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NASA NTRS1976

Potential biomedical applications of ion beam technology

Electron bombardment ion thrusters used as ion sources have demonstrated a unique capability to vary the surface morphology of surgical implant materials. The microscopically rough surface texture produced by ion beam sputtering of these materials may result in improvements in the biological response and/or performance of implanted devices. Control of surface roughness may result in improved attachment of the implant to soft tissue, hard tissue, bone cement, or components deposited from blood. Potential biomedical applications of ion beam texturing discussed include: vascular prostheses, artificial heart pump diaphragms, pacemaker fixation, percutaneous connectors, orthopedic prosthesis fixation, and dental implants.

Banks, B. A.↗

NASA NTRS2003

Nanolayered Features of Collagen-like Peptides

We have been investigating collagen-like model oligopeptides as molecular bases for complex ordered biomimetic materials. The collagen-like molecules incorporate aspects of native collagen sequence and secondary structure. Designed modifications to native primary and secondary structure have been incorporated to control the nanostructure and microstructure of the collagen-like materials produced. We find that the collagen-like molecules form a number of lyotropic rod liquid crystalline phases, which because of their strong temperature dependence in the liquid state can also be viewed as solvent intercalated thermotropic liquid crystals. The liquid crystalline phases formed by the molecules can be captured in the solid state by drying off solvent, resulting in solid nanopatterned (chemically and physically) thermally stable (to greater than 100 C) materials. Designed sequences which stabilize smectic phases have allowed a variety of nanoscale multilayered biopolymeric materials to be developed. Preliminary investigations suggest that chemical patterns running perpendicular to the smectic layer plane can be functionalized and used to localize a variety of organic, inorganic, and organometallic moieties in very simple multilayered nanocomposites. The phase behavior of collagen-like oligopeptide materials is described, emphasizing the correlation between mesophase, molecular orientation, and chemical patterning at the microscale and nanoscale. In many cases, the textures observed for smectic and hexatic phase collagens are remarkably similar to the complex (and not fully understood) helicoids observed in biological collagen-based tissues. Comparisons between biological morphologies and collagen model liquid crystalline (and solidified materials) textures may help us understand the molecular features which impart order and function to the extracellular matrix and to collagen-based mineralized tissues. Initial studies have utilized synthetic collagen-like peptides while future work will also focus on similar sequences generated via genetic engineering methods.

Valluzzi, Regina↗

NASA NTRS2005

How We Used NASA Lunar Set in Planetary Material Science Analog Studies on Lunar Basalts and Breccias with Industrial Materials of Steels and Ceramics

Analog studies play important role in space materials education. Various aspects of analogies are used in our courses. In this year two main rock types of NASA Lunar Set were used in analog studies in respect of processes and textures with selected industrial material samples. For breccias and basalts on the lunar side, ceramics and steels were found as analogs on the industrial side. Their processing steps were identified on the basis of their textures both in lunar and in industrial groups of materials.

Berczi, S.↗

NASA NTRS1978

The use of an ion-beam source to alter the surface morphology of biological implant materials

An electron bombardment, ion thruster was used as a neutralized-ion beam sputtering source to texture the surfaces of biological implant materials. Scanning electron microscopy was used to determine surface morphology changes of all materials after ion-texturing. Electron spectroscopy for chemical analysis was used to determine the effects of ion texturing on the surface chemical composition of some polymers. Liquid contact angle data were obtained for ion textured and untextured polymer samples. Results of tensile and fatigue tests of ion-textured metal alloys are presented. Preliminary data of tissue response to ion textured surfaces of some metals, polytetrafluoroethylene, alumina, and segmented polyurethane were obtained.

Weigand, A. J.↗

NASA NTRS1978

The use of an ion-beam source to alter the surface morphology of biological implant materials

An electron-bombardment ion-thruster was used as a neutralized-ion-beam sputtering source to texture the surfaces of biological implant materials. The materials investigated included 316 stainless steel; titanium-6% aluminum, 4% vanadium; cobalt-20% chromium, 15% tungsten; cobalt-35% nickel, 20% chromium, 10% molybdenum; polytetrafluoroethylene; polyoxymethylene; silicone and polyurethane copolymer; 32%-carbon-impregnated polyolefin; segmented polyurethane; silicone rubber; and alumina. Scanning electron microscopy was used to determine surface morphology changes of all materials after ion-texturing. Electron spectroscopy for chemical analysis was used to determine the effects of ion-texturing on the surface chemical composition of some polymers. Liquid contact angle data were obtained for ion-textured and untextured polymer samples. Results of tensile and fatigue tests of ion-textured metal alloys are presented. Preliminary data of tissue response to ion-textured surfaces of some metals, polytetrafluoroethylene, alumina, and segmented polyurethane have been obtained.

Weigand, A. J.↗

NASA NTRS1979

Mechanical and chemical effects of ion-texturing biomedical polymers

To determine whether sputter etching may provide substantial polymer surface texturing with insignificant changes in chemical and mechanical properties, an 8 cm beam diameter, electron bombardment, argon ion source was used to sputter etch (ion-texture process) nine biomedical polymers. The materials included silicone rubber, 32% carbon impregnated polyolefin, polyoxymethylene, polytetrafluoroethylene, ultrahigh molecular weight (UHMW) polyethylene, UHMW polyethylene with carbon fibers (10%), and several polyurethanes (bioelectric, segmented, and cross linked). Ion textured microtensile specimens of each material except UHMW polyethylene and UHMW polyethylene with 10% carbon fibers were used to determine the effect of ion texturing on tensile properties. Scanning electron microscopy was used to determine surface morphology changes, and electron spectroscopy for chemical analysis was used to analyze the near surface chemical changes that result from ion texturing. Ion energies of 500 eV with beam current densities ranging from 0.08 to 0.19 mA/sq cm were used to ion texture the various materials. Standard microtensile specimens of seven polymers were exposed to a saline environment for 24 hours prior to and during the tensile testing. The surface chemical changes resulting from sputter etching are minimal in spite of the often significant changes in the surface morphology.

Weigand, A. J.↗

NASA NTRS1974

Preliminary results of experiments to duplicate Boulder textures by thermal sintering of powders

Experiments seem to indicate that at the low pressures characteristic of an ejecta blanket, sintering or sintering/devitrification could have lithified boulder 1 matrix materials and produced the textural types observed in 72255 and 72275. This very preliminary conclusion is consistent with other observations that granitic clasts have undergone a slight degree of partial melting (and have therefore experienced temperatures on the order of 1000 C). It is concluded that maskelynite in the boulder is completely devitrified.

Hallam, M. E.↗

NASA NTRS2016

Organic Analysis in the Miller Range 090657 CR2 Chondrite: Part 3 C and N Isotopic Imaging

Primitive carbonaceous chondrites contain a wide variety of organic material, ranging from soluble discrete molecules to insoluble nanoglobules of macro-molecular carbon. The relationship between the soluble organic molecules, macromolecular organic material, and host minerals are poorly understood. Large H, C and N isotopic anomalies suggest some organic components formed in low-T interstellar or outer Solar System environments. The highest isotope anomalies occur in m-scale inclusions in the most primitive materials, such as cometary dust and the least altered carbonaceous chondrites. Often, the hosts of these isotopically anomalous 'hotspots' are discrete organic nanoglobules that probably formed in the outermost reaches of the protosolar disk or cold molecular cloud. Molecular and isotopic studies of meteoritic organic matter are aimed at identifying the chemical properties and formation processes of interstellar organic materials and the subsequent chemical evolutionary pathways in various Solar System environments. The combination of soluble and insoluble analyses with in situ and bulk studies provides powerful constraints on the origin and evolution of organic matter in the Solar System. Using macroscale extraction and analysis techniques as well as microscale in situ observations we have been studying both insoluble and soluble organic material in primitive astromaterial samples. Here, we present results of bulk C and N isotopic measurements and coordinated in situ C and N isotopic imaging and mineralogical and textural studies of carbonaceous materials in a Cr2 carbonaceous chondrite. In accompanying abstracts we discuss the morphology and distribution of carbonaceous components and soluble organic species of this meteorite.

Messenger, S.↗

NASA NTRS1984

Secondary electron emission characteristics of ion-textured copper and high-purity isotropic graphite surfaces

Experimentally determined values of true secondary electron emission and relative values of reflected primary electron yield for untreated and ion textured oxygen free high conductivity copper and untreated and ion textured high purity isotropic graphite surfaces are presented for a range of primary electron beam energies and beam impingement angles. This investigation was conducted to provide information that would improve the efficiency of multistage depressed collectors (MDC's) for microwave amplifier traveling wave tubes in space communications and aircraft applications. For high efficiency, MDC electrode surfaces must have low secondary electron emission characteristics. Although copper is a commonly used material for MDC electrodes, it exhibits relatively high levels of secondary electron emission if its surface is not treated for emission control. Recent studies demonstrated that high purity isotropic graphite is a promising material for MDC electrodes, particularly with ion textured surfaces. The materials were tested at primary electron beam energies of 200 to 2000 eV and at direct (0 deg) to near grazing (85 deg) beam impingement angles. True secondary electron emission and relative reflected primary electron yield characteristics of the ion textured surfaces were compared with each other and with those of untreated surfaces of the same materials. Both the untreated and ion textured graphite surfaces and the ion treated copper surface exhibited sharply reduced secondary electron emission characteristics relative to those of untreated copper. The ion treated graphite surface yielded the lowest emission levels.

Curren, A. N.↗

NASA NTRS1977

Scanning-electron-microscopy observations and mechanical characteristics of ion-beam-sputtered surgical implant alloys

An electron bombardment ion thruster was used as an ion source to sputter the surfaces of orthopedic prosthetic metals. Scanning electron microscopy photomicrographs were made of each ion beam textured surface. The effect of ion texturing an implant surface on its bond to bone cement was investigated. A Co-Cr-W alloy and surgical stainless steel were used as representative hard tissue implant materials to determine effects of ion texturing on bulk mechanical properties. Work was done to determine the effect of substrate temperature on the development of an ion textured surface microstructure. Results indicate that the ultimate strength of the bulk materials is unchanged by ion texturing and that the microstructure will develop more rapidly if the substrate is heated prior to ion texturing.

Weigand, A. J.↗

NASA NTRS1994

Collision of cometlike and slightly differentiated bodies as an origin for ordinary chondrites

One of the keys to understanding the origins of chondrites is given by the characteristics of relict minerals in chondrules that survived chondrule formation. Some of the relic materials show shock deformation textures, such as high dislocation densities in relict olivine and stacking faults in relict pyroxene. The textures suggest that shock deformation was the cause of melting of the chondrules. Some of the olivine and pyroxene fragments in the matrix of the chondrites have been shown to have a composition closer to the relict minerals than minerals crystallized during the chondrule formation. This suggests that some of the fragments originated from the precursor materials of the chondrules. A proposed origin for chondrites is discussed here along with supporting observations and conclusions.

Kitamura, M.↗

NASA NTRS2019

Exploration of Failure and Potential Damage Markers in Ti-6Al-4V

To improve prognostics for predicting component life, coupon tests were conducted on Ti-6Al-4V to investigate the development of damage. Various test types were employed (tension, creep, stress relaxation, and fatigue) under a wide range of temperatures and loading rates to engage various amounts of time-dependent and damage behavior. Both stiffness degradation and Poisson’s ratio were monitored to see if they were useful in indicating the initiation and accumulation of damage and subsequently the onset of failure. Stiffness exhibited large decreases with increasing strain when calculated using engineering stress and strain. However, minimal stiffness change was observed when using the true-stress and true- strain values. Detailed microscopy and image analysis were performed to document the actual physical damage that occurred within the various specimens. Two types of damage were observed: shallow surface cracks and internal pores. The severity of damage was greater in the region of localized necking and diminished further away from the neck. The area fraction of pores was higher in the necked region, yet even there it did not exceed more than a few percent and, in most cases, was significantly lower. It was observed that conditions that induced more time-dependent deformation (e.g., slower strain rate testing) resulted in a larger number of pores and larger pore sizes. The pores were always found to occur in the softer β-phase. The severity of observed damage was inconsistent with the large drop in engineering stiffness, but was more aligned with stiffness changes from the true-stress and -strain values. Poisson’s ratio was monitored on every test and showed promise as a damage indicator. It was found to be more sensitive than either the ultimate tensile strength or the inception of tertiary creep. However, calculation of Poisson’s ratio was found to be more involved than expected because of anisotropy and the presence of strain gradients along the specimen at large applied strains. First, the material had a moderate texture and resulted in anisotropy of the strains. Second, the evolution of Poisson’s ratio as a function of axial strain showed strange and unexpected behaviors, which necessitated more extensive analyses of its development. This led to an investigation on the use of small versus large strain approaches and the importance of making consistent measurements; that is, axial and transverse strain measurements over the same volume of material. Additionally, finite element analysis of a tensile sample indicated that non- uniform strain occurred in the sample prior to attaining the maximum strength. This, along with the location at which transverse strain was measured, had a significant influence on the resulting values of Poisson’s ratio. Based on this, lessons learned are offered for future testing.

Ti-6Al-4V↗

NASA NTRS1979

Geology of the lunar farside crater Necho

The ejecta morphology and distribution as well as the interior materials of the 30-km-diameter, Necho lunar crater is discussed and the effects of regional preimpact topography on the formation structure and modification of the crater are described. Three types of ejecta: hummocky, lineated, and smooth, that are concentrated in a band extending from the rim crest to a distance of less than one crater diameter are examined. The crater's interior, divided into floor units of textured, bubbled, and smooth material is analyzed and hypotheses of their origin are presented. The last area of study is the preimpact setting, characterized by a series of large, degraded, pre-Nectarian craters. Results showed that the Necho, in comparison with surrounding craters, was the freshest, insuring that the data from its excavation was preserved without a significant amount of degradation.

Gifford, A. W.↗

NASA NTRS2010

Use of DSC and DMA Techniques to Help Investigate a Material Anomaly for PTFE Used in Processing a Piston Cup for the Urine Processor Assembly (UPA) on International Space Station (ISS)

Human urine and flush water are eventually converted into drinking water with the Urine Processor Assembly (UPA) aboard the International Space Station (ISS). This conversion is made possible through the Distillation Assembly (DA) of the UPA. One component of the DA is a molded circular piston cup made of virgin polytetrafluoroethylene (PTFE). The piston cup is assembled to a titanium component using eight fasteners and washers. Molded PTFE produced for spare piston cups in the first quarter of 2010 was different in appearance and texture, and softer than material molded for previous cups. For the suspect newer PTFE material, cup fasteners were tightened to only one-half the required torque value, yet the washers embedded almost halfway into the material. The molded PTFE used in the DA piston cup should be Type II, based on AMS 3667D and ASTM D4894 specifications. The properties of molded PTFE are considerably different between Type I and II materials. Engineers working with the DA thought that if Type I PTFE was molded by mistake instead of Type II material, that could have resulted in the anomalous material properties. Typically, the vendor molds flat sheet PTFE from the same material lot used to mold the piston cups, and tensile testing as part of quality control should verify that the PTFE is Type II material. However, for this discrepant lot of material, such tensile data was not available. Differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) were two of the testing techniques used at the NASA/Marshall Space Flight Center (MSFC) to investigate the anomaly for the PTFE material. Other techniques used on PTFE specimens were: Shore D hardness testing, tensile testing on dog bone specimens and a qualitative estimation of porosity by optical and scanning electron microscopy.

Wingard, Doug↗

NASA NTRS1977

Orientale and Caloris

Based on revised stratigraphy, structural interpretation, explosion-crater data, and a genetic model for Orientale, it is suggested that Orientale and Caloris have much in common. It is noted that: (1) although the basin fill in Caloris is different from that seen in Orientale, the materials between the most prominent scarp and the weakly-developed outer scarp may be degraded equivalents of the massifs and knobs associated with the Montes Rook, (2) the Montes Rook and the main Caloris scarp have similar stratigraphic and structural features, (3) the lineated ejecta derived from shallower horizons are found near and beyond the weakly-developed outer Caloris scarp which is the counterpart of the Orientale scarp, (4) a well developed field of secondary craters is observed beyond 1 basin diameter at Caloris, (5) the observed textural differences between the material around the main Caloris scarp and the lineated material beyond suggest that Mercury is layered and that Caloris crater excavated coherent materials from one or more of these layers at depth, and (6) the difference in spacing between the Caloris rings is not related to internal layering effects.

Mccauley, J. F.↗

NASA NTRS1979

Ion-beam-textured graphite

Results of evaluation of seven different materials (copper, tantalum, titanium carbide, soot, smooth pyrolytic graphite, and ion-beam-textured graphite) for low secondary-electron emitting surface for depressed collects in microwave amplifiers indicate that ion-beam-textured graphite shows greatest potential for use.

Curren, A. N.↗

NASA NTRS2003

Crystal Size Distributions from Porphyritic Olivine Chondrules: Insights into Formation Conditions

Most chondrules preserve, in their texture, a record of their precursor material and the nature and intensity of the nebular events in which they were formed. We have used crystal size distributions (CSDs) together with crystallization experiments to explore the textures of natural chondrules and their relationships to natural formation conditions. Many careful experimental studies have demonstrated fundamental relationships between the texture of a chondrule and its precursor material, melting intensity, and cooling rate. However, until recently most studies have focused on distinctions between textural types (e.g., barred, radial, porphyritic). Previous work has shown that CSDs provide precise, reproducible characterizations of chondrule-scale textures, and can be used together with crystallization experiments to estimate chondrule formation conditions. Here, we expand this study to investigate the link between texture and formation conditions for a range of natural porphyritic olivine (PO) chondrules.

Zieg, M. J.↗

NASA NTRS1979

Shock metamorphism of granulated lunar basalt

The paper deals with an extensive series of shock-recovery experiments performed on both nonporous crystalline basalt and its granulated and sieved counterpart to study the role of porosity and grain size in shock motomorphic effects under otherwise identical conditions. Shocked samples are compared with unshocked starting material in terms of textural and mineralogical modifications attributable to shock. A comparative petrographic and chemical characterization is presented of pulverized and sieved lunar basalt 75035 shocked between 6 and 75 GPa in comparison with holocrystalline disks of the same basalts shocked in 10 earlier experiments. Specifically, a petrographic classification of shock features is given, along with an estimation of relative amounts of shock glasses and a chemical characterization of shock glasses in each shocked granular basalt.

Schaal, R. B.↗