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At least 73 records · Page 4

Summary of Activities for Health Monitoring of Composite Overwrapped Pressure Vessels

This new start project (FY12-14) will design and demonstrate the ability of nondestructive evaluation sensors for the measurement of stresses on the inner diameter of a Composite Overwrapped Pressure Vessel overwrap. Results will be correlated with other nondestructive evaluation technologies such as Acoustic Emission. The project will build upon a proof of concept study performed at KSC which demonstrated the ability of Magnetic Stress Gages to measure stresses at internal overwraps and upon current acoustic emission research being performed at WSTF; The gages will be produced utilizing Maundering Winding Magnetometer and/or Maundering Winding Magnetometer-array eddy current technology. The proof-of-concept study demonstrated a correlation between the sensor response and pressure or strain. The study also demonstrated the ability of Maundering Winding Magnetometer technology to monitor the stresses in a Composite Overwrapped Pressure Vessel at different orientations and depths. The ultimate goal is to utilize this technology for the health monitoring of Composite Overwrapped Pressure Vessels for all future flight programs.

Russell, Rick↗

Optimum performance of hovering rotors

A theory for the optimum performance of a rotor hovering out of ground effect is developed. The performance problem is formulated using general momentum theory for an infinitely bladed rotor, and the effect of a finite number of blades is estimated. The analysis takes advantage of the fact that a simple relation exists between the radial distributions of static pressure and angular velocity in the ultimate wake, far downstream of the rotor, since the radial velocity vanishes there. This relation permits the establishment of an optimum performance criterion in terms of the ultimate wake velocities by introducing a small local perturbation of the rotational velocity and requiring the resulting ratio of thrust and power changes to be independent of the radial location of the perturbation. This analysis fully accounts for the changes in static pressure distribution and axial velocity distribution throughout the wake as the result of the local perturbation of the rotational velocity component.

Wu, J. C.↗

Mass loss from red giants - A simple evolutionary model for NGC 7027

NGC 7027 is a young planetary nebula with the remnants of a red giant circumstellar envelope surrounding the central, ionized region. By comparing the outer molecular envelope with the inner ionized material, it is argued that the mass loss rate has decreased by at least a factor of 3, and more probably by about a factor of 10, during the past 1000 years. From this result, it is argued that the luminosity of the central star has also decreased substantially during the same time, consistent with models for the rapid evolution of stars just after they evolve off the asymptotic giant branch. In this picture, the distance to NGC 7027 is less than 1300 pc. NGC 7027 was the last (and best) example of a star where apparently the momentum in the outflowing mass /M(dot)v/ is considerably greater than the momentum in the radiation field (L/c). With the above description of this object, the evidence is now strong that quite often the mass lost from late-type giants is ultimately driven to infinity by radiation pressure on grains. If M(dot)v is as large as L/c for asymptotic branch stars, then it is expected that the total amount of mass lost during this stage of evolution is of the same magnitude as the initial mass of the star, and therefore this mass loss can profoundly affect the star's ultimate fate.

Jura, M.↗

Evolvable Cryogenics (ECRYO) Pressure Transducer Calibration Test

This paper provides a summary of the findings of recent activities conducted by Marshall Space Flight Center's (MSFC) In-Space Propulsion Branch and MSFC's Metrology and Calibration Lab to assess the performance of current "state of the art" pressure transducers for use in long duration storage and transfer of cryogenic propellants. A brief historical narrative in this paper describes the Evolvable Cryogenics program and the relevance of these activities to the program. This paper also provides a review of three separate test activities performed throughout this effort, including: (1) the calibration of several pressure transducer designs in a liquid nitrogen cryogenic environmental chamber, (2) the calibration of a pressure transducer in a liquid helium Dewar, and (3) the calibration of several pressure transducers at temperatures ranging from 20 to 70 degrees Kelvin (K) using a "cryostat" environmental chamber. These three separate test activities allowed for study of the sensors along a temperature range from 4 to 300 K. The combined data shows that both the slope and intercept of the sensor's calibration curve vary as a function of temperature. This homogeneous function is contrary to the linearly decreasing relationship assumed at the start of this investigation. Consequently, the data demonstrates the need for lookup tables to change the slope and intercept used by any data acquisition system. This ultimately would allow for more accurate pressure measurements at the desired temperature range. This paper concludes with a review of a request for information (RFI) survey conducted amongst different suppliers to determine the availability of current "state of the art" flight-qualified pressure transducers. The survey identifies requirements that are most difficult for the suppliers to meet, most notably the capability to validate the sensor's performance at temperatures below 70 K.

Diaz, Carlos E., Jr.↗

A fully coupled variable properties thermohydraulic model for a cryogenic hydrostatic journal bearing

The goal set forth here is to continue the work started by Braun et al. (1984-1985) and present an integrated analysis of the behavior of the two row, 20 staggered pockets, hydrostatic cryogenic bearing used by the turbopumps of the Space Shuttle main engine. The variable properties Reynolds equation is fully coupled with the two-dimensional fluid film energy equation. The three-dimensional equations of the shaft and bushing model the boundary conditions of the fluid film energy equation. The effects of shaft eccentricity, angular velocity, and inertia pressure drops at pocket edge are incorporated in the model. Their effects on the bearing fluid properties, load carrying capacity, mass flow, pressure, velocity, and temperature form the ultimate object of this paper.

Braun, M. J.↗

Test and Analysis of a Hyper-X Carbon-Carbon Leading Edge Chine

During parts production for the X43A Mach 10 hypersonic vehicle nondestructive evaluation (NDE) of a leading edge chine detected on imbedded delamination near the lower surface of the part. An ultimate proof test was conducted to verify the ultimate strength of this leading edge chine part. The ultimate proof test setup used a pressure bladder design to impose a uniform distributed pressure field over the bi-planar surface of the chine test article. A detailed description of the chine test article and experimental test setup is presented. Analysis results from a linear status model of the test article are also presented and discussed. Post-test inspection of the specimen revealed no visible failures or areas of delamination.

Smith, Russell W.↗

Pressure-stable supported ionic liquid membranes using isoporous supports for evaluating pure- and mixed-gas light paraffin fractionation

Advances in horizontal drilling and hydraulic fracturing have spurred the growth of domestic U.S. energy production. Membranes, typically silicone rubbers, have found utility in shale gas treatment as fuel gas conditioning units to selectively remove C 2 + hydrocarbons at pressures up to 30 bar, producing clean CH 4 for gas engines. However, more selective materials could be beneficial for broader shale gas treatment applications, such as dew point control units. Supported ionic liquid membranes (SILMs) offer a potential opportunity for improving C 3 H 8 /CH 4 selectivity, but they lack pressure-stability. Here, we report C 3 H 8 /CH 4 selective and pressure-stable SILMs using isoporous supports. SILMs with supports that had minimal defects remained stable up to 15 bar of transmembrane pressure. This stability allowed for pure- and mixed-gas testing of the resulting membranes at elevated pressures. Furthermore, these tests revealed that low viscosity ILs (<100 cp) may display mixed-gas permeances and permselectivity nearly identical to pure-gas results. On the other hand, higher viscosity ILs may display increasing permeances and permselectivity with increasing C 3 H 8 fugacity, similar to rubbery polymers. Ultimately, the SILMs demonstrated relatively high pressure-stability due to the isoporous supports and competitive mixed-gas C 3 H 8 /CH 4 permselectivity compared to silicone rubber.

Rosenthal, Justin J. [University of Texas at Austi↗

TPSAS-NF1676L-13678-DND

An area that shows promise in enhancing structural integrity of aircraft and aerospace structures is integral stitched composite technology. The most recent generation of this technology is the Pultruded Rod Stitched Efficient Unitized Structure (PRSEUS) concept. The goal of the PRSEUS concept is to provide damage-containment capability for composite structures while reducing overall structural weight. The National Aeronautics and Space Administration, the Boeing Company, and the Federal Aviation Administration (FAA) have partnered in an effort to assess the damage-containment features of a full-scale curved PRSEUS panel using the FAA Full-Scale Aircraft Structural Test Evaluation and Research facility. The background, test plan, fixture modifications, pre-test analysis, and planned experimental procedure were presented at the 2011 Aircraft Airworthiness and Sustainment Conference. This follow-on paper and presentation will provide details of the experimental procedure, test results, nondestructive inspection results, and preliminary test analysis comparison. The test program included three phases of loading and inspections: Phase I, as-built; Phase II, with barely visible impact damage (BVID); and Phase III, with a two-bay notch severing the central stiffener. Axial tension, internal pressure, and combined axial tension and internal pressure load conditions were applied during each phase using load levels that demonstrate compliance with the strength, deformation, and damage-tolerance requirements of Title 14 Code of Federal Regulations Part 25. Pressure loads were based on an operating pressure of 9.2 psi, designated as 1P, and the axial loads were based on a design limit load (DLL) of 227 kip. The Phase I test results provided a baseline. First, 50 percent limit-load levels were applied for each of the three load cases to verify proper load introduction and repeatability by examining strain and displacement results. Next, three limit-load cases were applied: limit pressure of 12.2 psi (1.33 P), axial DLL of 227 kip, and combined 1P pressure and axial DLL. Linear strain and displacement results were observed in all load cases. For Phase-II testing, the panel was impacted to introduce BVID with an energy of 40 ft-lb, with the impact located between the central stringer stitch line and flange edge. The impact created non-penetrating visual damage with fiber breaks and delamination between the skin and stringer flange. Limit-load conditions were applied followed by pressure overload of 18.4 psi (2P) and ultimate load conditions, defined as 1.5 times DLL. Inspections were performed after each load case; no damage growth was observed. For Phase-III testing, a two-bay notch was machined severing the central stiffener. The panel was then subjected to limit-load conditions, followed by combined 1P pressure while increasing axial tension load to catastrophic failure. As limit combined loads were approached, damage initiation was observed in the form of 45? splitting at 1P + 79% DLL. Axial loading was increased to 1P + 150 percent DLL causing damage to propagate to the adjacent stringer flanges. Damage was contained within the two-bay region by the stitching rows up to 1P + 176% DLL. Axial load was further increased until catastrophic failure, when a stringer rod failed at 1P + 192% DLL. These test results further verify the damage containment features of the PRSEUS concept and suggest its appropriateness for future flight vehicles.

Andrew Bergan↗

Causal mechanism of injection-induced earthquakes through the M w 5.5 Pohang earthquake case study

Causal mechanisms for fluid injection-induced earthquakes remain a challenge to identify. Past studies largely established spatiotemporal correlations. Here, we propose a multi-process causal mechanism for injection-induced earthquakes through a case study of the 2017 M w 5.5 induced earthquake near Pohang Enhanced Geothermal System, Korea, where detailed hydraulic stimulation and on-site seismicity monitoring data provide an unprecedented opportunity. Pore pressure modeling reveals that pore pressure changes initiate seismicity on critically stressed faults and Coulomb static stress transfer modeling reveals that earthquake interactions promote continued seismicity, leading to larger events. On the basis of these results, we propose the following causal mechanism for induced seismicity: pore pressure increase and earthquake interactions lead to fault weakening and ultimately triggering larger earthquakes later in the process. We suggest that it is prudent that pore pressure change, initial seismicity locations, and Coulomb static stress transfer from seismicity earlier in the sequence are assessed in real-time.

58 GEOSCIENCES↗

Origins of the Pressure-Induced Phase Transition and Metallization in the Halide Perovskite (CH 3 NH 3 )PbI 3

Hybrid halide perovskites are promising for applications because of their favorable optoelectronic properties and low cost. Here we investigate the effects of hydrostatic pressure on the structural and electronic properties of (MA)PbI 3 (MA = CH 3 NH 3 + ) using first-principles density functional theory calculations. Our calculations predict that at a pressure of 0.23 GPa, the orthorhombic Fmmm phase becomes unstable with respect to a cubic Im$\bar{3}$ phase, in good agreement with room-temperature experiments (~0.3 GPa). At higher pressures, about 6 GPa, we predict the onset of pronounced intra- and interoctahedral distortions. This symmetry lowering leads to the introduction of I 5p–I 5p* antibonding and Pb 6p–Pb 6p bonding character into the valence band maximum (VBM) and the conduction band minimum (CBM) states, respectively. We find this change in bond character explains the evolution of the VBM and CBM states under compression, trends that ultimately lead to metallization at significantly higher pressures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Investigating bubble pressures in irradiated UO 2 for understanding fragmentation of high burnup structure

This report summarized work carried out to investigate mechanisms relevant to fragmentation of high burnup UO 2 fuel. High pressure bubbles that form in high burnup structure are thought to be responsible for fragmentation and pulverization, when exposed to a temperature ramp during a transient. The over-pressurization of the bubbles during normal operation is a pre-requisite for this mechanism to occur. Therefore, in this work we investigate the role of interstitials, produced through irradiation, in over-pressurizing the bubbles by using a combined molecular dynamics (MD) and cluster dynamics approach. Firstly, the energies for the annihilation of interstitials and vacancies at bubbles have been determined from MD as a function of bubble pressure. Secondly, these reaction energies have been implemented in the cluster dynamics code Centipede to determine the steady-state defect concentrations and bubble pressure under irradiation. It was found that there is a transition from low pressure bubbles, at high temperature, to high pressure bubbles, at low temperatures. This indicates the formation of over-pressurized bubbles in the low temperature periphery of the pellet, where high burnup structure forms. This result supports the hypothesis that over-pressurized bubbles form during steady-state operation and can then contribute to fragmentation during a transient. Future work will examine the influence of bubble pressure on Xe diffusion and study the impact of other sinks (e.g. grain boundaries and dislocations) that are relevant to high burnup structure. Ultimately, the goal is to provide predictions of the bubble pressure as a function of burnup that can be used to derive a more mechanistic fragmentation threshold for use in BISON.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Application of Modified Meshgraphnets for Subsurface Prediction during CO2 Sequestration

In the face of the increasingly dire consequences of anthropogenic climate change, capturing and storing carbon dioxide is paramount. However, several impediments exist to the safe and effective subsurface storage of CO2, such as cost of transport, identification of suitable sites for subsurface storage, and assessment of long-term risk from storage in subsurface aquifers. Accurate subsurface modeling is necessary to ensure that CO2 storage is both safe and effective. Still, such modeling has traditionally required either substantial time and computational power (numerical simulation) or a substantial amount of pre-existing data for training (machine learning models). Additionally, these models lack flexibility in dealing with both changes in discretization of the input data and generalizability beyond the data on which they are trained. In order to address these issues, this research applies graph neural networks (GNNs) to predict subsurface saturation and pressure during CO₂ injection in a model of the Illinois Basin-Decatur Project (IBDP). GNNs provide a flexible, intuitive method for representing and manipulating complex unstructured data, which is often found in many practical domain problems such as fluid flow and subsurface characterization. These unstructured grids are easily represented in GNNs by representing spatially-localized features such as permeability, porosity, saturation, and pressure as nodes in a graph and relationships between these properties as edges connecting these nodes. This research applies a specific GNN model called MeshGraphNets (MGN) to model the change in CO2 saturation and pressure over a 50-month time period (36 months of injection, 14 months post-injection). The MGN model leverages a message passing process that allows the network to learn both the spatial and temporal dynamics of this system simultaneously. Additionally, training on a limited dataset (64 realizations, 20 time points each) resulted in a high degree of accuracy in saturation prediction both within the same timeframe as the training (20 months, 0.039 average RMSE) and when projecting out to the end of injection (36 months, 0.053 average RMSE). Temporal predictions such as those generated by MGNs and other similar models are prone to accumulated error over time; in order to address this, a multi-step rollout (MSR) training process was applied to calculate training loss. This method mimics the forward prediction during inference by “rolling out” multiple time points in a single training step using the previous prediction as input to the MGN model. By calculating the loss several time steps forward from the current prediction, the model is forced to find a more stable state over time. Application of MSR to the MGN model resulted in an average 15% reduction in inference error over time during forward prediction. This study showcases the immense potential of GNNs as a game-changing methodology for predicting pressure and saturation evolution in CCS projects, ultimately paving the way for more sustainable and effective carbon storage solutions. Presentation prepared for the 2024 AiChE Annual Meeting, October 27 to November 1 2024, San Diego, CA.

Holcomb, Paul↗

Thermal-structural combined loads design criteria study

A study was conducted to determine methodology for combining thermal structural loads and assessing the effects of the combined loads on the design of a thermal protection system and a hot structure of a high cross range delta wing space shuttle orbiter vehicle. The study presents guidelines for establishing a basis for predicting thermal and pressure environments and for determining limit and ultimate design loads on the vehicle during reentry. Limit trajectories were determined by using dispersions on a representative nominal mission and system parameters expected during the life of the vehicle. Nine chosen locations on the vehicle surface having TPS or hot structures were examined, and weight sensitivity analyses were performed for each location.

Deriugin, V.↗

The possibility of life on Mars during a water-rich past

Geomorphological evidence for past liquid water on Mars implies an early, warmer, epoch. In this review we compare this early warm environment to the first Gyr of Earth's history, the time within which we know life originated. We consider the key question about early Mars from the biological standpoint. How long was liquid water present? The range of answers encompasses the time interval for the origin of life on Earth. We use studies of early life on Earth as a guide, albeit a limited one, to the possible forms of evidence for past life on Mars. Presumptive evidence for microbial life on early Earth are stromatolites, layered deposits produced by microorganisms binding and trapping sediment. A search for fossils might be fruitful at sites on Mars that contained standing bodies of water over long periods of time. The ice-covered lakes of the dry valleys of Antarctica may provide analogs to the ultimate lakes on Mars as the surface pressure fell with a concomitant decrease in surface temperatures.

Mckay, C. P.↗

Study of the rotational-level and temperature dependence of the quenching rate of OH fluorescence due to collisions with water molecules

The importance of the OH radical as an intermediate in many combustion reactions and in atmospheric photochemistry has led many researchers to use it as a diagnostic tool in these processes. The amount of data that has been acquired over the years for this radical is quite considerable. However, the quenching rate of OH with water molecules as a function of temperature and the rotational level of the excited state is not very well understood. The motivation of the studies undertaken is to bridge the gap between the low temperature measurements and the high temperature ones reported in the literature. The technique generally employed in these diagnostics is laser-induced fluorescence (LIF), through which rotational state selective excitation of the radical is possible. Furthermore, in a combustion medium, water is produced in abundance so that knowledge of the quenching rate of OH due to water molecules plays a crucial role in interpreting the data. In general, the precursor to an understanding of the collisional quenching rates of OH involves a characterization of the mode in which the radical is produced; the resulting rotational and translational distribution, followed by a measurement of the OH temperature; and ultimately obtaining the rate constants from the pressure dependence of the fluorescence signal. The experimental implementation of these measurements therefore involved, as a first step, the production of the OH radicals in a microwave discharge cell using water vapor as the source, wherein a hydrogen atom is abstracted from H2O. The second step involved the absorption of photons from the frequency-doubled output of a pulsed amplified, single-frequency cw ring dye laser. By tuning the laser to the peak of the transition and observing the fluorescence decay after the laser pulse, the lifetime of the OH in a particular rotational electronic state was determined (tau = 1.4 microseconds for Q(sub 1)(3)). Knowledge of this parameter led to a determination of the quenching rate. By varying the water vapor pressure in the cell and measuring the lifetime as a function of pressure a linear plot of the quenching rate as a function of pressure was obtained. Using this plot, the quenching cross section was deduced. It has therefore been possible to measure the local translational temperature and the quenching cross section with one laser system.

Koker, Edmond B.↗

A Novel Method for Breath Capture Inside a Space Suit

Any non-robotic mission to the Mars surface will need to rely on various life support technologies. The large metabolic generation rate and low tolerance to elevated levels of carbon dioxide (CO2) in the Mars atmosphere make CO2 removal one of the preeminent tasks in this domain. In addition, these same features provide a strong impetus for using regenerable CO2 removal technologies. In the past, many of these regenerable technologies have relied on the low partial pressure CO2 surrounding the vehicle to provide an ultimate sink for removing this gas contaminant, however any Mars mission will have to overcome the presence of the Mars atmosphere. This paper describes the investigation of methods to capture the exhaled CO2 from a suited crewmember before it becomes diluted with the high volumetric air flow present within the space suit. Typical expired air contains CO2 partial pressures in the range of 20-35 mm Hg. This research investigated methods to capture this high partial pressure CO2 prior to its dilution with the low partial pressure CO2 ventilation flow. Specifically the research looked at potential designs for a collection cup for use inside the space suit helmet. This collection cup should not be considered the same as a breathing mask typical of that worn by firefighters, etc. Instead, the collection cup is a non-contact device that makes use of detailed analyses of the ventilation flow environment within the helmet. The research used a detailed Computational Fluid Dynamic (CFD) code called Fluent to provide modeling of the various gas species (CO2, water vapor, O2) as they pass through a helmet. This same model was used to numerically evaluate several different collection cup designs for this same CO2 segregation effort.

Paul, Heather↗

Effects of pressure on the electronic and magnetic properties of bulk NiI 2

Transition metal dihalides have recently garnered interest in the context of two-dimensional van der Waals magnets as their underlying geometrically frustrated triangular lattice leads to interesting competing exchange interactions. In particular, NiI 2 is a magnetic semiconductor that has been long known for its exotic helimagnetism in the bulk. Recent experiments have shown that the helimagnetic state survives down to the monolayer limit with a layer-dependent magnetic transition temperature that suggests a relevant role of the interlayer coupling. Here, we explore the effects of hydrostatic pressure as a means to enhance this interlayer exchange and ultimately tune the electronic and magnetic response of NiI 2 . We study first the evolution of the structural parameters as a function of external pressure using first-principles calculations combined with x-ray diffraction measurements. We then examine the evolution of the electronic structure and magnetic exchange interactions via first-principles calculations and Monte Carlo simulations. Further, we find that the leading interlayer coupling is an antiferromagnetic second-nearest-neighbor interaction that increases monotonically with pressure. The ratio between isotropic third- and first-nearest-neighbor intralayer exchanges, which controls the magnetic frustration and determines the magnetic propagation vector q of the helimagnetic ground state, is also enhanced by pressure. As a consequence, our Monte Carlo simulations show a monotonic increase in the magnetic transition temperature, indicating that pressure is an effective means to tune the magnetic response of NiI 2 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Pressure tuning of structural and magnetic transitions in EuAg 4 As 2

We report temperature-dependent measurements of ambient-pressure specific heat, magnetic susceptibility, anisotropic resistivity, and thermal expansion as well as in-plane resistivity under pressure up to 20.8 kbar on single crystals of EuAg 4 As 2 . Based on thermal expansion and in-plane electrical transport measurements at ambient pressure this compound has two, first-order, structural transitions in the 80–120 K temperature range. Ambient-pressure specific heat, magnetization, and thermal expansion measurements show a cascade of up to seven transitions between 8 and 16 K associated with the ordering of the $Eu^{2+}$ moments. In-plane electrical transport is able to detect the more prominent of these transitions, at 15.5, 9.9, and 8.7 K, as well as a weak feature at 11.8 K at ambient pressure. Pressure-dependent electrical transport data show that the magnetic transitions shift to higher temperatures under pressure, as does the upper structural transition, whereas the lower structural transition is suppressed and ultimately vanishes. A jump in resistivity, associated with the upper structural transition, decreases under pressure with an extrapolated disappearance (or a change of sign) by 30–35 kbar. In the 10–15 kbar range a kink in the pressure dependency of the upper structural transition temperature as well as the high- and low-temperature in-plane resistivities suggests that a change in the electronic structure may occur in this pressure range. The results are compared with the literature data for EuAg 4 As 2 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗