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At least 73 records · Page 4

Organisation of Diverse Mechanisms of Secondary Ice Production among Basic Convective and Stratiform Cloud-types

This 3-year DoE-funded joint project had the over-arching aim of understanding how ice is initiated in clouds of various types. Focus was given to processes of fragmentation of pre-existing ice, which can occur in positive feedback loops (‘ice multiplication’). A basic question to address was which fragmentation processes prevail in which basic cloud-types. The approach was to use cloud models and field observations, while pioneering our own lab observations of ice initiation to break the deadlock from the past lack of lab observations. Historically, the tendency of the cloud physics community to avoid doing lab observations has allowed a vast gap in knowledge about ice initiation to persist for decades. During the first part of the project, new formulations were created to treat two overlooked types of fragmentation of ice. First, sublimational breakup of ice was treated based on a theoretical formula that we fitted to a pooled dataset of lab observations published previously in the literature. Second, a new mode of fragmentation of freezing raindrops was treated, which involves a supercooled drop being hit by a more massive ice particle. Some of the secondary droplets from the impact freeze. This work was done at Manchester University by Co-I Connolly. Then during the second part, both formulations were implemented in our ‘aerosol-cloud model’ (AC). AC has a hybrid bin/bulk microphysics scheme, and now represents four processes of SIP. The accuracy of AC was evaluated for four cases typifying four basic cloud-types: slightly cold-based stratiform cloud and cold-, warm- and very warm-based convective clouds. We discovered that the warmth of cloud-base, especially in the tropics, promotes SIP processes of raindrop-freezing fragmentation and rime-splintering, and surprisingly, sublimational breakup too. It was found that breakup in ice-ice collisions is ubiquitous. Finally, a portable laboratory chamber was constructed at Lund and deployed in northern Sweden to observe breakup in graupel-snow collisions outdoors. This was seen to be even more prolific than treated in our 2018 formulation. Papers describing results are either published or soon to be published.

54 ENVIRONMENTAL SCIENCES↗

Growth and Stability of Stratiform Carrollite (CuCo2S4) in the Tenke-Fungurume Ore District, Central African Copperbelt

Abstract Carrollite (CuCo2S4) is the main ore mineral of the critical battery metal cobalt, yet, surprisingly, detailed characterization of its thermodynamic properties and of its trace element contents remain sparse in the scientific literature. To fill these knowledge gaps, we generated the first thermodynamic data set for carrollite using well-characterized samples obtained from the stratiform sulfide mineralization style at Fungurume 88 deposit in the Democratic Republic of Congo. Detailed mineralogical investigation of these same samples suggests that carrollite has limited ability to incorporate other ‘sweetener’ elements (except Cu and Ni) by substitution mechanisms. Modeling using CHNOSZ 2.0.0. software and an integrated Cu-Co-S-O thermodynamic data set provides insights into the stability of carrollite relative to other Co-bearing minerals under physicochemical conditions relevant to the Central African Copperbelt. Further exploration of these models indicates that dropping redox potential in the mineralizing system is insufficient to explain the mineral-scale and deposit-scale zonation patterns commonly observed in Cu-Co deposits of the Central African Copperbelt. Instead, factors such as increasing pH, decreasing T, decreasing sulfur activity, or some combination of changing physicochemical parameters may need to be invoked to explain these zonation trends. At the Fungurume 88 deposit, the absence of linnaeite (Co3S4) suggests that ore precipitation occurred at temperatures cooler than 211 °C. From our pH-logfO2 diagrams, and relative to higher temperatures, such a lower T regime is marked by a greater degree of offset between the modeled Cu and Co solubility contours, thus facilitating a more differentiated and zoned distribution of these two metals at the deposit scale. Our models are offered to the geoscience community as exceptionally useful tools for modeling and visualizing the Cu-Co-S-O systematics and may be applied to a variety of geological and geometallurgical questions in the Central African Copperbelt and other deposits elsewhere.

Mineralogy↗

Comprehensive quantification of height dependence of entrainment mixing between stratiform cloud top and environment

Different entrainment-mixing processes of turbulence are crucial to processes related to clouds; however, only a few qualitative studies have been concentrated on the vertical distributions of entrainment-mixing mechanisms with low vertical resolutions. To quantitatively study vertical profiles of entrainment-mixing mechanisms with a high resolution, the stratiform clouds observed in the Physics of Stratocumulus Top (POST) project are examined. The unique sawtooth flight pattern allows for an examination of the vertical distributions of entrainment-mixing mechanisms with a 5 m vertical resolution. Relative standard deviation of volume mean radius divided by relative standard deviation of liquid water content is introduced to be a new estimation of microphysical homogeneous mixing degree, to overcome difficulties of determining the adiabatic microphysical properties required in existing measures. The vertical profile of this new measure indicates that entrainment-mixing mechanisms become more homogeneous with decreasing altitudes and are consistent with the dynamical measures of Damköhler number and transition scale number. Further analysis shows that the vertical variation of entrainment-mixing mechanisms with decreasing altitudes is due to the increases of turbulent dissipation rate in cloud and relative humidity in droplet-free air and the decrease of size of droplet-free air. The results offer insights into the theoretical understanding and parameterizations of vertical variation of entrainment-mixing mechanisms.

54 ENVIRONMENTAL SCIENCES↗

Meteorological Analysis of Icing Conditions Encountered in Low-Altitude Stratiform Clouds

Liquid-water content, droplet size, and temperature data measured during 22 flights in predominatly stratiform clouds through the 1948-49 and the 1949-50 winters are presented. Several icing encounters were of greater severity than those previously measured over the same geographical area, but were within the limits of similar measurements obtained over different terrain within the United States. An analysis of meteorological conditions existing during the 74 flights conducted for four winters indicated an inverse relation of liquid-water concentration to maximum horizontal extent of icing clouds. Data on the vertical extent of supercooled clouds are also presented. Icing conditions were most likely to occur in the southwest and northwest quadrants of a cyclone area, and least likely to occur in the southeast and northeast quadrants where convergent air flow and lifting over the associated warm frontal surface usually cause precipitation. Additional data indicated that, icing conditions were usually encountered in nonprecipitating clouds existing at subfreezing temperatures and were unlikely over areas where most weather observing stations reported the existence of precipitation. Measurements of liquid-water content obtained during 12 flights near the time and location of radiosonde observations were compared with theoretical values. The average liquid-water content of a cloud layer, as measured by the multicylinder technique, seldom exceeded two-thirds of that which could be released by adiabatic lifting. Local areas near the cloud tops equaled or occasionally exceeded the calculated maximum quantity of liquid water.

Kline, D. B.↗

Analysis of Meteorological Data Obtained During Flight in a Supercooled Stratiform Cloud of High Liquid-Water Content

Flight icing-rate data obtained in a dense and. abnormally deep supercooled stratiform cloud system indicated the existence of liquid-water contents generally exceeding values in amount and extent previously reported over the midwestern sections of the United States. Additional information obtained during descent through a part of the cloud system indicated liquid-water contents that significantly exceeded theoretical values, especially near the middle of the cloud layer.. The growth of cloud droplets to sizes that resulted in sedimentation from the upper portions of the cloud is considered to be a possible cause of the high water contents near the center of the cloud layer. Flight measurements of the vertical temperature distribution in the cloud layer indicated a rate of change of temperature with altitude exceeding that of the moist adiabatic lapse rate. This excessive rate of change is considered to have contributed to the severity of the condition.

Perkins, Porter J.↗

The photochemistry of a remote marine stratiform cloud

The coupled gas- and aqueous-phase photochemistry of a stratiform cloud in a remote region of the marine atmosphere is investigated with a time-dependent box model. Both scavenging of ambient acidic aerosols and gases as well as aqueous-phase chemical reactions within droplets are found to be important sources of acidity to cloud water and can lead to pH levels in cloud water in the remote marine atmosphere well below 5.6. The major sources of acidity via aqueous-phase chemical reactions are the generation of sulfuric acid from dissolved SO2 and the generation of formic acid from dissolved formaldehyde. In both cases, aqueous-phase free radicals can play a significant role either directly by oxidizing dissolved SO2 and HCHO or indirectly by producing the aqueous-phase oxidant H2O2. The rate of SO2 conversion to sulfuric acid is sensitive to a variety of parameters including the accommodation or sticking coefficient for SO2, H2O2, HO2, and OH, the liquid water content, and the ambient levels of SO2, HNO3, and other acidic or basic gases. Because high levels of SO2 tend to deplete cloud water of H2O3, the possibility exists that the pH of precipitation in polluted regions will respond nonlinearly to reduced SO2 emissions.

Chameides, W. L.↗

A satellite infrared technique to estimate tropical convective and stratiform rainfall

A new method of estimating both convective and stratiform precipitation from satellite infrared data is described. This technique defines convective cores and assigns rain rate and rain area to these features based on the infrared brightness temperature and the cloud model approach of Adler and Mack (1984). The method was tested for four south Florida cases during the second Florida Area Cumulus Experiment, and the results are presented and compared with three other satellite rain estimation schemes.

Adler, Robert F.↗

Reflectivities of uniform and broken stratiform clouds: An update

The reflectivities of uniform and broken stratiform clouds obtained from the NOAA-9 and NOAA-10 overpasses collected during the FIRE Marine Stratocumulus Intensive Field Observations (IFO) were compared, and these reflectivities were compared with those obtained through radiative transfer calculation performed for plane-parallel cloud models. The objective was to determine the extent to which plane-parallel radiative transfer calculations could reproduce the reflectivities observed for uniform clouds and to determine the extent to which finite cloud effects cause broken clouds to reflect differently than uniform clouds. The latter study is to provide guidance in the parameterization of finite cloud effects in general circulation climate models as well as to assess the ability of plane-parallel theory, which is used by ISCCP to retrieve cloud properties, to treat the reflectivities of broken clouds. Some results from this study were reported at the last FIRE Science Team meeting and some were reported elsewhere (Coakley and Briegleb, 1989). Improvements since the previous reports include: (1) the analysis of additional satellite passes, and (2) a modification to the analysis which helps to show the significance of the differences in reflectivities for uniform and broken clouds.

Coakley, James A., Jr.↗

Flux divergence of thermal radiation within stratiform clouds

A longwave radiative transfer model based on the narrow-band transmission functions of Lowtran 6 has been developed to investigate the profile of radiative flux divergence at the tops of stratiform clouds. The model has a vertical resolution of 1 m and a spectral resolution of 20/cm. These features are shown to permit modeling of broadband radiative transfer in the presence of a cloud top inversion and finite liquid water gradient. Radiative cooling rates in excess of 40 K/hr are shown to be possible for extreme conditions, with values of 10 K/hr being representative of more typical conditions. The values obtained are shown to be strongly influenced by the magnitude of liquid water concentration, by the gradient of liquid water in the top 50 m, and by the strength of the temperature inversion.

Davies, Roger↗

Estimates of GATE convective and stratiform rainfall derived from radar and satellite data

The statistics of tropical rain system structure are studied, focusing on the division between convective and stratiform rainfall over the GARP Atlantic Tropical Experiment B-scale array. The satellite IR convective/stratiform technique of Adler and Negri (1988) is used to produce hourly estimates for two day of the GATE. The estimates are verified against the radar data. The results are compared with the results of Houze and Rappaport (1984) and Cheng and Houze (1979). The possible application of the results for estimating the vertical profile of latent heating is discussed.

Negri, Andrew J.↗

Model simulations of rainout and washout from a warm stratiform cloud

A one-dimensional, time-dependent cloud model with parameterized microphysics is used to investigate the processes which control the rainout and washout of soluble gases from warm, precipitating stratiform clouds. Calculations are presented simulating the distributions of soluble species within and below the cloud layer and in the precipitating raindrops as a function of time and species' solubility. Calculations indicate that for species with low solubility, wet removal processes are relatively slow and thus do not significantly affect the species' gas-phase abundance. As a result, the removal of low-solubility species by rainout and washout is controlled by thermodynamic processes with the concentration of the species in cloud and rainwater largely determined by the species' solubility. For highly soluble species on the other hand, dissolution into cloud droplets and removal in rain is quite rapid and the abundance of highly soluble species within and below the cloud falls rapidly as soon as the precipitation begins.

Xing, Lin↗

Model simulations of rainout and washout from a warm stratiform cloud

Calculations utilizing a one-dimensional, time-dependent stratiform cloud model with parameterized microphysics to study the washout and rainout of soluble trace gases are presented. It is shown that the in-cloud concentrations of relatively insoluble species remain essentially unaffected by the presence of cloudwater and rainwater, while the concentrations of highly soluble species are rapidly depleted within the cloud. Due to this depletion it is shown that for highly soluble species the below-cloud scavenging via washout can dominate over in-cloud scavenging via rainout; in-cloud, aqueous-phase cloudwater and rainwater concentrations can differ considerably and, near the cloudbase, cloudwater concentrations can exceed rainwater concentrations by factors of two to ten.

Xing, Lin↗

Satellite retrievals of marine stratiform cloud systems

The initial validation of a satellite-based cloud retrieval scheme of the spatial-coherence type that is being used to create a marine stratiform cloudiness (MSC) climatology is discussed. Initial results are presented which describe correlations between MSC properties and SST, which could be useful for providing guidelines for assessing potential climate feedbacks regarding these cloud types. The correlation of triangle-technique- and spatial-coherence-method-derived fractional cloud covers together with the regression line for all data points is shown.

Molnar, Gyula I.↗

Aircraft observations of the vertical structure of stratiform precipitation relevant to microwave radiative transfer

The retrieval of rainfall intensity over the oceans from passive microwave observations is based on a radiative transfer model. Direct rainfall observations of oceanic rainfall are virtually nonexistent making validation of the retrievals extremely difficult. Observations of the model assumptions provide an alternative approach for improving and developing confidence in the rainfall retrievals. In the winter of 1983, the NASA CV-990 aircraft was equipped with a payload suitable for examining several of the model assumptions. The payload included microwave and infrared radiometers, mirror hygrometers, temperature probes, and PMS probes. On two occasions the aircraft ascended on a spiral track through stratiform precipitation providing an opportunity to study the atmospheric parameters. The assumptions concerning liquid hydrometeors, water vapor, lapse rate, and nonprecipitating clouds were studied. Model assumptions seem to be supported by these observations.

Chang, A. T. C.↗

The seasonal cycle of low stratiform clouds

The seasonal cycle of low stratiform clouds is studied using data from surface-based cloud climatologies. The impact of low clouds on the radiation budget is illustrated by comparison of data from the Earth Radiation Budget Experiment with the cloud climatologies. Ten regions of active stratocumulus convection are identified. These regions fall into four categories: subtropical marine, midlatitude marine, Arctic stratus, and Chinese stratus. With the exception of the Chinese region, all the regions with high amounts of stratus clouds are over the oceans. In all regions except the Arctic, the season of maximum stratus corresponds to the season of greatest lower-troposphere static stability. Interannual variations in stratus cloud amount also are related to changes in static stability. A linear analysis indicates that a 6 percent increase in stratus fractional area coverage is associated with each 1 C increase in static stability. Over midlatitude oceans, sky-obscuring fog is a large component of the summertime stratus amount. The amount of fog appears to be related to warm advection across sharp gradients of SST.

Klein, Stephen A.↗

Characteristics of the vertical profiles of dual-frequency, dual-polarization radar data in stratiform rain

Airborne dual-wavelength and dual-polarization radar data are analyzed for measurements taken in stratiform rain in the western Pacific during September 1990. The focus of the paper is on the vertical profiles of the linear depolarization ratio, LDR (10 GHz); the reflectivity factor, dBZ (10 GHz); and the dual-frequency ratio, DFR (10, 34.45 GHz). Statistical characterizations of the maxima of these quantities and the relative locations at which they occur suggest that the eccentricity of the melting particles is fairly large and that the shape and size of the particles are correlated. To try to explain these features, two types of simulation are presented. In the first, a set of measured drop size distributions is used in the context of a standard model of the melting layer. Variations in snow density, as well as shape, size, and orientation distributions are used to study the relationship between these parameters and the radar measurements. To reduce the amount of ambiguity in the estimation, a second type of simulation is described in which the size distribution of the snow is estimated. Comparisons between the simulated and measured profiles indicate that radar measurements can be used to derive certain characteristics of the particle size and shape distributions in the melting layer.

Meneghini, R.↗