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NASA NTRS1983

Effects of nitric oxide and nitrogen dioxide on bacterial growth

While it is generally thought that the bactericidal effects of NO and NO2 derive from their reaction with water to form nitrous and nitric acids (Shank et al., 1962), this appears to be true only at high concentrations. The data presented here suggest that at low NO and NO2 concentrations, acids are not present in high enough concentrations to act as toxic agents. Reference is made to a study by Grant et al. (1979), which found that exposing acid forest soil to 1 ppm of NO2 did not cause the soil pH to drop. The results presented here show that at low concentrations of NO and NO2, the NO is bacteriostatic for some organisms and not for others, whereas NO2 may protect some bacteria from the inhibitory effects of NO. Since it has been shown that bacteria can divide while airborne (Dimmick et al., 1979), the present results suggest that NO at the low concentrations found in the atmosphere can select for resistant bacteria in the air and affect the viable airborne bacterial population.

Mancinelli, R. L.↗

DOE OSTI2022

Climatology of the Vertical Profiles of Polarimetric Radar Variables and Retrieved Microphysical Parameters in Continental/Tropical MCSs and Landfalling Hurricanes

Most existing cloud models tend to overestimate the size of cloud ice particles and underestimate their concentration. This emphasizes the need to provide a reliable observational reference to optimize cloud model performance, particularly in areas of high concentration of ice at high altitudes. The dual-polarization radars give the community a unique opportunity to quantify cloud ice with a good accuracy using polarimetric radar retrievals. Here, in this study, we utilize the network of operational WSR-88D radars to build a climatology of the vertical profiles of radar variables, such as radar reflectivity Z, differential reflectivity Z DR , and specific differential phase K DP as well as the radar-retrieved vertical profiles of ice water content (IWC) above the melting layer and liquid water content below it, mean volume diameter D m , and total number concentration N t of ice and liquid particles. Such climatology was created for continental/marine mesoscale convective systems (MCSs) and tropical cyclones including hurricanes. The dataset includes 13 continental MCSs, 10 marine MCSs, and 11 tropical cyclones. Separate statistics of the “background” vertical profiles and the ones associated with high IWC aloft have been obtained in the course of this study. It is shown that continental MCSs exhibit larger size of ice in lower concentration aloft compared to the marine MCSs and especially tropical cyclones/hurricanes. A combination of high KDP and low Z aloft signifies lower D m , higher N t , and often substantial IWC.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2024

Reverse Osmosis Simulation Data

This dataset consists of computational fluid dynamics (CFD) output for various spacer configurations in a feed-water channel in reverse osmosis (RO) applications. Feed-water channels transport brine solution to the RO membrane surfaces. The spacers embedded in the channels help improve membrane performance by disrupting the concentration boundary layer growth on membrane surfaces. Refer to the "Related Work" resource below for more details. This dataset considers a feed-water channel of length 150mm. The inlet brine velocity and concentration are fixed at 0.1m/s and 100kg/m3 respectively. The diameter of the cylindrical spacers is fixed as 0.3mm and six varying inter-spacer distances of 0.75mm, 1mm, 1.5mm, 2mm, 2.5mm, and 3mm are simulated. The dataset comprising the steady, spatial fields of solute concentration, velocity, and density near each spacer is placed in the folder corresponding to the spacer configuration considered. We run two sets of CFD simulations and include the outputs from both sets for each configuration: (1) with a coarser mesh, producing low-resolution (LR) data of spatial resolution 20x20, and (2) with a finer mesh, producing high-resolution (HR) data of spatial resolution 100x100. These data points can be treated as images with the quantities of interest as their channels and can be used to train machine learning models to learn a mapping from the LR images as inputs to the HR images as outputs.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

DOE OSTI2025

Accumulation of trace elements in soil and fauna within a site historically contaminated with coal combustion residues

Legacy contaminants tied to energy production are a worldwide concern. Coal combustion residues (CCRs) contain high concentrations of potentially toxic trace elements such as arsenic (As), mercury (Hg), and selenium (Se), which can persist for decades after initial contamination. Coal combustion residue disposal methods, including aquatic settling basins and landfills, can facilitate environmental exposure through intentional and accidental releases. Wildlife exposed to CCRs can experience numerous deleterious effects, such as on development, reproduction, and survival. In the current study, we quantified and compared concentrations of As, Hg, Se, and strontium (Sr) within soils and target fauna (three vertebrate and three invertebrate taxa) from a CCR-contaminated site and a reference site within the U.S. Department of Energy’s Savannah River Site, South Carolina, United States. Our objectives were to (1) compare current concentrations of tested elements in soil and resident fauna to levels from our reference site, (2) assess natural attenuation of elements in soils by comparing current concentrations to historic levels, and (3) evaluate the biomagnification potential of the elements measured via body burden and trophic position correlations among fauna. Here, element concentrations were higher in contaminated soils than reference soils; however, concentrations in 2022 were unchanged from concentrations measured in 2003, suggesting no natural attenuation of tested elements. Additionally, target fauna had elevated As, Se, and Sr levels in comparison to reference samples. A positive correlation was observed in southern toads between Sr concentrations and trophic position, as assessed by nitrogen stable isotope ratios, suggesting potential for biomagnification of Sr within our study system. Collectively, our results demonstrate that legacy contaminants are still present and bioaccumulate in a diversity of taxa in a CCR-contaminated site that has not received effluents in more than 50 years, suggesting monitoring programs in CCR-contaminated sites should be maintained long term in the absence of remediation.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗

DOE OSTI2022

Microglia are implicated in the development of paclitaxel chemotherapy-associated cognitive impairment in female mice

Chemotherapy remains a mainstay in the treatment of many types of cancer even though it is associated with debilitating behavioral side effects referred to as “chemobrain,” including difficulty concentrating and memory impairment. The predominant hypothesis in the field is that systemic inflammation drives these cognitive impairments, although the brain mechanisms by which this occurs remain poorly understood. Here, we hypothesized that microglia are activated by chemotherapy and drive chemotherapy-associated cognitive impairments. To test this hypothesis, we treated female C57BL/6 mice with a clinically-relevant regimen of a common chemotherapeutic, paclitaxel (6 i.p. doses at 30 mg/kg), which impairs memory of an aversive stimulus as assessed via a contextual fear conditioning (CFC) paradigm. In this work, paclitaxel increased the percent area of IBA1 staining in the dentate gyrus of the hippocampus. Moreover, using a machine learning random forest classifier we identified immunohistochemical features of reactive microglia in multiple hippocampal subregions that were distinct between vehicle- and paclitaxel-treated mice. Paclitaxel treatment also increased gene expression of inflammatory cytokines in a microglia-enriched population of cells from mice. Lastly, a selective inhibitor of colony stimulating factor 1 receptor, PLX5622, was employed to deplete microglia and then assess CFC performance following paclitaxel treatment. PLX5622 significantly reduced hippocampal gene expression of paclitaxel-induced proinflammatory cytokines and restored memory, suggesting that microglia play a critical role in the development of chemotherapy-associated neuroinflammation and cognitive impairments. This work provides critical evidence that microglia drive paclitaxel-associated cognitive impairments, a key mechanistic detail for determining preventative and intervention strategies for these burdensome side effects.

60 APPLIED LIFE SCIENCES↗

DOE OSTI2021

Microbial drivers of methane emissions from unrestored industrial salt ponds

Wetlands are important carbon (C) sinks, yet many have been destroyed and converted to other uses over the past few centuries, including industrial salt making. A renewed focus on wetland ecosystem services (e.g., flood control, and habitat) has resulted in numerous restoration efforts whose effect on microbial communities is largely unexplored. We investigated the impact of restoration on microbial community composition, metabolic functional potential, and methane flux by analyzing sediment cores from two unrestored former industrial salt ponds, a restored former industrial salt pond, and a reference wetland. We observed elevated methane emissions from unrestored salt ponds compared to the restored and reference wetlands, which was positively correlated with salinity and sulfate across all samples. 16S rRNA gene amplicon and shotgun metagenomic data revealed that the restored salt pond harbored communities more phylogenetically and functionally similar to the reference wetland than to unrestored ponds. Archaeal methanogenesis genes were positively correlated with methane flux, as were genes encoding enzymes for bacterial methylphosphonate degradation, suggesting methane is generated both from bacterial methylphosphonate degradation and archaeal methanogenesis in these sites. These observations demonstrate that restoration effectively converted industrial salt pond microbial communities back to compositions more similar to reference wetlands and lowered salinities, sulfate concentrations, and methane emissions.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2024

Finding a needle in a haystack: quantitative HERFD-XRF imaging and HERFD-XANES characterization of trace platinum in gold solidi from the Late Roman and Byzantine Empires

High-Energy Resolution Fluorescence Detection X-Ray Fluorescence (HERFD-XRF) imaging and HERFD X-ray Absorption Near Edge Structure (XANES) spectroscopy are used to quantify and characterize trace platinum (Pt) in gold solidi from the Late Roman and Byzantine Empires. Historically, the elemental analysis of coins has been pivotal in distinguishing authentic artifacts from forgeries, elucidating minting practices, and understanding economic shifts. Notably, a new gold source with high platinum content appeared in the fourth century CE, transforming the Roman economy. Traditional methods struggled to detect platinum due to the overwhelming gold matrix. Here, this study demonstrates the effectiveness of HERFD techniques in resolving this challenge. Three gold solidi, minted between 654 and 659 CE, were analyzed alongside reference gold materials with known Pt concentrations. The HERFD-XRF imaging revealed spatial distributions of platinum, highlighting non-uniformities within the coins. Additionally, HERFD-XANES spectroscopy identified the oxidation states and chemical speciation of platinum. Results demonstrate that platinum in the solidi primarily exists as metallic Pt, with some surface oxidation. The findings align with previous measurements but reveal higher Pt concentrations and significant inhomogeneities. This research confirms the reliability of HERFD methods for quantifying trace elements and provides new insights into the raw material sources and minting techniques of ancient gold coins. The non-destructive nature of this approach allows for extensive analyses, offering valuable data for historical, economic, and archaeological studies. This innovative application of HERFD-XRF imaging and XANES in cultural heritage research underscores the potential for detailed material characterization and conservation, enhancing our understanding of ancient economies and trade patterns.

Van Loon, Lisa L.↗

DOE OSTI2024

Demonstrating MeV-Scale Physics Capabilities of Large Neutrino LArTPCs with Ambient Blip Activity in MicroBooNE

Large neutrino liquid argon time projection chamber (LArTPC) experiments can broaden their physics reach by incorporating isolated MeV-scale features present in their data. We use data from MicroBooNE, an 85 tonne LArTPC exposed to Fermilab neutrino beams from 2015 until 2021, to demonstrate new calorimetric and particle discrimination capabilities for isolated ~O(1 MeV) energy depositions referred to as "blips". We observe concentrations of blips near fiberglass support struts along the TPC edge, with an energy spectrum indicative of specific gamma-ray decays. These and other blip sources are being used to validate calibrations in MicroBooNE's data by leveraging spectral features. This work further reports on the progress towards distinguishing between low-energy protons and electrons in large LArTPCs using cosmogenic data. The composition of proton-like blips selected using this new technique is being studied to evaluate the accuracy of cosmic ray flux models used in LArTPCs

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS1978

High efficiency low cost solar cell power

A concept for generating high-efficiency, low-cost, solar-cell power is outlined with reference to solar cell parameters, optical concentrators, and thermal control procedures. A design for a 12.5-kw power module for space operation is discussed noting the optical system, spectrum splitter, light conversion system, cell cooling, power conditioner, and tracking mechanism. It is found that for an unconcentrated array, efficiency approaches 60% when ten or more bandgaps are used. For a 12-band system, a computer program distributed bandgaps for maximum efficiency and equal cell currents. Rigid materials and thin films have been proposed for optical components and prisms, gratings, and dichroic mirrors have been recommended for spectrum splitting. Various radiator concepts are noted including that of Weatherston and Smith (1960) and Hedgepeth and Knapp (1978). The concept may be suitable for the Solar Power Satellite.

Bekey, I.↗

NASA NTRS1984

The initial thermal state of the Moon

It is argued that the initial thermal state of the Moon was molten. The existence of young thrust fault scarps in the highlands and kbar stress drop, shallow moonquakes both suggest that the thermoelastic stresses in the outer crust are currently in the kbar range. This is expected if the Moon was initially molten, but not if the Moon had a magma ocean only a few hundred km deep. The thesis is also supported by reference to model studies of the concentrations of refractory incompatible elements.

Binder, A. B.↗

DOE OSTI2024

Demonstrating MeV-Scale Physics Capabilities of Large Neutrino LArTPCs with Ambient Blip Activity in MicroBooNE

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

DOE OSTI2022

2021 Results for Avian Monitoring of Inorganic and Organic Element Concentrations in Passerine Eggs and Nestlings Collected from Technical Area 16 Burn Grounds, Technical Area 36 Minie, and Technical Area 39 Point 6 at Los Alamos National Laboratory (Rev. 2)

In 2021, non-viable avian eggs and one nestling were opportunistically collected at Los Alamos National Laboratory (LANL) near open detonation sites located at Technical Area (TA) 16 burn grounds and TA-36 Minie. Similar to previous years, nestboxes were monitored at TA-39 Point 6, however, no avian samples were available for opportunistic collection. Samples were evaluated for inorganic elements (mostly metals), dioxins, and furans. One ash-throated flycatcher (Myiarchus cinerascens) egg sample was collected from TA-16 burn grounds. One ash-throated flycatcher and one mountain bluebird (Sialia currucoides) egg sample and one deceased western bluebird (Sialia mexicana) nestling sample were collected from TA-36 Minie. Concentrations of inorganic elements observed in this study were compared with the regional statistical reference level (RSRL) which is the upper-level bounds of background concentrations (mean + three standard deviations = 99% confidence interval). Several inorganic elements were not detected in avian eggs. Most inorganic elements detected were below the RSRL and all were the lowest observable adverse effect level (LOAEL), when available. The nestling collected from TA-36 did not contain detectable concentrations of dioxin or furan congeners. These data suggest that inorganic and organic element concentrations in eggs and nestlings are not of ecological concern. More data are needed to make a robust assessment and to evaluate trends over time.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1979

The distribution of titanium on the lunar surface

Titanium concentrations derived from the lunar-orbiting gamma-ray experiment on Apollo 15 and 16 by analyzing a spectral interval in which the titanium signal is relatively enhanced are presented. Landing site soil values provide the reference for a regression curve from which Ti concentrations in 137 regions of adequate counting statistics are calculated. Mare Tranquillitatis contains the highest, and Mare Crisium the lowest Ti concentration, and regional values in the western maria range from 1.1% to 4.1%. Highland Ti concentrations suggest a north-south symmetry which is not consistent with previously reported Fe and Th results. Comparisons with telescopic spectral reflectance studies of the maria do not show complete agreement and suggest that effects due to Fe may not have been fully removed from the reflectance data.

Metzger, A. E.↗

DOE OSTI2022

International interlaboratory compilation of trace element concentrations in the CUP-2 uranium ore concentrate standard

Herein, a nuclear forensics investigation involving a uranium ore concentrate relies on accurate and precise analysis of impurities. Analytical data defensibility requires the use of reference materials as part of quality control. This study presents a compilation of trace element concentration results of the CUP-2 Uranium Ore Concentrate Standard measured by 11 different laboratories. The laboratories employed various dissolution methods, analytical preparation methods, and instrumental platforms. The data presented here contain concentrations of 66 impurities with up to 138 individual data points for each impurity. Consensus values have been assigned to each impurity following a statistical analysis of the data set.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

DOE OSTI2021

The Role of Concentrating Solar-Thermal Technologies in a Decarbonized U.S. Grid

The National Renewable Energy Laboratory’s Solar Futures Study explores the roles solar energy technologies could play in the future U.S. energy markets under different scenarios. This report discusses the role of concentrating solar-thermal (CST) technologies in those future scenarios with an emphasis on concentrating solar-thermal power (CSP), which refers to converting thermal energy to electricity. The report begins with an overview of the CSP resource and market status. Next we discuss the results from the grid-scale capacity planning modeling under future scenarios considered in the Solar Futures Study, focusing on the results for CSP and presenting several sensitivity model results not discussed in the main report. We then discuss likely CST research and industry directions over the next decade. Finally we discuss three potential future markets for CST beyond electricity generation -- industrial process heat, solar fuels production, and electric thermal energy storage.

14 SOLAR ENERGY↗

NASA NTRS2012

Detection of Chemical Precursors of Explosives

Certain selected chemicals associated with terrorist activities are too unstable to be prepared in final form. These chemicals are often prepared as precursor components, to be combined at a time immediately preceding the detonation. One example is a liquid explosive, which usually requires an oxidizer, an energy source, and a chemical or physical mechanism to combine the other components. Detection of the oxidizer (e.g. H2O2) or the energy source (e.g., nitromethane) is often possible, but must be performed in a short time interval (e.g., 5 15 seconds) and in an environment with a very small concentration (e.g.,1 100 ppm), because the target chemical(s) is carried in a sealed container. These needs are met by this invention, which provides a system and associated method for detecting one or more chemical precursors (components) of a multi-component explosive compound. Different carbon nanotubes (CNTs) are loaded (by doping, impregnation, coating, or other functionalization process) for detecting of different chemical substances that are the chemical precursors, respectively, if these precursors are present in a gas to which the CNTs are exposed. After exposure to the gas, a measured electrical parameter (e.g. voltage or current that correlate to impedance, conductivity, capacitance, inductance, etc.) changes with time and concentration in a predictable manner if a selected chemical precursor is present, and will approach an asymptotic value promptly after exposure to the precursor. The measured voltage or current are compared with one or more sequences of their reference values for one or more known target precursor molecules, and a most probable concentration value is estimated for each one, two, or more target molecules. An error value is computed, based on differences of voltage or current for the measured and reference values, using the most probable concentration values. Where the error value is less than a threshold, the system concludes that the target molecule is likely. Presence of one, two, or more target molecules in the gas can be sensed from a single set of measurements.

Li, Jing↗

NASA NTRS2003

Flow Visualization of Low Prandtl Number Fluids using Electrochemical Measurements

It is well established that residual flows exist in contained liquid metal processes. In 1-g processing, buoyancy forces often drive these flows and their magnitudes can be substantial. It is also known that residual flows can exist during microgravity processing, and although greatly reduced in magnitude, they can influence the properties of the processed materials. Unfortunately, there are very few techniques to visualize flows in opaque, high temperature liquid metals, and those available are not easily adapted to flight investigation. In this study, a novel technique is developed that uses liquid tin as the model fluid and solid-state electrochemical cells constructed from Yttria-Stabilized Zirconia (YSZ) to establish and measure dissolved oxygen boundary conditions. The melt serves as a common electrode for each of the electrochemical cells in this design, while independent reference electrodes are maintained at the outside surfaces of the electrolyte. By constructing isolated electrochemical cells at various locations along the container walls, oxygen is introduced or extracted by imposing a known electrical potential or passing a given current between the melt and the reference electrode. This programmed titration then establishes a known oxygen concentration boundary condition at the selected electrolyte-melt interface. Using the other cells, the concentration of oxygen at the electrolyte-melt interface is also monitored by measuring the open-circuit potentials developed between the melt and reference electrodes. Thus the electrochemical cells serve to both establish boundary conditions for the passive tracer and sense its path. Rayleigh-Benard convection was used to validate the electrochemical approach to flow visualization. Thus, a numerical characterization of the second critical Rayleigh numbers in liquid tin was conducted for a variety of Cartesian aspect ratios. The extremely low Prandtl number of tin represents the lowest value studied numerically. Additionally, flow field oscillations are visualized and the effect of tilt on convecting systems is quantified. Experimental studies of the effect of convection in liquid tin are presented. Three geometries are studied: (1) double electrochemical cell with vertical concentration gradients; (2) double cell with horizontal concentration gradients; and (3) multiple cells with vertical temperature gradients. The first critical Rayleigh number transition is detected with geometry (1) and it is concluded that current measurements are not as affected by convection as EMF measurements. The system is compared with numerical simulations in geometry (2), and oscillating convection is detected with geometry (3).

Crunkleton, D.↗

DOE OSTI2022

MCS solutions for the TVA Watts Bar Unit 1 multi-physics depletion benchmark

The high-fidelity solution for exercises 1-3 of the recently developed TVA Watts Bar Unit 1 multi-physics and multi-cycle depletion benchmark using MCS was coupled with two different thermal-hydraulics (TH) codes: TH1D and COBRA-TF (CTF), and their solutions were compared. The solutions from MCS/CTF and MCS/TH1D for typical Pressurized Water Reactor (PWR) problems are quite close. And to evaluate MCS solutions for the benchmark, their results were also compared against measured data as well as publicly available high-fidelity solutions. The MCS criticality solutions at Hot Zero Power (HZP) deviate within 50 pcm against the reference solutions. While for the critical boron concentration (CBC) search calculations, the difference on the MCS calculated CBC is about 7 ppm, and the root-mean-squared (RMS) errors for the assembly power distribution and outlet coolant temperature are less than 0.5% and 1 Celsius degree respectively. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗