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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Layered-rocksalt intergrown cathode for high-capacity zero-strain battery operation

Abstract The dependence on lithium-ion batteries leads to a pressing demand for advanced cathode materials. We demonstrate a new concept of layered-rocksalt intergrown structure that harnesses the combined figures of merit from each phase, including high capacity of layered and rocksalt phases, good kinetics of layered oxide and structural advantage of rocksalt. Based on this concept, lithium nickel ruthenium oxide of a main layered structure ( R $$\bar{3}$$ 3 ¯ m ) with intergrown rocksalt ( Fm $$\bar{3}$$ 3 ¯ m ) is developed, which delivers a high capacity with good rate performance. The interwoven rocksalt structure successfully prevents the anisotropic structural change that is typical for layered oxide, enabling a nearly zero-strain operation upon high-capacity cycling. Furthermore, a design principle is successfully extrapolated and experimentally verified in a series of compositions. Here, we show the success of such layered-rocksalt intergrown structure exemplifies a new battery electrode design concept and opens up a vast space of compositions to develop high-performance intergrown cathode materials.

25 ENERGY STORAGE↗
DOE OSTI2025

Flexible Operation of Microgrids Through Operator-Configurable Microgrid Controllers

Microgrids are becoming critical assets in power distribution systems. This is partly due to the resiliency and reliability challenges faced by power distribution systems in the last decade and partly due to the increased integration of distributed energy resource assets, such as solar photovoltaic. This increased need for microgrids has created a multitude of needs for microgrid controllers. Most microgrid controllers in the past decade have been uniquely programmed or custom programmed to meet the needs of a specific microgrid. Currently, IEEE standards aim to integrate the needs and capabilities of microgrid controllers under a unified umbrella. But the standards do not recommend necessary or appropriate software development practices for microgrid controllers. In addition, the programmable nature and maintenance of controllers are also key characteristics that fall outside the coverage of the standards. In this paper, we present the best software practices that utility engineers and microgrid operators should consider in the microgrid software platform. This paper can be used as an information document for developing documentation of controller requirements and assessing microgrid controller requirements.

Banshee microgrid↗
DOE OSTI2025

Hazard and Operability Analysis for Operating, Refueling, and Maintenance of Fuel Cell Electric Buses

​​Since hydrogen vehicles can be implemented in heavy-duty transportation applications such as buses, it is important to understand safety hazards and risks of hydrogen fuel cell electric bus (FCEB) and refueling technology. We conducted a hazard and operability analysis for FCEB operation/driving, refueling, and maintenance/inspection. We identified failure modes and consequences and defined a qualitative risk metric as the product of the likelihood of a failure and the severity of the worst-ca

08 HYDROGEN↗
DOE OSTI2023

First feedback-controlled divertor detachment in W7-X: Experience from TDU operation and prospects for operation with actively cooled divertor

In the last experimental campaign (OP1.2b) of the stellarator Wendelstein 7-X (W7-X), boronisation as a mean for first wall conditioning was applied for the first time which led to strongly reduced impurity fluxes from plasma-facing components. Thermal detachment at the uncooled target plates of the test divertor unit (TDU) was reached at higher plasma densities and was accompanied by high recycling of neutrals at the target plate. A feedback control system was established in W7-X to actively control the gas injection (actuator) for plasma fuelling and impurity seeding [3] through the divertors. It allowed very successful stabilisation of the detached plasma condition state as well as mitigation of thermal overloads to some baffle tiles. Different routinely available diagnostic signals were used as input parameters (sensors). We describe the setup of the feedback control system, its performance and provide some example results with the main focus on the development of the control scheme which led to the detachment stabilisation over the entire longest (30 s) high-power discharge at W7-X so far. In view of the achieved very successful detachment stabilisation and the necessity to include simultaneous optimisation of the core performance in the future, the feedback control system is being upgraded for the upcoming campaign (OP2.1) in which the water cooled and hereby inherently steady-state capable divertor has been currently installed. The prospects and some experiment ideas for active detachment control are discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

2D analysis of tokamak divertor-plasma detachment-bifurcation with operational parameters and geometries

UEDGE simulations with density scans for various input power, transport coefficients and outer poloidal leg length are performed to study the conditions for the existence of a bifurcation-like drop of T e at the outer strike point, commonly referred to as a detachment cliff, when transitioning to a detached plasma from an attached plasma in the outer divertor as the upstream density increases (McLean et al., 2015). The simulation results show that a detachment cliff tends to occur with a higher power input regardless of diffusivities and leg length. Further analysis of change of plasma profiles at a cliff indicate that, in addition to the sharp reduction of the E x B drift fluxes in the outer divertor studied in Jaervinen et al., (2018), the substantial change of the Mach number in the outer divertor and the decrease of the outer mid-plane T e due to the radiation front moving across the separatrix into the confinement region above the X-point consistently occur for all UEDGE density scans that have a detachment cliff. UEDGE time-dependent simulation of the evolution of a detachment cliff shows that the rapid increase of radiation above the X-point occurs in a time scale of ~0.3–0.5, which could possibly be the trigger for the formation of a detachment cliff, quicker than the Mach number change in a time scale of ~1 ms and the drop of T e in a time scale of ~2–3 ms in the outer divertor.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Prediction of the Thermal Runaway Limit and Optimal Operation of Heat Transfer-Limited, Fixed-Bed Reactor Systems

Here, we derive a new prediction for thermal runaway starting from the alpha model for fixed-bed reactor systems. This method accounts for thermal resistance internal to the reactor tube and the radial temperature gradients that result. To showcase our method, we compare its predictions to other common criteria for thermal runaway using o-xylene oxidation as the example chemistry. Even in systems where internal heat transfer is negligible, the empirical practical design criterion for thermal runaway is inaccurate. For cases where internal heat transfer is relevant, our runaway limit is more stringent than limits derived from simpler 1-D models. To augment our work, we optimize the product yield with the thermal runaway constraint using orthogonal collocation. Using the alpha model, the results illustrate that the thermal runaway limit can be accurately determined using either numerical or analytical methods.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Light Dark Matter Search with a High-Resolution Athermal Phonon Detector Operated Above Ground

We present limits on spin-independent dark matter-nucleon interactions using a 10.6 g silicon athermal phonon detector with a baseline energy resolution of 4.92 +/- 0.01 eV. This exclusion analysis sets the most stringent dark matter-nucleon cross-section limits for masses from 87--140 MeV/c^2 , with a raw exposure of 9.9 g d acquired at an above-ground facility. This work illustrates the scientic potential of athermal phonon sensors with eV-scale energy resolution for future dark matter searches.

Alkhatib, I↗
DOE OSTI2024

Management of Risks Associated with Application of Novel Materials in Novel Operating Environments in Novel Reactor Designs

There is currently no widely agreed, detailed general method for licensing a novel plant incorporating novel materials (or materials being deployed in novel environments); in many such situations, there are no directly applicable engineering code cases for decision-makers (including regulators) to rely on. This paper discusses a framework for solving this problem that is based on the Reliability and Integrity Management (RIM) approach delineated in ASME BPVC Section XI Division 2. NRC Regulatory Guide 1.246, Rev. 0, endorses, with conditions, the subject portion of the ASME Code. The proposed framework is meant to support development of a licensing case by addressing certain technical challenges. The framework discussed here is compatible with the Licensing Modernization Project, but applying it in a specific case will call for advances in the state of practice, if not the state of the art. The RIM approach calls for applicants to (a) allocate reliability targets to plant structures, systems, and components (SSCs), (b) show that they are able to relate the currently observed physical condition of each SSC in the program to its failure probability well enough to determine whether the target reliability allocations are being satisfied, allowing for uncertainty related to the novelty of the materials/designs/operating environments, and (c) be able to demonstrate that the proposed program of surveillances will reliably detect unacceptable degradation of an SSC before SSC failure occurs. These challenges are discussed in the paper, and a potentially applicable modeling approach based on cumulative damage rather than failure rates is briefly illustrated.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2026

Testing of operating envelope to support DF LAW operations

The primary objective of the present work was to investigate the potential impact of likely process variations on the nominal glass composition for LAW AP-107 waste that is determined by the LAW glass correlation (AP107WDFL). This was accomplished by evaluating glass and feed variations at crucible scale and DM100 melter tests.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗