Highly statistically significant decreasing trend for the failure rate of FTOP for low-demand AOVs o Highly statistically significant decreasing trend for the frequency of FTOP events (failures per reactor year) for low-demand AOVs o Statistically significant decreasing trend for the failure rate of SO for low-demand AOVs o Statistically significant decreasing trend for the frequency of SO events (failures per reactor year) for low-demand AOVs.

99 GENERAL AND MISCELLANEOUS↗

Enhanced Component Performance Study: Motor-Operated Valves 1998-2020

This report presents an enhanced performance evaluation of motor-operated valves (MOVs) at U.S. commercial nuclear power plants. The data used in this study are based on the operating experience failure reports from calendar year 1998 through 2020 as reported in the Institute of Nuclear Power Operations (INPO) Industry Reporting and Information System (IRIS). The MOV failure modes considered are fail to open or close (FTOC), fail to operate or control (FTOP), and spurious operation (SO). The component reliability estimates and the reliability data are trended for the most recent 10-year period while yearly estimates for reliability are provided for the entire study period. The following increasing trend was identified for MOVs for the most recent 10-year period: • Low-demand MOV frequency of FTOC demands (demands per reactor year). The following increasing trends were identified for MOVs for the most recent 10-year period: • Low-demand MOV FTOC failure probability • Low-demand MOV frequency of FTOC events (failures per reactor year).

99 GENERAL AND MISCELLANEOUS↗

Enhanced Component Performance Study: Motor Operated Valves 1998–2022

This report presents an enhanced performance evaluation of motor-operated valves (MOVs) at U.S. commercial nuclear power plants. The data used in this study are based on the operating experience failure reports from calendar year 1998 through 2022 as reported in the Institute of Nuclear Power Operations (INPO) Industry Reporting and Information System (IRIS). The MOV failure modes considered are fail to open or close (FTOC), fail to operate or control (FTOP), and spurious operation (SO). The component reliability estimates and the reliability data are trended for the most recent 10-year period while yearly estimates for reliability are provided for the entire study period. The following increasing trend was identified for MOVs for the most recent 10-year period: • Low-demand MOV frequency of FTOC demands (demands per reactor year). The following decreasing trends were identified for MOVs for the most recent 10-year period: • Low-demand MOV FTOC failure probability • Low-demand MOV frequency of FTOC events (failures per reactor year).

99 GENERAL AND MISCELLANEOUS↗

Enhanced Component Performance Study: Air Operated Valves 1998–2022

This report presents an enhanced performance evaluation of air operated valves (AOVs) at U.S. commercial nuclear power plants. The data used in this study are based on the operating experience failure reports from calendar year 1998 through 2022 as reported in the Institute of Nuclear Power Operations (INPO) Industry Reporting and Information System (IRIS). The AOV failure modes considered are fail to open or close (FTOC), fail to operate or control (FTOP), and spurious operation (SO). The component reliability estimates and the reliability data are trended for the most recent 10 year period while yearly estimates for reliability are provided for the entire study period. The following increasing trends were identified for AOVs for the most recent 10 year period: • Low demand AOV frequency of FTOC demands (demands per reactor year) • High demand AOV frequency of FTOC demands. The following decreasing trends were identified for AOVs for the most recent 10 year period: • Low demand AOV FTOC failure probability • Low demand AOV FTOP failure rate • Low demand AOV frequency of FTOC events (failures per reactor year) • Low demand AOV frequency of FTOP events.

99 GENERAL AND MISCELLANEOUS↗

Enhanced Component Performance Study: Motor-Operated Valves 1998-2024

This report presents an enhanced performance evaluation of motor-operated valves (MOVs) at U.S. commercial nuclear power plants. The data used in this study are based on the operating experience failure reports from calendar year 1998 through 2024 as reported in the Institute of Nuclear Power Operations (INPO) Industry Reporting and Information System (IRIS). The MOV failure modes considered are fail to open or close (FTOC), fail to operate or control (FTOP), and spurious operation (SO). The component reliability estimates and the reliability data are trended for the most recent 10-year period while yearly estimates for reliability are provided for the entire study period. The following increasing trend was identified for MOVs for the most recent 10-year period: • Low-demand MOV frequency of FTOC demands (demands per reactor year). The following decreasing trends were identified for MOVs for the most recent 10-year period: • Low-demand MOV FTOC failure probability • High-demand MOV SO failure rate • Low-demand MOV frequency of FTOC events (failures per reactor year) • High-demand MOV frequency of SO events (failures per reactor year).

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Valve Regulated Lead Acid Battery Evaluation under Peak Shaving and Frequency Regulation Duty Cycles

This work highlights the performance metrics and the fundamental degradation mechanisms of lead-acid battery technology and maps these mechanisms to generic duty cycles for peak shaving and frequency regulation grid services. Four valve regulated lead acid batteries have been tested for two peak shaving cycles at different discharge rates and two frequency regulation duty cycles at different SOC ranges. Reference performance and pulse resistance tests are done periodically to evaluate battery degradation over the time. The results of the studies are expected to provide a valuable understanding of lead acid battery technology suitability for grid energy-storage applications.

25 ENERGY STORAGE↗

Sizing and Selection of Pressure Relief Valves for High-Pressure Thermal–Hydraulic Systems

This study covers the critical concerns related to the sizing, selection, installation, maintenance, and testing of pressure safety valves (PSVs). The aim is to ensure the safety of pressurized systems, hydrostatic transmission systems, and hydraulic plants, including process plants, thermal power plants, and nuclear reactor systems. PSVs are devices that ensure the safety and reliability of pressurized vessels, lines, and systems during overpressure events. The task of selecting which PSV features are of greatest value for a specific purpose is complex—especially in the design of a high-pressure experimental thermal–hydraulic facility for hydrostatic and transient testing of the reactor system—when the systems are in the design and development phases and require qualification and demonstration to prove that they have reached a given level of technological readiness. The present study highlights the required steps for users to follow the associated rules, guidelines, and recommendations. As a part of this research, case studies are presented to help readers better understand the applicable strategy and standards. A discussion and a review of PSV performance degradation and failure are summarized to provide a better understanding of varied process applications and conditions, including fluid flow dynamics, boundary-layer formation and pressure drops, gas bubble formation and collapse, geometric configurations, inlet/outlet piping, abrupt pressure fluctuations, and acoustic resonance. Moreover, this study discusses the servicing and testing of PSVs in a multiphase pressurized system. Overall, it provides a basic overview of how PSVs ensure the safety of pressurized systems, supported by case studies and industrial practices.

02 PETROLEUM↗

Enhanced Laser Damage Threshold in Optically Addressable Light Valves via Aluminum Nitride Photoconductors

Abstract Optically addressable light valves (OALVs) are specialized optical components utilized for spatial beam shaping in various laser‐based applications, including optics damage mitigation, and enhanced functionality in diode‐based additive manufacturing requiring high intensities. Current state‐of‐the‐art OALVs employ photoconductors such as Bismuth Silicon Oxide (BSO) or Bismuth Germanium Oxide (BGO), which suffer from limited laser‐induced damage thresholds (LiDT) and inadequate thermal conductivities, thus restricting their use in high peak and average power applications. Aluminum nitride (AlN), an emerging ultra‐wide band gap (UWBG) III–V semiconductor, offers promising optoelectronic properties and superior thermal conductivity (>300 Wm −1 K −1 at 298° K, compared to BSO's 3.29 Wm −1 K −1 ). In this study, the first AlN‐based OALVs are designed, fabricated, and experimentally demonstrated using commercially available single‐crystal AlN substrates. These AlN‐based OALVs have shown clear superiority over BSO and BGO‐based devices. Design considerations for OALVs incorporating UWBG photoconductors are discussed, and the photoresponsivity from defect‐mediated sub‐bandgap absorption in AlN crystals is verified as sufficient for OALVs operating under high light fluences. The optimum driving voltage for the AlN‐based OALV is determined to be ≈ 45 V pp at 100 Hz, achieving a transmittance of 91.3%, an extinction ratio (ER) of more than 100, and a 51:1 image contrast.

36 MATERIALS SCIENCE↗

Oxidation Behavior of Candidate NiCr Alloys for Engine Exhaust Valves: Part I—Effect of Minor Alloying Elements

Oxidation-induced degradation of structural materials employed as exhaust valves within internal combustion engines (ICEs) will be a relevant life-limiting mechanism, in addition to creep and mechanical fatigue, due to ever-increasing severity of operating temperatures and pressures. Ni–Cr-based alloys, which form external chromia-based scales at the relevant operating temperatures are being considered as suitable candidate materials. Thermal cycling of these alloys in water vapor-containing atmospheres, such as those present during hydrocarbon fuel combustion within ICEs, can considerably influence their oxidation behavior. Here, the role of typical alloying additions such as Mn, Si, Al and Ti on the cyclic oxidation behavior of model NiCr–X (X = Mn,Si,Al,Ti) alloys exposed in dry air and air + 10% H 2 O at 800°C and 950°C was investigated. Combined additions of Mn and Si reduced scaling rates compared to binary Ni–22Cr alloys. The presence of water vapor possibly suppressed formation of NiMnCr spinel and thereby the Cr depletion in the alloy. Combined Al and Ti additions mainly resulted in accelerated oxidation kinetics due to the Ti doping of chromia scales. More porous external scales were observed in water vapor leading to a much deeper depth of nitridation in the Ni–22Cr–Al–Ti alloys.

36 MATERIALS SCIENCE↗

Quasiparticle conductance in spin valve Josephson structures

We study the quasiparticle current in clean ferromagnetic Josephson structures of the form $S_1/F_1/N/F_2/S_2$, where $\textit{S, F,}$ and $\textit{N}$ denote superconducting, ferromagnetic, or normal layers, respectively. Our focus is on the structure of the conductance $\textit{G}$ as a function of bias $\textit{V$, emphasizing the subgap region. We use a fully self-consistent numerical method, coupled to a transfer matrix procedure to extract $\textit{G(V)}$. We choose material parameters appropriate to experimentally realized Co Cu Nb structures. In this work, we find a resonance peak structure as a function of the intermediate layer thickness and of the misalignment angle $\phi$ between $\textit{F}$ layers. To understand this resonance structure, we develop an approximate analytic method. For experimentally relevant thicknesses, the conductance has multiple subgap peaks, which oscillate in position between low and critical bias positions. These oscillations occur in both $\phi$ and the layer thicknesses. We compare our results with those obtained for the spin valve structures ($F_1/N/F_2/S_2$) and discuss the implications of our results for the fabrication of spin Josephson devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Wide bandgap photoconductor (SiC:V)-based optically addressed light valve for high fluence operation

Optically addressable light valves based on wide bandgap 4H- and 6H-SiC as photoconductors were designed to withstand higher operational laser fluences than the state of-the-art bismuth silicon oxide (BSO; Bi 12 SiO 20 ) based devices. Vanadium-doped SiC was selected as the photoconductors due to their reasonable photoresponsivity while many fold improvement in laser induced damage threshold as compared to BSO. The laser induced damage threshold values of the materials were measured after exposing ~ 200 sites on the samples to increasing levels of fluence of a gaussian pulsed Nd: YAG laser system (1064 nm) with a 5 Hz repetition rate. The measured damage threshold values for BSO, 4H- and 6H-SiC were 0.4 J/cm 2 , 1.75 J/cm 2 and 1.8 J/cm 2 , respectively. Photoconductive switches based on 4H and 6H-SiC samples were characterized at wavelengths of 380 nm, 405 nm, and 447 nm. The peak photoresponsivity values of the 4H- and 6H-SiC materials were measured to be under 380 nm and 405 nm, respectively. The photoconductor was bonded to a BK7 optical window with 5 μm diameter microspheres as spacers. A twisted nematic type E7 liquid crystal (LC) was filled in the 5 μm gap in a vacuum chamber. The desired alignment of the liquid crystal was achieved by mutually orthogonal orientation of LC alignment layers on the two mating faces (SiC and BK7). The fabricated devices were modulated using address beams of wavelengths 380 nm, 405 nm, and 447 nm. In conclusion, required transmission levels of > 90% was achieved for the fabricated OALVs for a sinusoidal voltage waveform that meets the lifetime requirement of the device.

36 MATERIALS SCIENCE↗

Lawrence Livermore National Laboratory Ultrafast Closure Valve Use Cases

The purpose of this report is to document several use cases of the Ultra-Fast Closure Valve System (UCVS) at the Joint Actinide Shock Physics Experimental Research (JASPER) facility. The goal is to clearly identify the use cases so that an explosive hazard classification may be assigned.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Development of Cast Valve Bodies For High Temperature Service

Gen 3 Concentrating Solar-Thermal Power (CSP) system components are required to operate at 750°C - 800°C to achieve the Sunshot target of 6 cents/kWh. Haynes ® 282 and IN ® 740H are preferred alloys for the construction of these components due to their high tensile and creep strengths for service at temperatures greater than 750°C. There is significant motivation to lower the cost of materials and components so that the capital costs can be minimized. One approach to reduce costs is to fabricate castings at the lowest possible cost. To obtain the lowest cost in castings, there is a significant need to maximize yields in castings by decreasing rejects due to casting defects and to minimize wastage in material lost in the gating systems. However, very little work has been performed to develop cast products using Haynes ® 282. Although preliminary work has established the feasibility of casting Haynes ® 282 using investment and sand casting, there are no commercial cast components available. In particular, there is significant interest in the development of casting design and process technology for the fabrication of components such as valve bodies using Haynes ® 282.

14 SOLAR ENERGY↗

Equipment Qualification Report Environmental Qualification of GNB Absolyte Valve Regulated Lead Acid (VRLA) 1600 Ah100G33 Battery Rack Assembly (24590-QL-POA-EDB0-00001-11-00002_00A)

Greenberry Environmental Qualification Report 550001.001-35.0.5 provides basis for assignment of qualified life for: GNB Absolyte Valve Regulated Lead Acid (VRLA) 1600 Ah 100G33 Battery Rack Assembly in accordance with the requirements specified 24590-WTP-3PS-G000-T0015 (Rev 2) and Environmental Qualification Plan 550001.001-35.0.1 (Rev. 3). The equipment qualification basis represents the most conservative capability of the equipment. The analysis performed for the qualification is not less conservative than the bounding environmental conditions detailed in contract documents issued to Greenberry in contract 24509-QL-POA-EDB0-00001 Rev.0. The qualified life of 10 years has been established based upon an end-condition objective of the equipment condition indicators that correlate to the ability of equipment to perform its safety function. The VRLA Battery Cell Assembly was aged by 10 years (minimum) in accordance with conditions specified by Bechtel Equipment Qualification Datasheet 24590-LAW-EUQ-UPE 00003 Rev. 3 and the process conditions specified by the Instrument Data Sheet 24590-LAW EUD-UPE-00009 Rev. 2. Greenberry Industrial has contracted with GNB Industrial Battery Co located at 4115 S Zero St, Fort Smith, AR 72908 to perform age conditioning, monitoring, and capacity testing in accordance with Environmental Qualification Plan 550001.001-35.0.1 Rev. 1. The required process at the stated conditions set by the parameters established by the plan were completed satisfactorily. The details of the of the test process observed by Greenberry is detailed in the attached Seismic Test Log 550001.001-7.0.3, including examples of the objective evidence collected during the qualification process.

54 ENVIRONMENTAL SCIENCES↗

High-Temperature Freeze & Leak-Resistant Advanced Molten Salt Valve (Final Project Report)

The overall goal of this investigation was to develop an innovative high-temperature chloride molten salt flow control valve capable of operation up to 750 °C. The team developed an integrated active and passive thermal management system to ensure robust design for freeze-thaw cycles, with either a bellows-sealed configuration, a high-temperature stuffing box, or combination of the two. The STM system is unique in the industry.

14 SOLAR ENERGY↗