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At least 73 records · Page 4

An overview of the first results on the solar array materials passive LDEF experiment (sample), A0171

Power degradation in the solar cells was consistent with the exposure environment and appears to be produced principally by the radiation and atomic oxygen environments. Atomic oxygen erosion was generally as expected; atomic oxygen effects dominated for the most part in materials that were both atomic oxygen and ultraviolet vulnerable. Silicone coatings appear to protect Kapton, and adhesive systems contained under photon opaque materials were surprisingly environmentally resistant. A high density of small micro-meteroid/space debris impacts were observed on mirrors, protective coatings, paints, and composites. New synergistic effects of the space environment were noted in the interaction of atomic oxygen and copious amounts of contamination and in the induced luminescence of many materials.

Ann F Whitaker

Research on medium and high temperature solar heat storage materials

Characteristics of solar heat storage materials, preliminary tests in which melting and solidification characteristics are tested, and service life and cycling tests are reported. Various aspects of corrosion are discussed as well as decision about ultimate selection of materials. A program for storage and evaluation of data is included.

Heine, D.

Owens-Illinois liquid solar collector materials assessment

From the beginning, it was noted that the baseline drawings for the liquid solar collector exhibited a distinct weakness concerning materials specification where elastomers, plastics, and foam insulation materials were utilized. A relatively small effort by a competent design organization would alleviate this deficiency. Based on results obtained from boilout and stagnation tests on the solar simulator, it was concluded that proof testing of the collector tubes prior to use helps to predict their performance for limited service life. Fracture mechanics data are desirable for predicting extended service life and establishing a minimum proof pressure level requirement. The temperature capability of this collector system was increased as the design matured and the coating efficiency improved. This higher temperature demands the use of higher temperature materials at critical locations in the collector.

Nichols, R. L.

Detection of solid C(triple bond)N bearing materials on solar system bodies

We found observational evidence for the presence of C(triple bond)N-bearing solid materials on four classes of Solar System bodies: comets, asteroids, the rings of Uranus, and Saturn's satellite Iapetus. Gaseous CN was known in comet spectra, and the IR spectra of Comet P/Halley show emission of the CN fundamental at 4.5 microns interpreted as solids containing CN- group in the grains of the inner coma. The presented data offer the first evidence for chemically related material on the other objects.

Cruikshank, Dale P.

Oxygen Isotopes in Early Solar System Materials: A Perspective Based on Microbeam Analyses of Chondrules from CV Carbonaceous Chondrites

Some of the biggest challenges to understanding the early history of the solar system include determining the distribution of oxygen isotopes amongst materials that existed in the solar nebula, and interpreting the processes that might have resulted in the observed isotopic distributions. Oxygen isotope ratios in any individual mineral grain from a chondritic meteorite may be the cumulative product of a variety of processes, including stellar nucleosynthetic events, gas/solid interactions in the molecular cloud, mixing of independent isotopic reservoirs in the nebula, mass-independent processing in the nebula, and mass-dependent fractionation effects in various environments. It is not possible to unravel this complex isotopic record unless the distribution of oxygen isotope ratios in chondritic materials is fully understood.

Jones, R. H.

Solar concentrator materials development

Materials with potential applications in reflective and refractive solar dynamic concentrators are tested for resistance to atomic oxygen degradation. It is found that inorganic coatings such as MgF2, SiO(x), and ITO provide excellent protection for reflective surfaces while organic materials are much more susceptible to erosion and mass loss. Of the organic polymers tested, the silicones have the highest intrinsic resistance to atomic oxygen degradation.

Morel, D. E.

Selection and Manufacturing of Membrane Materials for Solar Sails

Commercial metallized polyimide or polyester films and hand-assembly techniques are acceptable for small solar sail technology demonstrations, although scaling this approach to large sail areas is impractical. Opportunities now exist to use new polymeric materials specifically designed for solar sailing applications, and take advantage of integrated sail manufacturing to enable large-scale solar sail construction. This approach has, in part, been demonstrated on the JAXA IKAROS solar sail demonstrator, and NASA Langley Research Center is now developing capabilities to produce ultrathin membranes for solar sails by integrating resin synthesis with film forming and sail manufacturing processes. This paper will discuss the selection and development of polymer material systems for space, and these new processes for producing ultrathin high-performance solar sail membrane films.

Bryant, Robert G.

Evaluation of silicon ribbon material for solar cell fabrication

Optical microscopy, electron microscopy, and X-ray diffraction were utilized to characterize silicon ribbon structure. Complex twin formation was observed in nearly all ribbons examined. Twins formed in the 110-plane 112-line ribbon orientation appear stable, and this orientation may be preferable when the ribbon is utilized for solar cells. In addition to twinning, grain boundaries and other structural defects were observed in the ribbon material. Hall effect, resistivity, spreading resistance, surface photovoltage, and solar cell electrical/optical measurements were performed on ribbon samples and correlated with structural and ribbon growth characteristics. Only those ribbon samples with either single-crystal structure or with 'parallel' twin formations were capable of solar-cell performance approaching that of Czochralski material.

Leipold, M.

Space station solar concentrator materials research

The Space Station will represent the first time that a solar dynamic power system will be used to generate electrical power in space. In a system such as this, sunlight is collected and focused by a solar concentrator onto the receiver of a heat engine which converts the energy into electricity. The concentrator must be capable of collecting and focusing as much of the incident sunlight as possible, and it must also withstand the atomic oxygen bombardment which occurs in low Earth orbit (LEO). This has led to the development of a system of thin film coatings applied to the concentrator facet surface in a chamber designed especially for this purpose. The system of thin film coatings employed gives both the necessary degree of reflectance and the required protection from the LEO atomic oxygen environment.

Gulino, Daniel A.

Laboratory and observational study of the interrelation of the carbonaceous component of interstellar dust and solar system materials

By studying the chemical and isotopic composition of interstellar ice and dust, one gains insight into the composition and chemical evolution of the solid bodies in the solar nebula and the nature of the material subsequently brought into the inner part of the solar system by comets and meteorites. It is now possible to spectroscopically probe the composition of interstellar ice and dust in the mid-infrared, the spectral range which is most diagnostic of fundamental molecular vibrations. We can compare these spectra of various astronomical objects (including the diffuse and dense interstellar medium, comets, and the icy outer planets and their satellites) with the spectra of analogs we produce in the laboratory under conditions which mimic those in these different objects. In this way one can determine the composition and abundances of the major constituents of the various ices and place general constraints on the types of organics coating the grains in the diffuse interstellar medium. In particular we have shown the ices in the dense clouds contain H2O, CH3OH, CO, perhaps some NH3 and H2CO, we well as nitriles and ketones or esters. Furthermore, by studying the photochemistry of these ice analogs in the laboratory, one gains insight into the chemistry which takes place in interstellar/precometary ices. Chemical and spectroscopic studies of photolyzed analogs (including deuterated species) are now underway. The results of some of these studies will be presented and implications for the evolution of the biogenic elements in interstellar dust and comets will be discussed.

Allamandola, L. J.

Far Ultraviolet Refractive Index of Optical Materials for Solar Blind Channel (SBC) Filters for HST Advanced Camera for Surveys

Refractive index measurements using the minimum deviation method have been carried out for prisms of a variety of far ultraviolet optical materials used in the manufacture of Solar Blind Channel (SBC) filters for the HST Advanced Camera for Surveys (ACS). Some of the materials measured are gaining popularity in a variety of high technology applications including high power excimer lasers and advanced microlithography optics operating in a wavelength region where high quality knowledge of optical material properties is sparse. Our measurements are of unusually high accuracy and precision for this wavelength region owing to advanced instrumentation in the large vacuum chamber of the Diffraction Grating Evaluation Facility (DGEF) at Goddard Space Flight Center (GSFC). Index values for CaF2, BaF2, LiF, and far ultraviolet grades of synthetic sapphire and synthetic fused silica are reported and compared with values from the literature.

Leviton, Douglas B.

Reflectance spectrophotometry (about 0.5-1.0 micron) of oute-belt asteroids - Implications for primitive, organic solar system material

The surface compositions of outer-belt asteroids were used to obtain information about the origin of these asteroids. High-resolution CCD reflectance spectra of 21 asteroids, primarily P class, were examined for compositional information. Distinct slope changes are observed that suggest that these asteroids are the remnants of a compositional gradation of planetesimals in the outer solar system, which were retained selectively in location when other material was ejected from the solar system. Other data suggest that this gradation could extend through the orbits of Uranus and Neptune.

Vilas, F.

Optical Studies of Low Reflectance Materials at Solar Reflective Wavelengths in Support of Remote Sensing Instrument Development and Calibration

We report the Bidirectional Reflection Distribution Function (BRDF) and Total Hemispheric Reflectance (THR) results of several low reflectance materials using a Table-top Goniometer (TTG) and a commercial UV-VIS-NIR spectrophotometer in support of the NASA GSFC PACE project. The newly developed TTG was utilized to perform the BRDF measurements for several black candidate samples in in-plane and out-of-plane configurations from 300 nm to 2000 nm. These measurements demonstrated the BRDF capability of the TTG to calibrate the dim calibration target with a reflectance of approximately 2 % for the OCI of the PACE project. The spectral THR of the black samples from 200 nm to 2500 nm was determined using a 10 % reflectance diffuse black standard and a monochromator-based light source equipped with a 150 mm diameter integrating sphere. The THR measurement is used to compliment and validate the BRDF measurements acquired from these samples. In this presentation, we also show examples of UV induced BRDF and THR changes on two black coatings. We will discuss validation of the BRDF scale, source stability, measurement repeatability, instrument signature, and uncertainty components.

Bidirectional Reflection Distribution Function (BR

The Edison infrared space observatory and the study of extra-solar planetary material

Edison is a proposed large-aperture, radiatively-cooled space observatory planned to operate at wavelengths between 2 and 130 micrometers or longer. Current estimates for the telescope allow an aperture of 1.7 m which will achieve a final equilibrium temperature of about 30 K, although use of cryocoolers may permit temperatures below 20 K. Edison will be a powerful tool to investigate our Solar System, as well as planetary material around distant stars. At near- and mid-infrared wavelengths, where planetary material emits most of its radiation, Edison will be the most sensitive photometric and spectroscopic observatory under current consideration by the space agencies. With its large aperture, Edison will be able both to resolve the structure in nearby circumstellar 'Vega disks' and to discriminate faint IR emission in the crowded environment of the galactic plane. With its long lifetime, Edison will allow extensive follow-up observations and increase the likelihood of catching transient events. We propose Edison as a precursor to elements of a future space-based IR interferometer.

Thronson, H. A., Jr.

On diamond, graphitic and amorphous carbons in primitive extraterrestrial solar system materials

Carbon is among the most abundant elements in the universe and carbon chemistry in meteorites and comets is an important key to understanding many Solar System and interstellar processes. Yet, the mineralogical properties and interrelations between various structural forms of elemental carbon remain ambiguous. Crystalline elemental carbons include rhombohedral graphite, hexagonal graphite, cubic diamond, hexagonal diamond (i.e., lonsdaleite or carbon-2H) and chaoite. Elemental carbon also occurs as amorphous carbon and poorly graphitized (or turbostratic) carbon but of all the forms of elemental carbon only graphite is stable under physical conditions that prevail in small Solar System bodies and in the interstellar medium. The recent discovery of cubic diamond in carbonaceous chondrites and hexagonal diamond in chondritic interplanetary dust particles (IDPs) have created a renewed interest in the crystalline elemental carbons that were not formed by shock processes on a parent body. Another technique, Raman spectroscopy, confirms a widespread occurrence of disordered graphite in the Allende carbonaceous chondrite and in chondritic IDPs. Elemental carbons have also been identified by their characteristic K-edge features in electron energy loss spectra (EELS). However, the spectroscopic data do not necessarily coincide with those obtained by selected area electron diffraction (SAED). In order to interpret these data in terms of rational crystalline structures, it may be useful to consider the principles underlying electron diffraction and spectroscopic analyses. Electron diffraction depends on electron scattering, on the type of atom and the distance between atoms in a crystal lattice. Spectroscopic data are a function of the type of atom and the energy of bonds between atoms. Also, SAED is a bulk sampling technique when compared to techniques such as Raman spectroscopy or EELS. Thus, it appears that combined analyses provide contradictory results and that amorphous, or short-range ordered, carbon identified by conventional TEM imaging and SAED may show evidence for sp(3) bonds in EELS spectra. It is suggested that complex, nanometer-scale, mineralogical interrelations are common to all elemental carbons irrespective of their origin. The subsequent thermal history, or energy balance, will determine the ultimate microstructure.

Rietmeijer, Frans J. M.