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Factors affecting thermal structure of ocean, error sources in surface temperature, and calculated energy exchange effects at surface to forecast ocean temperature structure
Bi-directional reflectance models for describing distribution of reflected energy from rough metallic spacecraft surfaces
Accurate quartet- and doublet-state potential-energy surfaces for the interaction of a hydrogen atom and an oxygen molecule in their ground states have been determined from an ab initio calculation using large-basis sets and the internally contracted multireference configuration interaction method. These potential surfaces have been used to calculate the H-O2 electron-spin-exchange cross section; the square root of the cross section (in a(sub 0)), not taking into account inelastic effects, can be obtained approximately from the expressions 2.390E(sup -1/6) and 5.266-0.708 log10(E) at low and high collision energies E (in E(sub h)), respectively. These functional forms, as well as the oscillatory structure of the cross section found at high energies, are expected from the nature of the interaction energy. The mean cross section (the cross section averaged over a Maxwellian velocity distribution) agrees reasonably well with the results of measurements.
The N + N2 exchange rate is calculated using a time-dependent quantum dynamics method on a newly determined ab initio potential energy surface (PES) for the ground A" state. This ab initio PES shows a double barrier feature in the interaction region with the barrier height at 47.2 kcal/mol, and a shallow well between these two barriers, with the minimum at 43.7 kcal/mol. A quantum dynamics wave packet calculation has been carried out using the fitted PES to compute the cumulative reaction probability for the exchange reaction of N + N2(J=O). The J - K shift method is then employed to obtain the rate constant for this reaction. The calculated rate constant is compared with experimental data and a recent quasi-classical calculation using a LEPS PES. Significant differences are found between the present and quasiclassical results. The present rate calculation is the first accurate 3D quantal dynamics study for N + N2 reaction system and the ab initio PES reported here is the first such surface for N3.
The main focus of this work is to understand the dynamics of mass exchange between the tropics and the midlatitudes and to determine any links between tropospheric exchange and that in the stratosphere. We have approached this problem from two different perspectives. The first is aimed towards understanding the troposphere's role in inducing lower stratospheric tropical/midlatitude exchange. For this project we focus on observational analysis of the lower stratosphere to assess the key regions of transport in/out of the tropics and to what extent this transport is driven by tropospheric processes. The second approach is to determine the extent to which stratospheric processes influence the troposphere. In this project we are performing potential vorticity (PV) inversions to assess the winds induced near the tropopause when the stratospheric polar vortex is displaced equatorward. These are each discussed in more detail in the subsections below. Also, we have organized a session on Tropical/Midlatitude Interaction and Transport at the Fall AGU where we will be showing our latest results.
The presence of sulfur dioxide (SO2) on Io, together with the fact that the surface layer of Io has extremely high porosity, suggests the possibility of diffusion of this volatile within the surface, as well as exchange between the surface and an atmosphere. The former possibility is investigated through the development of a surface layer thermal model and subsequent calculations of the thermally driven diffusion flux of SO2 within the layer. The major factors affecting the diffusion process are the temperature and temperature gradient in the surface layer throughout the day, and the porosity and grain size in the surface layer. The results indicate that the net transport of SO2 in the near-surface region is downward into the subsurface, causing near-surface depletion of SO2. Near-surface depletion would result in a layer of reduced thermal inertia overlying the bulk of the surface, consistent with thermal eclipse observations of Io. For the present nominal model with 10-micron grains and a porosity of 85 percent, the peak net diurnal downward flux reaches nearly 0.008 g/sq cm per period.
The semianalytical model outlined in a previous study (Massman, 1987) to describe momentum exchange between the atmosphere and vegetated surfaces is extended to include the exchange of heat. The methods employed are based on one-dimensional turbulent diffusivities, and use analytical solutions to the steady-state diffusion equation. The model is used to assess the influence that the canopy foliage structure and density, the wind profile structure within the canopy, and the shelter factor can have upon the inverse surface Stanton number (kB exp -1), as well as to explore the consequences of introducing a scalar displacement height which can be different from the momentum displacement height. In general, the triangular foliage area density function gives results which agree more closely with observations than that for constant foliage area density. The intended application of this work is for parameterizing the bulk aerodynamic resistances for heat and momentum exchange for use within large-scale models of plant-atmosphere exchanges.
Solar and other renewable energy systems are optimized using geophysical parameters describing information about the solar resource and meteorological environments and how those environments may be changing in time. The Prediction of Worldwide Renewable Energy Resource (POWER) team at the NASA LaRC Research Center deployed its first version of the revitalized POWER geophysical parameter website that employs Esri Geographic Information System (GIS) tools. This web application provides access to both time series and climatological data sets spanning from a few days behind real-time back to the early 1980’s with a spatial resolution of 0.5 x 0.5 degree, thus extending over 30 years. The GIS tools enable, generate and store climatological averages using spatial queries and calculations in a spatial database resulting in greater accessibility to government agencies, industry and individuals. There is an API that provides data through a URL coding and can also invoked inside user software packages. Output data formats now include ASCII, CSV, geoTiff, JSON and .netCDF. Since May 2018, over 10.4 TB of data have been delivered to fulfill over 110 million data requests from 240,000 unique user IPs (https://power.larc.nasa.gov). This presentation provides an overview of this project and the current version of the new POWER web capabilities through to the end usage. Surface solar parameters are adapted from both the NASA/GEWEX (Global and Energy Water Cycle Exchange) SRB (Surface Radiation Budget) project and the CERES (Clouds and Earth’s Radiant Energy System) data products. The meteorological parameters are adapted from NASA’s MERRA-2 (Modern Era Retrospective-analysis for Research and Applications). We review uncertainty of various basic parameters using surface measurements. After the introduction, we specifically discuss various clusters of parameters for equator pointing tilted surfaces that provide for the estimation of optimal tilt angle by month and year. The discussion will emphasize a few examples of how solar and building engineers are using the data products. We will then preview the capabilities of Version 2 featuring examples of hourly solar and meteorological data products, customized user reports and expanded web mapping services from CERES data products. The web services provide a unique, expandable resource for renewable energy systems engineers to design, evaluate and optimize to environments worldwide.
Particle adhesion is relevant in fields ranging from aerospace and energy to civil engineering and medicine. The functions of aerodynamic surfaces, heat exchangers, solar panels, ventilation systems, and blood vessels are affected by the buildup of particulates on their surfaces. Direct measurement of the adhesive force between a particle and a surface is key to understanding and mitigating particle fouling. Approaches such as the Johnson-Kendall-Roberts (JKR) and Derjaguin-Muller-Toporov (DMT) models offer a first approximation of the forces involved but do not account for non-idealities like roughness or plastic deformation. Experimental measurements of adhesive forces often deviate significantly from predictions. One approach to measure adhesion is the colloidal probe technique, which uses a particle attached to the tip of an atomic force microscope (AFM) cantilever. The particle is touched to a surface and then withdrawn and a pull-off force (FPO) determined by cantilever deflection. FPO can be used to estimate work of adhesion (Wa) and other properties from existing models. We describe a new method for producing colloidal probes using wax as an adhesive to attach micrometer-scale spheres to AFM tips. This method can be used with a range of particles and minimizes the potential for changes to the particle surface chemistry or geometry from exposure to heat, chemicals, radiation, or external forces. Particle attachment to AFM tips is robust and reversible, allowing old particles to be replaced with new ones in a few minutes. Pull-off measurements using polystyrene (PS) particles, pristine and modified with myristyltrimethylammonium bromide (14-TAB), were collected from various substrates to demonstrate the viability of this technique and investigate the impact of particle surface modification.
This is a Final Report for a Joint Research Interchange (JRI) between NASA Ames Research Center and San Jose State University, Department of Meteorology. We present below a summary of progress made during the duration of this JRI. The focus of this JRI has been to investigate seasonal water vapor transport in the atmosphere of Mars and its effects on the planet's present climate. To this end, the primary task has been to adapt a new dynamical processor for the adiabatic tendencies of the atmospheric circulation into the NASA Ames Mars general circulation model (MGCM). Using identical boundary and initial conditions, several comparative tests between the new and old MGCMs have been performed and the nature of the simulated circulations have been diagnosed. With confidence that the updated version of the Ames MGCM produces quite similar mean and eddy circulation statistics, the new climate model is well poised as a tool to pursue fundamental questions related to the spatial and seasonal variations of atmospheric water vapor on Mars, and to explore exchanges of water with non-atmospheric reservoirs and transport within its atmosphere. In particular, the role of surface sources and sinks can be explored, the range of water-vapor saturation altitudes can be investigated, and plausible precipitation mechanisms can be studied, for a range of atmospheric dust loadings, such future investigations can contribute to a comprehensive study of surface inventories, exchange mechanisms, and the relative importance of atmospheric transport Mars' water cycle. A listing of presentations made and manuscripts submitted during the course of this project is provided.
This is a Final Report for a Joint Research Interchange (JRI) between NASA Ames Research Center and San Jose State University, Department of Meteorology. We present below a summary of progress made during the duration of this JRI. The focus of this JRI has been to investigate seasonal water vapor transport in the atmosphere of Mars and its effects on the planet's present climate. To this end, the primary task has been to adapt a new dynamical processor for the adiabatic tendencies of the atmospheric circulation into the NASA Ames Mars general circulation model (MGCM). Using identical boundary and initial conditions, several comparative tests between the new and old MGCMs have been performed and the nature of the simulated circulations have been diagnosed. With confidence that the updated version of the Ames MGCM produces quite similar mean and eddy circulation statistics, the new climate model is well poised as a tool to pursue fundamental questions related to the spatial and seasonal variations of atmospheric water vapor on Mars, and to explore exchanges of water with non-atmospheric reservoirs and transport within its atmosphere. In particular, the role of surface sources and sinks can be explored, the range of water-vapor saturation altitudes can be investigated, and plausible precipitation mechanisms can be studied, for a range of atmospheric dust loadings. Such future investigations can contribute to a comprehensive study of surface inventories, exchange mechanisms, and the relative importance of atmospheric transport Mars' water cycle. A listing of presentations made and manuscripts submitted during the course of this project is provided.
A model for exchange of water from the atmosphere to condensing CO2 caps is developed. The rate of water condensation in the caps is assumed to be proportional to the meridional heat flux. It follows that the amount of water condensed in the caps varies inversely with the amount of CO2 condensed. The seasonal phase of the release of water from the caps is not consistent with observed variations in the abundance of atmospheric water. Seasonal variations of atmospheric water abundance are most consistent with vapor exchange between the atmosphere and permafrost in the subtropics.
The exchange of carbon between the Earth’s atmosphere and biosphere influences the atmospheric abundances of carbon dioxide (CO2) and methane (CH4). Airborne eddy covariance can quantify surface-atmosphere exchange from landscape-to-regional scales, offering a unique perspective on carbon cycle dynamics. We use extensive airborne measurements to quantify fluxes of sensible heat, latent heat, CO2, and CH4across multiple ecosystems in the Mid-Atlantic region during September 2016 and May 2017. In conjunction with footprint analysis and land cover information, we use the airborne dataset to explore the effects of landscape heterogeneity on measured fluxes. Our results demonstrate large variability in CO2 uptake over mixed agricultural and forested sites, with fluxes ranging from -3.4 ± 0.7 to -11.5 ± 1.6μmol m-2s-1 for croplands and -9.1 ± 1.5 to -22.7 ± 3.2μmol m-2s-1for forests. We also report substantial CH4emissions of 32.3 ± 17.0to 76.1 ± 29.4nmol m-2s-1 from a brackish herbaceous wetland and 58.4± 12.0 to 181.2 ± 36.8nmol m-2s-1 from a freshwater forested wetland. Comparison of ecosystem-specific aircraft observations with measurements from eddy covariance flux towers along the flight path demonstrate that towers capture ~30–75% of the regional variability in ecosystem fluxes. Diel patterns measured at the tower sites suggest that peak, midday flux measurements from aircraft accurately predicts net daily CO2exchange. We discuss next steps in applying airborne observations to evaluate bottom-up flux models and improve understanding of the biophysical processes that drive carbon exchange from landscape-to-regional scales.
Diffuse reflectance spectroscopy of fuel hydrazines adsorbed on silica, silica-alumina and alimina surfaces indicates that the primary surface-hydrazine interaction is hydrogen bonding. Hydrazine, on adsorption to a deuterated silica surface, undergoes a rapid H/D exchange with deuterated surface silanol (Si-OD) groups. Adsorption equilibria are rapidly established at room temperature. Monomethylhydrazine and unsymmetrical dimethylhydrazine are similarly adsorbed. On adsorption, the C-H stretching and methyl deformation modes of the methylhydrazines are shifted to higher frequencies by 10 to 20 cm(-1). These shifts are postulated to be due to changes in the lone-pair electro-density on the adjacent nitrogen atom and an electronegativity effect.
Global climate studies have shown that sea ice is a critical component in the global climate system through its effect on the ocean and atmosphere, and on the earth's radiation balance. Polar energy studies have further shown that the distribution of thin ice and open water largely controls the distribution of surface heat exchange between the ocean and atmosphere within the winter Arctic ice pack. The thickness of the ice, the depth of snow on the ice, and the temperature profile of the snow/ice composite are all important parameters in calculating surface heat fluxes. In recent years, researchers have used various combinations of DMSP SSMI channels to independently estimate the thin ice type (which is related to ice thickness), the thin ice temperature, and the depth of snow on the ice. In each case validation efforts provided encouraging results, but taken individually each algorithm gives only one piece of the information necessary to compute the energy fluxes through the ice and snow. In this paper we present a comparison of the results from each of these algorithms to provide a more comprehensive picture of the seasonal ice zone using passive microwave observations.
The geology and geomorphology of Mars provide clear evidence for the presence of liquid water on its surface during the Noachian and Hesperien eras (i.e., >3 Ga). In contrast to the ancient watery environment, today the surface of Mars is relatively dry. The current desert-like surface conditions, however, do not necessarily indicate a lack of surface or near-surface water/ice. In fact, massive deposits of ground ice and/or icy sediments have been proposed based on subsurface radar sounder observations. Hence, accurate knowledge of both the evolution of the distribution of water and of the global water inventory is crucial to our understanding of the evolution of the climate and near-surface environments and the potential habitability of Mars. This study presents insights from hydrogen isotopes for the interactive evolution of Martian water reservoirs. In particular, based on our new measurement of the D/H ratio of 4 Ga-old Noachian water, we constrain the atmospheric loss and possible exchange of surface and subsurface water through time.
The mechanism of insulator-insulator triboelectric (contact) charging is being studied by the Electrostatics and Surface Physics Laboratory at KSC. The hypothesis that surface ion exchange is the primary mechanism is being tested experimentally. A two-phase model based on a small partial pressure of singly charged ions in an ambient ideal gas in equilibrium with a submonolayer adsorbed film will provide predictions about charging as a function Of ion mass, pressure, temperature, and surface adsorption energy. Interactions between ions will be considered in terms of coulombic and screened potential energies. This work is yielding better understanding of the triboelectrification of insulators, which is an important problem in. space exploration technology. The work is also relevant to important industrial processes such as xerography and the application of paints and coatings. Determining a better understanding of the fundamental mechanism of insulator-insulator triboelectrification will hopefully lead to better means of eliminating or at least mitigating its hazards and enhancing its useful applications.
With the recent development of multi-dimensional thermal protection system (TPS) material response codes, the capability to account for surface-to-surface radiation exchange in complex geometries is critical. This paper presents recent efforts to implement such capabilities in the CHarring Ablator Response (CHAR) code developed at NASA's Johnson Space Center. This work also describes the different numerical methods implemented in the code to compute geometric view factors for radiation problems involving multiple surfaces. Verification of the code's radiation capabilities and results of a code-to-code comparison are presented. Finally, a demonstration case of a two-dimensional ablating cavity with enclosure radiation accounting for a changing geometry is shown.