Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “surface characterization”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

Quaoar: New, Longitudinaly Resolved, Spectroscopic Characterization of Its Surface

(50000) Quaoar, one of the largest Trans-neptunian objects, is comparable in size to Pluto's moon Charon. However, while Charon's surface is rich almost exclusively in H2O ice, Quaoar's surface characterized by ices of CH4, N2, as well as C2H6, a product of irradiation of CH4 (Dalle Ore et al. 2009). Because of its distance from the Sun, Quaoar is expected to have preserved, to a degree, its original composition, however, its relatively small size did not make it a prime candidate for presence of volatile ices in the study by Schaller and Brown (2007). Furthermore, based on the Brown et al. (2011) study (Brown, Schaller, & Fraser, 2011. A Hypothesis for the Color Diversity of the Kuiper Belt. ApJL, 739, L60) its red coloration points to CH3OH as the ice which, when irradiated, might have produced the red material. We present new visible to near-infrared (0.3-2.48 micrometers) spectro-photometric data obtained with the XSHOOTER (Vernet et al. 2011, A&A, 536A, 105 ) instrument at the VLT-ESO facility at four different longitudes on the surface of Quaoar. The data are complemented by previously published photometric observations obtained in the near-infrared (3.6, 4.5 micrometers) with the Spitzer Space Telescope, which provide an extra set of constraints in the model calculation process in spite of the different observing times that preclude establishing the spatial consistency between the two sets. For each of the four spectra we perform spectral modeling of the entire wavelength range -from 0.3 to 4.5 micrometers- by means of a code based on the Shkuratov radiative transfer formulation of the slab model. We obtain spatially resolved compositional information for the surface of Quaoar supporting the presence of CH4 and C2H6, as previously reported, along with evidence for N2 and NH3OH. The albedo at the two Spitzer bands indicates the likely presence of CO and CO2. CH3OH, predicted on the basis of Quaoar's coloration (Brown et al. 2011), is not found at any of the four longitudes, implying that the presence of this ice is a sufficient, but not necessary condition for reddening of TNO surfaces. Other ices, in particular CH4 (Brunetto et al. 2006), have been shown to be plausible precursors for reddening of TNO surfaces.

Ices↗
NASA NTRS2015

Measuring Skew in Average Surface Roughness as a Function of Surface Preparation

Characterizing surface roughness is important for predicting optical performance. Better measurement of surface roughness reduces polishing time, saves money and allows the science requirements to be better defined. This study characterized statistics of average surface roughness as a function of polishing time. Average surface roughness was measured at 81 locations using a Zygo white light interferometer at regular intervals during the polishing process. Each data set was fit to a normal and Largest Extreme Value (LEV) distribution; then tested for goodness of fit. We show that the skew in the average data changes as a function of polishing time.

Stahl, Mark↗
NASA NTRS2015

Measuring Skew in Average Surface Roughness as a Function of Surface Preparation

Characterizing surface roughness is important for predicting optical performance. Better measurement of surface roughness reduces grinding saving both time and money and allows the science requirements to be better defined. In this study various materials are polished from a fine grind to a fine polish. Each sample's RMS surface roughness is measured at 81 locations in a 9x9 square grid using a Zygo white light interferometer at regular intervals during the polishing process. Each data set is fit with various standard distributions and tested for goodness of fit. We show that the skew in the RMS data changes as a function of polishing time.

Stahl, Mark T.↗
NASA NTRS2003

White Light Used to Enable Enhanced Surface Topography, Geometry, and Wear Characterization of Oil-Free Bearings

A new optically based measuring capability that characterizes surface topography, geometry, and wear has been employed by NASA Glenn Research Center s Tribology and Surface Science Branch. To characterize complex parts in more detail, we are using a three-dimensional, surface structure analyzer-the NewView5000 manufactured by Zygo Corporation (Middlefield, CT). This system provides graphical images and high-resolution numerical analyses to accurately characterize surfaces. Because of the inherent complexity of the various analyzed assemblies, the machine has been pushed to its limits. For example, special hardware fixtures and measuring techniques were developed to characterize Oil- Free thrust bearings specifically. We performed a more detailed wear analysis using scanning white light interferometry to image and measure the bearing structure and topography, enabling a further understanding of bearing failure causes.

Lucero, John M.↗
NASA NTRS2003

Raman Spectroscopic Characterization of the Feldspars: Implications for Surface Mineral Characterization in Planetary Exploration

The availability in the last decade of improved Raman instrumentation using small, stable, intense lasers, sensitive CCD array detectors, and advanced fast grating systems enabled us to develop the Mars Microbeam Raman Spectrometer (MMRS), a field-portable Raman spectrometer with precision and accuracy capable of identifying minerals and their different compositions. For example, we can determine Mg cation ratios in pyroxenes and olivines to +/-0.1 on the basis of Raman peak positions. Feldspar is another major mineral formed in igneous systems whose characterization is important for determining rock petrogenesis and alteration. From their Raman spectral pattern, feldspars can be readily distinguished from ortho- and chain-silicates and from other tecto-silicates such as quartz and zeolites. We show here how well Raman spectral analysis can distinguish among members within the feldspar group.

Freeman, J. J.↗
DOE OSTI2025

Characterizing the surface compositions of supported bimetallic PtSn clusters: Effects of cluster-support interactions and surface adsorbates

PtSn bimetallic clusters on TiO2(110) and highly oriented pyrolytic graphite (HOPG) surfaces have been characterized by scanning tunneling microscopy, low energy ion scattering (LEIS), Xray photoelectron spectroscopy, and temperature programmed desorption (TPD); density functional theory (DFT) calculations have also been performed to better understand adsorption of CO and D2 on the PtSn surfaces. On TiO2 at coverages of 2 ML of Pt and 2 ML of Sn, exclusively bimetallic clusters are formed for both orders of deposition because clusters of the first metal completely cover the surface such that all atoms of the second metal are incorporated into the existing clusters. In contrast, on HOPG, the high mobility and weak cluster-support interactions on HOPG result in much larger 2 ML monometallic clusters (~30 Å high) that do not completely cover the surface, and deposition of the second metal produces larger clusters as well as smaller ones. Despite the difference in cluster morphologies for the different orders of deposition and supports, the LEIS experiments demonstrate that in all cases, the PtSn clusters are rich in Sn at the surface, as expected based on the lower surface free energy for Sn compared to Pt. Furthermore, the +0.2 eV shift in the Sn(3d5/2) binding energy observed on all surfaces in the presence of Pt is consistent with PtSn alloy formation. Deposition of 2 ML of Sn on TiO2 produces two-dimensional clusters with oxidation of Sn and reduction of titania at the clustersupport interface, but addition of Pt to the Sn clusters causes Sn to diffuse away from this interface, leaving Sn in the metallic state. TPD experiments on 2 ML Pt/TiO2 with increasing coverages of Sn show that the number of adsorption sites for D2 sharply decreases to nearly zero at 0.5 ML, while CO adsorption decreases to zero only at much higher Sn coverages of 2 ML. DFT studies for Sn modified Pt surfaces and bulk structures demonstrate that for CO adsorption at low Sn coverages (<0.25 ML), the strong Pt-CO interactions induce diffusion of Pt to the cluster surface and the formation of a bulk Pt3Sn alloy, whereas D2 adsorption does not lead to interactions with the Pt surface that are strong enough to induce alloy formation. A single Sn adatom prevents D2 adsorption on four neighboring Pt atoms via site-blocking and the donation of electron density to Pt.

Li, Fangliang↗
NASA NTRS1985

Surface texture characterization by angular distributions of scattered light

Work at the National Bureau of Standards to develop an on-line optical measurement device and attendant algorithms for automated optical scattering measurements of machined metal surfaces are described. The surfaces could be milled, ground or lapped, and the system is intended to categorize the resulting surface characteristics. The optical device consists of a He-Ne laser which is shone on a surface. The scattered light is captured by a semicircular array of 87 detector elements rotated over the scanned area. The light signals are processed through a digital voltmeter and then an A/D converter. The signals are then stored for later comparisons with optical scattering data obtained by optical instruments used with stylus instruments for characterizing surface topographies. A theoretical model has been defined which relates light scattering and the characteristics of the surface roughness. Initial experimental results with a sinusoidal surface have indicated that although the system can follow the trend of the roughness, the roughness amplitude is as yet uncertainly defined and the computations require excessive time.

Gilsinn, D. E.↗
NASA NTRS1980

Method for observing the features characterizing the surface of a land mass

A method is described where a propeller driven, hydrazine powered aircraft is remotely piloted through rarefied atmosphere of a selected planet, including the planet Earth. It is employed as a communication platform for a telemetry system provided for relaying information relating to features characterizing the surface of the planet.

Reed, R. D.↗
DOE OSTI2022

Design and characterization of surface molecular assemblies for the preparation of solar fuels

A key issue in solar energy conversion is the utilization of solar energy for the preparation of solar fuels. In this area, artificial photosynthesis offers promising approaches for the conversion of H 2 O and CO 2 into usable solar fuels. This review highlights both the design and characterization of surface molecular assemblies for the preparation of solar fuels. It includes mechanistic summaries of the details of the underlying surface chemical reactions including water oxidation and proton/water reduction. The surface mechanisms are shown to integrate molecular reactivity with surface electron transfer in integrated assemblies that lead to impressive efficiencies for water oxidation and proton or CO 2 reduction.

catalysts and catalysis↗
NASA NTRS1984

Microwave reflector characterization using simple instruments in EVA

An antenna with rigid panels which can be measured under ground conditions, carried to space in a packaged condition, deployed into a form similar to the Earth-measured one, measured under space conditions, restowed, and brought back to Earth so that the original measurements can be verified is the type being proposed for this experiment. The antenna chosen will be measured under ground conditions, carried aloft, deployed into its antenna shape, lifted by the remote manipulator system to a position where it can be sighted by two astronauts at the two theodolites, and held there until the surface characterization can be completed. An alternate method would be to use photogrammetry and take pictures of the surface from the payload handling station. After the surface characterization is completed, the antenna will be folded and restowed into the Shuttle bay for return to Earth. The surface characterization will be repeated on Earth after its return for verification both of the original measurement taken on Earth and the measurement taken in space.

Goslee, J. W.↗
DOE OSTI2021

Characterization of Surface Water Dynamics within Fourmile Branch and its Linkages with Groundwater and I-129 Geochemistry

This research work has been supported by the DOE-FIU Science & Technology Workforce Development Initiative, an innovative program developed by the U.S. Department of Energy’s Environmental Management (DOE-EM) and Florida International University’s Applied Research Center (FIU-ARC). During the summer of 2021, DOE Fellow intern, Stevens Charles, spent 10 weeks doing a summer internship at Lawrence Berkley National Laboratory (LBNL) under the supervision and guidance of Dr. Haruko Wainwright from LBNL and Dr. Hansell GonzalezRaymat from Savannah River National Laboratory (SRNL). The intern’s project was initiated on June 1, 2020, and continued through August 6, 2020, with the objective of characterizing the surface water dynamics in the F-Area of Savannah River Site (SRS) and analyzing the surface water dynamics to find any linkages with groundwater and Iodine-129(I-129) geochemistry.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRSDate not supplied

Understanding Relationships Between Satellite, Model, and Ground-Based Surface Temperature Characterizations From Overcast to Clear Conditions in Support of Satellite Remote Sensing of Clouds and Radiation

Accurate and consistent global estimates of cloud coverage and their properties are fundamental to long-term Earth radiation budget (ERB) monitoring efforts like the Clouds and the Earth’s Radiant Energy System (CERES) project. Cloud detection algorithms often apply thresholding approaches to identify where clouds occur by comparing satellite-measured radiances with those that are expected under cloud-free conditions. In addition, once a cloud is detected, the derivation of cloud optical and microphysical properties also requires knowledge of the background radiances below the cloud. In the infrared, knowledge of the surface emissivity and the expected skin temperature under both cloudy and cloud-free conditions is needed. These traits are generally well known over the oceans. Over land, however, comparisons between satellite-derived land surface temperature (LST) with that characterized in numerical weather analyses reveal large differences in many parts of the world, often exceeding 5 K, which can lead to significant satellite cloud detection and cloud property retrieval errors. Furthermore, clouds have a dramatic influence on the LST, and therefore characterization of that model parameter also depends on the capability of the model to accurately resolve clouds. Thus, the LST characterized in models is, at times, a poor approximation for what would otherwise be observed, thereby impeding accurate satellite cloud retrievals. As a result, we seek to develop a more robust method for estimating the LST required for satellite cloud characterizations. This effort is accomplished through a combination of surface emission/air temperature relationship studies in all-sky conditions using ground measurement stations, along with deep neural network (DNN) estimates of expected LST under overcast and cloud-free conditions. We demonstrate that substituting DNN-predicted LST for that generated by numerical models can mitigate model-inherent diurnal dependencies and reduce overall bias and uncertainty relative to satellite/ground observations by 0.5–4 K and 0.5–2 K, respectively. It is expected that this work will lead to improved satellite cloud retrievals that enhance ERB monitoring efforts.

B Scarino↗
DOE OSTI2024

Tuning Surface, Phase, and Magnetization of Superparamagnetic Magnetite by Ionic Liquids: Single-Step Microwave-Assisted Synthesis

Achieving colloidal and chemical stability in ferrofluids by surface modification requires multiple steps, including purification, ex situ modification steps, and operation at high temperatures. In this study, a single-step microwave-assisted methodology is developed for iron oxide nanoparticle (IONP) synthesis utilizing a series of imidazolium-based ionic liquids (ILs) with chloride, bis(trifluoromethylsulfonyl)imide, and pyrrolide anions as the reaction media, thus eliminating the use of volatile organics while enabling rapid synthesis at 80 °C as well as in situ surface functionalization. The characterized surface functionality, hydrodynamic particle size, magnetization, and colloidal stability of the IONPs demonstrate a strong dependence on the IL structure, ion coordination strength, reactivity, and hydrophilicity. The IONPs present primarily a magnetite (Fe 3 O 4 ) phase with superparamagnetism with the highest saturation magnetization at 81 and 73 emu/g at 10 and 300 K, respectively. Depending on the IL coating, magnetization and exchange anisotropy decrease by 20 and 2–3 emu/g (at 35 wt % IL), respectively, but still represent the highest magnetization achieved for coated IONPs by a coprecipitation method. Further, the surface-functionalized superparamagnetic magnetite nanoparticles show good dispersibility and colloidal stability in water and dimethyl sulfoxide at 0.1 mg/mL concentration over the examined 3 month period. This study reports on the intermolecular and chemical interactions between the particle surface and the ILs under synthetic conditions as they relate to the magnetic and thermal properties of the resulting IONPs that are well suited for a variety of applications, including separation and catalysis.

36 MATERIALS SCIENCE↗
NASA NTRS2017

Picosecond Pulsed Laser Ablation for the Surface Preparation of Epoxy Composites

As part of a technical challenge under the Advanced Composites Program, methods for improving pre-bond process control for aerospace composite surface treatments and inspections, in conjunction with Federal Aviation Administration guidelines, are under investigation. The overall goal is to demonstrate high fidelity, rapid and reproducible surface treatment and surface characterization methods to reduce uncertainty associated with the bonding process. The desired outcomes are reliable bonded airframe structure, and reduced timeline to certification. In this work, laser ablation was conducted using a q-switched Nd:YVO4 laser capable of nominal pulse durations of 8 picoseconds (ps). Aerospace structural carbon fiber reinforced composites with an epoxy resin matrix were laser treated, characterized, processed into bonded assemblies and mechanically tested. The characterization of ablated surfaces were conducted using scanning electron microscopy (SEM), water contact angle (WCA) goniometry, micro laser induced breakdown spectroscopy (uLIBS), and electron spin resonance (ESR). The bond performance was assessed using a double cantilever beam (DCB) test with an epoxy adhesive. The surface characteristics and bond performance obtained from picosecond ablated carbon fiber reinforced plastics (CFRPs) are presented herein.

Palmieri, Frank↗
DOE OSTI2021

First-Principles Characterization of Surface Phonons of Halide Perovskite CsPbI 3 and Their Role in Stabilization

The stability of halide perovskites has been a long-standing issue for their real-world application. Approaches to improve stability include nanostructuring, dimensionality reduction, and strain engineering, where surfaces play an important role in the formation of a stable structure. To understand the mechanism we compute the lattice dynamics of the surface of CsPbI 3 using density functional theory. We demonstrate, for the first time, that CsPbI 3 crystals exhibit surface phonons that are localized on the outermost layers of the slabs, and we perform a complete symmetry characterization including an identification of the Raman/IR active modes. These surface phonons are present in the optically active cubic phase but are absent in the optically inactive "yellow" phase. Furthermore, we show that the surface suppresses bulk instabilities by hardening soft modes of the bulk cubic phase, resulting in phase stabilization and quenching of dynamical disorder. Finally, this study is fundamental for understanding the structural behavior of halide perovskite materials with high surface area-to-volume ratios, and for guiding stabilization strategies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗