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At least 73 records · Page 4

All sources NASA NTRS DOE OSTI

DOE OSTI2026

Influence of controlled disorder on the dipolar spin-ice state of Ho-based pyrochlores

Pyrochlore magnets of the form 𝑅 2 ⁢𝐵 2 ⁢O 7 , in which rare-earth ions on the 𝑅 site form a three-dimensional network of corner-sharing tetrahedra, provide a canonical setting for geometrical frustration. Ho-based pyrochlores host a dipolar spin-ice ground state, characterized by Ising moments constrained by the ice rules and elementary excitations analogous to magnetic monopoles. Here, in this work, we examine how controlled chemical disorder influences this state by introducing site mixing on the nonmagnetic 𝐵 site in two compounds. Ho 2⁢ GaSbO 7 contains only Ga 3+ /Sb 5+ charge disorder, whereas Ho 2 ⁢ScSbO 7 exhibits both charge and substantial size disorder arising from the large ionic-radius mismatch between Sc 3+ and Sb 5+ . Although both materials retain the pyrochlore structure, neutron-scattering measurements reveal a reduced correlation length for the 𝑅/𝐵-site cation ordering and enhanced local structural distortions in Ho 2 ⁢ScSbO 7 . Despite these structural differences, bulk thermodynamic measurements and magnetic diffuse scattering demonstrate that both systems exhibit the defining signatures of a dipolar spin-ice state. Low-energy inelastic neutron spectroscopy further uncovers broad magnetic excitations that develop within the dipolar spin-ice regime, a feature absent in pristine Ho pyrochlores and indicative of disorder-induced splitting of the non-Kramers ground-state doublet. Together, these results show that controlled disorder generates tunable transverse-field-driven quantum fluctuations in Ho-based pyrochlores, although the dipolar spin-ice state is remarkably robust to this disorder.

magnetic anisotropy↗

DOE OSTI2025

Bridge connectivity effects on photoinduced ground-state electron spin polarization

Transient electron paramagnetic resonance (TREPR) spectroscopy has been used to probe photoinduced electron spin polarization in the recovered ground states of four radical-elaborated (CAT)Pt(bpy) donor-acceptor complexes (CAT = catechol; bpy = 4,4'-di-tert-butyl-2,2'-bipyridine). These complexes are comprised of one or two S = 1/2 nitronyl nitroxide radicals attached through different phenylethynyl bridges to the 3- or 3,6 positions of the CAT donor. In this paper, we demonstrate the effects of substitution patterns on the magnitude of the TREPR signal, thereby guiding future design principles for generating and understanding the origin of photoinduced electron spin polarization in these and related chromophores.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2024

Measurements of the branching fractions of the P -wave charmonium spin-singlet state h c ( P 1 1 ) → h + h − π 0 / η

Based on ( 2712.4 ± 14.3 ) × 10 6 ψ ( 3686 ) events, we investigate four hadronic decay modes of the P -wave charmonium spin-singlet state h c ( 1 P 1 ) → h + h − π 0 / η ( h = π or K ) via the process ψ ( 3686 ) → π 0 h c at BESIII. The h c → π + π − π 0 decay is observed with a significance of 9.6 σ after taking into account systematic uncertainties. Evidences for h c → K + K − π 0 and h c → K + K − η are found with significances of 3.5 σ and 3.3 σ , respectively, after considering the systematic uncertainties. The branching fractions of these decays are measured to be B ( h c → π + π − π 0 ) = ( 1.36 ± 0.16 ± 0.14 ) × 10 − 3 , B ( h c → K + K − π 0 ) = ( 3.26 ± 0.84 ± 0.36 ) × 10 − 4 , and B ( h c → K + K − η ) = ( 3.13 ± 1.08 ± 0.38 ) × 10 − 4 , where the first uncertainties are statistical and the second are systematic. No significant signal of h c → π + π − η is found, and the upper limit of its decay branching fraction is determined to be B ( h c → π + π − η ) < 4.0 × 10 − 4 at the 90% confidence level. Published by the American Physical Society 2024

Astronomy & Astrophysics↗

DOE OSTI2025

Potential for tensor polarized deuterons in Hall D at Jefferson lab

Hall D at Jefferson lab is an ideal place to install a polarized deuteron target which can be “tensor polarized”, allowing the separation of the spin states m = 0, ±1 or the measurement of tensor asymmetries. The bremsstrahlung photon beam with 3 - 12 GeV endpoint provides very little heating or radiation damage compared to an electron beam, allowing the target to be run in frozen spin mode. Adiabatic fast passage spin manipulations can then be used to greatly enhance the population of the m = 0 spin state of the deuteron. Coherent photoproduction of ρ mesons from deuterium is sensitive to double-scattering at high momentum transfer and in the m = 0 spin state an additional sensitivity at intermediate momentum transfer opens up. In conclusion, we propose a frozen spin target for Hall D and the measurement of ρ photoproduced coherently from the deuteron as a flagship measurement.

43 PARTICLE ACCELERATORS↗

NASA NTRS1987

Quantized synchrotron radiation in strong magnetic fields

Spectra from electrons making synchrotron transitions in high magnetic fields are calculated using the exact quantum transition rates for Landau states up to n = 500, and the results are compared with spectra calculated from the classical formula and the asymptotic quantum formula. The behavior of the transition rates are examined at low and high harmonics as a function of the spin state of the electron. The calculations confirm those of Herold, Ruder, and Wunner (1982) for low Landau states, extending them to higher states and individual spin state transitions. The results also confirm the dominance of ground-state transitions at high field strengths noted by White (1976). Single particle emissivities for electrons with both spin-up and spin-down in the initial state are calculated using these transition rates. Spectra for thermal electron distributions at transrelativistic temperatures and for steady state injection of monoenergetic electrons with isotropic pitch angles are also presented.

Harding, Alice K.↗

NASA NTRS1973

Feasibility test of a solid state spin-scan photo-imaging system

The feasibility of using a solid-state photo-imaging system to obtain resolution imagery from a Pioneer-type spinning spacecraft in future exploratory missions to the outer planets is discussed. Evaluation of the photo-imaging system performance, based on electrical video signal analysis recorded on magnetic tape, shows that the signal-to-noise (S/N) ratios obtained at low spatial frequencies exceed the anticipated performance and that measured modulation transfer functions exhibited some degradation in comparison with the estimated values, primarily owing to the difficulty in obtaining a precise focus of the optical system in the laboratory with the test patterns in close proximity to the objective lens. A preliminary flight model design of the photo-imaging system is developed based on the use of currently available phototransistor arrays. Image quality estimates that will be obtained are presented in terms of S/N ratios and spatial resolution for the various planets and satellites. Parametric design tradeoffs are also defined.

Laverty, N. P.↗

NASA NTRS2019

Mercury's Internal Structure

We describe the current state of knowledge about Mercury's interior structure. We review the available observationalconstraints, including mass, size, density, gravity eld, spin state, composition, and tidal response. These data enablethe construction of models that represent the distribution of mass inside Mercury. In particular, we infer radial prolesof the pressure, density, and gravity in the core, mantle, and crust. We also examine Mercury's rotational dynamicsand the inuence of an inner core on the spin state and the determination of the moment of inertia. Finally, we discussthe wide-ranging implications of Mercury's internal structure on its thermal evolution, surface geology, capture in aunique spin-orbit resonance, and magnetic eld generation.

Mercury↗

DOE OSTI2026

Spin Polarization from Circularly Polarized Light Induced Charge Transfer

Here, we show how a spin polarization can be generated through the photoinduced electron transfer of an achiral donor–acceptor complex following chiral light excitation. In particular, we illustrate the basic energetic and symmetry requirements for chirality induced spin selectivity where the chirality emerges from the electronic degrees of freedom following excitation with circularly polarized light. We study this effect in a simple model of a metalloporphyrin complex with an axial acceptor ligand using quantum mechanical rate theories and numerical simulations. We find that the spin polarization emerges due to the selective excitation of a ring current within the porphryin, breaking the degeneracy of the two degenerate spin states. The resultant spin polarization increases with the spin orbit coupling between the metal in the porphyrin and the axial ligand, and is transient, with a lifetime dependent on the rate of dephasing from the Jahn–Teller distortion mode. This proposed effect should be observable in spin-resolved photoemission spectroscopy.

charge transfer↗

DOE OSTI2024

Quantum Spin Probe of Single Charge Dynamics

Electronic defects in semiconductors form the basis for emerging quantum technologies, but many defect centers are difficult to access at the single-particle level. A method for probing optically inactive spin defects would reveal semiconductor physics at the atomic scale and advance the study of new quantum systems. Here, we exploit the intrinsic correlation between the charge and spin states of defect centers to measure the charge populations and dynamics of single substitutional nitrogen spin defects in diamond. By probing their steady-state spin population, read out at the single-defect level with a nearby nitrogen vacancy center, we directly measure the defect ionization-corroborated by first-principles calculations-an effect we do not have access to with traditional coherence-based quantum sensing.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2026

Mixed Nd 4+/3+ and Cluster Magnetism in Hexagonal Perovskite 12R-Ba 4 NdMn 3 O 12−γ

Hexagonal perovskite oxides with 12R stacking host well-separated face-sharing octahedral metal trimers with short metal–metal distances, leading in some cases to large degrees of magnetic frustration and cluster magnetism. Introducing magnetic ions in proximity to these trimers can influence the degree of frustration and cluster magnetism, but the extent to which the magnetism can be tuned by varying neighboring metal cations remains an open question. In this work, we test the impacts of using Nd in proximity to Mn trimers in the hexagonal perovskite 12R-Ba 4 NdMn 3 O 12−γ . Given this stoichiometry, Nd should assume the 4+ oxidation state with a spin state of S = 1, which would be the first realization of Nd 4+ in an oxide environment. Through detailed bulk magnetic, X-ray absorption spectroscopic, and powder neutron diffraction (PND) measurements, we find that Nd 4+ is realized in this material, but there is also partial reduction to Nd 3+ , which is charge-balanced by O vacancies. Magnetometry measurements indicate an antiferromagnetic ordering temperature T N ≈ 16 K, and PND measurements reveal a surprising collinear antiferromagnetic structure with magnetic space group Pc2/m (no. 10.49 in BNS notation), which has not previously been seen in this class of materials. Our results represent a comprehensive analysis of the structural, electronic, and magnetic properties of 12R-Ba 4 NdMn 3 O 12−γ , showing the first observation of partial Nd 4+ in an oxide, and demonstrating that this structural class can host a broad range of magnetic structures which are not easily predicted based on compositional trends.

14 SOLAR ENERGY↗

NASA NTRS1971

Fluorescence of the gamma, epsilon, and delta systems of nitric oxide - Polarization and use of calculated intensities for spectrometer calibration.

Results of a study in which fluorescence of the gamma system of nitric oxide was obtained by excitation from both the 2144 A line of ionized cadmium and a continuum source. Individual rotational lines of the 2144 A excited fluorescence spectrum were found to be partially polarized and to have polarizations of differ ing sign. Measured relative vibrational band intensities from line and continuum excitation were compared to calculated Franck-Condon factors. Those Franck-Condon factors based on a single potential for the two spin states of the X super pi state agreed better with measured values than those based on separate potentials for the two spin states. Calculated intensities of the v prime = 3 progression were used to calibrate the instrument response in the wavelength region from 2000 to 2500 A and were checked with measured intensities of the v prime = 0.1, and 2 progressions. Fluorescence of the epsilon and delta bands obtained with continuum lamp excitation also were compared to calculated intensities.

Poland, H. M.↗

DOE OSTI2024

Engineering and revealing Dirac strings in spinor condensates

Artificial monopoles have been engineered in various systems, yet there has been no systematic study of the singular vector potentials associated with the monopole field. We show that the Dirac string, the line singularity of the vector potential, can be engineered, manipulated, and made manifest in a spinor atomic condensate. We elucidate the connection among spin, orbital degrees of freedom, and the artificial gauge, and show that there exists a mapping between the vortex filament and the Dirac string. We also devise a proposal where preparing initial spin states with relevant symmetries can result in different vortex patterns, revealing an underlying correspondence between the internal spin states and the spherical vortex structures. Such a mapping also leads to a new way of constructing spherical Landau levels, and monopole harmonics. Our observation provides insights into the behavior of quantum matter possessing internal symmetries in curved spaces. Published by the American Physical Society 2024

Xu, Gui-Sheng↗

NASA NTRS1976

Inferences from the dynamical history of Mercury's rotation

The history of Mercury's spin angular momentum is reviewed. It is shown that the current nonsynchronous but resonant spin and the nearly zero obliquity place almost no restrictions on the primordial spin state. The only exception comes about from a liquid core-solid mantle interaction which excludes a slow primordial spin concurrent with a large obliquity. The current occupancy of a final evolutionary spin state leads to the description of a scheme by which we can determine the extent of a currently liquid Mercurian core.

Peale, S. J.↗

NASA NTRS1990

Positronium ions and molecules

Recent theoretical studies on positronium ions and molecules are discussed. A positronium ion is a three particle system consisting of two electrons in singlet spin state, and a positron. Recent studies include calculations of its binding energy, positron annihilation rate, and investigations of its doubly excited resonant states. A positronium molecule is a four body system consisting of two positrons and two electrons in an overall singlet spin state. The recent calculations of its binding energy against the dissociation into two positronium atoms, and studies of auto-detaching states in positronium molecules are discussed. These auto-dissociating states, which are believed to be part of the Rydberg series as a result of a positron attaching to a negatively charged positronium ion, Ps-, would appear as resonances in Ps-Ps scattering.

Ho, Y. K.↗

DOE OSTI2025

Spin-glass state in nickelate superconductors

Magneto-optical measurements in La 0.8 Sr 0.2 NiO 2 and Nd 0.825 Sr 0.175 NiO 2 reveal an intriguing new facet of infinite-layer nickelate superconductors: the onset of spin-glass behavior at a temperature far exceeding the superconducting critical temperature T c . This discovery sharply contrasts with copper oxide superconductors, where magnetism and superconductivity remain largely exclusive. Moreover, the magnitude and onset temperature of the polar Kerr effect in Nd 0.825 Sr 0.175 NiO 2 fabricated on SrTiO 3 and (LaAlO 3 ) 0.3 (Sr 2 TaAlO 6 ) 0.7 substrates differ dramatically, while T c does not.

FOS: Physical sciences↗

DOE OSTI2025

ZnO quantum dot–molecule conjugates: Chemical interactions, charge dynamics, and spin polarization

Conjugates between molecules and quantum dots (QDs) have been explored for a range of potential applications from photocatalysis and photovoltaics to quantum information science technologies. A particularly ubiquitous material in many of these applications are ZnO QDs since they can accept and transport electrons and can also act as hosts for unique spin states. Conjugates between molecular light absorbers and ZnO QDs have been explored for decades as components in dye-sensitized solar cells. Recently, these materials have also attracted interest for their ability to produce spin-polarized states upon photoexcitation. The current paper employs a series of light absorbing perylene molecules with different ZnO QD sizes to explore key features of these QD–molecule conjugates: (1) chemical interactions, (2) charge dynamics, and (3) spin polarization. The chemical interactions between the molecules and QDs are determined with binding equilibria and reveal dramatic impact of ligand size. The charge transfer dynamics from photoexcited perylenes to ZnO QDs were found to depend exponentially on the linker length. Finally, time-resolved electron paramagnetic resonance experiments reveal that these conjugates generate spin-polarized states in the form of radical pairs and triplets. These spin states hold promise as potential qubits and also offer an avenue to efficiently sensitize molecular triplets.

Hernandez, Frida S. [Amherst College, MA (United S↗

NASA NTRS1985

Hyperion - Analysis of Voyager observations

Voyager imges of Hyperion are analyzed with respect to spin state, dimensions and shape, surface features, photometry, and colors. It is suggested that the two most important observations concerning Hyperion are the demonstration of the satellite's unusual spin state and the discovery of the apparent low density of large craters on the satellite's surface. A possible implication of such a reduced density of craters is that the last important fragmentation of Hyperion might have occurred near the end or after the period of initial heavy bombardment.

Thomas, P.↗

NASA NTRS1974

The significance of observed rotational magnetic hysteresis in lunar samples

Rotational magnetic hysteresis curves for lunar soils 10084, 12070, and 14259, and rock 14053 have been published. There is no adequate explanation to date for the observed large hysteresis at high fields. Lunar rock magnetism researchers consider fine particle iron to be the primary source of stable magnetic remanence in lunar samples. Iron has cubic anisotropy with added shape anisotropy for extreme particle shapes. The observed high-field hysteresis must have its source in uniaxial or unidirectional anisotropy. This implies the existence of minerals with uniaxial anisotropy or exchange-coupled spin states. Therefore, the source of this observed high-field hysteresis must be identified and understood before serious paleointensity studies are made. It is probable that the exchange-coupled spin states and/or the source of uniaxial anisotropy responsible for the high-field hysteresis might be influenced by the lunar surface diurnal temperature cycling. The possible sources of high-field hysteresis in lunar samples are presented and considered.

Wasilewski, P.↗