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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

Positive ions and the winter anomaly.

A coordinated rocket program to study winter variability in D-region ionization was conducted at White Sands Missile Range, New Mexico, during the winter of 1970-1971. Parachute-borne blunt probes that measure positive-ion and electron conductivities were flown, in conjunction with other experiments, on Jan. 22 and 26 and Feb. 1, 1971. Both A1 and A3 radiowave absorption techniques were used to indicate anomalous winter days. The two rocket shots in January occurred on such days of high absorption. The first of these was one of quiet solar activity, whereas the second was preceded by a major solar proton event on January 24. The third flight occurred on a normal winter day. We tentatively conclude that we have observed two days of 'anomalous' winter absorption of very different character, one possibly related to a solar disturbance, and one probably entirely induced by meteorological effects. The former day was probably characterized by inhibition of the formation of negative ions due to increased detachment and the latter by decreased ionization loss rate.

Mitchell, J. D.↗
NASA NTRS1972

Positive ion chemistry of the D and E regions.

A comparison of ion-molecule reaction rates implied by E- and F-region chemistry and measured in the laboratory shows on the whole good agreement except that the ionospheric analysis demands stronger temperature dependences. In the daytime D region, it is claimed that the reconciliation of positive ion densities with production rates and laboratory rate constants would best be achieved if (1) ionization of O2(1 delta g) and hydration of O4(+) in competition with the reduction of O4(+) to O2(+) by O were the dominant source of hydrates between 85 and 77 km, (2) ionization of NO by solar Lyman alpha followed by hydration was the dominant source of hydrates below 77 km, and (3) for some reason, Lyman alpha did not ionize NO effectively at pressures below those prevailing at 75 km.

Donahue, T. M.↗
DOE OSTI2022

Aluminum hydroxide, bayerite, boehmite, and gibbsite ToF-SIMS spectra in the positive ion mode. II

We report time-of-flight secondary ion mass spectrometry (ToF-SIMS) was performed for boehmite (AOH-60) and its potential products of oxidation including pseudo-boehmite (AOH-180), α- and γ-Al 2 O 3 , and α- and γ-Al(OH) 3 . Since boehmite often forms on the cladding materials to prevent corrosion, surface analysis techniques are performed to determine the amount of oxidation present. This ToF-SIMS spectral library is of significance because it includes boehmite and its potential oxidation products (i.e., aluminum oxide and hydroxide), which can be used to compare to spectra obtained for real-world samples containing boehmite. Furthermore, ToF-SIMS is often used as a complementary technique to x-ray photoelectron spectroscopy (XPS) due to its surface sensitivity and ability to compare spectra via multivariate analysis, therefore establishing the molecular signatures of boehmite and relevant compounds are essential for peak identification. The SIMS spectra shown are acquired from commercially available powders, which were deposited onto a Si wafer substrate via liquid slurry drop casting. This library of SIMS mass spectra will serve as a comparison of boehmite [γ-AlO(OH)], pseudo-boehmite [AlOOH∙nH 2 O], α- and γ-Al 2 O 3 aluminum oxide, and α- and γ-Al 2 O 3 aluminum hydroxide in the positive ion mode, which compliments those reported in the negative ion mode (Part 1).

36 MATERIALS SCIENCE↗
DOE OSTI2026

AMAROK: A Radio Frequency Development Platform for High-Power, Full-Scale Positive Ion Sources for DIII-D Neutral Beam Injectors

Next-generation neutral beam injection (NBI) systems demand RF ion sources capable of efficiently coupling >120 kW at 2–4-MHz frequencies, yet existing designs face voltage standoff and impedance-matching challenges. To address this, the advanced multicoil antenna for RF operations at kilowatts (AMAROK) was developed as a high-power RF inductively coupled plasma (ICP) source delivering up to 200 kW in the 2–4-MHz range via four phase-controlled generators for flexible power sharing. Two antenna designs—a single-strap multiturn (MT) and a multistrap single-turn (ST) design—were evaluated to optimize resonance, impedance matching, and power coupling across plasma loads. Here, a semi-analytical self-resonant frequency (SRF) model, validated experimentally, predicts resonance trends for arbitrary turn counts and tubing diameters, enabling rapid antenna optimization. Strap-to-strap mutual inductance in the ST configuration showed strong spatial dependence, guiding generator operation and total load inductance. These insights informed a custom π -topology matching network, achieving stable impedance matching over a wide range of plasma-driven loads. Collectively, these results position AMAROK as a versatile testbed for advancing high-power RF source technology in fusion NBI applications.

DIII-D↗
DOE OSTI2024

In-house synthesized poly(ether ether ketone) ionenes. I. ToF-SIMS spectra in the positive ion mode

Static time-of-flight secondary ion mass spectrometry (ToF-SIMS) was performed for acquiring the high-resolution surface spectra of four types of synthesized imidazolium ionene membranes. These novel membranes have aromatic ether–ketone–ether linkages inspired by poly(ether ether ketone) (PEEK). The PEEK-ionenes synthesized for this study have imidazolium cations placed in the polymeric backbone with bistriflimide [Tf 2 N]- counterions. The attention given to synthetically modified PEEK derivatives, such as PEEK-ionenes, is considerable due to their ability to selectively capture CO 2 molecules and other light gases. Therefore, it is important to characterize the surface of these synthesized novel PEEK-ionenes. In this work, characteristic and unique peaks were identified in the positive spectra of each sample. The differences in mass spectra among the samples provide insights for optimizing or fine-tuning the PEEK-ionenes synthesis to achieve a high-performance CO 2 separation membrane with enhanced permeability, selectivity, and mechanical stability. The SIMS spectra and identified characteristic peaks of these synthesized ionenes will serve as a reference in the positive mode, complementing the corresponding spectra reported in the negative ion mode (Paper II).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Spatially resolved absolute densities of reactive species and positive ion flux in He-O 2 RF-driven atmospheric pressure plasma jet: touching and non-touching with dielectric substrate

Atmospheric pressure plasma jets (APPJs) are operating in direct contact with dielectric substrates for many applications. Nonetheless, many studies have been focusing on free jets. In this letter, we report spatially resolved measurements of reactive species including neutral and ionic species in an He + 1% O 2 RF-driven APPJ by molecular beam mass spectrometry equipped with a dielectric sampling plate, enabling to detect species densities for APPJ operating remotely or in direct contact with a substrate. Here, the spatially resolved distribution of O, O 2 (a 1 Δ g ) and O 3 is dominated by convection and, remarkably, shows minimum differences between touching and non-touching conditions.

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS1972

Prevention of cathode damage from positive ion bombardment

Mixed alkaline earth oxide compounds deposited into hole at cathode surface center prevent ion back bombardment damage to cathode by reducing oxide layer and by creating metallic diffusion along sides of hole for enhanced electron emission.

Bennett, W. H.↗
NASA NTRS1972

The plasmapause as measured in positive ions.

Use of extensions of the existing theory of magnetospheric convection to describe the dynamics of the plasmasphere and the variation in the plasmapause location. The equatorial local time plane is divided into three separate and physically distinct regions, the bulge region, the nightside region, and the dayside region, corresponding to local times of 1500 to 2200 hrs, 2200 to 0600 hrs, and 0600 to 1500 hrs, respectively. The characteristics predicted by the model in the bulge region are: presence of the bulge at dusk, 1/R to the 4th power radial dependence of plasma concentration, and large fluctuations in plasma density at the plasmapause and plasma detachment. In the nightside region the predicted characteristics are: rapid response to magnetic activity changes, formative region for plasmasphere ripples, and the formative region for the dayside plasmapause location. The model also predicts the dayside plasmasphere characteristics, such as the slow response to magnetic activity changes, and filling of the plasmasphere from the ionosphere, including the formation of a 'double plasmapause.'

Sharp, G. W.↗
NASA NTRS1971

Effects of positive ion implantation into antireflection coating of silicon solar cells

The state of technological development of Si solar cells for highest obtained efficiency and radiation resistance is summarized. The various theoretical analyses of Si solar cells are reviewed. It is shown that factors controlling blue response are carrier diffusion length, surface recombination, impurity concentration profile in surface region, high level of surface impurity concentration (degeneracy), reflection coefficient of oxide, and absorption coefficient of Si. The theory of ion implantation of charge into the oxide antireflection coating is developed and side effects are discussed. The experimental investigations were directed at determining whether the blue response of Si solar cells could be improved by phosphorus ion charges introduced into the oxide antireflection coating.

Middleton, A. E.↗
NASA NTRS1974

Measurements of positive ion conversion and removal reactions relating to the Jovian ionosphere

Measured rates are presented for the reaction of He(+) ions with H2 (and D2) molecules to form H(+), H2(+), and HeH(+) ions, as well as for the subsequent reactions of H(+) and HeH(+) ions with H2 to form H3(+). The neutralization of H3(+) /and H5(+)/ ions by dissociative recombination with electrons is shown to be fast. The reaction He(+) + H2 is slow (k 1.1 x 10 to the minus 13th cu cm/sec at 300 K) and produces principally H(+) by the dissociative charge transfer branch. It is concluded that there may be a serious bottleneck in the conversion of two of the primary ions of the upper Jovian ionosphere, H(+) and He(+) (which recombine slowly), to the rapidly recombining H3(+) ion.

Johnsen, R.↗