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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Simultaneous visible and ultraviolet spectroscopy of stellar wind variability in Zeta Puppis

Spectra of He II 4686 A and H-alpha in Zeta Pup were obtained simultaneously with Copernicus ultraviolet scans of several P Cygni profiles in this O4 If supergiant with strong mass loss. The visible-wavelength data show significant variations in the profiles of both lines, consisting of doubling of the emission over times of less than a day. Recent theoretical calculations show that the observed profile variations in 4686 A can be produced by significant fluctuations in the wind density. The Copernicus data show less variability, although in one scan of the 1400-A Si IV doublet there appears to be a significant enhancement of the emission which may be correlated with one of the doublings observed in 4686 A and H-alpha, as though a density enhancement formed at low levels and then moved outward in the wind.

Wegner, G. A.↗
NASA NTRS2023

Cryolite Overcoated Aluminum Reflectors for Far-Ultraviolet Spectroscopy

Aluminum (Al) mirrors are conventionally protected with metal-fluoride coatings (e.g., MgF2, LiF, or AlF3) immediately after deposition to prevent oxidation and preserve its far-ultraviolet (FUV) spectral efficiency. However, the resulting FUV reflectance of the aluminum reflector is limited by the metal-fluoride overcoat film index of refraction, morphology, stoichiometry, and its absorption cut-off in the lower end of the FUV spectra. Cryolite (sodium hexafluoroaluminate, Na3AlF6) emerges as a potential candidate to preserve the aluminum FUV reflectance due to its relatively lower index of refraction in the visible to ultraviolet; therefore, allowing for the thin-film design of highly spectral efficient reflectors over a wide spectral range. We investigate the use of cryolite in aluminum reflector FUV coating design. The deposited aluminum reflector overcoated with cryolite will be examined in terms of spectral efficiency and environmental durability. The deposited cryolite overcoat will be evaluated in terms of optical constants and structural properties. Preliminary results have shown that the use of cryolite as an overcoat to protect aluminum would yield unprecedented results as an optimal Hydrogen Lyman-alpha (HLyα) spectral line reflector, with experimental reflectance values >96%.

optical coatings↗
NASA NTRSDate not supplied

Cryolite Overcoated Aluminum Reflectors for Far-Ultraviolet Spectroscopy

Aluminum (Al) mirrors are conventionally protected with metal-fluoride coatings (e.g., MgF 2 , LiF, or AlF 3 ) immediately after deposition to prevent oxidation and preserve its far-ultraviolet (FUV) spectral efficiency. However, the resulting FUV reflectance of the aluminum reflector is limited by the metal-fluoride overcoat film index of refraction, morphology, stoichiometry, and its absorption cut-off in the lower end of the FUV spectra. Cryolite (sodium hexafluoroaluminate, Na 3 AlF 6 ) emerges as a potential candidate to preserve the aluminum FUV reflectance due to its relatively lower index of refraction in the visible to ultraviolet; therefore, allowing for the thin-film design of highly spectral efficient reflectors over a wide spectral range. We investigate the use of cryolite in aluminum reflector FUV coating design. The deposited aluminum reflector overcoated with cryolite will be examined in terms of spectral efficiency and environmental durability. The deposited cryolite overcoat will be evaluated in terms of optical constants and structural properties. Preliminary results have shown that the use of cryolite as an overcoat to protect aluminum would yield unprecedented results as an optimal Hydrogen Lyman-alpha (HLyα) spectral line reflector, with experimental reflectance values >96%.

optical coating↗
NASA NTRS1984

Ultraviolet spectroscopy of the planetary nebula in the Fornax galaxy

The planetary nebula in the Fornax dwarf spheroidal galaxy is carbon rich, according to calculations based on measurements of the 1909 A emission line doublet of semiforbidden C III obtained with the International Ultraviolet Explorer. The ratio N(C)/N(O) is approximately equal to 3.7, comparable to the largest reliably determined carbon/oxygen ratios in high excitation planetaries of the Milky Way. The present result is based on four low-dispersion spectra with a combined exposure time of 27.2 hours; the Fornax planetary nebula is probably the most distant known planetary that can be observed with IUE. The IUE data were analyzed together with visible-wavelength emission-line fluxes reported by Danziger et al. (1978) to compute abundances for various elements. In terms of chemical composition, the Fornax nebula resembles planetary nebulae in the Magellanic Clouds more closely than it does typical or carbon-rich planetaries in the Galaxy.

Maran, S. P.↗
NASA NTRS1983

Ultraviolet spectroscopy and the composition of cometary ice

A brief description of the nature of comets and of their interactions with their environments is given. Past observations are discussed, and particularly the data obtained for the West and Bradfield comets are compared. Far-ultraviolet observations are discussed in terms of the possibility of detecting the more volatile species such as H2O, CO2 and CO, which all have signatures in the ultraviolet spectral region. The comets observed by the International Ultraviolet Explorer are listed with the corresponding data. The space missions to be made in 1985-1986 are mentioned and these are the Giotto spacecraft mission, and the OSS-3 observatory that will fly aboard the Space Shuttle.

Feldman, P. D.↗
NASA NTRS1983

Epsilon Aurigae in eclipse. I - Ultraviolet spectroscopy during ingress and totality

Epsilon Aurigae is a long-period eclipsing system containing a F0 Ia supergiant and an unseen slightly less-massive secondary. A primary eclipse began in mid-1982 with the unseen companion passing in front of the supergiant. Low-resolution ultraviolet (IUE) spectra of Epsilon Aur in 1982 and early 1983 provide eclipse light curves extending into the total phase of the current eclipse. The depth of eclipse from 3000 A to 1700 A is slightly deeper than at visual wavelengths (0.8 m). The depth declines for wavelengths less than 1700 A and is just 0.2 m at wavelengths less than 1300 A. The disappearance of the eclipse at wavelengths less than 1300 A may be attributed to a hot star or spot within the disk-shaped secondary. A main-sequence star of spectral type B0 accounts for the observations. However, an alternative site of the ultraviolet excess may be the primary's upper photosphere or chromosphere.

Parthasarathy, M.↗
NASA NTRS1982

Ultraviolet spectroscopy of F and G supergiants with IUE. II - The hot companions of HR 2786 and HR 2859

Hot companion stars in two binary systems are analyzed by means of IUE low-dispersion spectra. HR 2859B is found to be a B2 IV or V star, and analysis of ultraviolet to near-infrared photometry indicates the primary to be an early G star only one magnitude brighter in V with a magnitude of -4.0. A third star probably associated with this system was classified B9p Hg a probable visual absolute magnitude of about -1.6 is obtained for it. HR 2786 is now confirmed to have a hot secondary, for which a spectral class of B9-9.5 is obtained. With an assumed luminosity for this component, the G2 Ib primary then has a magnitude of -3.8.

Parsons, S. B.↗
NASA NTRS1992

Near-ultraviolet spectroscopy of Comet Austin (1989c1)

Comet Austin (1989c1) was observed post-perihelion at a heliocentric distance near 1.25 AU. The wavelength range was from the atmospheric cutoff at 3000 to 4000 A. The coma spectra were calibrated into flux units and the contaminating sky spectrum and solar scattered light continuum were subtracted, leaving an ultraviolet spectrum of about 1.5-A resolution and excellent signal-to-noise ratio. The spectrum is dominated by emissions from OH, NH, CH, C3, and CN, some of the weaker emissions of which are seen here for the first time. More bands of CO(2+) were found than in any previous investigation and several intensity anomalies were noted; H2CO, OH(+), NCN, N(2+), and CN(+) may be present. Several emission features well above the noise level remain unidentified. The relative intensities of the OH and CN bands agree with the predictions of resonance fluorescence when one considers the potential effects of contamination by other molecules. The effects of the ozone absorption spectrum are not fully removed by the data-reduction process, although this does not affect these results.

Valk, Jacobus H.↗
NASA NTRS1981

Ultraviolet spectroscopy of old novae and symbiotic stars

The IUE spectra are presented for two old novae and for two of the symbiotic variables. Prominent emission line spectra are revealed as a continuum whose appearance is effected by the system inclination. These data provide evidence for hot companions in the symbiotic stars, making plausible the binary model for these peculiar stars. Recent IUE spectra of dwarf novae provide additional support for the existence of optically thick accretion disks in active binary systems. The ultraviolet data of the eclipsing dwarf novae EX Hya and BV Cen appear flatter than for the noneclipsing systems, an effect which could be ascribed to the system inclination.

Lambert, D. L.↗
NASA NTRS1988

Ultraviolet spectroscopy of R Coronae Borealis

Observations of the hydrogen-deficient supergiant R CrB were obtained with the IUE over an interval of 54 days in order to study the nature of this star's irregular, small-amplitude variations in light. By chance, the series of observations coincided with a dip in the light intermediate between the normal fluctuations and the deep declines associated with the formation of an obscuring dust cloud. High-resolution spectra have been used to search for radial velocity variations, while low-resolution spectra yield ultraviolet light curves down to 1810 A. Both types of spectra have been analyzed for indications of temperature changes. It is found that a combination of photospheric temperature variation and variable extinction is necessary to account for the details of the observations. A simple, ad hoc, periodic model is presented in which the amount of obscuring dust varies in proportion to the drop in temperature, but at a later time, reproduces the wavelength dependence of both the amplitudes and phase shifts of the light curves. The radial velocities are consistent with pulsation being responsible for the temperature variation.

Holm, A. V.↗
NASA NTRS1980

X-ray and ultraviolet spectroscopy of Cygnus X-1 = HDE 226868

Observations of Cygnus X-1 with the solid-state spectrometer on the Einstein Observatory are presented. The X-ray spectra of two intensity dips viewed near superior conjunction did not exhibit increased photoelectric absorption. Rather, the data support a model in which an increase in the electron-scattering optical depth modifies both the observed spectrum and the intensity. The characteristic temperature of the intervening material is greater than about 50 million K. These measurements were in part simultaneous with observations by IUE. The ultraviolet spectrum and intensity remained relatively constant during an X-ray intensity dip.

Pravdo, S. H.↗
DOE OSTI2022

The R -process Alliance: A Nearly Complete R -process Abundance Template Derived from Ultraviolet Spectroscopy of the R -process-enhanced Metal-poor Star HD 222925 *

We present a nearly complete rapid neutron-capture process (r-process) chemical inventory of the metal-poor ([Fe/H] = -1.46 ± 0.10) r-process-enhanced ([Eu/Fe] = +1.32 ± 0.08) halo star HD 222925. This abundance set is the most complete for any object beyond the solar system, with a total of 63 metals detected and seven with upper limits. It comprises 42 elements from 31 ≤ Z ≤ 90, including elements rarely detected in r-process-enhanced stars, such as Ga, Ge, As, Se, Cd, In, Sn, Sb, Te, W, Re, Os, Ir, Pt, and Au. We derive these abundances from an analysis of 404 absorption lines in ultraviolet spectra collected using the Space Telescope Imaging Spectrograph on the Hubble Space Telescope and previously analyzed optical spectra. A series of appendices discusses the atomic data and quality of fits for these lines. The r-process elements from Ba to Pb, including all elements at the third r-process peak, exhibit remarkable agreement with the solar r-process residuals, with a standard deviation of the differences of only 0.08 dex (17%). In contrast, deviations among the lighter elements from Ga to Te span nearly 1.4 dex, and they show distinct trends from Ga to Se, Nb through Cd, and In through Te. The r-process contribution to Ga, Ge, and As is small, and Se is the lightest element whose production is dominated by the r-process. The lanthanide fraction, log X La = -1.39 ± 0.09, is typical for r-process-enhanced stars and higher than that of the kilonova from the GW170817 neutron-star merger event. We advocate adopting this pattern as an alternative to the solar r-process-element residuals when confronting future theoretical models of heavy-element nucleosynthesis with observations.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Ballistic Δ S = 2 intersystem crossing in a cobalt cubane following ligand-field excitation probed by extreme ultraviolet spectroscopy

We report femtosecond M 2,3 -edge X-ray absorption near-edge structure (XANES) spectroscopy is used to probe the excited-state dynamics of the cobalt cubane [Co III 4 O 4 ](OAc) 4 (py) 4 (OAc = acetate, py = pyridine), a model for water oxidation catalysts. After ligand-field excitation, intersystem crossing (ISC) to a metal-centered quintet occurs in 38 fs. 30% of the hot quintet undergoes ballistic back-ISC directly to the singlet ground state, with the remainder relaxing to a long-lived triplet.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗