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Atmospheric Research 2014 Technical Highlights

Atmospheric research in the Earth Sciences Division (610) consists of research and technology development programs dedicated to advancing knowledge and understanding of the atmosphere and its interaction with the climate of Earth. The Division's goals are to improve understanding of the dynamics and physical properties of precipitation, clouds, and aerosols; atmospheric chemistry, including the role of natural and anthropogenic trace species on the ozone balance in the stratosphere and the troposphere; and radiative properties of Earth's atmosphere and the influence of solar variability on the Earth's climate. Major research activities are carried out in the Mesoscale Atmospheric Processes Laboratory, the Climate and Radiation Laboratory, the Atmospheric Chemistry and Dynamics Laboratory, and the Wallops Field Support Office. The overall scope of the research covers an end-to-end process, starting with the identification of scientific problems, leading to observation requirements for remote-sensing platforms, technology and retrieval algorithm development; followed by flight projects and satellite missions; and eventually, resulting in data processing, analyses of measurements, and dissemination from flight projects and missions. Instrument scientists conceive, design, develop, and implement ultraviolet, infrared, optical, radar, laser, and lidar technology to remotely sense the atmosphere. Members of the various Laboratories conduct field measurements for satellite sensor calibration and data validation, and carry out numerous modeling activities. These modeling activities include climate model simulations, modeling the chemistry and transport of trace species on regional-to-global scales, cloud resolving models, and developing the next-generation Earth system models. Satellite missions, field campaigns, peer-reviewed publications, and successful proposals are essential at every stage of the research process to meeting our goals and maintaining leadership of the Earth Sciences Division in atmospheric science research. Figure 1.1 shows the 20-year record of peer-reviewed publications and proposals among the various Laboratories. This data shows that the scientific work being conducted in the Laboratories is competitive with the work being done elsewhere in universities and other government agencies. The office of Deputy Director for Atmospheric Research will strive to maintain this record by rigorously monitoring and promoting quality while emphasizing coordination and integration among atmospheric disciplines. Also, an appropriate balance will be maintained between the scientists' responsibility for large collaborative projects and missions and their need to carry out active science research as a principal investigator. This balance allows members of the Laboratories to improve their scientific credentials, and develop leadership potentials. Interdisciplinary research is carried out in collaboration with other laboratories and research groups within the Earth Sciences Division, across the Sciences and Exploration Directorate, and with partners in universities and other government agencies. Members of the Laboratories interact with the general public to support a wide range of interests in the atmospheric sciences. Among other activities, the Laboratories raise the public's awareness of atmospheric science by presenting public lectures and demonstrations, by making scientific data available to wide audiences, by teaching, and by mentoring students and teachers. The Atmosphere Laboratories make substantial efforts to attract and recruit new scientists to the various areas of atmospheric research. We strongly encourage the establishment of partnerships with Federal and state agencies that have operational responsibilities to promote the societal application of our science products. This report describes our role in NASA's mission, provides highlights of our research scope and activities, and summarizes our scientists' major accomplishments during calendar year 2014. The composition of the organization is shown in Figure 1.2 for each code. This report is published in a printed version with an electronic version on our atmospheres Web site, http://atmospheres.gsfc.nasa.gov/.

Technical↗

Characterizing the impact of water uptake on light absorption by aerosol particles

Absorbing aerosols (AA) have an important impact on the global radiation budget. The composition and properties of AA can vary substantially throughout the atmosphere, depending on the particle source and the influence of chemical aging. Uncertainties associated with the radiative effects of AA remain substantial. A key contributor to this uncertainty is understanding the extent to which water uptake alters absorption by AA particles and how this depends on particle composition. We have used new and existing experimental tools to systematically characterize the relationship(s) between AA chemical and physical characteristics, relative humidity, and mixing of AA with other aerosol components through a combination of laboratory and field measurements. We have developed fundamental understanding through laboratory experiments that will enable interpretation of field observations at DOE ARM sites and facilitate process-based improvements in the simulation of absorption by carbonaceous aerosols in climate models. In the laboratory experiments we have considered a variety of different AA types, including fullerene soot (a surrogate for refractory black carbon, or BC) and nigrosine (a surrogate for partially soluble brown carbon, or BrC). By examining a range of AA types we will develop insight into how the chemical and physical properties of AA particles (e.g. whether they are refractory or soluble) impact the influence of water uptake on absorption. These AA particles will also be mixed—both internally and externally—with compounds having a wide range of hygroscopic properties to establish how the impact of water uptake on absorption will vary with photochemical processing. These laboratory observations have been compared with commonly used theoretical models, enabling development of empirical models that will facilitate improved representation of absorption by AA particles in regional and global climate models. Overall, our study has contributed to the mission of the Atmospheric System Research program by quantifying how interactions between aerosols and radiation depend on relative humidity. Through this, our work will improve understanding and model representation of aerosol processes as they affect the Earth’s radiation budget.

54 ENVIRONMENTAL SCIENCES↗

Characterization of carbonaceous aerosols during TRACER-CAT

Absorbing aerosols (AA) have an important impact on the global radiation budget and cloud properties. The composition and properties of AA can vary substantially throughout the atmosphere, depending on the particle source and the influence of chemical aging. Uncertainties associated with the radiative effects of AA remain substantial. A key contributor to this uncertainty is understanding the extent to which coatings in general, and water uptake especially, alters absorption by AA particles and how this depends on particle composition. We deployed new and existing experimental tools during the Tracking Aerosol Convection Interactions Experiment (TRACER) campaign in Houston, TX as part of the Carbonaceous Aerosols Thrust (CAT) to provide detailed characterization of aerosol optical, chemical, and physical properties. Our TRACER-CAT measurements complemented and expanded on the planned TRACER instrumentation, allowing for more detailed characterization of aerosol properties of relevance to cloud development (a core focus of TRACER), such as the composition of particles that can act as cloud condensation nuclei, than would otherwise be available. Our measurements have allowed for assessment of the relationship(s) between AA optical properties (with a focus on absorption) and the chemical and physical characteristics (including the mixing state of black carbon (BC) containing particles). These field observations occurred in collaboration with Los Alamos National Laboratory in summer 2022 during the TRACER intensive operating period. The instrumentation we co-deployed provided for measurement of (i) multi-wavelength dry aerosol absorption, scattering, and extinction, (ii) the size-dependent composition and abundance of sub-micron aerosol, differentiating between those particles that do and do not contain BC, (iii) BC-specific concentrations and size distributions, (iv) particle size, and (v) the first field measurements at an ARM site of the influence of RH on multi-wavelength absorption by ambient AA. We have leveraged the natural variability of the atmosphere and of aerosol sources in the Houston region to (i) specifically disentangle contributions to light absorption from BC, absorbing organic carbon (brown carbon), and coatings on BC, (ii) characterize the mixing state of BC and assess the factors that give rise to compositional differences between BC-containing and BC-free aerosol, and (iii) establish how water uptake influences absorption and how any such effect depends on particle composition and BC mixing state. Overall, our study contributed to the mission of the Atmospheric System Research program in multiple ways. Through the deployment of complementary, advanced instrumentation for characterization of a wide range of aerosol properties our work helped to maximize the scientific impact of the TRACER campaign. Our work also allowed for development of new insights into the relationship(s) between aerosol composition, hygroscopicity, and the mixing state of BC with aerosol optical properties. Through this, our work has provided knowledge that can improve understanding and model representation of aerosol processes as they affect the Earth’s radiation budget.

54 ENVIRONMENTAL SCIENCES↗

A Revised Calibration Function and Results for the Phoenix Mission TECP Relative Humidity Sensor

The original calibration function of the R(sub H) sensor on the Phoenix Thermal and Electrical Conductivity Sensor (TECP) has been revised in order to extend the range of the valid calibration, and to improve accuracy. The original function returned non-physical R(sub H) values at the lowest temperatures. To resolve this, and because the original calibration was performed against a pair of hygrometers that measured frost point (T(sub f)), the revised calibration equation is also cast in terms of frost point. Because of the complexity of maintaining very low temperatures and high R(sub H) in the laboratory, no calibration data exists at T is greater than 203K. However, sensor response during the mission was smooth and continuous down to 181 K. Therefore we have opted to include flight data in the calibration data set; selection was limited to data acquired during periods when the atmosphere is known to have been saturated. T(sub f) remained below 210 K throughout the mission(P is greater than 0.75 Pa). R(sub H), conversely, ranged from 1 to well under 0.01 diurnally, due to approximately 50 K temperature variations. To first order, both vapor pressure and its variance are greater during daylight hours. Variance in overnight humidity is almost entirely explained by temperature, while atmospheric turbulence contributes substantial variance to daytime humidity. Likewise, data gathered with the TECP aloft reflect higher H2O abundances than at the surface, as well as greater variance. There is evidence for saturation of the atmosphere overnight throughout much of the mission. In virtually every overnight observation, once the atmosphere cooled to T(sub f), water vapor begins to decrease, and tracks air temperature. There is no evidence for substantial decreases in water vapor prior to saturation, as expected for adsorptive exchange. Likewise, there is no evidence of local control of vapor by phases such as perchlorate hydrates hydrated minerals. The daytime average H2O pressure does not change substantially over the course of the mission, although the H2O column abundance varies by a factor of 2. Column abundances calculated from TECP data are lower than orbital measurements if one assumes that H2O is uniformly mixed through a single scale height. These results argue that the vertical distribution of H2O begins to change well in advance of surface concentrations as northern autumn approaches.

Phoenix Thermal and Electrical Conductivity Sensor↗

Reconciling Satellite-Derived Atmospheric Properties with Fine-Resolution Land Imagery: Insights for Atmospheric Correction

This paper investigates to what extent satellite measurements of atmospheric properties can be reconciled with fine-resolution land imagery, in order to improve the estimates of surface reflectance through physically based atmospheric correction. The analysis deals with mountainous area (Landsat scene of Peruvian Amazon/Andes, 72 E and 13 S), where the atmosphere is highly variable. Data from satellite sensors were used for characterization of the key atmospheric constituents: total water vapor (TWV), aerosol optical depth (AOD), and total ozone. Constituent time series revealed the season-dependent mean state of the atmosphere and its variability. Discrepancies between AOD from the Advanced Along-Track Scanning Radiometer (AATSR) and Moderate Resolution Imaging Spectroradiometer (MODIS) highlighted substantial uncertainty of atmospheric aerosol properties. The distribution of TWV and AOD over a Landsat scene was found to be exponentially related to ground elevation (mean R(sup 2) of 0.82 and 0.29, respectively). In consequence, the atmosphere-induced and seasonally varying bias of the top-of-atmosphere signal was also elevation dependent (e.g., mean Normalized Difference Vegetation Index bias at 500 m was 0.06 and at 4000 m was 0.01). We demonstrate that satellite measurements of key atmospheric constituents can be downscaled and gap filled with the proposed "background + anomalies" approach, to allow for a better compatibility with fine-resolution land surface imagery. Older images (i.e., predating the MODIS/ATSR era), without coincident atmospheric data, can be corrected using climatologies derived from time series of satellite retrievals. Averaging such climatologies over space compromises the quality of correction result to a much greater degree than averaging them over time. We conclude that the quality of both recent and older fine-resolution land surface imagery can be improved with satellite-based atmospheric data acquired to date.

Zelazowski, Przemyslaw↗

Volatiles on satellites of the outer solar system

Molecules of cosmochemically abundant elements can act as volatiles and hence play a dominant role in the climatic and surficial evolution of solid bodies. Examples on terrestrial planets are H2O on Earth and H2O and CO2 on Mars. Analogous processes in the outer solar system focussing on CH4, its associated hydrocarbons, and N2 on Titan and Triton, the large moons of Saturn and Neptune were explored. A kilometer-deep C2H6-CH4 ocean was proposed for the surface of Titan to reconcile data on the lower atmosphere with understanding of the photochemical conversion of methane to heavier hydrocarbons. If such ocean exists, then it has dissolved in it an amount of N2 equal to the present atmospheric abundance. Since N2 contributes with CH4 a substantial greenhouse effect, the atmospheric physical and chemical characteristics are strongly coupled to those of the ocean, which change with time as methane is photolyzed in the stratosphere. Some relationship exists to the runaway greenhouse model for primordial Venus and the possible climatic implications of the buffering of Earth's atmospheric CO2 by the oceans. Two important diagnostics, measurable in Titan's atmosphere, of the conditions under which icy satellites formed are the abundances of noble gases and the CHd/CH4 radio. Both of these indicators have been altered during the evolution of Titan's surface-atmosphere system, the former by interaction with the ocean and the latter by progressive photolysis of methane into heavier hydrocarbons. The physical state and composition of volatiles on the surface of Triton is controversial, but plausibly could include CH4 N2 and perhaps CO. If condensed CH4 and N2 are widespread, their transformation to and from the vapor phase dominates the surface energy balance with sunlight. The extreme seasonal modulation of subsolar latitude on Triton is thus primarily expressed by volatile transport rather than large teperature changes, with possibly drastic observational consequences. The presence of two volatile species differing greatly in their vapor pressures make Triton a crude analog of Mars. Triton might be more appropriately regarded as a deep-freeze version of Titan.

Lunine, J. I.↗

Effects of atmospheric structure on radiative heating for Jupiter entry probe

New estimates of the radiative heat load to a Jupiter entry probe have been obtained for revised models of Jupiter's atmosphere based on the latest data from Pioneer 10 and 11 missions and earth-based experiments. The new estimates of the radiative heat load are compared with results obtained for the previous atmospheric models. The changes in Jupiter's atmospheric models cause a substantial reduction in the radiative heat load for the atmosphere denoted as 'cool', but only moderate reductions for the atmospheres denoted as 'nominal' and 'warm'. Results are also presented showing the effects of inertial entry angle for off-equatorial entries in the revised model atmospheres.

Sutton, K.↗

Cosmic dust particle densities - Evidence for two populations of stony micrometeorites

The existence of two populations of stony micrometeorites of distinctly different densities would result in significantly different orbital evolution properties for particles from each group. The densities inferred from deceleration of meteors in the earth's atmosphere suggest a substantial amount of the meteoric material has densities of 1 g/cu cm or less (Verniani, 1973). However, measurements of microcraters on lunar rock surfaces led Brownlee et al. (1973) to the conclusion that most micrometeoroids impacting the moon had densities in the 2-4 g/cu cm range, and low-density micrometeoroids were rare. The recovery of stony micrometeorites from the earth's stratosphere after atmospheric deceleration provides the opportunity to resolve the discrepancies. Here, the densities of 12 stony micrometeorites are determined, using synchrotron X-ray fluorescence to infer the particle mass and optical microscope measurements of the volumes. The particles fall into two distinct density groups, with mean values of 0.6 and 1.9 g/cu cm. The factor of 3 difference in the mean densities between the two populations implies differences in the orbital evolution time scales.

Flynn, G. J.↗

The atmospheres of Io and other satellites

Voyager measurements of gaseous SO2 in a hot spot region and of ions of sulfur, oxygen, and SO2(+) in the plasma torus, combined with the groundbased measurements of SO2 frost on the surface, indicate that SO2 is perhaps the dominant constituent of Io's atmosphere. Indeed the ionosphere of Io can be sustained by a pure SO2 atmosphere in thermal equilibrium with the surface. Upper limits on common volatiles H2O, CO2, NH3, and CH4 and exceedingly small, although S2 and Ar may still be present. Photochemistry of SO2 could lead to O2 as the major gas on the night side. Reasonable processes for loss to the torus include thermal escape, sputtering, and sweep-up of ions. The symmetry of the sodium cloud between eastern and western elongation is difficult to reconcile with any substantial, diurnally varying atmosphere. Europa, Ganymede, and Callisto may have oxygen atmospheres resulting from photolysis of water vapor. A pressure of approximately 10 to the -6th microbar is predicted, consistent with the Voyager upper limit for Ganymede. A much higher pressure might be present if the water vapor pressure is increased by a low albedo (Callisto) or sputtering (Europa).

Kumar, S.↗

Hot season gets hotter due to rainfall delay over tropical land in a warming climate

Tropical land generally experiences the hottest period (spring) in a year just before the onset of wet season. Previous studies suggested that in a warming climate, the wet season would come later, but its origin is debated and its impact on temperature remains unknown. Here, we find that the warming of hot season would be amplified under global warming, and refer to it as “hot-season-gets-hotter” phenomenon. The amplified hot season warming is closely tied to the amplified warming of hot temperature percentiles. The hot-season-gets-hotter phenomenon is mainly due to the rainfall delay and most evident in the Amazon, where spring is warming by almost 1?K more than the annual mean and the 99th percentile temperatures are warming ~30% more than the mean by the end of 21st century in a high emission scenario. Comparing experiments with and without land-atmosphere coupling, it is further found that the rainfall delay is initially driven by the enhanced effective atmospheric heat capacity and then substantially amplified by positive soil moisture-atmosphere feedback. In the satellite period, observations consistently show that the hot-season-gets-hotter phenomenon has already emerged along with the rainfall delay in the Amazon. Intensified hot and dry spring climate can enhance risks of drought, heatwaves and wildfires, threatening the Amazon forest and habitats in the tropics.

54 ENVIRONMENTAL SCIENCES↗

Photochemical processes induced by a major warming of the upper atmosphere - Variations in mesospheric trace constituents

The temperature rise and enhanced winds during an upper atmospheric warming cause substantial changes in the high level ozone profile of the sunlit winter hemisphere. Calculations based on a photochemical model, using temperatures measured at Fort Churchill during a major warming, predict a factor of 2 variation in the ozone number density near 60 km over a time period of approximately 3 weeks. This temporal variability at a fixed location results from the planetary wave structure of the temperature field and reflects a similar longitudinal behavior at a given time. The ozone number density at fixed altitude is a maximum when the temperature is greatest at and below this level. This is due primarily to thermal expansion of the atmosphere which results in a large increase in pressure at constant altitude. However, chemical activity during a warming decreases the mesospheric ozone mixing ratio at fixed pressure. The ozone mixing ratio at constant pressure during the peak of the event studied is near 75% of its unperturbed value. The predicted variability of ozone in longitude and time demonstrates the need for hemispheric scale information on trace gas abundances, temperature, and winds in order to delineate adequately the response of upper atmospheric composition to a major perturbation.

Frederick, J. E.↗

Consideration of probability of bacterial growth for Jovian planets and their satellites

Environmental parameters affecting growth of bacteria are compared with current atmospheric models for Jupiter and Saturn, and with the available physical data for their satellites. Different zones of relative probability of growth are identified for Jupiter and Saturn. Of the more than two dozen satellites, only the largest (Io, Europa, Ganymede, Callisto, and Titan) are found to be interesting biologically. Titan's atmosphere may produce a substantial greenhouse effect providing increased surface temperatures. Models predicting a dense atmosphere are compatible with microbial growth for a range of pressures at Titan's surface. For Titan's surface the probability of growth would be enhanced if: (1) the surface is entirely or partially liquid; (2) volcanism is present; or (3) access to internal heat sources is significant.

Taylor, D. M.↗

Consideration of probability of bacterial growth for Jovian planets and their satellites

Environmental parameters affecting growth of bacteria (e.g., moisture, temperature, pH, and chemical composition) were compared with current atmospheric models for Jupiter and Saturn, and with the available physical data for their satellites. Different zones of relative probability of growth were identified for Jupiter and Saturn, with the highest in pressure regions of 1-10 million N/sq m (10 to 100 atmospheres) and 3-30 million N/sq m (30 to 300 atmospheres), respectively. Of the more than two dozen satellites, only the largest (Io, Europa, Ganymede, Callisto, and Titan) were found to be interesting biologically. Titan's atmosphere may produce a substantial greenhouse effect providing increased surface temperatures. Models predicting a dense atmosphere are compatible with microbial growth for a range of pressures at Titan's surface. For Titan's surface the probability of growth would be enhanced if (1) the surface is entirely or partially liquid (water), (2) volcanism (in an ice-water-steam system) is present, or (3) access to internal heat sources is significant.

Taylor, D. M.↗

Integrative Analysis of Desert Dust Size and Abundance Suggests Less Dust Climate Cooling

Desert dust aerosols affect Earths global energy balance through interactions with radiation, clouds, and ecosystems. But the magnitudes of these effects are so uncertain that it remains unclear whether atmospheric dust has a net warming or cooling effect on global climate. Consequently, it is still uncertain whether large changes in atmospheric dust loading over the past century have slowed or accelerated anthropogenic climate change, and the climate impact of possible future alterations in dust loading is similarly disputed. Here we use an integrative analysis of dust aerosol sizes and abundance to constrain the climatic impact of dust through direct interactions with radiation. Using a combination of observational, experimental, and model data, we find that atmospheric dust is substantially coarser than represented in current climate models. Since coarse dust warms global climate, the dust direct radiative effect (DRE) is likely less cooling than the 0.4 W m superscript 2 estimated by models in a current ensemble. We constrain the dust DRE to -0.20 (-0.48 to +0.20) W m superscript 2, which suggests that the dust DRE produces only about half the cooling that current models estimate, and raises the possibility that dust DRE is actually net warming the planet.

Atmospheric chemistry↗

Decomposing Cloud Radiative Feedbacks by Cloud-Top Phase

Changes in cloud scattering properties and emissivity that arise from atmospheric warming cause substantial radiative feedbacks in model projections of anthropogenic climate change, and the relative importance of the underlying mechanisms is poorly understood. One leading hypothesis is that ice-to-liquid conversions cause clouds to optically thicken, producing a major negative feedback. We test this hypothesis by developing a method to decompose cloud radiative feedbacks by cloud-top phase. The method is applied to an ensemble of six state-of-the-art global climate models run with prescribed sea surface temperature. In these simulations, the global mean of the net cloud scattering and emissivity feedback from cloud-phase conversions ranges from −0.17 to −0.01 W m −2 K −1 , while the overall net cloud feedback ranges from 0.02 to 0.91 W m −2 K −1 . The multimodel mean of the cloud scattering and emissivity feedback from cloud-phase conversions is approximately 19% of the magnitude of the multimodel mean of the overall cloud feedback (−0.10 vs 0.52 W m −2 K −1 ). These results indicate that cloud-phase conversions cause a robust negative feedback by changing cloud scattering and emissivity, but this mechanism makes a modest contribution to the overall cloud feedback at the global scale.

Climate change↗

The Great Dimming of Betelgeuse: A Surface Mass Ejection and Its Consequences

The bright supergiant, Betelgeuse(Alpha Orionis, HD 39801), underwent a historic optical dimming during 2020 January 27–February 13. Many imaging and spectroscopic observations across the electromagnetic spectrum were obtained prior to, during, and subsequent to this dimming event. These observations of Betelgeuse reveal that a substantial surface mass ejection (SME) occurred and moved out through the extended atmosphere of the supergiant. A photospheric shock occurred in 2019 January–March, progressed through the extended atmosphere of the star during the following 11 months and led to dust production in the atmosphere. Resulting from the substantial mass outflow, the stellar photosphere was left with lower temperatures and the chromosphere with a lower density. The mass ejected could represent a significant fraction of the total annual mass-loss rate from the star suggesting that episodic mass-loss events can contribute an amount comparable to that of the stellar wind. Following the SME, Betelgeuse was left with a cooler average photosphere, an unusual short photometric oscillation, reduced velocity excursions, and the disappearance of the∼400 day pulsation in the optical and radial velocity for more than two years following the Great Dimming.

M supergiant stars↗

Nitrogen fertiliser and stratospheric ozone - Latitudinal effects

Substantial increases in atmospheric N2O resulting from the increased use of nitrogen fertilizers might cause large (to 10%) decreases in the stratospheric ozone content. Such ozone decreases would be caused by catalytic reaction cycles involving odd-nitrogen that is formed by N2O decomposition in the upper stratosphere. Turco et al. (1978), using a background chlorine level of 2 ppbv, have shown that if the measured values of specified reactions are used a 50% increase in N2O would lead to a 2.7% increase in the stratospheric column density, although the ozone content above 30 km would be reduced by more than 5%; they also estimated (unpublished data) that the change in the ozone column density caused by doubling the N2O abundance would be very close to zero (within about 0.1%). The present paper extends these calculations of N2O/ozone effects to two dimensions, thereby identifying the latitude dependence expected for such ozone perturbations. The effects of changes in stratospheric chlorine levels on predicted ozone changes are also discussed.

Whitten, R. C.↗

The role of FGGE data in the understanding and prediction of atmospheric planetary waves

The augmented observational data base provided by FGGE offers a unique opportunity to improve the understanding and prediction of atmospheric planetary waves. Substantial progress was made, but a number of problems remain. The research on planetary waves conducted thus far with FGGE data is reviewed. Areas of progress are summarized, and some remaining problems are discussed.

Baker, W. E.↗