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At least 73 records · Page 4
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DOE OSTI2024

Hemispherically symmetric strategies for stratospheric aerosol injection

Stratospheric aerosol injection (SAI) comes with a wide range of possible design choices, such as the location and timing of the injection. Different stratospheric aerosol injection strategies can yield different climate responses; therefore, understanding the range of possible climate outcomes is crucial to making informed future decisions on SAI, along with the consideration of other factors. Yet, to date, there has been no systematic exploration of a broad range of SAI strategies. This limits the ability to determine which effects are robust across different strategies and which depend on specific injection choices. This study systematically explores how the choice of SAI strategy affects climate responses in one climate model. Here, we introduce four hemispherically symmetric injection strategies, all of which are designed to maintain the same global mean surface temperature: an annual injection at the Equator (EQ), an annual injection of equal amounts of SO 2 at 15° N and 15° S (15N+15S), an annual injection of equal amounts of SO 2 at 30° N and 30° S (30N+30S), and a polar injection strategy that injects equal amounts of SO 2 at 60° N and 60° S only during spring in each hemisphere (60N+60S). We compare these four hemispherically symmetric SAI strategies with a more complex injection strategy that injects different quantities of SO 2 at 30° N, 15° N, 15° S, and 30° S in order to maintain not only the global mean surface temperature but also its large-scale horizontal gradients. All five strategies are simulated using version 2 of the Community Earth System Model with the middle atmosphere version of the Whole Atmosphere Community Climate model, version 6, as the atmospheric component, CESM2(WACCM6-MA), with the global warming scenario, Shared Socioeconomic Pathway (SSP)2-4.5. We find that the choice of SAI strategy affects the spatial distribution of aerosol optical depths, injection efficiency, and various surface climate responses. In addition, injecting in the subtropics produces more global cooling per unit injection, with the EQ and the 60N+60S cases requiring, respectively, 59 % and 50 % more injection than the 30N+30S case to meet the same global mean temperature target. Injecting at higher latitudes results in larger Equator-to-pole temperature gradients. While all five strategies restore Arctic September sea ice, the high-latitude injection strategy is more effective due to the SAI-induced cooling occurring preferentially at higher latitudes. These results suggest trade-offs wherein different strategies appear better or worse, depending on which metrics are deemed important.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Resolved gravity waves in the tropical stratosphere: Impact of horizontal resolution and deep convection parametrization

Convectively generated gravity waves (CGGWs) are important for numerical weather prediction due to their effect on the quasi-biennial oscillation (QBO) in the stratosphere. Here, using global ECMWF IFS simulations at TCo7999 (or 1.25 km), TCo2559 (or 3.9 km) and TCo1279 (or 7.8 km) horizontal resolutions, sensitivity of resolved CGGWs to the horizontal resolution and to the explicit versus parametrized representation of deep convection is elucidated during the westerly shear phase of the QBO. Parametrized deep convection is found to inhibit CGGWs, resulting in a twofold reduction in CGGW forcing. When deep convection is explicitly resolved, the total CGGW forcing is almost unchanged across the horizontal resolutions. However, the contribution of long and mesoscale CGGWs (with horizontal wavelengths 100 km ≤ $λ_h$ < $1,900$ km) to the total CGGW forcing decreases and the contribution of smaller-scale CGGWs (with $λ_h$ < $100$ km) increases as the horizontal resolution increases. At the maximum CGGW forcing altitude, at TCo7999 resolution 43% of the total CGGW forcing is due to long and mesoscale waves, whereas at TCo2559 and TCo1279 resolutions their contribution is 70% and 90%, respectively. While CGGW forcing from long and mesoscale waves is similar at TCo7999 resolution with explicit deep convection and at TCo1279 resolution with parametrized deep convection, CGGW forcing from these waves is artificially enhanced at TCo1279 and TCo2559 resolutions with explicit deep convection. This is due to the explicit deep convection being too strong and having too much variance for 100 km ≤ $λ_h$ < $1,900$ km. Therefore, parametrizations of deep convection and CGGWs (to account for forcing from waves with $λ_h$ < $100$ km) are required even at TCo2559 resolution. Additionally, resolved CGGW forcing at TCo7999 resolution is examined for the easterly shear phase of the QBO; similar to the westerly shear phase, the smaller-scale waves contribute 55% to the total CGGW forcing at the maximum CGGW forcing altitude.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Implication of stratospheric aerosol geoengineering on compound precipitation and temperature extremes in Africa

Three Coupled Model Intercomparison Project 5 (CMIP5) models that simulated the G4 experiment of the Geoengineering Model Intercomparison Project (GeoMIP) were used to investigate the impact of stratospheric aerosol injection (SAI) on combined temperature and precipitation extremes in Africa that can have greater negative impacts on human and the environment than individual rainfall or temperature extremes. The examined compound extremes included the dry (R warm|dry and R cold|dry ) and wet (R warm|wet and R cold|wet ) modes assessed during the injection (SAI, 2050-2069) and post-injection (postSAI, 2070-2089) periods compared with the historical period (1986-2005). We found a significant projected change in the occurrence of both wet and dry modes during SAI and postSAI related to the historical period. The magnitude and sign of this change depend on the season and the geographical location. During the SAI and postSAI, the wet (R warm|wet and R cold|wet ) modes are projected to be significantly lower while the dry modes are noted to increase in a large part of African continent depending on the season and the geographical location and may consequently leads to an increase of the droughts prone areas. Furthermore, the termination effect is noted to re duce the occurrence of dry modes, which may reduce the potential negative effects of the injection after halting. As the effect may vary from one region to another and according to the season, it suggested assessing the key sector impacts of SAI. Thus, this change in dry modes due to SAI could affect all activities which depend on water resources such as water supply, agriculture and food production, energy demand, and production with adverse effects on health, security, and sustainable development, but this needs to be assessed and quantified at regional scales.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Pyrocumulonimbus Events Over British Columbia in 2017: An Ensemble Model Study of Parameter Sensitivities and Climate Impacts of Wildfire Smoke in the Stratosphere

Abstract The Pyrocumulonimbus (pyroCb) events over British Columbia in 2017 were observed in the lower stratosphere for about 8–10 months after the smoke injections. Several previous studies used global climate models to investigate the physical parameters for the 2017 pyroCb events, but the conclusions show strong model dependency. In this study, we use the Energy Exascale Earth System Model (E3SM) and complete an ensemble of runs exploring three injection parameters: smoke aerosol mass, the percentage of black carbon within the smoke aerosols, and plume injection height. Additionally, we consider the heterogeneous reaction of ozone and primary organic matter. According to the satellite daily observed aerosol optical depth (AOD), we find that the best ensemble member is the simulation with 0.4 Tg of smoke, 3% of which is black carbon, a 13.5 km smoke injection height, and a 10 −5 probability factor of the heterogeneous reaction. Besides AOD, we examine the ensemble score based on the metrics used in previous studies: the metrics of the extinction coefficient at 18 km altitude and the maximum plume height. The conclusion of the best estimate of the injection parameters for 2017 pyroCb events shows strong not only model but also evaluation metric dependency. We use the Random Forest machine learning technique to quantify the relative importance of each parameter in accurately simulating the 2017 pyroCb events and find that the injection height is the most critical feature, no matter which metric is used to score the ensemble members.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

Satellite Reentry Predictions During Sudden Stratospheric Warmings

Prediction of uncontrolled satellite reentry time and trajectory are essential to avoid damages to human being and properties over land. Reentry time and trajectory are largely controlled by aerodynamic drag and mass neutral density below 200 km. In this paper, using a numerical model of the whole atmosphere, WACCM‐X, and a Precision Orbital Determination software, we demonstrate the major sudden stratospheric warming (SSW) in January 2009, during the deep solar minimum of 2009, may cause 0.2–0.3 day of variation in reentry time. The SSW can alter the mass density and composition mixing ratio in the lower thermosphere below 200 km through changed wave forcing and general circulation in the lower thermosphere. This is comparable to the effect of a 2‐SFU (Solar Flux Unit) solar radiance variation on the neutral density. 0.1 day of reentry time uncertainty corresponds to a global shift in impact location, that is, thousands of kilometers distance. For comparison, a major SSW during solar maximum contributes little to reentry time variation, which is predominantly controlled by the solar and geomagnetic forcing. We suggest a few proxies such as O/N 2 in the lower thermosphere or mean meridional wind to account for the lower atmosphere impacts in an operational model. This needs to be investigated in rigorous future work.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

A subpolar-focused stratospheric aerosol injection deployment scenario

Stratospheric aerosol injection (SAI) is a prospective climate intervention technology that would seek to abate climate change by deflecting back into space a small fraction of the incoming solar radiation. While most consideration given to SAI assumes a global intervention, this paper considers an alternative scenario whereby SAI might be deployed only in the subpolar regions. Subpolar deployment would quickly envelope the poles as well and could arrest or reverse ice and permafrost melt at high latitudes. This would yield global benefit by retarding sea level rise. Given that effective SAI deployment could be achieved at much lower altitudes in these regions than would be required in the tropics, it is commonly assumed that subpolar deployment would present fewer aeronautical challenges. An SAI deployment intended to reduce average surface temperatures in both the Arctic and Antarctic regions by 2 °C is deemed here to be feasible at relatively low cost with conventional technologies. However, we do not find that such a deployment could be undertaken with a small fleet of pre-existing aircraft, nor that relegating such a program to these sparsely populated regions would obviate the myriad governance challenges that would confront any such deployment. Nevertheless, given its feasibility and potential global benefit, the prospect of subpolar-focused SAI warrants greater attention.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Resolved Gravity Waves in the Extratropical Stratosphere: Effect of Horizontal Resolution Increase from O (10) to O (1) km

Global ECMWF IFS simulations with horizontal grid spacings of 1, 4, and 9 km are used to assess gravity wave forcing (GWF) in the extratropical stratosphere. Results with important implications for GWF parameterizations at high and intermediate resolutions are presented. A doubling in the zonal-mean resolved GWF is observed when the horizontal resolution is increased from 9 to 1 km. Small-scale gravity waves with horizontal wavelengths < 100 km dominate this increase. Over most regions, excluding the polar night jet in the Antarctic spring, the total (resolved + parameterized) GWF at 9 km (4 km) is underestimated by up to 30% (15%). This implies that the parameterization of GWF is still required at 9 and 4 km horizontal resolutions. Despite the small land area in the Southern Hemisphere (SH), the resolved orographic and nonorographic GWF contribute equally to the total GWF in the SH at 1 km resolution. This is not reflected in the partitioning of the parameterized GWF, which has a significantly larger nonorographic contribution at 9 km. As a result, a zonal-mean momentum budget analysis reveals that the total GWF contributes one-third of SH springtime polar vortex deceleration at 1 km, whereas the contribution is as much as 50% at 9 km. In conclusion, this suggests that a rebalancing of the parameterized nonorographic and orographic GWF is required.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Performance assessment for climate intervention (PACI): preliminary application to a stratospheric aerosol injection scenario

As the prospect of exceeding global temperature targets set forth in the Paris Agreement becomes more likely, methods of climate intervention are increasingly being explored. With this increased interest there is a need for an assessment process to understand the range of impacts across different scenarios against a set of performance goals in order to support policy decisions. The methodology and tools developed for Performance Assessment (PA) for nuclear waste repositories shares many similarities with the needs and requirements for a framework for climate intervention. Using PA, we outline and test an evaluation framework for climate intervention, called Performance Assessment for Climate Intervention (PACI) with a focus on Stratospheric Aerosol Injection (SAI). We define a set of key technical components for the example PACI framework which include identifying performance goals, the extent of the system, and identifying which features, events, and processes are relevant and impactful to calculating model output for the system given the performance goals. Having identified a set of performance goals, the performance of the system, including uncertainty, can then be evaluated against these goals. Using the Geoengineering Large Ensemble (GLENS) scenario, we develop a set of performance goals for monthly temperature, precipitation, drought index, soil water, solar flux, and surface runoff. The assessment assumes that targets may be framed in the context of risk-risk via a risk ratio, or the ratio of the risk of exceeding the performance goal for the SAI scenario against the risk of exceeding the performance goal for the emissions scenario. From regional responses, across multiple climate variables, it is then possible to assess which pathway carries lower risk relative to the goals. The assessment is not comprehensive but rather a demonstration of the evaluation of an SAI scenario. Future work is needed to develop a more complete assessment that would provide additional simulations to cover parametric and aleatory uncertainty and enable a deeper understanding of impacts, informed scenario selection, and allow further refinements to the approach.

climate intervention↗
DOE OSTI2022

The Atlantic Jet Response to Stratospheric Events: A Regime Perspective

The tropospheric response to Sudden Stratospheric Warmings (SSWs) is associated with an equatorward shift in the midlatitude jet and associated storm tracks, while Strong Polar Vortex (SPV) events elicit a contrasting response. Recent analyses of the North Atlantic jet using probability density functions of a jet latitude index have identified three preferred jet latitudes, raising the question of whether the tropospheric response to SSWs and SPVs results from a change in relative frequencies of these preferred jet regimes rather than a systematic jet shift. We explore this question using atmospheric reanalysis data from 1979 to 2018 (26 SSWs and 33 SPVs), and a 202-years integration of the Whole Atmosphere Community Climate Model (92 SSWs and 68 SPVs). Following SSWs, the northern jet regime becomes less common and the central and southern regimes become more common. These changes occur almost immediately following “split” vortex events, but are more delayed following “displacement” events. In contrast, the northern regime becomes more frequent and the southern regime less frequent following SPV events. Following SSWs, composites of 500-hPa geopotential heights, surface air temperatures, and precipitation most closely resemble composites of the southern jet regime, and are generally opposite in sign to the composites of the northern jet regime. These comparisons are reversed following SPVs. Thus, one possible interpretation is that the two southernmost regimes appear to be favored following SSWs, while the southernmost regime becomes less common following SPVs.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Infrasound From a Buried Chemical Explosion Recorded on a Balloon in the Lower Stratosphere

Abstract Infrasound waveforms generated by natural and anthropogenic phenomena contain important clues about the size and nature of the event. We show that sensors on balloons in the lower stratosphere can record faithful representations of the near‐source acoustic wave field at unprecedented range. The acoustic signature of a buried chemical explosion recorded at a range of 56 km and an altitude of 21.8 km was nearly identical to that recorded on the ground 0.5 km from the epicenter, but absent on a ground sensor located 46 km away. Our results demonstrate that balloon‐borne infrasound techniques greatly increase the range at which well‐preserved acoustic representations of near‐source physics can be acquired, and that their propagation is simple to model. Our work has implications for monitoring remote regions of the earth for explosions, volcanic eruptions, and other phenomena. It also supports the prospect of balloon‐based infrasound seismology on Venus.

Bowman, Daniel C.↗
DOE OSTI2022

Topographically Scattered Infrasound Waves Observed on Microbarometer Arrays in the Lower Stratosphere

When an acoustic wave strikes a topographic feature, some of its energy is scattered. Sensors on the ground cannot capture these scattered signals when they propagate at high angles. We report observations of upwardly-scattered acoustic waves prior to refraction back to the ground, intercepting them with a set of balloon-borne infrasound microbarometers in the lower stratosphere over northern Sweden. We show that these scattered waves generate a coda whose presence can be related to topography beneath balloons and low-altitude acoustic ducts. The inclination of the coda signals changes systematically with time, as expected from waves arriving from scatterers successively closer to receivers. The codas are present when a temperature inversion channels infrasound from a set of ground chemical explosions along the ground, but are absent following the inversion's dissipation. Since scattering partitions energy away from the main arrival, these observations imply a mechanism of amplitude loss that had previously been inaccessible to measurement. As such, these data and results allow for a better comprehension of interactions between atmospheric infrasound propagation and the solid earth

58 GEOSCIENCES↗
DOE OSTI2023

High‐Latitude Stratospheric Aerosol Injection to Preserve the Arctic

Abstract Stratospheric aerosol injection (SAI) has been shown in climate models to reduce some impacts of global warming in the Arctic, including the loss of sea ice, permafrost thaw, and reduction of Greenland Ice Sheet (GrIS) mass; SAI at high latitudes could preferentially target these impacts. In this study, we use the Community Earth System Model to simulate two Arctic‐focused SAI strategies, which inject at 60°N latitude each spring with injection rates adjusted to either maintain September Arctic sea ice at 2030 levels (“Arctic Low”) or restore it to 2010 levels (“Arctic High”). Both simulations maintain or restore September sea ice to within 10% of their respective targets, reduce permafrost thaw, and increase GrIS surface mass balance by reducing runoff. Arctic High reduces these impacts more effectively than a globally focused SAI strategy that injects similar quantities of SO 2 at lower latitudes. However, Arctic‐focused SAI is not merely a “reset button” for the Arctic climate, but brings about a novel climate state, including changes to the seasonal cycles of Northern Hemisphere temperature and sea ice and less high‐latitude carbon uptake relative to SSP2‐4.5. Additionally, while Arctic‐focused SAI produces the most cooling near the pole, its effects are not confined to the Arctic, including detectable cooling throughout most of the northern hemisphere for both simulations, increased mid‐latitude sulfur deposition, and a southward shift of the location of the Intertropical Convergence Zone. For these reasons, it would be incorrect to consider Arctic‐focused SAI as “local” geoengineering, even when compared to a globally focused strategy.

Lee, Walker Raymond↗
DOE OSTI2022

Significant Effective Radiative Forcing of Stratospheric Wildfire Smoke

Abstract The radiative forcing (RF) of volcanic sulfate is well quantified. However, the RF of pyrocumulonimbus (pyroCb) smoke with absorbing carbonaceous aerosols has not been considered in climate assessment reports. With the Community Earth System Model, we studied two record‐breaking wildfire events, the 2017 Pacific Northwest Event (PNE) and the 2019–2020 Australian New Year event (ANY), that perturbed stratospheric chemistry and the earth's radiation budget. We calculated a global annual‐mean effective RF (ERF) of −0.04 ± 0.02 and −0.17 ± 0.02 W/m 2 at the top of the atmosphere (TOA) for PNE and ANY, respectively. The complexity of longwave RF led to an uncertainty of about 50% in the ERF at the TOA among climate models. We found that modeled ERF from wildfire smoke was 70%–270% more negative than the ERF of mass‐equivalent sulfate aerosol, highlighting its important role in the climate radiative budget.

Liu, Cheng‐Cheng↗
DOE OSTI2022

Recent Trends in Transport of Surface Carbonaceous Aerosols to the Upper-Troposphere-Lower-Stratosphere Linked to Expansion of the Asian Summer Monsoon Anticyclone

Using Modern-Era Retrospective analysis for Research and Applications Version-2 (MERRA-2) re-analyses, we have examined recent trends (2000–2019) in transport of surface carbonaceous aerosols (CAs), that is, organic carbon and black carbon, to the upper troposphere and lower stratosphere (UTLS) during the Asian summer monsoon (ASM). We find a significant increased concentration of UTLS CA, linked to a linear trend in an expansion of the Asian Summer Monsoon Anticyclone (ASMA). Over core monsoon latitudes (25°–35°N), the trends in UTLS CA are enabled by increased upward transport from surface sources via an intensified monsoon meridional circulation, with increased latent heating over the southern Tibetan Plateau and foothill regions, enhanced by feedback processes associated with radiative heating by UTLS CA. In the extra-tropics, increased UTLS CA stems primarily from an extended source of increased wildfire emissions over eastern Siberia and northern Asia, coincident with a large-scale anomalous anticyclone with enhanced surface warming and drying near (80°–120°E, 55°–70°N). Here, CAs are transported upward from the surface to the ULS, likely by increased pyro-convection associated with enhanced wildfires, and enter the tropical UTLS via increased equatorward transport on the eastern flanks of anomalous upper-level anticyclones, coupled to the expanded ASMA. Overall, the increasing UTLS CA trends associated with expansion of the ASMA are consistent with a hydrostatic expansion of a warming troposphere, reflected in a rise in the tropical tropopause and consequential dynamical adjustments of the ASM subtropical jetstream, modulating the climate of the greater ASM region.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Different Strategies of Stratospheric Aerosol Injection Would Significantly Affect Climate Extreme Mitigation

Abstract Stratospheric aerosol injection (SAI) has been proposed as a potential supplement to mitigate some climate impacts of anthropogenic warming. Using Community Earth System Model ensemble simulation results, we analyze the response of temperature and precipitation extremes to two different SAI strategies: one injects SO 2 at the equator to stabilize global mean temperature and the other injects SO 2 at multiple locations to stabilize global mean temperature as well as the interhemispheric and equator‐to‐pole temperature gradients. Our analysis shows that in the late 21st century, compared with the present‐day climate, both equatorial and multi‐location injection lead to reduced hot extremes in the tropics, corresponding to overcooling of the mean climate state. In mid‐to‐high latitude regions, in comparison to the present‐day climate, substantial decreases in cold extremes are observed under both equatorial and multi‐location injection, corresponding to residual winter warming of the mean climate state. Both equatorial and multi‐location injection reduce precipitation extremes in the tropics below the present‐day level, associated with the decrease in mean precipitation. Overall, for most regions, temperature and precipitation extremes show reduced change in response to multi‐location injection than to equatorial injection, corresponding to reduced mean climate change for multi‐location injection. In comparison with equatorial injection, in response to multi‐location injection, most land regions experience fewer years with significant change in cold extremes from the present‐day level, and most tropical regions experience fewer years with significant change in hot extremes. The design of SAI strategies to mitigate anthropogenic climate extremes merits further study.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

The Potential of Stratospheric Aerosol Injection to Reduce the Climatic Risks of Explosive Volcanic Eruptions

Sulfur-rich volcanic eruptions happen sporadically. If Stratospheric Aerosol Injection (SAI) were to be deployed, it is likely that explosive volcanic eruptions would happen during such a deployment. Here we use an ensemble of Earth System Model simulations to show how changing the injection strategy post-eruption could be used to reduce the climate risks of a large volcanic eruption; the risks are also modified even without any change to the strategy. For a medium-size eruption (10 Tg-SO 2 ) comparable to the SAI injection rate, the volcanic-induced cooling would be reduced if it occurs under SAI, especially if artificial sulfur dioxide injections were immediately suspended. Alternatively, suspending injection only in the eruption hemisphere and continuing injection in the opposite would reduce shifts in precipitation in the tropical belt and thus mitigate eruption-induced drought. Finally, we show that for eruptions much larger than the SAI deployment, changes in SAI strategy would have minimal effect.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Stratospheric Aerosol Injection Can Reduce Risks to Antarctic Ice Loss Depending on Injection Location and Amount

Owing to increasing greenhouse gas emissions, the Antarctic Ice Sheet is vulnerable to rapid ice loss in the upcoming decades and centuries. Here this study examines the effectiveness of using stratospheric aerosol injection (SAI) that minimizes global mean temperature (GMT) change to slow projected 21st century Antarctic ice loss. We simulate 11 different SAI cases which vary by the latitudinal location(s) and the amount(s) of the injection(s) to examine the climatic response near Antarctica in each case as compared to the reference climate at the turn of the last century. We demonstrate that injecting at a single latitude in the northern hemisphere or at the Equator increases Antarctic shelf ocean temperatures pertinent to ice shelf basal melt, while injecting only in the southern hemisphere minimizes this temperature change. We use these results to analyze the results of more complex multi-latitude injection strategies that maintain GMT at or below 1.5°C above the pre-industrial. All these multi-latitude cases will slow Antarctic ice loss relative to the mid-to-late 21st century SSP2-4.5 emissions pathway. Yet, to avoid a GMT threshold estimated by previous studies pertaining to rapid West Antarctic ice loss (1.5°C above the pre-industrial GMT, though large uncertainty), our study suggests SAI would need to cool about 1.0°C below this threshold and predominately inject at low southern hemisphere latitudes (~15°S - 30°S). These results highlight the complexity of factors impacting the Antarctic response to SAI and the critical role of the injection strategy in preventing future ice loss.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Stratospheric ozone depletion in the Antarctic region triggers intense changes in sea salt aerosol geochemistry

Abstract Since the early 1980s, the Antarctic environment has served as a natural field laboratory for researchers to investigate the effects of stratospheric ozone depletion, which has resulted in increased surface ultraviolet radiation levels. However, its effective threats still present gaps. We report new pieces of evidence of increased ultraviolet radiation impacting West Antarctica sea salt aerosols. Salt aerosols, particularly in the Southern Ocean Sea, play an important role in the radiative earth balance. To disclose the molecular details of sea salt aerosols, we used a synchrotron-based multi-element microscopic speciation of individual microparticles (Scanning Transmission X-ray Microscopy with Near-Edge X-ray Absorption Fine Structure Spectroscopy combined with Computer-Controlled Scanning Electron Microscopy). Here we identified substantial abundances of chlorine-enriched aerosols in sea salt generated by photolytic products, whereas ice core records revealed increased chlorine depletion from the onset of ozone depletion. Our findings reveal that modern sea salt modification has no Holocene precedent.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗