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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Multilayer Electrodes with Metalized Polymer Current Collector for High-Energy Lithium-Ion Batteries with Extreme-Fast-Charging Capability

The pursuit of batteries capable of extreme fast charging (XFC), that also satisfy high energy and safety criteria, poses a significant challenge to current lithium-ion battery technologies. Additionally, the increasing demand for aluminum (Al) and copper (Cu) in electrification, and vehicle light weighting is driving these metals towards near-critical status in the medium term. This study introduced metalized polymer films by depositing an Al or Cu thin layer onto two sides of a polyethylene terephthalate (PET) film – named mPET/Al and mPET/Cu, as lightweight, cost-effective alternatives to traditional metal current collectors in LIBs. We have utilized current collectors that significantly reduce weight (by 73%), thickness (by 33%), and cost (by 85%) compared to traditional metal foil counterparts. We conducted an extensive evaluation of their mechanical and electrical properties, including in-plane and through-plane resistivities, affirming their suitability for the roll-to-roll battery manufacturing process. Additionally, a novel XFC testing protocol was employed to thoroughly assess the cells' (both half and full-cell) performance across various C-rates and under long-term tests. These advancements have the potential to enhance energy density to 280 Wh/kg at the electrode level under 10-minute charging at 6C. Through testing, including a novel XFC protocol across various C-rates and long-term cycling (up to 1000 cycles) in different cell configurations, we have demonstrated the superior performance of these metalized polymer films. Notably, mPET/Cu and mPET/Al foils exhibited comparable capacities to conventional cells under XFC, with the mPET cells showing a 27% improvement in energy density at 6C and maintaining significant energy density after 1000 cycles. This study underscored the potential of mPET foils to revolutionize the roll-to-roll battery manufacturing process and significantly advance the performance metrics of LIBs in EV applications. Moreover, our results suggest that there is potential to enhance the performance of mPET foils, especially mPET/Al, by optimizing the manufacturing process to achieve higher conductivity.

99 GENERAL AND MISCELLANEOUS↗

Test facility for 6000 hour life test of 30 cm mercury ion thruster

The environmental and instrumentation requirements for long term testing of electrical propulsion thrusters which impose severe and unusual requirements upon the simulation facility were studied. High speed ions ejected from a mercury thruster erode material from collecting surfaces, which is then scattered and redeposited upon other surfaces, with resultant damage to the chamber and test article. By collecting the thruster plume on a frozen mercury surface damage to the thruster and chamber by back-scattered erosion products was minimized. Provisions for unattended operation, remote data acquisition, personnel safety, and instrumentation for assessing thruster performance are also discussed.

Caldwell, J. J.↗

Carbon Capture Pilot at Vicksburg Containerboard Mill (Final Technical Report)

This is the final technical report for the DOE-OCED project DE-CD0000051. The report provides the progress at the close of the project. The objective of the project is to design and build a large pilot plant for carbon dioxide (CO 2 ) capture from a pulp and paper (P&P) mill using RTI’s non-aqueous solvent (NAS) technology at a capacity of 120,000 t-CO 2 /year, with >90% CO 2 captured. The pilot plant will be used for testing and evaluating the NAS capture process using real flue gas from the P&P mill’s power boiler for a minimum of 1 year of parametric testing and a minimum of 2,000 hours of continuous long-term testing. The testing will provide data for process optimization and scale-up for the P&P industry, provide information on interaction of flue gas contaminants on solvent performance and degradation, and inform strategies for emission control. At the end of the project, the pilot plant will be managed by International Paper (IP), the host site owner, which will continue to capture CO 2 , sequester the captured CO 2 , and be eligible for the 45Q credit.

42 ENGINEERING↗

A Process with Decoupled Absorber Kinetics and Solvent Regeneration through Membrane Dewatering and In-Column Heat Transfer (Final Report)

This report summarizes the work conducted on project DE-FE0031604 where University of Kentucky Center for Applied Energy (UK CAER) has validated its intensified CO 2 capture process through substantial enhancements to the kinetics of the absorption process and energy reductions by absorber temperature profile modification, dewatering and heat integration technologies for achieving significant capital and operating cost reductions. To address DOE’s objective of improving post-combustion CO 2 capture technology and reducing associated cost, UK CAER employed an intensified process which combined three key aspects targeted at overcoming inherent limitations or barriers in the conventional CO 2 capture and desorption process. The process designed to be independent of the type of solvent used, included (1) the use of 3-D printed two-channel structured packing material to control the temperature profile and increase the CO 2 absorption rate in the absorber, (2) a zeolite membrane dewatering unit for dewatering of the carbon-rich solvent to decouple solvent concentration needs for CO 2 absorption and desorption, and (3) a rich-split feed with two-phase flow heat transfer prior to the stripper that provided a secondary point of vapor generation to provide energy savings in steam extraction and solvent regeneration. The project was executed over two budget periods. This involved testing of individual process components which included the advanced heat transfer packing and the dewatering membrane on UK CAER’s 30 liter per minute (L/min) CO 2 (3” Column) capture bench unit with simulated flue gas in the first budget period. Subsequent scaled-up testing of these components together with the split-feed configuration were also tested in UK CAER’s 0.1 MWth CO 2 capture unit with coal-derived flue gas in the second-budget period. Long term studies were done during this period to assess process and solvent performance over extended duration. Project partners Lawrence Livermore National Laboratory (LLNL) and Media & Process Technology (MPT) led the development efforts for the advanced packing material and dewatering membrane respectively. Data from the long term testing was used as input for an environmental, health and safety (EH&S) assessment for the process and scaled technology performed by ALL4 LLC. Trimeric Corporation also completed a techno-economic analysis (TEA) for the UK CAER technology which was compared to the DOE reference Case B12B. Tests on the 3” column capture unit showed that the advanced heat transfer packing could be used to lower the bulge temperature in the absorber, and this was also proven in the scaled testing in the 0.1 MWth CO 2 capture unit. The bulge temperature could be lowered by >10 °C, changing the temperature profile in the absorber, and showed potential to enhance absorption with the ability to tailor the profile to provide conditions suitable for a solvent’s properties and kinetics. Conditions for short term evaluation of a 19” zeolite dewatering membrane on the 3” column capture unit yielded desirable fluxes and sustained rejection rates of >80%. However, for the scaled testing of six membrane modules consisting of 21 parts of 31-inch-long membrane tubes in each bundle (surface area 0.3 m 2 ), over a more extended duration, similar rejection rates could not be achieved. With the split-feed of the rich stream to the stripper, improved heat recovery minimized waste heat exiting the top of the stripper. The stripper exhaust temperatures could be reduced by >10 °C; reducing the amount of water vaporization contributed to lowering the regeneration energy by ~ 15%. The energy benefit could be sustained from the long term monitoring of the solvent performance. The solvent properties were not significantly impacted over the long-term operations. The benefits of the UK CAER process demonstrated experimentally were mostly validated from the TEA comparing a commercial scale application of the technology to DOE reference Case B12B. The cost of CO 2 capture for the UK CAER technology was estimated to be ~$34.97/tonne of CO 2 captured; a reduction of 23% compared to Case B12B. The increase in cost of electricity was also shown to be 16% lower than that of Case B12B. The total parasitic demand was also shown to be 11% lower. The key drivers for the benefits are a result of the process intensification approaches employed in the UK CAER technology for enhanced solvent performance, effective heat recovery and improved energy performance. The EH&S assessment did not find any major environmental concerns or barriers to the full scale implementation of the technology.

20 FOSSIL-FUELED POWER PLANTS↗

Further Tests of 38 Ball-Bearing Greases

Interim report presents recent results in program of long-term testing of ball-bearing greases in vacuum, oxidizing, and otherwise hostile environments. Class of lubricants based on perfluoroalkylpolyether (PFPE) gave best results in vacuum operation in both 1-year and 5-year tests.

Mcmurtrey, E.↗

Fire Chemistry Testing of Spray-On Foam Insulation (SOFI)

An experimental study was initiated that included the long-term testing of the following SOFI materials, which make up the majority of the Thermal Protection System of the Shuttle External Tank: NCFI 24-124 (acreage foam) and BX-265 (close-out foam, including the intertank flange and bipod areas). A potential alternate material, NCFI 27-68 (acreage foam with flame retardant removed), was also tested. Fire chemistry testing was completed on samples that were retrieved after aging/weathering at intervals of 3, 6, and 12 months. The testing included three standard test methods: limiting oxygen index (ASTM G125), radiant panel (ASTM E162), and cone calorimeter (ASTM E1354).

Source record↗

Phase 9 Fiber Optic Cable Microbending and Temperature Cycling Tests

Optical fibers represent the back bone of the current communications networks. Their performance in the field lacks long term testing data because of the continuous evolution of the manufacturing of fibers and cables. An optical fiber cable that is installed in NASA's KSC has experienced a dramatic increase in attenuation after three years of use from 0.7 dB/km to 7 dB/km in some fibers. A thorough study is presented to assess the causes of such an attenuation increase. Material and chemical decomposition testing showed that there are no changes in the composition of the fiber which might have caused the increase in attenuation. Microbending and heat cycling tests were performed on the cable and individual fibers. It was found that the increase in attenuation is due to microbending caused by excessive stress exerted on the fibers. This was the result of manufacturing and installation irregularities.

Abushagur, Mustafa A.G.↗

High Temperature Superconductor Lead Assemblies for XRISM

The RESOLVE instrument on the upcoming XRISM mission is a rebuild of the SXS instrument that successfully demonstrated high resolution X-ray spectroscopy on the Hitomi mission using a microcalorimeter array at 50 mK. As with SXS, the RESOLVE instrument requires High Temperature Superconductor (HTS) lead assemblies to carry high current to the Adiabatic Demagnetization Refrigerator (ADR) while meeting a very stringent heat conductance budget. For the RESOLVE HTS lead assemblies, we have used new materials and processes to improve the stability and consistency of solder joints to the HTS material. We have also designed a new thermal strap that eliminates stress concentrations on the HTS tapes. We present the results of testing on the engineering model and flight model units, as well as the results of long term testing on prototype solder joints.

Canavan, Edgar R.↗

Test results of six-month test of two water electrolysis systems

The two water electrolysis systems used in the NASA space station simulation 90-day manned test of a regenerative life support system were refurbished as required and subjected to 26-weeks of testing. The two electrolysis units are both promising systems for oxygen and hydrogen generation and both needed extensive long-term testing to evaluate the performance of the respective cell design and provide guidance for further development. Testing was conducted to evaluate performance in terms of current, pressure, variable oxygen demands, and orbital simulation. An automatic monitoring system was used to record, monitor and printout performance data at one minute, ten minute or one-hour intervals. Performance data is presented for each day of system operation for each module used during the day. Failures are analyzed, remedial action taken to eliminate problems is discussed and recommendations for redesign for future space applications are stated.

Mills, E. S.↗

Dehumidification via membrane separation for space-based applications

The paper describes the development of a membrane-based dehumidification process for space-based applications, such as spacecraft cabins and EVA space suits. Results presented are from: (1) screening tests conducted to determine the efficacy of various membranes to separate water vapor from air, and (2) parametric and long-term tests of membranes operated at conditions that simulate the range of environmental conditions (e.g., temperature and relative humidity) expected in the planned Space Station. Also included in this paper is a discussion of preliminary designs of membrane-based dehumidification processes for the Space Station and EVA space suits. These designs result in compact and energy-efficient systems that offer significant advantages over conventional dehumidification processes.

Gienger, Jane Kucera↗

Near-field measurement facility plans at Lewis Research Center

The direction of future antenna technology will be toward antennas which are large, both physically and electrically, will operate at frequencies up to 60 GHz, and are non-reciprocal and complex, implementing multiple-beam and scanning beam concepts and monolithic semiconductor devices and techniques. The acquisition of accurate antenna performance measurements is a critical part of the advanced antenna research program and represents a substantial antenna measurement technology challenge, considering the special characteristics of future spacecraft communications antennas. Comparison of various antenna testing techniques and their relative advantages and disadvantages shows that the near-field approach is necessary to meet immediate and long-term testing requirements. The LeRC facilities, the 22 ft x 22 ft horizontal antenna boresight planar scanner and the 60 ft x 60 ft vertical antenna boresight plant scanner (with a 60 GHz frequency and D/lamdba = 3000 electrical size capabilities), will meet future program testing requirements.

Sharp, R. G.↗

Development and characterization of the Capillary DirectINJECT System

The DirectINJECT Project was initiated to create a reliable in-line dosing system for delivering a concentrated silver ion biocide solution into spacecraft potable water. Three dosing systems, including a miniature peristaltic pump, a multi-piston pump, and a differential pressure-driven capillary tube, were quickly prototyped and tested. Although the peristaltic and multi-piston pump systems met the desired flow rate range, the capillary system showed the most promise and was chosen for further development. In FY23, the Capillary DirectINJECT dosing system underwent extensive testing with a nominal injection rate of 1.0 μl/min into varying backpressure conditions. A Primary DirectINJECT System with triplicate testbeds was employed for long-term testing, and auxiliary systems like the Secondary DirectINJECT System and Leak Testbed were developed to characterize specific components and investigate various phenomena related to the dosing system. Parameters such as flow rates, reservoir pressures, and temperature were monitored throughout the testing campaigns.

DirectINJECT↗

Develop and test fuel cell powered on-site integrated total energy systems. Phase 3: Full-scale power plant development

The testing of two 25-cell stacks of the 13 inch x 23 inch cell size (about 4kW) was carried out for 7000 and 8400 hours, respectively. A 25kW stack containing 175 cells of the same size and based on the same technology was constructed and is on test. A third 4kW stack, which will contain 24 cells, will comprise several new technology features; these will be assesed for performance and durability in long-term testing.

Kaufman, A.↗

Lunar base - A stepping stone to Mars

Basic elements of technology and programmatic development are identified that appear relevant to the Case for Mars, starting from a base on the moon. The moon is a logical stepping stone toward human exploration of Mars because a lunar base can provide the first test of human ability to use the resources of another planetary body to provide basic materials for life support. A lunar base can provide the first long-term test of human capability to work and live in a reduced (but not zero) gravity field. A lunar base requires creation of the elements of a space transportation system that will be necessary to deliver large payloads to Mars and the space operations capability and experience necessary to carry out a Mars habitation program efficiently and with high reliability. A lunar base is feasible for the first decade of the 21st Century. Scenarios have been studied that provide advanced capability by 2015 within budget levels that are less than historical U.S. space expenditures (Apollo). Early return on the investment in terms of knowledge, practical experience and lunar products are important in gaining momentum for an expanded human exploration of the solar system and the eventual colonization of Mars.

Duke, M. B.↗

Potential utilization of the NASA/George C. Marshall Space Flight Center in earthquake engineering research

Earthquake engineering research capabilities of the National Aeronautics and Space Administration (NASA) facilities at George C. Marshall Space Flight Center (MSFC), Alabama, were evaluated. The results indicate that the NASA/MSFC facilities and supporting capabilities offer unique opportunities for conducting earthquake engineering research. Specific features that are particularly attractive for large scale static and dynamic testing of natural and man-made structures include the following: large physical dimensions of buildings and test bays; high loading capacity; wide range and large number of test equipment and instrumentation devices; multichannel data acquisition and processing systems; technical expertise for conducting large-scale static and dynamic testing; sophisticated techniques for systems dynamics analysis, simulation, and control; and capability for managing large-size and technologically complex programs. Potential uses of the facilities for near and long term test programs to supplement current earthquake research activities are suggested.

Scholl, R. E.↗

Upscaling of asymmetric hollow fiber‐supported thin film membranes for oxygen separation from air: Proof of concept

Abstract Hollow fiber membranes demonstrate various advantages for high performance oxygen separation. However, the small diameters of hollow fibers and the brittleness of ceramics limit their mechanical strength, imposing great difficulties on stack and module development. Gas‐tight sealing is another challenge for upscaling of hollow fiber membrane technology. Low temperature sealant materials of epoxy resin or silicon are typically used for hollow fiber stacks, requiring that the sealing portions be located out of hot zone. Consequently, only partial length of hollow fibers participates in oxygen permeation. In this study, upscaling of our recently developed asymmetric hollow fiber‐supported thin film membranes is conducted, where individual hollow fibers are assembled in parallel to form a stack. A reliable gas‐tight sealing is obtained by combining ceramic paste with conductive adhesive ink cohesively. Comprehensive oxygen permeation test is conducted with the sealing portions being in hot zone and compared with a single hollow fiber membrane. Fundamental mechanism is discussed to understand the performances and their differences. An accelerated long‐term test (∼320 h, 16 thermal cycles) demonstrates excellent stability and robustness of the stack and sealing. The characterization of post‐test samples further confirms excellent stability and robustness of the phases and microstructures of the stack.

36 MATERIALS SCIENCE↗

Microstructural and Material Quality Effects on Rolling Contact Fatigue of Highly Elastic Intermetallic Ball Bearings

Rolling element bearings made from highly-elastic intermetallic materials (HIM)s, such as 60NiTi, are under development for applications that require superior corrosion and shock resistance. Compared to steel, intermetallics have been shown to have much lower rolling contact fatigue (RCF) stress capability in simplified 3-ball on rod (ASTM STP 771) fatigue tests. In the 3-ball tests, poor material quality and microstructural flaws negatively affect fatigue life but such relationships have not been established for full-scale 60NiTi bearings. In this paper, 3-ball-on-rod fatigue behavior of two quality grades of 60NiTi are compared to the fatigue life of full-scale 50mm bore ball bearings made from the same materials. 60NiTi RCF rods with material or microstructural flaws suffered from infant mortality failures at all tested stress levels while high quality 60NiTi rods exhibited no failures at lower stress levels. Similarly, tests of full-scale bearings made from flawed materials exhibited early surface fatigue and through crack type failures while bearings made from high quality material did not fail even in long-term tests. Though the full-scale bearing test data is yet preliminary, the results suggest that the simplified RCF test is a good qualitative predictor of bearing performance. These results provide guidance for materials development and to establish minimum quality levels required for successful bearing operation and life.

tribology↗