Deterministic Positioning of Defect Based Qubits using Ion Beam Implantation for Nanofabrication and Modification.
Abstract not provided.
Bielejec, Edward S.↗
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Results for “ion modification”
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Deterministic Positioning of Defect Based Qubits using Ion Beam Implantation for Nanofabrication and Modification.
Abstract not provided.
Bielejec, Edward S.↗
Ion Beam Implantation for Nanofabrication and Modification.
Abstract not provided.
Bielejec, Edward S.↗
Mode coupling and wave particle interactions for unstable ion acoustic waves
A theory for the spatial development of linearly unstable, coupled waves is presented in which both quasi-linear and mode coupling effects are treated in a self-consistent manner. Steady state excitation of two waves is assumed at the boundary x = 0, the plasma being homogeneous in the y and z directions. Coupled equations are derived for the x dependence of the amplitudes of the primary waves and the secondary waves, correct through second order terms in the wave amplitude, but without usual approximation of small growth rates. This general formalism is then applied to the case of coupled ion acoustic waves driven unstable by an ion beam streaming in the direction of the x axis. If the modifications of the ion beam by the waves (quasi-linear effects) are ignored, explosive instabilities (singularities in all of the amplitudes at finite x) are found, even when all of the waves have positive energy. If these wave-particle interactions are included, the solutions are no longer singular, and all of the amplitudes have finite maxima.
Martin, P.↗
Mode-coupling and wave-particle interactions for unstable ion-acoustic waves.
A theory for the spatial development of linearly unstable, coupled waves is presented in which both quasilinear and mode-coupling effects are treated in a self-consistent manner. Steady-state excitation of two waves is assumed at the boundary x = 0, the plasma being homogeneous in the y and z directions. Coupled equations are derived for the x dependence of the amplitudes of the primary waves and the secondary waves, correct through terms of second order in the wave amplitude, but without the usual approximation of small growth rates. This general formalism is then applied to the case of coupled ion-acoustic waves driven unstable by an ion beam streaming in the direction of the x axis. If the modifications of the ion beam by the waves (quasilinear effects) are ignored, explosive instabilities (singularities in all of the amplitudes at finite x) are found even when all of the waves have positive energy. If these wave-particle interactions are included, the solutions are no longer singular, and all of the amplitudes have finite maxima.
Martin, P.↗
Ion Beam Implantation for Nanofabrication and Modification.
Abstract not provided.
Bielejec, Edward S.↗
Ion Beam Implantation for Nanofabrication and Modification.
Abstract not provided.
Bielejec, Edward S.↗
Site-Selective Modification of Lanthanum Oxychloride to Modulate Halide-Ion Conduction
Design principles for solid-state halide-ion conduction remain poorly defined despite the increasing importance of halide ions as charge carriers in a variety of energy storage and electrochemical computing technologies. Here, we employ a siteselective modification strategy in which aliovalent cations are preferentially introduced at the La 3+ crystallographic site of LaOCl in the 2c Wyckoff position, enabling controlled generation of chloride vacancies and modification of lattice dynamics to enhance chloride-ion conductivity. Aliovalent substitution of La 3+ with Mg 2+ , Ca 2+ , and Sr 2+ generates charge-compensating Cl vacancies while preserving the matlockite crystal structure. X-ray excited optical luminescence measurements with Dy 3+ as a reporter chromophore evidence vacancy-derived midgap electronic states and an extended energy range of radiation-less Auger electron emission corresponding to substantial modification of electronic structure and local electrostatic potentials. Ca alloying at 8−10 at. % increases the chloride-ion conductivity by three- to 4 orders of magnitude as compared to unalloyed LaOCl, whereas comparable amounts of Sr- and Mg-alloying in LaOCl imbue less pronounced conductivity enhancements. Temperature-dependent Raman spectroscopy measurements reveal that Ca- and Sr-alloying substantially soften the La−Cl sublattice and yield a more compliant crystal lattice that can deform to accommodate Cl-ion migration. Structure solutions derived from Rietveld refinements to powder Xray diffraction reveal larger O−La−Cl bond-angle deviations and enhanced out-of-plane cation displacements for Ca- and Sr-alloyed compositions as compared to Mg-alloyed LaOCl. Such local distortions enhance chloride-ion mobility by reshaping and flattening vacancy migration energy landscapes and by modulating lattice dynamics governing anion conduction. We further illustrate that coalloying of Ca with Mg and Sr induces a nonmonotonic conductivity−defect stoichiometry relationship that can be rationalized based on cooperative interactions. Together, these results establish site-selective aliovalent alloying of LaOCl as an effective route to halide-ion solid electrolytes and provide broadly generalizable design principles for site-selective modification to induce vacancy formation and lattice softening to engender facile anion transport
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Quantitative investigation of surface structure and interatomic potential with impact-collision ion scattering spectroscopy
Helium ion beam interactions with materials have important implications for magnetic confinement fusion, material modification, and helium ion microscopy. These interactions depend on the precise physics of how helium ions channel into the materials, which can vary greatly based on the local crystalline orientation. Here, we performed a dedicated experiment to investigate helium ion channeling in a well-characterized tungsten single crystal. Time-of-flight impact-collision ion scattering spectroscopy was used to obtain multi-angle maps of the backscattering intensity for 3 keV He + → W(111). We found that the backscattering intensity profile arising from helium ion channeling could be well described by a shadow cone analysis. This analysis revealed that subsurface W atoms as deep as the ninth monolayer contributed to the backscattering intensity profile. Binary collision approximation simulations were performed with MARLOWE to model the experimental maps with sufficient accuracy to allow for quantitative comparisons using reliability factors. These quantitative comparisons were applied to investigate how the W lattice structure and He–W interatomic potential affect the multi-angle maps.
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
Cross-beam energy transfer saturation by ion trapping-induced detuning
The performance of direct-drive inertial confinement fusion implosions relies critically on the coupling of laser energy to the target plasma. Cross beam energy transfer (CBET), the resonant exchange of energy between intersecting laser beams mediated by ponderomotively driven ion-acoustic waves (IAW), inhibits this coupling by scattering light into unwanted directions. Furthermore, the variety of beam intersection angles and varying plasma conditions in an implosion results in IAWs with a range of phase velocities. Here we show that CBET saturates through a resonance detuning that depends on the IAW phase velocity and that results from trapping-induced modifications to the ion distribution functions. For smaller phase velocities, the modifications to the distribution functions can rapidly thermalize in the presence of mid-Z ions, leading to a blueshift in the resonant frequency. For larger phase velocities, the modifications can persist, leading to a redshift in the resonant frequency. Ultimately, these results may reveal pathways towards CBET mitigation and inform reduced models for radiation hydrodynamics codes to improve their predictive capability.
70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
Finite beta effects on the drift-cyclotron instability
The effects of finite plasma beta and strong plasma inhomogeneities on the microinstability resulting from the unstable coupling of ion-cyclotron oscillations and an ion drift wave are examined. A local electromagnetic, kinetic dispersion equation, which takes into account finite orbit modifications of both ions and electrons as well as the effects of strong inhomogeneities on the ions and permits the continuous tracking of the instability from the weak gradient regime to the strong gradient regime, is derived and solved numerically. Finite beta is shown to increase the frequency and reduce the growth rate of the instability, but not completely stabilize it due to electromagnetic effects. When plasma inhomogeneity is sufficiently strong, finite beta reduces the growth rate of the large k sub y band of a given harmonic more than the small k sub y band; however, the most unstable bands remain the same as in the case of zero beta. Implications of these results for the Tandem Mirror Experiment are discussed.
Gladd, N. T.↗
Weak double layers in the auroral ionosphere
Previous work on the evolution of weak double layers in a hydrogen plasma was extended to include H(+) and O(+) with relative drift. The relative drift between hydrogen and oxygen ions due to a quasi-static parallel electric field gives rise to a strong linear fluid instability which dominates the ion-acoustic mode at the bottom of the auroral acceleration region. This ion-ion instability can modify ion distributions at lower altitudes and the subsequent nonlinear evolution of weak double layers at higher altitudes in the ion-acoustic regime. Ion hole formation can occur for smaller relative electron-ion drifts than seen in previous simulations, due to the hydrogen-oxygen two-stream instability. This results in local modification of the ion distributions in phase space, and a partial filling of the valley between the hydrogen and oxygen peaks, which would be expected at higher altitudes on auroral field lines. The observed velocity diffusion does not necessarily preclude ion hole and double layer formation in hydrogen in the ion-acoustic regime. These simulation results are consistent with the experimentally measured persistence of separate hydrogen and oxygen peaks, and the observation of weak double layers above an altitude of 3000 km on auroral field lines.
Hudson, M. K.↗
Modification of a Silicon Photomultiplier for Reduced High Temperature Dark Count Rate
In this work we present a novel method for improving the high-temperature performance of silicon photomultipliers (SiPMs) via focused ion beam (FIB) modification of individual microcells. The literature suggests that most of the dark count rate (DCR) in a SiPM is contributed by a small percentage (<5%) of microcells. By using a FIB to electrically deactivate this relatively small number of microcells, we believe we can greatly reduce the overall DCR of the SiPM at the expense of a small reduction in overall photodetection efficiency, thereby improving its high temperature performance. In this report we describe our methods for characterizing the SiPM to determine which individual microcells contribute the most to the DCR, preparing the SiPM for FIB, and modifying the SiPM using the FIB to deactivate the identified microcells.
42 ENGINEERING↗
Observations of enhanced ion line frequency spectrum during Arecibo ionospheric modification experiment
The Arecibo 430 MHz incoherent scatter radar (ISR) was used to monitor the effects of modifying the ionosphere by a high power HF transmitter feeding the 305 m reflector antenna. When in the ordinary magnetoionic mode parametric instabilities develop in the ionosphere near the reflection level. Manifestations of these instabilities are the strong enhancement of Langmuir oscillations in the direction of the ISR beam at a wavelength of 35 cm and the simultaneous much weaker enhancement of ion oscillations in that direction. The spectral analysis of the enhanced peak with a height resolution of 2.4 km shows that the ionic mode enhancement most often has a double humped frequency spectrum corresponding to up- and down-going ion acoustic waves. The shape of the frequency spectrum is interpreted in terms of a stable oscillation which is driven by a secondary electrostatic field caused by nonlinear interaction of Langmuir waves within a cone centered on the magnetic field and by the scattering of the pump field on stable Langmuir waves travelling along the direction of the ISR.
Hagfors, T.↗
Organic Modification of a Layered Silicate by Co-Ion Exchange of an Alkyl Ammonium and a Mono-Protonated Diamine
Co-Ion exchange of the interlayer cations of a layered silicate with a mono-protonated aromatic diamine and an alkyl ammonium ion into the silicate galleries. The presence of the alkyl ammonium ion provides low oligomer melt viscosity during processing. The presence of the diamine allows chemical reaction between the silicate surface modification and the monomers. This reaction strengthens the polymer silicate interface, and ensures irreversible separation of the individual silicate layers. Improved polymer thermal oxidative stability and mechanical properties are obtained.
Sandi G Campbell↗
SRAM As An Array Of Energetic-Ion Detectors
Static random-access memory (SRAM) designed for use as array of energetic-ion detectors. Exploits well-known tendency of incident energetic ions to cause bit flips in cells of electronic memories. Design of ion-detector SRAM involves modifications of standard SRAM design to increase sensitivity to ions. Device fabricated by use of conventional complementary metal oxide/semiconductor (CMOS) processes. Potential uses include gas densimetry, position sensing, and measurement of cosmic-ray spectrum.
Buehler, Martin G.↗
Properties of coated and modified surfaces
The ability to create surface and near-surface properties distinct from the bulk properties of a material by means of coating or surface modification techniques is an important new field of development for engineering materials, encompassing ion implantation, plasma processing, reactive deposition methods, ion beam deposition and modification, molecular beam epitaxy, and fast quench thermal processing. Attention is given to specific areas of process control which illustrate (1) the use of process development to control material properties, (2) the importance of surface modification and coating to the tribology and ion-surface interactions of semiconductor film growth, and (3) recent findings in surface science which exemplify potential applications of ion-surface interactions that generate novel material qualities.
Mattox, D. M.↗
Near-surface modification of defective KTaO 3 by ionizing ion irradiation
The synergistic effect of nuclear (S n ) and electronic (S e ) energy loss observed in some ABO 3 perovskites has attracted considerable attention due to the real possibility to modify various near-surface properties, such as the electronic and optical properties, by patterning ion tracks in the defective near-surface regions. In this study, we show that low-energy ion-induced disordering in conjunction with ionizing ion irradiation (18 MeV Si, 21 MeV Ni and 91.6 MeV Xe) is a promising approach for tailoring ion tracks in the near-surface of defective KTaO 3 . Experimental characterization and computer simulations reveal that the size of these latent ion tracks increases with S e and level of pre-existing damage. These results further reveal that the threshold S e value (S e th ) for track creation increases with decreasing pre-damage level. The values of S e th increase from 5.02 keV nm -1 , for a pre-existing fractional disorder of 0.53 in KTaO 3 , to 10.81 keV nm -1 for pristine KTaO 3 . Above these thresholds, amorphous latent tracks are produced due local melting and rapid quenching. Below a disorder fraction of 0.08 and S e ≤ 6.68 keV nm -1 , the synergistic effect is not active, and damage accumulation is suppressed due to a competing ionization-induced damage annealing process. These results indicate that, depending on S e and the amount of pre-existing damage, highly ionizing ions can either enhance or suppress damage accumulation in KTaO 3 , thus providing a pathway to tailoring defects states. Comprehending the conflicting roles of highly ionizing ions in defective ABO 3 oxides is vital for understanding and predictive modeling of ion-solid interactions in complex oxides, as well as for achieving control over ion track size in the near-surface of defective KTaO 3 .
36 MATERIALS SCIENCE↗