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On the New Optical Constants Database (OCdb) and its Importance for the Interpretation of Observational Data
The Optical Constants database(ocdb.smce.nasa.gov) came online in February 2023 and provides complex refractive indices of laboratory-generated organic refractory materials and ices relevant to (exo) planetary and astrophysical environments.The goal of the OCdb is to centralize published optical constants data to facilitate both their access by the scientific community and their use to analyze observational data returned by space missions and ground-based observatories. Computational tools are also under development to facilitate scientific use of the available OCdb optical constants data sets. Investigators generating laboratory optical constants are therefore encouraged to contribute their data to OCdb in order to increase the availability of their data and to enhance the scientific effectiveness of the database. Optical constants are critical input parameters in models (e.g.,radiative transfer, atmospheric, and reflectance spectral models)that are used to simulate the absorption, reflection, and scattering of light due to solid materials present in planetary and astrophysical environments (planets, their satellites, exoplanets, asteroids, comets, protoplanetary disks, etc.), and are key to the compositional interpretation of observations. We will first present the infrastructure of the OCdb and show how to use and contribute to it. We will introduce the two large NASA projects, namely, the Laboratory Astrophysics Directed Work Package and the NASA Center for Optical Constants, that have been instrumental in (i) developing the OCdb, (ii) generating planetary-and astrophysics-relevant ices and organic refractory materials from gas and ice irradiation in the laboratory, and (iii) determining their optical constants for inclusion in OCdb. We will also present two studies that are making use of these optical constants to interpret observations of Titan’s atmosphere and Pluto’s surface. These studies show the importance of measuring optical constants of laboratory-generated materials, and their impact on the models used to analyze and interpret astronomical observations. These studies also demonstrate the essential importance of such a database and the need for optical constants of a broad range of materials and wavelengths to enable the scientific community and to maximize the scientific return from space missions (e.g., Cassini, New Horizons, SOFIA, JWST).
Formation of H2 on amorphous ice grains and their importance for planetary atmospheres
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Stress-activated electric currents in icy planetary bodies: H2O2-doped H2O ices
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Remote Pulsed Laser Raman Spectroscopy System for Detecting Qater, Ice, and Hydrous Minerals
For exploration of planetary surfaces, detection of water and ice is of great interest in supporting existence of life on other planets. Therefore, a remote Raman spectroscopy system was demonstrated at NASA Langley Research Center in collaboration with University of Hawaii for detecting ice-water and hydrous minerals on planetary surfaces. In this study, a 532 nm pulsed laser is utilized as an excitation source to allow detection in high background radiation conditions. The Raman scattered signal is collected by a 4-inch telescope positioned in front of a spectrograph. The Raman spectrum is analyzed using a spectrograph equipped with a holographic super notch filter to eliminate Rayleigh scattering, and a holographic transmission grating that simultaneously disperses two spectral tracks onto the detector for higher spectral range. To view the spectrum, the spectrograph is coupled to an intensified charge-coupled device (ICCD), which allows detection of very weak Stokes line. The ICCD is operated in gated mode to further suppress effects from background radiation and long-lived fluorescence. The sample is placed at 5.6 m from the telescope, and the laser is mounted on the telescope in a coaxial geometry to achieve maximum performance. The system was calibrated using the spectral lines of a Neon lamp source. To evaluate the system, Raman standard samples such as calcite, naphthalene, acetone, and isopropyl alcohol were analyzed. The Raman evaluation technique was used to analyze water, ice and other hydrous minerals and results from these species are presented.
The Compact Microimaging Spectrometer (CMIS): A New Tool for In-Situ Planetary Science
In-situ identification of trace minerals, ices, or organics in planetary samples may be difficult with panchromatic microscopic imagery and spot spectroscopy. The panchromatic imagery acquired by a microscopic imager provides morphological information and albedo, but these are generally insufficient for unambiguous identification. The spatially-averaged spectra acquired by a nonimaging ( point- or spot- ) spectrometer may enable identification of the major components but identification of unknown trace components is difficult at best. With our Compact Micro-Imaging Spectrometer (CMIS), however, we acquire spectroscopic data in an imaging format at microscopic scales. The distinct spectra of individual grains, provided by our approach, make detection and identification possible even for trace components in regolith or heterogeneous samples.
Sublimation and Infrared Spectral Properties of Ammonium Cyanide
The ammonium ion (NH 4 + ) has been suggested to be present in interstellar ices and has been observed on the surfaces of planetary bodies using infrared (IR) spectroscopy as the primary means of identification. Evidence for several ammonium salts has also been found in the dust and surface ices of comet 67P/Churyumov-Gerasimenko. Here we present a laboratory study of ammonium cyanide (NH 4 CN) and report on several properties of this compound, measured with higher accuracy than in previous reports, including its IR band strengths and optical constants for use in quantifying its abundance in interstellar and planetary ices. We also report the first measurements since 1882 of NH 4 CN vapor pressures, sublimation fluxes, and sublimation enthalpy measured at temperatures relevant to subliming cometary ices (134–155 K). The density and refractive index of NH 4 CN at 125 K and the sublimation enthalpy and vapor pressures of NH 3 at ~100 K are also reported.
Acoustic Sensor Network for Planetary Exploration
This paper investigates the concept of an acoustic sensor network that can monitor a variety of geophysical processes occurring on other planetary bodies. In many cases sound is naturally omnidirectional and travels at known speeds which depend on the composition and density of the atmosphere. The differences in the time of flight of signals received by a distributed microphone network can be used to locate the source of the sound. We suggest this property is ideal for mobile planetary robots and can be used to expand the exploration envelope considerably by directing camera pointing or rover path planning thus extending beyond line-of-sight exploration. Acoustic signatures have been used in a variety of fields (e.g., sonar, heavy machinery) to identify and catalog sounds associated with a specific vessels and malfunctioning machinery. Our ears have cataloged hundreds of sounds and we continuously use these sounds both consciously and subconsciously to extract information about our surroundings. This paper investigates the use acoustic measurements on other planetary bodies that could be used to characterize specific environmental parameters such as rain droplet size, wind speed, thunder, or dust devil vortex diameter. The paper identified other important sound sources that are thought to occur on other bodies in our solar system include; booming or singing dunes, waves, rivers, streams, fluidfalls, geysers, hurricanes, tornados, ice flow, volcanoes, planetary quakes, avalanche, rock slides and ice cracking. In addition, this paper focused on issues associated with the development of appropriate sensors for the network including the specification of the sensitivity, frequency response, and directional response of each of the microphones in the network in order to aid in localization of sound sources. We also presented our initial development of the transducers for potential mission targets including Mars and Titan and investigated the use of signal processing techniques including windowing, time frequency plots and correlation techniques to resolve phase differences between sensors in the network to aid in localization. We also identified additional benefits of these sensor networks in that they could used as engineering sensors to diagnose mechanical malfunctions on a rover or lander actuators or mechanisms. We also noted that they could also enhance public outreach by adding sound to videos.
Aerocapture as an Enabling Option for Ice Giants Missions
Investigation of Uranus and Neptune, via orbiter and atmospheric probes, is required to answer pressing science questions that have been raised in previous Decadal Surveys. As the Ice Giants are the farthest planets from Earth, traditional fully-propulsive orbit insertion missions have transit times to the planetary bodies nearing 13-15 years and require a large amount of propellant, leaving less mass for the scientific payload (dry mass percentages of around 30-40%). Aerocapture uses aerodynamic forces generated by flight within a planetary atmosphere to decelerate and achieve orbit insertion. Although, aerocapture has not been used in the past, recent developments in thermal protection systems, guidance and control, and interplanetary navigation capabilities enable the use of rigid, heritage entry vehicle configurations already flown at other planetary bodies for Ice Giants aerocapture. With the addition of these recent capabilities, aerocapture can robustly deliver spacecraft to Ice Giant orbits, while substantially increasing on-orbit payload mass (more than 40%) and reducing the transit time by 2-5 years (15-30%) relative to fully-propulsive orbit insertion.
Enabling In-Situ Exploration of the Ice Giants Using Aerocapture
Investigation of the Ice Giants, especially Uranus, via orbiter and atmospheric probes, is required to answer pressing science questions that have been raised in the latest Decadal Survey. As the Ice Giants are the farthest planets from Earth, traditional fully-propulsive orbit insertion missions have transit times to the planetary bodies nearing 13- 15 years and require a large amount of propellant, leaving less mass for the scientific payload and a planetary probe (dry mass percentages of around 30- 40%). Aerocapture uses aerodynamic forces generated by flight within a planetary atmosphere to decelerate and achieve orbit insertion. Although, aerocapture has not been used in the past, recent developments in thermal protection systems (TPS), guidance and control, and interplanetary navigation capabilities enable the use of rigid, heritage entry vehicle configurations already flown at other planetary bodies for Ice Giants aerocapture. Aerocapture can robustly deliver spacecraft to Ice Giant orbits, while substantially increasing on-orbit payload mass (more than 40%) that can be used for a robust atmospheric entry probe. Additionally, the aerocapture maneuver would reduce the interplanetary transit time by 2-5 years (15-30%) relative to fully-propulsive orbit insertion.
Flagship-Class Uranus Orbiter and Probe Using Aerocapture
Exploration of the Ice Giants, especially Uranus, via orbiter and atmospheric probes, is required to answer pressing science questions that have been raised in the latest Decadal Survey. As the Ice Giants are the farthest planets from Earth, traditional fully-propulsive orbit insertion missions have transit times to the planetary bodies nearing 13-15 years and require a large amount of propellant (wet mass percentages of around 60-70%) for the orbit insertion maneuver, leaving less mass for the scientific payload and a planetary probe. Aerocapture uses aerodynamic forces generated by flight within a planetary atmosphere to decelerate and achieve orbit insertion. Aerocapture has been considered for several past missions but it has not been demonstrated. However, recent developments in thermal protection systems (TPS), guidance and control (G&C), and interplanetary navigation capabilities show the potential for using rigid, heritage entry vehicle configurations already flown at other planetary bodies for Ice Giants aerocapture. Aerocapture can robustly deliver spacecraft to Ice Giant orbits, while substantially increasing on-orbit payload mass (more than 40%) that can be used for a robust atmospheric entry probe. Additionally, the aerocapture maneuver would reduce the interplanetary transit time by 2-5 years (15-30%) relative to fully-propulsive orbit insertion. Recent work has shown that a flagship-class mission can be conducted in a shorter time than fully-propulsive missions if using aerocapture.
Issues in subsurface exploration of ice sheets
Exploration of the deep subsurface ice sheets of Earth, Mars, Europa, and Titan has become a major consideration in addressing scientific objectives in climate change, extremophile biology, exobiology,chemical weathering, planetary evolution and ice dynamics.
Rotational Spectroscopy is SubLIME: Site-Specific Identification of Compounds Formed on UV-photolyzed Cosmcs Ice
A variety of organic compounds has been detected in comets, meteorites, and the cold gas enveloping infant stars. These compounds display a range of complexity and include so-called complex organic molecules that may have astrobiological implications. Laboratory studies of photolyzed and nonirradiated interstellar, planetary, and cometary ices have demonstrated many astrochemical formation routes and require sensitive analytical techniques to identify the composition of ice and gas products formed. The unique identification of organics can be challenging and often requires structure-specific techniques to identify structural isomers, conformers, and isotopologues. We present the approaches used in SubLIME, the Sublimation of Laboratory Ices Millimeter/submillimeter Experiment, which uses the structure-specificity of rotational spectroscopy to identify the composition and abundances of sublimated products of UV-photolyzed ice samples. Ices are formed and photolyzed at low temperature (~10 K) and slowly heated to 300 K to sublimate the volatile products. The gas mixture is then investigated with millimeter/submillimeter spectroscopy, and the resulting spectra compared to observational spectra collected with submillimeter/far-IR telescopes. We present the experimental set-up and results of UV-photolyzed interstellar ice analogues containing water (H O) and carbon monoxide (CO). Formation routes for identified molecules are proposed for follow-up experimental and theoretical investigations.
Aerocapture as an Enhancing Option for Ice Giants Missions
Investigation of Uranus and Neptune, via orbiter and atmospheric probes, is required to answer pressing science questions that have been raised in previous Decadal Surveys. As the Ice Giants are the farthest planets from Earth, traditional fully-propulsive orbit insertion missions would require a large amount of propellant, leaving less mass for the scientific payload; additionally, transit time to the planetary bodies near 13-15 years. Aerocapture uses aerodynamic forces generated by flight within a planetary atmosphere to decelerate and achieve orbit insertion. Although, aerocapture has not been used in the past, recent developments in thermal protection systems, guidance and control, and navigation capabilities enable the use of rigid, heritage entry vehicle configurations already flown at other planetary bodies for Ice Giants aerocapture. With the addition of these recent capabilities, aerocapture can robustly deliver spacecraft to Ice Giant orbits, while substantially increasing on-orbit payload mass (more than 40%) and reducing the transit time by 2-5 years (15-30%) relative to fully-propulsive orbit insertion.
Lunar and Planetary Science XXXV: Lunar Remote Sensing: Fire, Ice, and Regolith
The session "Lunar Remote Sensing: Fire, Ice, and Regolith" included the following:Compositional and Structural Study of the Aristarchus Plateau from Integrated UV-VIS-NIR Spectral Data; Clementine 2.7-?m Data: Mapping the Mare and Searching for Water; On the Search for Water at the Lunar Poles: Results of Forward Modeling of Permanently Shaded Areas and Lunar Prospector Measurements; Searching the Moon for Aluminous Mare Basalts Using Compositional Remote-Sensing Constraints I: Finding the Regions of Interest; Semi-automated Extraction of Contours from Lunar Topographic Maps; Basalts in Mare Humorum and S.E. Procellarum; The Hansteen and Helmet Volcanic Dome Regions on the Moon: Stratigraphy and Ages; Derivation of Elemental Abundance Maps at 15-km Spatial Resolution from the Merging of Clementine Optical and Lunar Prospector Geochemical Data; Remote Sensing and Geologic Studies of the Balmer Region of the Moon; Lava Flows in Mare Nubium and Mare Cognitum: A Geological History Based on Analysis of Multispectral Data; Development of Ground-based Lunar VIS/NEAR IR Spectral Imager; A BRDF Measurement Apparatus for Lab-based Samples; A New Source of High Resolution Lunar Images: Amateur Astronomers! ; Leakage of Gamma Rays and Neutrons from Thick Targets Bombarded by Energetic Protons; Progress on Reviving Lunar Orbiter: Scanning, Archiving, and Cartographic Processing at USGS; Modeling Lateral and Vertical Mixing by Impact Cratering with Applications for the Moon; Optical Maturity Study of Stuart#s Crater Candidate Impact; Evidence for Three Basins Beneath Oceanus Procellarum; and Ellipses of the South Pole-Aitken Basin: Implications for Basin Formation.
Rheology of Diabase: Implications for Tectonics on Venus and Mars
Two important goals of our experimental investigation of the rheological behavior of diabase rocks were: (1) to determine flow laws describing their creep behavior over wide ranges of temperature, stress and strain rate and (2) to develop an understanding of the physical mechanisms by which these rocks flow under laboratory conditions. With this basis, a primary objective then was to construct constitutive equations that can be used to extrapolate from laboratory to planetary conditions. We specifically studied the rheological properties of both natural rock samples and synthetic aggregates. The former provided constraints for geologic systems, while the latter defined the relative contributions of the constituent mineral phases and avoided the influence of glass/melt found in natural samples. In addition, partially molten samples of crustal rock composition were deformed in shear to large strains (greater than 200%) important in crustal environments. The results of this research yielded essential rheological properties essential for models of crustal deformation on terrestrial planets, specifically Venus and Mars, as well as on the geodynamical evolution of these planets. Over the past three years, we also completed our investigation of the creep behavior of water ice with applications to the glaciers, ice sheets and icy satellites. Constitutive equations were determined that describe flow over a wide ranged of stress, strain rate, grain size and temperature. In the case of ice, three creep regimes were delineate. Extrapolation demonstrates that dislocation glide and grain boundary sliding processes dominate flow in ice I under planetary conditions and that diffusion creep is not an important deformation mechanism either in the laboratory or on icy satellites. These results have already been incorporated by other investigators into models describing, for example, the thickness and stability of the ice shell on Europa and to unravel long-standing discrepancies between field observations on glaciers and laboratory results.
Surface Water-Ice Deposits in the Northern Shadowed Regions of Ceres
Ceres, a dwarf planet located in the main asteroid belt, has a low bulk density, and models predict that a substantial amount of water ice is present in its mantle and outer shell. The Herschel telescope and the Dawn spacecraft have observed the release of water vapor from Ceres, and exposed water ice has been detected by Dawn on its surface at mid-latitudes. Water molecules from endogenic and exogenic sources can also be cold-trapped in permanent shadows at high latitudes, as happens on the Moon and Mercury. Here we present the first image-based survey of Ceres's northern permanent shadows and report the discovery of bright deposits in cold traps. We identify a minimum of 634 permanently shadowed craters. Bright deposits are detected on the floors of just 10 of these craters in multiscattered light. We spectroscopically identify one of the bright deposits as water ice. This detection strengthens the evidence that permanently shadowed areas have preserved water ice on airless planetary bodies.
Uranus and Neptune Missions: A Study in Advance of the Next Planetary Science Decadal Survey
The ice giant planets, Uranus and Neptune, represent an important and relatively unexplored class of planet. Most of our detailed information about them comes from fleeting looks by the Voyager 2 spacecraft in the 1980s. Voyager, and ground-based work since then, found that these planets, their satellites, rings, and magnetospheres, challenge our understanding of the formation and evolution of planetary systems. We also now know that Uranus- Neptune size planets are common around other stars. These are some of the reasons ice giant exploration was a high priority in NASA's most recent Planetary Science Decadal Survey. In preparation for the next Decadal Survey, NASA, with ESA participation, conducted a broad study of possible ice giant missions in the 2024–2037 timeframe. This paper summarizes the key results of the study, and addresses questions that have been raised by the science community and in a recent NASA review. Foremost amongst these are questions about the science objectives, the science payload, and the importance of an atmospheric probe. The conclusions of the NASA/ESA study remain valid. In particular, it is a high priority to send an orbiter and atmospheric probe to at least one of the ice giants, with instrumentation to study all components of an ice giant system. Uranus and Neptune are found to be equally compelling as science targets. The two planets are not equivalent, however, and each system has things to teach us the other cannot. An additional mission study is needed to refine plans for future exploration of these worlds.