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At least 73 records · Page 4

Memory effect and magnetocrystalline anisotropy impact on the surface magnetic domains of magnetite(001)

The structure of magnetic domains, i.e. regions of uniform magnetization separated by domain walls, depends on the balance of competing interactions present in ferromagnetic (or ferrimagnetic) materials. When these interactions change then domain configurations also change as a result. Magnetite provides a good test bench to study these effects, as its magnetocrystalline anisotropy varies significantly with temperature. Using spin-polarized electron microscopy to map the micromagnetic domain structure in the (001) surface of a macroscopic magnetite crystal (~1 cm size) shows complex domain patterns with characteristic length-scales in the micrometer range and highly temperature dependent domain geometries. Although heating above the Curie temperature erases the domain patterns completely, cooling down reproduces domain patterns not only in terms of general characteristics: instead, complex microscopic domain geometries are reproduced in almost perfect fidelity between heating cycles. A possible explanation of the origin of the high-fidelity reproducibility is suggested to be a combination of the presence of hematite inclusions that lock bulk domains, together with the strong effect of the first order magnetocrystalline anisotropy which competes with the shape anisotropy to give rise to the observed complex patterns.

36 MATERIALS SCIENCE↗

Local structure memory effects in the polar and nonpolar phases of MoTe 2

We use total scattering to study the reversible transition between the polar 1T' and nonpolar T d phases of layered MoTe 2 taking place at 240 K. Whereas, macroscopically, the transition appears to be first order, locally, it is not. In particular, a great deal of the stacking sequence of Te-Mo-Te layers characteristic of the polar 1T' phase persists locally in the nonpolar T d phase, and vice versa, over a broad temperature range extending about 100 K both below and above the transition. The intermixing ratio for the two sequences evolves gradually across the transition temperature, consistent with a second-order transition behavior. Here, the presence of coexisting local polar and nonpolar regions and the resulting variety of internal interfaces where the spatial inversion symmetry is broken may be behind some of the unusual electronic properties of T d –MoTe 2 , including its putative type-II Weyl semimetal state.

2-dimensional systems↗

Nanoimaging of Organic Charge Retention Effects: Implications for Nonvolatile Memory, Neuromorphic Computing, and High Dielectric Breakdown Devices

While a large variety of organic and molecular materials have been found to exhibit charge memory effects, the underlying mechanism is not well-understood, which hinders rational device design. Here, we study the charge retention mechanism of a nanoscale memory system, an organic monolayer on a silicon substrate, with Au nanoparticles on top serving as the electrical contact. Combining scanning probe imaging/manipulation and density functional simulations, we observe stable charge retention effects in the system and attributed it to polaron effects at the amine functional groups. Finally, our findings can pave the way for applications in nonvolatile memory, neuromorphic computing, and high dielectric breakdown devices.

36 MATERIALS SCIENCE↗

MemGaze: Rapid and Effective Load-Level Memory Trace Analysis

A major challenge of memory analysis tools is combining high-resolution analysis and low overhead measurement. Currently, hardware/software-based analysis of load-level sequences incurs time slowdowns of O(100×). We present MemGaze, a tool for low-overhead, high-resolution memory analysis. MemGaze uses Intel’s Processor Tracing (PT) instruction ptwrite to collect sampled and compressed memory address traces for load-level, sequence-aware analysis of data reuse. We describe multi-resolution analysis for locations vs. operations, accesses vs. spatio-temporal reuse, and reuse (distance, rate, volume) vs. access patterns. Both trace size and resolution are controllable. We use MemGaze to elucidate the memory effects of different data structures and algorithms. For sampled traces that are ˜1% of a full one, analysis metrics have 1-25% MAPE for histograms of varying dynamic sequence lengths. With current suboptimal kernel support (PT runs continuously), MemGaze’s time overhead is typically 10–95%; 7× at worst. However, when PT runs only during samples, overhead is 10–35% on memory intensive regions and correlates with executed ptwrites.

Kilic, Ozgur O.↗

Fatigue of graphite/epoxy /0/90/45/-45/s laminates under dual stress levels

A model for the prediction of loading sequence effects on the statistical distribution of fatigue life and residual strength in composite materials is generalized and applied to (0/90/45/-45)s graphite/epoxy laminates. Load sequence effects are found to be caused by both the difference in residual strength when failure occurs (boundary effect) and the effect of previously applied loads (memory effect). The model allows the isolation of these two effects, and the estimation of memory effect magnitudes under dual fatigue loading levels. It is shown that the material memory effect is insignificant, and that correlations between predictions of the number of early failures agree with the verification tests, as do predictions of fatigue life and residual strength degradation under dual stress levels.

Yang, J. N.↗

Origin of “memory glass” effect in pressure-amorphized rare-earth molybdate single crystals

The memory glass effect (MGE) describes the ability of some materials to recover the initial structure and crystallographic orientation after pressure-induced amorphization (PIA). In spite of numerous studies the nature and underlying mechanisms of this phenomenon are still not clear. Here we report investigations of MGE in β′-Eu{sub 2}(MoO{sub 4}){sub 3} single crystal samples subjected to high pressure amorphization. Using the XRD and TEM techniques we carried out detailed analysis of the structural state of high pressure treated single crystal samples as well as structural transformations due to subsequent annealing at atmospheric pressure. The structure of the sample has been found to be complex, mainly amorphous, however, the amorphous medium contains evenly distributed nanosize inclusions of a paracrystalline phase. The inclusions are highly correlated in orientation and act as “memory units” in the MGE. - Graphical abstract: Schematic representation of pressure-induced amorphization and “memory glass” effect in rare-earth molybdate single crystals. The XRD and TEM measurements have revealed the presence of the residual identically oriented paracrystalline nanodomains in the pressure-amorphized state. These domains preserve the information about initial structure and orientation of the sample. They act as memory units and crystalline seeds during transformation of the amorphous phase back to the starting single crystalline one. - Highlights: • Pressure-amorphized Eu{sub 2}(MoO4){sub 3} single crystals were studied ex-situ by XRD and TEM. • Tiny residual crystalline inclusions were found in amorphous matrix of sample. • The inclusions keep in memory the parent crystal structure and orientation. • The inclusions account for “memory glass” effect in rare-earth molibdates.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗