Hybrid Solid State ?Chaperone? Phases to Improve Solid State Sodium Electrolytes.
Abstract not provided.
Spoerke, Erik David↗
SEARCH · Engineering Papers
Results for “phase state”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Mixed-state geometric phases of coherent and squeezed spin states
Two mixed-state geometric phases, known as the Uhlmann phase and interferometric geometric phase (IGP), of spin coherent states (CSSs) and spin squeezed states (SSSs) are analyzed. Exact solutions and numerical results of selected examples are presented. For the 𝑗=3/2 CSS, the Uhlmann phase exhibits finite-temperature topological phase transitions characterized by abrupt jumps. The IGP for the same state similarly shows discontinuous jumps as the temperature varies. In the case of the 𝑗=1 one-axis SSS, both the Uhlmann phase and IGP display discrete finite-temperature jumps. By contrast, the 𝑗=1 two-axis SSS shows no such transitions because the Uhlmann phase and IGP both vary smoothly with temperature. Here, we also briefly discuss potential realizations and simulations related to these phenomena in spin systems.
Geometric & topological phases↗
Predicting the influence of particle size on the glass transition temperature and viscosity of secondary organic material
Abstract Atmospheric aerosols can assume liquid, amorphous semi-solid or glassy, and crystalline phase states. Particle phase state plays a critical role in understanding and predicting aerosol impacts on human health, visibility, cloud formation, and climate. Melting point depression increases with decreasing particle diameter and is predicted by the Gibbs–Thompson relationship. This work reviews existing data on the melting point depression to constrain a simple parameterization of the process. The parameter $$\xi $$ ξ describes the degree to which particle size lowers the melting point and is found to vary between 300 and 1800 K nm for a wide range of particle compositions. The parameterization is used together with existing frameworks for modeling the temperature and RH dependence of viscosity to predict the influence of particle size on the glass transition temperature and viscosity of secondary organic aerosol formed from the oxidation of $$\alpha $$ α -pinene. Literature data are broadly consistent with the predictions. The model predicts a sharp decrease in viscosity for particles less than 100 nm in diameter. It is computationally efficient and suitable for inclusion in models to evaluate the potential influence of the phase change on atmospheric processes. New experimental data of the size-dependence of particle viscosity for atmospheric aerosol mimics are needed to thoroughly validate the predictions.
36 MATERIALS SCIENCE↗
A thermodynamically consistent finite strain phase field approach to ductile fracture considering multi-axial stress states
Phase field models for ductile fracture have gained significant attention in the last two decades due to their ability in implicitly tracking the nucleation and propagation of cracks. However, most crack phase field formulations for elastoplastic solids focus only on the effects of plastic deformation, and do not consider the different multi-axial stress states that may arise in practical designs. In this work, a thermodynamically consistent phase field approach coupled with finite strain plasticity, considering multi-axial stress states is presented. In order to account for the coupling between plasticity and stress states, the Stress-Weighted Ductile Fracture Model (SWDFM) is utilized. The SWDFM represents a criterion for predicting ductile crack initiation under both monotonic and cyclic loadings based on histories of an internal plastic variable, stress triaxiality, and the Lode angle parameter. The excellent performance of the SWDFM for predicting ductile crack initiation motivates for its incorporation into a phase field approach for predicting both crack initiation and propagation through degradation of the fracture toughness. Moreover, based on the second law of thermodynamics, exact requirements are imposed on the rate at which the fracture toughness can evolve. Here, a novel function for degrading the plastic yield surface during the evolution of damage is introduced. This function, in line with experimental observations, leads to an accumulation of plastic deformation in damaged regions of a solid, and avoids numerical instabilities arising from concentrations of large plastic deformations in severely damaged regions. For validating the proposed model, results of computational simulations are compared to data from selected tests considering different multi-axial stress states. Comparisons of the numerical results with data from laboratory experiments demonstrate the capabilities of the proposed framework.
42 ENGINEERING↗
Phase array calibration orthogonal phase sequence
Methods and systems for calibrating an array antenna are described. The array antenna has a plurality of antenna elements each having a signal with a phase and an amplitude forming an array antenna signal. For calibration, the phase of each element signal is sequentially switched one at a time through four orthogonal phase states. At each orthogonal phase state, the power of the array antenna signal is measured. A phase and an amplitude error for each of the element signals is determined based on the power of the array antenna signal at each of the four orthogonal phase states. The phase and amplitude of each of the element signals is then adjusted by the corresponding phase and amplitude errors.
Sorace, Ronald E.↗
On the dependence of travelling wave stability on basic state wave phase speed
The dependence of stability on basic state wave phase speed is examined in a nondivergent barotropic model on a sphere for planetary scale waves with phase speeds typical of waves observed in the atmosphere. Triad interactions are examined analytically and compared to numerical results from a full spectral model. A number of triads may result in growth of the perturbation components for each basic state wave; for each triad there is a basic state wave phase speed where it is resonant, identified as the point where the critical amplitude for instability to that perturbation becomes zero. Critical amplitudes for instability obtained using the full spectral model generally agree well with triad results. Since the basic state wave phase speed determines which triad will grow, spatial structure and critical amplitudes for instability for the growing disturbances depend strongly on basic state wave phase speed. The results of this idealized study suggest that phase speed may be an important factor in determining the stability of planetary scale waves in the atmosphere.
Manney, Gloria L.↗
Solid-state retrodirective phased array concepts for microwave power transmission from Solar Power Satellite
Two prototype solid-state phased array systems concepts for potential use in the Solar Power Satellite are described. In both concepts, the beam is centered on the rectenna by means of phase conjugation of a pilot signal emanating from the ground. Also discussed is on-going solid-state amplifier development.
Schroeder, K. G.↗
Topological Mott transition in a two band model of spinless fermions with on-site Coulomb repulsion
Highlights: • The effect of the on-site Coulomb repulsion and the spin–orbit Rashba coupling lead to the 2D topological semimetal. • The ground state phase diagram is calculated. • The topological semimetal phase is characterized by the zero energy Majorana states. In the framework of mean field approach, we study topological Mott transition in a two band model of spinless fermions on a square lattice at half filling. We consider the combined effect of the on-site Coulomb repulsion and the spin–orbit Rashba coupling. The ground state phase diagram is calculated as a function of the strength of the spin–orbit Rashba coupling and the Coulomb repulsion. The spin–orbit Rashba coupling leads to a distinct phase of matter, the topological semimetal. We study a new type of phase transition between the non-topological insulator and topological semimetal states. Topological phase state is characterized by the zero energy Majorana states, which there are in defined region of the wave vectors and are localized at the boundaries of the sample. The region of existence of the zero energy Majorana states tends to zero at the point of the Mott phase transition. The zero energy Majorana states are dispersionless (they can be considered as flat bands), the Chern number and Hall conductance are equal to zero (note in two dimensional model).
36 MATERIALS SCIENCE↗
A General State Estimation Formulation for Three-Phase Unbalanced Power Systems
Almost all of the three-phase state estimation algorithms assume existence of a reference bus whose phase angles are perfectly balanced. This assumption is quite realistic for transmission systems, and also for most distribution systems that are connected to a strong transmission system where transmission side can modeled by a balanced reference bus. However, for distribution systems having high penetration of renewable sources or for microgrids operating in islanded mode, the assumption of a balanced reference bus will not be realistic. While there are recent publications focusing on this problem, formulation of the three-phase unbalanced state estimation problem with proper treatment of the reference bus remains unaddressed. In this paper, a new formulation will be described where an accurate state estimation solution can be obtained for any unbalanced threephase system irrespective of its operating conditions (balanced or highly unbalanced), configuration (isolated microgrid, connected to transmission system, etc.) and whether or not it contains any synchronous generators. Validation of the proposed formulation will be carried out via simulations.
State Estimation, Distribution System, Unbalanced ↗
International Space Station Bipropellant Plume Contamination Model Update for Short Thruster Pulse Widths
The International Space Station (ISS) Bipropellant Plume Contamination Model has been a vital tool for characterizing the thruster plume-induced contamination environment at the ISS but was not intended to be used for very short thruster pulse widths. This paper presents an updated model that ensures full start-up and shut-down phases are modeled for each thruster firing, when the majority of liquid phase contaminant mass is released. The updated ISS Bipropellant Plume Contamination Model prevents potential under-prediction of thruster plume-induced contamination due to visiting vehicle proximity operations and provides a way to take advantage of thruster start-up and shut-down data performance data gathered during thruster test programs, if available. The International Space Station (ISS) Bipropellant Plume Contamination Model developed by Boeing Space Environments is a semi-empirical model anchored in flight experiment data and has been a vital tool for characterizing the thruster plume-induced contamination environment at the ISS.[1] The current model utilizes flight experiment data from the Plume Impingement Contamination (PIC) and Shuttle Plume Impingement Flight Experiment (SPIFEX) studies, which include Orbiter 3870 N Primary Reaction Control System (PRCS) and Russian 130 N thrusters operating in pulse mode with 80-100 ms.[2] As the next generation of crew and cargo visiting vehicles are developed and arrive at ISS, minimum pulse widths of vehicle thrusters used for ISS proximity operations have decreased significantly below 80 ms. An update to the ISS Bipropellant Contamination Model is needed to prevent potential under-prediction of thruster plume-induced contamination for these very short pulse widths. Contamination due to thruster plumes occurs in the liquid phase (i.e., unburned or partially burned propellant in the plume). Liquid phase releases primarily occur during thruster start-up and shut-down phases, with the steady state phase contributing a small amount to the total contaminant mass released. The current ISS Bipropellant Plume Contamination Model includes functional dependencies on thruster parameters (thrust, mass flow rate, specific impulse (Isp)), distance to receiver surface, and angle off plume centerline. For modeling purposes, contaminant mass released scales linearly with pulse width. This is a conservative approach for pulse widths greater than 80 ms but could under-predict contamination for very short pulse widths (i.e., with little or no steady state phase). This paper presents a model update to add a functional dependency on commanded pulse width to ensure the portion of the pulse spent in start-up and shut-down phases is appropriately modeled, when the majority of liquid phase contaminant mass is released. The updated model prevents potential under-prediction of thruster plume-induced contamination due to visiting vehicle proximity operations while providing a way to take advantage of thruster start-up and shut-down data gathered during test programs, if available. Developing the plume model for a specific thruster using the ISS Bipropellant Plume Contamination Model must be done in consideration of all available thruster performance data. Example thruster data will be used to illustrate this point and options for implementing the model update with existing ISS Bipropellant Plume Contamination Model code will be discussed.
plume contamination↗
Revisiting the Effects of Seed Liquid Water Content on Isoprene Secondary Organic Aerosol Growth
Aerosol liquid water content (LWC) has been shown to enhance partitioning of water-soluble oxygenated organic vapors into the aerosol particles and facilitate aqueous chemistry, impact SOA formation, composition, and physicochemical properties. Here, this study examines the effect of aerosol liquid water content (LWC) on isoprene SOA formation using effloresced and deliquesced ammonium sulfate ((NH 4 ) 2 SO 4 ) and sodium chloride (NaCl) seed particles in an environmental chamber with photo-oxidation extending over hours under moderate relative humidity (50%-60%). Our findings indicate that isoprene SOA mass yield is not significantly influenced (p value >> 0.05) by the phase state or the chemical identity of the seed particles within a 3–4-hour reaction time scale. Detailed molecular analysis using advanced high resolution mass spectrometry indicates that while both effloresced and deliquesced seed types produced similar molecular formula distributions, deliquesced (NH 4 ) 2 SO 4 slightly favored the production of less volatile compounds. Depth-profiling analysis by single particle mass spectrometry confirmed that isoprene SOA predominantly located on the surfaces of particles with core-shell morphologies, with partial dissolution of the effloresced inorganic salt observed even below the deliquescence relative humidity (DRH) of salt. This finding suggests that assuming dry salt core particles do not interact with SOA coatings, based on salt deliquescence points, may overlook important aqueous chemistry. These results emphasize the critical role of reaction time scale and mixing state on SOA formation and call for further research to understand LWC effects on SOA from different precursors.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Haze processing of atmospheric particles during wintertime in the Indo-Gangetic Plains
The impacts of haze on visibility, air quality, and climate are not well quantified due to a lack of understanding of the evolution of the mixing state and phase state of atmospheric particles during haze processing. The variability of the mixing state of atmospheric particles contributes significantly to uncertainties associated with the estimated aerosol radiative forcing. We collected particle samples in January 2018 from the highly polluted Indo-Gangetic plain during hazy conditions to study haze-processed particles. Single particle analysis using multi-modal micro-spectroscopy techniques revealed an abundance (40–70% by number) of potassium-rich sulfate particles from biomass-burning influenced smoke. Tilted view imaging showed that most of the organic particles that had inorganic potassium and sulfate inclusions were liquid-like while those without inclusions were more semi-solid. High-resolution mass spectrometry analysis revealed a significant presence of organosulfates and nitroxy-organosulfates in the morning samples (24%) compared to the afternoon samples (9%), despite higher relative humidity in the afternoon. Overall, our results highlight the significant contribution of both organic and inorganic sulfate to the total particulate sulfur budget during haze processing in winter, when anthropogenic emissions such as household burning, agricultural burning, and vehicular emissions are major contributors to particle mass.
Mathai, Susan [Pacific Northwest National Laborato↗
Propagating confined states in phase dynamics
Theoretical treatment is given to the possibility of the existence of propagating confined states in the nonlinear phase equation by generalizing stationary confined states. The nonlinear phase equation is set forth for the case of propagating patterns with long wavelengths and low-frequency modulation. A large range of parameter values is shown to exist for propagating confined states which have spatially localized regions which travel on a background with unique wavelengths. The theoretical phenomena are shown to correspond to such physical systems as spirals in Taylor instabilities, traveling waves in convective systems, and slot-convection phenomena for binary fluid mixtures.
Brand, Helmut R.↗
State-to-state rotational phase coherence effect on the vibration-rotation band shape - An accurate quantum calculation for CO-He
Accurate coupled state calculations of line coupling are performed for infrared lines of carbon monoxide perturbed by helium. Such calculations lead to both real and imaginary line couplings. For the first time, the effect of this imaginary line couplings, connected with state-to-state rotational phase coherences, on infrared band shape, is analyzed. An extension of detailed balance principle to the complex plane is suggested from the present computed off-diagonal cross sections. This allows us to understand the physical mechanism underlying the weak effect of phase coherences on CO-He infrared band shape.
Boissoles, J.↗
Equation of state and phase diagram of dense hydrogen
The equation of state of hydrogen was calculated for specific volumes ranging from 0.01 to 0.0001 cm3/mole and for temperatures ranging from 200 to 1 million K. Three phases are considered: the molecular solid, the metallic solid and the fluid. Chemical equilibrium between molecules, atoms, ions and electrons is considered in calculating the properties of the fluid phase. Transitions between the three phases will be discussed. The triple point, where the three phases coexist, is calculated to occur at 2.3 Mbar and 1679 K. At higher temperatures and pressures, the molecular solid is unstable.
Kerley, G. I.↗
Stabilizing Non-Abelian Topological Order Against Heralded Noise via Local Lindbladian Dynamics
An important open question for the current generation of highly controllable quantum devices is understanding which phases can be realized as stable steady states under local quantum dynamics. In this work, we show how robust steady-state phases with both Abelian and non-Abelian mixed-state topological order can be stabilized, in two spatial dimensions, against generic “heralded” noise using active dynamics that incorporate measurement and feedback, modeled as a fully local Lindblad master equation. These topologically ordered steady states are two-way connected to pure topologically ordered ground states using local quantum channels, and preserve quantum information for a time that is exponentially large in the system size. Specifically, we present explicit constructions of families of local Lindbladians for both Abelian (ℤ 2 ) and non-Abelian (𝐷 4 ) topological order whose steady states host mixed-state topological order when the noise is below a threshold strength. As the noise strength is increased, these models exhibit first-order transitions to intermediate mixed-state phases where they encode robust classical memories, followed by (first-order) transitions to a trivial steady state at high noise rates. When the noise is imperfectly heralded, steady-state order disappears but our active dynamics significantly enhances the lifetime of the encoded logical information. To carry out the numerical simulations for the non-Abelian 𝐷 4 case, we introduce a generalized stabilizer tableau formalism that permits efficient simulation of the non-Abelian Lindbladian dynamics.
Monte Carlo methods↗
Memory cell comprising coupled Josephson junctions
Methods and apparatus are disclosed for operating a memory cell formed from the plurality of coupled Josephson junctions. The memory cell is configured such that applying an electrical signal to the junctions can cause at least one, but not all, of the junctions to change their respective phase states. Subsequent writes to the memory cell using substantially the same electrical pulse do not change the phase state of the plurality of junctions. The memory cell can be ready by providing another electrical pulse to one of the junctions and receiving an output electrical pulse generated in response by a different Josephson junction of the memory cell. A set of phase states are selected to represent the logic values that are stable across anticipated operating conditions for the memory cell. Methods of selecting electrical parameters and manufacturing memory cells are further disclosed.
97 MATHEMATICS AND COMPUTING↗
Twisted bilayer graphene. IV. Exact insulator ground states and phase diagram
Here, we derive the exact insulator ground states of the projected Hamiltonian of magic-angle twisted bilayer graphene (TBG) flat bands with Coulomb interactions in various limits, and study the perturbations away from these limits. We define the (first) chiral limit where the AA stacking hopping is zero, and a flat limit with exactly flat bands. In the chiral-flat limit, the TBG Hamiltonian has a U(4) × U(4) symmetry, and we find that the exact ground states at integer filling – 4 ≤ $\textit{ν}$ ≤ 4 relative to charge neutrality are Chern insulators of Chern numbers $ν_C$ = 4 – |$\textit{ν}$ |, 2 – |$\textit{ν}$ |, $\cdots$, |$\textit{ν}$ | – 4, all of which are degenerate. This confirms recent experiments where Chern insulators are found to be competitive low-energy states of TBG. When the chiral-flat limit is reduced to the nonchiral-flat limit which has a U(4) symmetry, we find $\textit{ν}$ = 0 , ± 2 has exact ground states of Chern number 0, while $\textit{ν}$ = ±1, ± 3 has perturbative ground states of Chern number $ν_C$ = ± 1, which are U(4) ferromagnetic. In the chiral-nonflat limit with a different U(4) symmetry, different Chern number states are degenerate up to second-order perturbations. In the realistic nonchiral-nonflat case, we find that the perturbative insulator states with Chern number $ν_C$ = 0 (0 < |$ν_C$| < 4 – |$\textit{ν}$ |) at integer fillings $\textit{ν}$ are fully (partially) intervalley coherent, while the insulator states with Chern number |$ν_C$| = 4 – |$\textit{ν}$ | are valley polarized. However, for 0 < |$ν_C$| ≤ 4 – |$\textit{ν}$ |, the fully intervalley coherent states are highly competitive (0.005 meV/electron higher). At nonzero magnetic field |$\textit{B}$ | > 0, a first-order phase transition for $\textit{ν}$ = ± 1, ± 2 from Chern number $ν_C$ = sgn ($\textit{νB}$)(2 – |$\textit{ν}$ |) to $ν_C$ = sgn ($\textit{νB}$)(4 – |$\textit{ν}$ |) is expected, which agrees with recent experimental observations. Lastly, the TBG Hamiltonian reduces into an extended Hubbard model in the stabilizer code limit.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗