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At least 73 records · Page 4

Remote Detection of Biological Particles and Chemical Plumes Using UV Fluorescence Lidar

A lidar system based on ultraviolet (UV) laser induced fluorescence (LIF) was developed for the remote detection of atmospherically dispersed biological particles and chemical vapors. This UV fluorescence lidar has many potential applications for monitoring environmental pollution, industrial waste emission, agricultural insect control, illicit chemical processing, and military defense operations. The general goal of this work is to investigate the research issues associated with the long range detection and identification of chemicals, e.g. aromatic solvents and chemical precursors, and biological materials, e.g. bacillus thuringiensis (BT) and bacillus globiggi (BG). In the detection of biological particulates, we are particularly interested in extending the detection range of an existing solar-blind 248-nm lidar system. We are investigating the use of longer excitation laser wavelengths (i.e. lambda greater than 280-nm to have more favorable atmospheric light transmission characteristics) for improving detection range to better than 10 km. In the detection of chemical plumes, our main research objectives are to determine how accurately and sensitively a chemical plume can be located at range, and how well spectrally the chemical species can be measured to allow their identification.

J J Tiee↗

Sylph: Life Detection Probe for a Europa Plume

Jupiter’s Galilean satellite Europa likely contains a vast, global, subsurface salt-water ocean. A singular telescope observation in 2012 indicated possible plume activity, in some ways similar to the continuous plume activity seen at Enceladus. If a Europan plume does expel ocean water into space, its vapor, ice grains, and dust grains could be analyzed by a spacecraft equipped with high-resolution mass spectrometers. Such plume measurements would be sufficient to measure the contextual habitability profile of the ocean, and to detect multiple signatures of life, should it exist in the ocean. Instrumented with MASPEX (Mass Spectrometer for Planetary Exploration) and SUDA (Surface Dust Analyzer), NASA’s planned Europa Mission now in development could theoretically conduct this investigation. However, the mission’s closest flyby altitude would be 25 km; due to Europa’s large gravity, frozen ocean spray containing non-volatile molecular species critical to biosignature detection can be sampled only within 5 km of the surface. The Europa Mission would not fly this low. Sylph is a concept for a complementary, free-flyer smallsat probe, about the same size as an office water-cooler bottle, that could be deployed by the Europa Mission as it conducts a plume fly-through. Sylph would execute a single ~2 km altitude plume pass below the main spacecraft. With a mass of 40 kg and a 24-hr life, the probe would autonomously navigate its low-altitude pass, and carry a dualchannel Mini-SUDA impact ionization mass spectrometer that would measure the composition of large grains, complementing the main spacecraft’s measurements of small grains and gas. Sylph is a novel smallsat concept: purpose-built configuration optimized for both the harsh Jovian environment and for Europan planetary-protection requirements, and built with advanced manufacturing methods from both deep space and smallsat components. For $80M (~4% marginal cost), the Europa Mission could buy a Sylph “insurance policy,” hedging the possibility that it does discover ocean plumes upon arrival in 2028. At less than 85 kg for probe and accommodations, the mission could carry two or three of the probes.

Sherwood, Brent↗

Space Shuttle Main Engine plume diagnostics: OPAD approach to vehicle health monitoring

The process of applying spectroscopy to the Space Shuttle Main Engine (SSME) for plume diagnostics, as it exists today, originated at Marshall Space Flight Center in Huntsville, Alabama, and its implementation was assured largely through the efforts of Sverdrup, AEDC, in Tullahoma, Tennessee. This process, Optical Plume Anomaly Detection (OPAD), has formed the basis for various efforts in the development of in-flight plume spectroscopy and in addition produced a viable test stand vehicle health monitor. The purpose of this paper will be to provide an introduction to the OPAD system by discussing the process of obtaining data as well as the methods of examining and interpreting the data.

Powers, W. T.↗

OPAD-EDIFIS Real-Time Processing

The Optical Plume Anomaly Detection (OPAD) detects engine hardware degradation of flight vehicles through identification and quantification of elemental species found in the plume by analyzing the plume emission spectra in a real-time mode. Real-time performance of OPAD relies on extensive software which must report metal amounts in the plume faster than once every 0.5 sec. OPAD software previously written by NASA scientists performed most necessary functions at speeds which were far below what is needed for real-time operation. The research presented in this report improved the execution speed of the software by optimizing the code without changing the algorithms and converting it into a parallelized form which is executed in a shared-memory multiprocessor system. The resulting code was subjected to extensive timing analysis. The report also provides suggestions for further performance improvement by (1) identifying areas of algorithm optimization, (2) recommending commercially available multiprocessor architectures and operating systems to support real-time execution and (3) presenting an initial study of fault-tolerance requirements.

Katsinis, Constantine↗

Detection of particulate air pollution plumes from major point sources using ERTS-1 imagery

The Earth Resources Technology Satellite (ERTS-1) launched by NASA in July 1972 has been providing thousands of high resolution multispectral images of interest to geographers, cartographers, hydrologists, and agroculturists. It has been found possible to detect the long-range (over 50 km) transport of suspected particulate plumes from the Chicago-Gary steel mill complex over Lake Michigan. The observed plumes are readily related to known steel mills, a cement plant, refineries, and fossil-fuel power plants. This has important ramifications when discussing the interregional transport of atmospheric pollutants. Analysis reveals that the Multispectral Scanner Band 5 (0.6 to 0.7 micrometer) provides the best overall contrast between the smoke and the underlying water surface.

Lyons, W. A.↗

SSME Propellant Path Leak Detection

The complicated high-pressure cycle of the space shuttle main engine (SSME) propellant path provides many opportunities for external propellant path leaks while the engine is running. This mode of engine failure may be detected and analyzed with sufficient speed to save critical engine test hardware from destruction. The leaks indicate hardware failures which will damage or destroy an engine if undetected; therefore, detection of both cryogenic and hot gas leaks is the objective of this investigation. The primary objective of this phase of the investigation is the experimental validation of techniques for detecting and analyzing propellant path external leaks which have a high probability of occurring on the SSME. The selection of candidate detection methods requires a good analytic model for leak plumes which would develop from external leaks and an understanding of radiation transfer through the leak plume. One advanced propellant path leak detection technique is obtained by using state-of-the-art technology infrared (IR) thermal imaging systems combined with computer, digital image processing, and expert systems for the engine protection. The feasibility of IR leak plume detection is evaluated on subscale simulated laboratory plumes to determine sensitivity, signal to noise, and general suitability for the application.

Roger Crawford↗

SSME Propellant Path Leak Detection

The primary objective of this phase of the investigation is the experimental validation of techniques for detecting and analyzing propellant path external leaks which have a high probability of occurring on the SSME. The selection of candidate detection methods requires a good analytic model for leak plumes which would develop from external leaks and an understanding of radiation transfer through the leak plume. One advanced propellant path leak detection technique is obtained by using state-of-art technology of infrared (IR) thermal imaging systems combined with computer, digital image processing and expert systems for the engine protection. The feasibility of the IR leak plume detection will be evaluated on subscale simulated laboratory plumes to determine sensitivity, signal to noise, and general suitability for the application. The theoretical analysis was undertaken with the objective of developing and testing simple, easy-to-use models to predict the amount of radiation coming from a radiation source, background plate (BP), which can be absorbed, emitted and scattered by the gas leaks.

Roger Crawford↗

Dynamics of suspended sediment plumes in Lake Ontario

The author has identified the following significant results. Imagery obtained on 25 January 1974, shows a well-defined plume at the mouth of the Niagara River and a much smaller but intense plume emanating from Port Dalhousie Harbor, Ontario. Additionally, a plume can be seen trailing eastward from the outer end of the Welland Canal. This is the first time that a clear-cut winter view of these plumes was detected by the ERTS-1 satellite outside the navigation season. Since the Welland Canal was not in operation, it is likely that the plume, visible along the canal's outer jetty on frames 1551-15313-4-5, was the result of westward moving turbid water emanating from Port Dalhousie Harbor to the west.

Pluhowski, E. J.↗

An Infrared Database of n/k Optical Constants for Calculating Aerosol Spectra for the PICARD Program

The objective of the PICARD Program is to develop fieldable sensing platforms for the rapid chemical identification of aerosol particles in plumes. Standoff detection involves interrogating the aerosol cloud from a distance using optical methods and probing the signal returned from direct backscattering from the aerosol particles or transmitted through the plume after reflection from a retroreflector or surface of opportunity (SOO). The identification of chemical species, however, in aerosols is complicated by their complex compositions and morphologies, chemical interferants, and non-uniform particle sizes. To advance standoff detection of aerosols, modelling the infrared transmittance, reflectance and scattering spectra of aerosolized liquid and solid chemical compounds is required, and then testing that model experimentally via laboratory and field experiments. To perform accurate modeling, the infrared optical constants (n/k), i.e., the complex refractive index, of the compounds of interest are required. Thus, PNNL was tasked to provide the optical constants for a set of analytes relevant to the PICARD program. This report describes the experimental techniques used to derive the optical constants of both liquid and solid compounds using established “gold-standard” protocols, how the experimental data are processed to produce the wavenumber dependent optical constant vectors, and how the data are used in the aerosol absorption spectra modeling.

complex refractive index↗

In situ observations in aircraft exhaust plumes in the lower stratosphere at mid-latitudes

The effect of NO(x) (NO + NO2) from aircraft engine exhaust on ozone and climate is of increasing concern as a result of anticipated growth in the world's subsonic aircraft fleet and new international efforts to build a supersonic transport (SST). Knowledge of NO(x) emissions currently relies on limited ground based testing of combustors and engines and on scaling relations to extrapolate emission values to upper atmosphere conditions. Direct observations made in the engine exhaust plume of the NASA ER-2 high altitude aircraft cruising at subsonic speeds in the lower midlatitude stratosphere are presented. Results demonstrate the technical feasibility of detecting aircraft plumes within minutes after emission with sufficient completeness and precision to calculate emission indices for reactive nitrogen and other species. Furthermore, the combined results increase confidence in using ground based observations to assess the atmospheric impact of some aircraft emissions.

Fahey, David W.↗

SSME Condition Monitoring Using Neural Networks and Plume Spectral Signatures

For a variety of reasons, condition monitoring of the Space Shuttle Main Engine (SSME) has become an important concern for both ground tests and in-flight operation. The complexities of the SSME suggest that active, real-time condition monitoring should be performed to avoid large-scale or catastrophic failure of the engine. In 1986, the SSME became the subject of a plume emission spectroscopy project at NASA's Marshall Space Flight Center (MSFC). Since then, plume emission spectroscopy has recorded many nominal tests and the qualitative spectral features of the SSME plume are now well established. Significant discoveries made with both wide-band and narrow-band plume emission spectroscopy systems led MSFC to develop the Optical Plume Anomaly Detection (OPAD) system. The OPAD system is designed to provide condition monitoring of the SSME during ground-level testing. The operational health of the engine is achieved through the acquisition of spectrally resolved plume emissions and the subsequent identification of abnormal emission levels in the plume indicative of engine erosion or component failure. Eventually, OPAD, or a derivative of the technology, could find its way on to an actual space vehicle and provide in-flight engine condition monitoring. This technology step, however, will require miniaturized hardware capable of processing plume spectral data in real-time. An objective of OPAD condition monitoring is to determine how much of an element is present in the SSME plume. The basic premise is that by knowing the element and its concentration, this could be related back to the health of components within the engine. For example, an abnormal amount of silver in the plume might signify increased wear or deterioration of a particular bearing in the engine. Once an anomaly is identified, the engine could be shut down before catastrophic failure occurs. Currently, element concentrations in the plume are determined iteratively with the help of a non-linear computer code called SPECTRA, developed at the USAF Arnold Engineering Development Center. Ostensibly, the code produces intensity versus wavelength plots (i.e., spectra) when inputs such as element concentrations, reaction temperature, and reaction pressure are provided. However, in order to provide a higher-level analysis, element concentration is not specified explicitly as an input. Instead, two quantum variables, number density and broadening parameter, are used. Past experience with OPAD data analysis has revealed that the region of primary interest in any SSME plume spectrum lies in the wavelength band of 3300 A to 4330 A. Experience has also revealed that some elements, such as iron, cobalt and nickel, cause multiple peaks over the chosen wavelength range whereas other elements (magnesium, for example) have a few, relatively isolated peaks in the chosen wavelength range. Iteration with SPECTRA as a part of OPAD data analysis is an incredibly labor intensive task and not one to be performed by hand. What is really needed is the "inverse" of the computer code but the mathematical model for the inverse mapping is tenuous at best. However, building generalized models based upon known input/output mappings while ignoring details of the governing physical model is possible using neural networks. Thus the objective of the research project described herein was to quickly and accurately predict combustion temperature and element concentrations (i.e., number density and broadening parameter) from a given spectrum using a neural network. In other words, a neural network had to be developed that would provide a generalized "inverse" of the computer code SPECTRA.

Hopkins, Randall↗

Diagnostics of Carbon Nanotube Formation in a Laser Produced Plume: Spectroscopic in situ nanotube detection using spectral absorption and surface temperature measurements by black body emission

Carbon nanotubes hold great promise for material advancements in the areas of composites and electronics. The advancement of research in these areas is dependent upon the availability of carbon nanotubes to a broad spectrum of academic and industrial researchers. Although there has been much progress made in reducing the costs of carbon nanotubes and increasing the quality and purity of the products, an increase in demand for still less expensive and specific nanotubes types has also grown. This summer's work has involved two experiments that have been designed to further the understanding of the dynamics and chemical mechanisms of carbon nanotube formation. It is expected that a better understanding of the process of formation of nanotubes will aid current production designs and stimulate ideas for future production designs increasing the quantity, quality, and production control of carbon nanotubes. The first experiment involved the measurement of surface temperature of the target as a function of time with respect to the ablation lasers. A peak surface temperature of 5000 K was determined from spectral analysis of black body emission from the target surface. The surface temperature as a function of various changes in operating parameters was also obtained. This data is expected to aid the modeling of ablation and plume dynamics. The second experiment involved a time and spatial measurement of the spectrally resolved absorbance of the laser produced plume. This experiment explored the possibility of developing absorbance and fluorescence to detect carbon nanotubes during production. To attain control over the production of nanotubes with specific properties and reduce costs, a real time in situ diagnostics method would be very beneficial. Results from this summer's work indicate that detection of nanotubes during production may possibly be used for production feed back control.

DeBoer, Gary D.↗

Radiative signatures from impact of Comet Shoemaker-Levy-9 on Jupiter

The visible optical power emitted from the expansion plumes from 0.4 and 2 km diameter fragments of Shoemaker-Levy are expected to be, approximately 25% and comparable to, the visible solar flux reflected from Jupiter, respectively, for several minutes, and could be easily observed by sensors on the Galileo spacecraft. Earth-based observers can detect these plumes as these expand over the SW limb of Jupiter and come into earth view some minutes after impact!

Ahrens, Thomas J.↗

Novel and Rugged Electromagnetic Wireless System for Long-Term Subsurface CO₂ Plume Monitoring and Saturation Mapping

Novel and rugged electromagnetic wireless system for long-term subsurface CO₂ plume monitoring and saturation mapping is a Phase I SBIR project led by Cyentech Consulting LLC to develop a permanently installed, outside-casing electromagnetic monitoring system for long-term carbon storage monitoring. The project addresses a major challenge in carbon capture and storage: the need for reliable, cable-free downhole monitoring that can detect CO₂ plume movement and saturation changes without compromising well integrity through casing perforations or external umbilical cables.

58 GEOSCIENCES↗

Dynamics of suspended sediment plumes in Lake Ontario

The absence of turbidity plumes during the winter was well documented in an ususually successful sequence of images obtained February 10 - 12, 1974. Useful imagery of the south shore of Lake Ontario was obtained on 3 successive days at a time when sky cover over the area normally approaches complete coverage. Imagery of the Oswego, Genesee, and Niagara rivers failed to detect any plumes, however faint. Despite strong northwest winds on February 11 there was no indication of shoreline erosion generated by wave action. Frozen ground, snow cover, shoreline icing and minimal construction and farm activity without doubt reduces the probability of sediment movement in winter. Thunderstorm activity over the study area is very rare during the cold season so that the erosive energy of rainfall is greatly reduced. Moreover, a fairly high percentage of the winter precipitation is in the form of snow or sleet further reducing the impact of rainfall energy on sediment transport.

Pluhowski, E. J.↗

Neural network architectures to analyze OPAD data

A prototype Optical Plume Anomaly Detection (OPAD) system is now installed on the space shuttle main engine (SSME) Technology Test Bed (TTB) at MSFC. The OPAD system requirements dictate the need for fast, efficient data processing techniques. To address this need of the OPAD system, a study was conducted into how artificial neural networks could be used to assist in the analysis of plume spectral data.

Whitaker, Kevin W.↗

Using neural networks to assist in OPAD data analysis

The space shuttle main engine (SSME) became the subject of plume emission spectroscopy in 1986 when researchers from NASA-Marshall Space Flight Center (MSFC), Arnold Engineering Development Center (AEDC), and Rocketdyne went to the SSME test stands at the NASA-Stennis Space Center and at Rocketdyne's Santa Susan Field Laboratory to optically observe the plume. Since then, plume spectral acquisitions have recorded many nominal tests and the qualitative spectral features of the SSME plume are now well established. Significant discoveries made with both wide-band and narrow-band plume emission spectroscopy systems led MSFC to promote the Optical Plume Anomaly Detection (OPAD) program with a goal of instrumenting all SSME test stands with customized spectrometer systems. A prototype OPAD system is now installed on the SSME Technology Test Bed (TTB) at MSFC. The OPAD system instrumentation consists of a broad-band, optical multiple-channel analyzer (OMA) and a narrow-band device called a polychrometer. The OMA is a high-resolution (1.5-2.0 Angstroms) 'super-spectrometer' covering the near-ultraviolet to near-infrared waveband (2800-7400 Angstroms), providing two scans per second. The polychrometer consists of sixteen narrow-band radiometers: fourteen monitoring discrete wavelengths of health and condition monitoring elements and two dedicated to monitoring background emissions. All sixteen channels are capable of providing 500 samples per second. To date, the prototype OPAD system has been used during 43 SSME firings on the TTB, collecting well over 250 megabytes of plume spectral data. One goal of OPAD data analysis is to determine interatively with the help of a computer code, SPECTRA4, developed at AEDC. Experience has shown that iteration with SPECTRA4 is an incredibly labor intensive task and not one to be performed by band. What is really needed is the 'inverse' of SPECTRA4 but the mathematical model for this inverse mapping is tenuous at best. However, the robustness of PSECTRA4 run in the 'forward' direction means that accurate input/output mappings can be obtained. If the mappings were inverted (i.e., input becomes output and output becomes input) then an 'inverse' of SPECTRA4 would be at hand but the 'model' would be specific to the data utilized and would in no way be general. Building a generalized model based upon known input/output mappings while ignoring the details of the governing physical model is possible through the use of a neural network. The research investigation described involves the development of a neural network to provide a generalized 'inverse' of SPECTRA4. The objectives of the research were to design an appropriate neural network architecture, train the network, and then evaluate its performance.

Whitaker, Kevin W.↗

A Fly-Through Mission Strategy Targeting Peptide as a Signature of Chemical Evolution and Possible Life in Enceladus Plumes

In situ detection of organic molecules in the extraterrestrial environment provides a key step towards better understanding the variety and the distribution of building blocks of life and it may ultimately lead to finding extraterrestrial life within the Solar System. Here we present combined results of two separate experiments that enable us to realize such in situ life signature detection from the deep habitats of the "Ocean World": a hydrothermal reactor experiment simulating complex organic synthesis and a simulated fly-through capture experiment of organic-bearing microparticles using silica aerogels, followed by subsequent analysis. Both experiments employ peptide as a plausible organics existing in Encleadus plume particles produced in its subsurface ocean. Recent laboratory hydrothermal experiments and a theoretical model on silica saturation indicated an on going hydrothermal reactions in subsurface Enceladus ocean. Given the porous chondritic origin of the core, it is likely that organic compounds originated by radiation chemistry such as amino acid precursors could have been provided, leached, and altered through widespread water-rock interactions. By using the same laboratory experimental setup from the latest water-rock interaction study, we performed amino acid polymerization experiments for 144 days and monitored the organic complexity changing over time. So far over 3,000 peaks up to the size of greater than 600 MW were observed through the analysis of capillary electrophoresis time-of-flight mass spectrometry (CE-TOF-MS) with an indication of amino acid derivatives and short peptides. Generally abiotic polymerization of enantiomeric amino acids results in forming stereoisomeric peptides with identical molecular weight and formula as opposed to homochiral biopolymers. Assuming Enceladus plume particles may contain a mixture of stereoisomeric peptides, we were able to distinguish 16 of the 17 stereoisomeric tripeptides as a test sample using capillary electrophoresis (CE) under optimized conditions. We further conducted Enceladus plume fly-through capture experiment by accelerating peptides soaked in rock particles up to a speed of 5.7 km/s and capturing with originally developed hydrophobic silica aerogels. Direct peptide extraction with acetonitrile-water followed by CE analysis led to detection of only but two stereoisomeric acidic peptide peaks, presenting the first run-through hypervelocuty impact sample analysis targeting peptides as key molecule to to understand the ongoing astrobiology on Enceladus.

organic molecules↗