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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

The JPL deep-well mid-infrared array camera

We describe the development of a mid-infrared camera intended for use at the Palomar 5-m telescope and at the NASA Infrared Telescope Facility. The camera is based on Rockwell's HF-16 128x128 Si:As blocked impurity band (BIB) array. This array is unusual in that it has a well depth of approximately 30 million electrons; this will allow the use of traditional broadband astronomical filters (N and Q) while keeping a reasonable field-of-view. Measured array performance indicates that it has a read noise of 1100 electrons and shows non-linearities of less than 1% up to 65% of full well. In this paper, we discuss the array and its operating characteristics, and we give a brief overview of the camera design.

Ressler, Michael E.↗
NASA NTRS1996

Epitaxial Silicon Doped With Antimony

High-purity epitaxial silicon doped with antimony made by chemical vapor deposition, using antimony pentachloride (SbCI5) as source of dopant and SiH4, SiCI2H2, or another conventional source of silicon. High purity achieved in layers of arbitrary thickness. Epitaxial silicon doped with antimony needed to fabricate impurity-band-conduction photodetectors operating at wavelengths from 2.5 to 40 micrometers.

Huffman, James E.↗
NASA NTRS2002

Large Format Si:As IBC Array Performance for NGST and Future IR Space Telescope Applications

A mid-IR (5-30micrometer) instrument aboard a cryogenic space telescope can have an enormous impact in resolving key questions in astronomy and cosmology. A space platform's greatly reduced thermal backgrounds (compared to airborne or ground-based platforms), allow for more sensitive observations of dusty young galaxies at high redshifts, star formation of solar-type stars in the local universe, and formation and evolution of planetary disks and systems. The previous generation's largest, in sensitive IR detectors at these wavelengths are 256x256 pixel Si:As Impurity Band Conduction (IBC) devices built by Raytheon Infrared Operations (RIO) for the Space Infrared Telescope Facility/Infrared Array Camera (SIRTF)/(IRAC) instrument. RIO has successfully enhanced these devices, increasing the pixel count by a factor of 16 while matching or exceeding SIRTF/IRAC device performance. NASA-ARC in collaboration with RIO has tested the first high performance large format (1024x 1024) Si:As IBC arrays for low background applications, such as for the middle instrument on Next Generation Space Telescope (NGST) and future IR Explorer missions. These hybrid devices consist of radiation hard SIRTF/IRAC-type Si:As IBC material mated to a readout multiplexer that has been specially processed for operation at low cryogenic temperatures (below 10K), yielding high device sensitivity over a wavelength range of 5-28 micrometers. We present laboratory testing results from these benchmark, devices. Continued development in this technology is essential for conducting large-area surveys of the local and early universe through observation and for complementing future missions such as NGST, Terrestrial Planet Finder (TPF), and Focal Plane Instruments and Requirement Science Team (FIRST).

Ennico, Kimberly↗
NASA NTRS2004

Chirped-Superlattice, Blocked-Intersubband QWIP

An Al(x)Ga(1-x)As/GaAs quantum-well infrared photodetector (QWIP) of the blocked-intersubband-detector (BID) type, now undergoing development, features a chirped (that is, aperiodic) superlattice. The purpose of the chirped superlattice is to increase the quantum efficiency of the device. A somewhat lengthy background discussion is necessary to give meaning to a brief description of the present developmental QWIP. A BID QWIP was described in "MQW Based Block Intersubband Detector for Low-Background Operation" (NPO-21073), NASA Tech Briefs Vol. 25, No. 7 (July 2001), page 46. To recapitulate: The BID design was conceived in response to the deleterious effects of operation of a QWIP at low temperature under low background radiation. These effects can be summarized as a buildup of space charge and an associated high impedance and diminution of responsivity with increasing modulation frequency. The BID design, which reduces these deleterious effects, calls for a heavily doped multiple-quantum-well (MQW) emitter section with barriers that are thinner than in prior MQW devices. The thinning of the barriers results in a large overlap of sublevel wave functions, thereby creating a miniband. Because of sequential resonant quantum-mechanical tunneling of electrons from the negative ohmic contact to and between wells, any space charge is quickly neutralized. At the same time, what would otherwise be a large component of dark current attributable to tunneling current through the whole device is suppressed by placing a relatively thick, undoped, impurity-free AlxGa1 x As blocking barrier layer between the MQW emitter section and the positive ohmic contact. [This layer is similar to the thick, undoped Al(x)Ga(1-x)As layers used in photodetectors of the blocked-impurity-band (BIB) type.] Notwithstanding the aforementioned advantage afforded by the BID design, the responsivity of a BID QWIP is very low because of low collection efficiency, which, in turn, is a result of low electrostatic- potential drop across the superlattice emitter. Because the emitter must be electrically conductive to prevent the buildup of space charge in depleted quantum wells, most of the externally applied bias voltage drop occurs across the blocking-barrier layer. This completes the background discussion. In the developmental QWIP, the periodic superlattice of the prior BID design is to be replaced with the chirped superlattice, which is expected to provide a built-in electric field. As a result, the efficiency of collection of photoexcited charge carriers (and, hence, the net quantum efficiency and thus responsivity) should increase significantly.

Gunapala, Sarath↗
NASA NTRS2008

Performance of the JWST/MIRI Si:As Detectors

The Mid-Infrared Instrument (MIRI) is a 5 to 28 micron imager and spectrometer that is slated to fly aboard the JWST in 2013. Each of the flight arrays is a 1024x1024 pixel Si:As impurity band conductor detector array, developed by Raytheon Vision Systems. JPL, in conjunction with the MIRI science team, has selected the three flight arrays along with their spares. We briefly summarize the development of these devices, then describe the measured performance of the flight arrays along with supplemental data from sister flight-like parts.

arsenic-doped silicon↗
NASA NTRS2021

Design, Calibration, and Application of A Cryogenic Low-Background Infrared Radiometer for Spectral Irradiance and Radiance Measurements From 4- to 20-μm Wavelength

We have constructed, calibrated, and tested a cryogenic low-background infrared (IR) radiometer for both spectral radiance and irradiance measurements over the 4- to 20-μm wavelength range. The primary purpose of the Missile Defense Transfer Radiometer (MDXR) is to measure absolute irradiance or radiance from cryogenic IR test chamber sources using a photoconductive Si:As blocked-impurity band (BIB) detector and a set of spectral filters. The MDXR also includes an absolute cryogenic radiometer (ACR) and a Fourier-transform spectrometer (FTS). For irradiance measurements, the ACR is used to provide the primary power scale for the BIB detector in conjunction with spectral filters, whereas the FTS/BIB configuration derives its scale from an internal blackbody source. The two measurement scales show agreement for the irradiance of highly collimated (<1 mrad) IR beams from 10 -13 to 10 -8 W / μm / cm 2 within the combined relative uncertainties of 2.6% (coverage factor k = 1.) We have also calibrated the radiometer for radiance measurements using a large cavity fluid bath blackbody that overfills the spatial and angular extent of the radiometer entrance pupil. The radiometric calibration uncertainty analysis of the radiometer and its maintenance and stability are discussed.

radiometry↗
NASA NTRS2020

Mid-infrared detector development for the Origins Space Telescope

Mid-infrared detector arrays operating from 2.8 to 20 μm are baselined in the design of the Origins Space Telescope Mid-Infrared Spectrometer Instrument. This instrument is designed to detect and measure the spectral signatures of gases of biogenic origin in the atmospheres of exoplanets as they transit their host stars. In order to make these detections, the detector array’s pixels need to have high-signal stability when exposed to a constant flux in multiple time-series integration over a typical transit time of a few hours. With the use of a densified pupil spectrometer design, pointing effects can be mitigated because pointing variations do not displace spectra on the detector and each wavelength of light is averaged over a large number of pixels, giving good spectrophotometric stabilities. The current state-of-the-art detector arrays do not achieve these stabilities, although with a feasible development program this level of performance should be achievable. Three detector technologies are under consideration for this development, HgCdTe arrays, Si:As impurity band conduction arrays, and transition edge super-conductor bolometer arrays. We primarily treat the HgCdTe technology development, but also introduce the paths forward for the other two technologies. After a few years-long investigative programs, a down-select will be undertaken to select the flight technology.

Astronomy↗
DOE OSTI2023

Possible impacts of Mo chemical banding and second phase impurities on the irradiation behavior of monolithic U-10Mo fuels

This study investigated the microstructural behavior of both full-size and mini-size monolithic U-10Mo fuel plates irradiated to high burnup with a focus on the evolution of the second phase impurities in monolithic U-Mo using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and wavelength dispersive spectroscopy (WDS). Key indicators of possible mechanical and thermal compromise include cracks, large fission gas porosity, and interconnection of fission gas pores. For the fission densities evaluated in this work (3.5 × 10 21 fissions/cm 3 -5.1 × 10 21 fissions/cm 3 ), fine porosity can develop along the UC phase boundary; however, the size of the fission gas pores is no more than those observed in the U-Mo fuel phase. Further, other inclusions such as Si-rich second-phase impurities found in the as-fabricated microstructure were difficult to resolve post-irradiation because they can become overshadowed by porosity development in the fuel phase. Additionally, the presence of a Fe-rich sublayer formed in the Zr diffusion layer during fabrication remained enriched in the Zr layer in the irradiated U-10Mo microstructures near the U-Mo/Zr interface; however, based on the burnup assessed in this study the identified impurities did not appear to contribute to notable microstructural degradation.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2022

Temperature dependence of band shifts induced by impurity ionization in ZrTe 5

We report the topological phase transition in ZrTe 5 remains a challenge for its sensitivity to the structural parameters and carrier densities. One important issue is that the temperature dependence of the band shifts has been reported controversially. Using angle-resolved photoemission spectroscopy, we study the temperature evolution of the band structures of ZrTe 5 with samples prepared by chemical vapor transport and flux methods. We find two distinct types of band shift with temperature, one monotonically moving downward to high binding energies with the increase of temperature and another one moving downward first and then reversely upward. By assuming ZrTe 5 is a semiconductor with a limited amount of impurities, we analyze the temperature-induced ionization of the impurities and chemical potential shift to interpret the discrepant experimental observations. In this scenario, the discrepancies in band structures and the controversial results on temperature-dependent band shifts can be reconciled in a unified picture.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1985

The Effects of Mode Impurity of Ka-band System Performance

Problems associated with spurious mode generation in the proposed Ka-Band gyroklystron transmitter tube, overmoded transmission line, and feed are discussed. A brief description of the overall problem is presented. The theory used to evaluate feed and antenna performance when spurious modes are present is given. Results for feed patterns and overall antenna patterns for various levels and types of spurious modes are presented. Worst case antenna efficiency is calculated as a function of spurious mode level. Conclusions are drawn regarding the results of this study and their application to specifications on the transmitter tube and transmission line system.

Hoppe, D. J.↗
DOE OSTI2020

Magnetic impurities in Kondo insulators: An application to samarium hexaboride

Impurities and defects in Kondo insulators can have an unusual impact on dynamics that blends with effects of intrinsic electron correlations. Such crystal imperfections are difficult to avoid, and their consequences are incompletely understood. In this work, we study magnetic impurities in Kondo insulators via perturbation theory of the s-d Kondo impurity model adapted to small-band-gap insulators. The calculated magnetization and specific heat agree with recent thermodynamic measurements in samarium hexaboride (SmB 6 ). This qualitative agreement supports the physical picture of multichannel Kondo screening of local moments by electrons and holes involving both intrinsic and impurity bands. Specific heat is thermally activated in zero field by Kondo screening through subgap impurity bands and exhibits a characteristic upturn as the temperature is decreased. In contrast, magnetization obtains a dominant quantum correction from partial screening by virtual particle-hole pairs in intrinsic bands. We point out that magnetic impurities could impact de Haas–van Alphen quantum oscillations in SmB6, through the effects of Landau quantization in intrinsic bands on the Kondo screening of impurity moments.

36 MATERIALS SCIENCE↗
NASA NTRS1987

HIRIS - EOS instrument with high spectral and spatial resolution

The High-Resolution Imaging Spectrometer (HIRIS) is designed for NASA's Earth Observing System (EOS). It will have 10-nm wide spectral bands from 0.4-2.5 microns at 30 m spatial resolution over a 30 km swath. The spectral resolution allows identification of many minerals in rocks and soils, important algal pigments in oceans and inland waters, spectral changes associated with plant canopy biochemistry, composition of atmospheric aerosols, and grain size of snow and contamination by absorbing impurities. The bands will have 12-bit quantization over a dynamic range suitable for bright targets, such as snow. For targets of low brightness, such as water bodies, image-motion compensation will allow gains up to a factor of 8 to increase signal-to-noise ratios. The sensor will be able to point + or - 24 deg crosstrack and +60/-30 deg downtrack. In the 824-km orbit altitude proposed for EOS, the crosstrack pointing capability will allow 4-5 views during a 16-day revisit cycle.

Dozier, Jeff↗
NASA NTRS1988

HIRIS - The High Resolution Imaging Spectrometer

The High-Resolution Imaging Spectrometer (HIRIS) is a JPL facility instrument designed for NASA's Earth Observing System (Eos).It will have 10-nm wide spectral bands from 0.4-2.5 microns at 30 m spatial resolution over a 30 km swath. The spectral resolution allows identification of many minerals in rocks and soils, important algal pigments in oceans and inland waters, spectral changes associated with plant canopy biochemistry, composition of atmospheric aerosols, and grain size of snow and its contamination by absorbing impurities. The bands wil have 12-bit quantization over a dynamic range suitable for bright targets, such as snow. For targets of low brightness, such as water bodies, image-motion compensation will allow gains up to a factor of eight to increase signal-to-noise ratios. In the 824-km orbit altitude proposed for Eos, the crosstrack pointing capability will allow 4-5 views during a 16-day revisit cycle.

Dozier, Jeff↗
DOE OSTI2025

Multiple Carrier Generation at an Exceptionally Low Energy Threshold

Multiple carrier generation (MCG), a process wherein two or more carriers are generated from a single high-energy absorbed photon, holds immense promise for quantum sensing, metrology, low-threshold lasers, and photovoltaics. Despite its potential, MCG has faced obstacles such as low efficiency and a high threshold photon energy at least twice the band gap (2?Eg) of the semiconductor, limiting its application only to a class of materials with low Eg. Here, we present a new approach that overcomes this limitation by leveraging carrier-donor scattering to excite secondary electrons from donor states strategically positioned below the conduction band. Our method relies on strong Coulomb interaction, reduced dielectric screening, slow hot carrier cooling, and strictly follows the energy conservation rules. We experimentally demonstrated this idea in a model system of monolayer (1L) MoS2 by exploiting electron-donating chalcogen vacancy states. We observed an exceptionally low MCG threshold of ~1.12?Eg for the first time in 1L MoS2. Remarkably, the quantum yield can be further increased to >3 by increasing the photon energy to 1.65?Eg, representing a substantial advancement over existing methods. Our findings extend the horizon of MCG into next-generation high-performance optoelectronic devices with an on-demand operating spectral range spanning from infrared to ultraviolet.

CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS↗
NASA NTRS1994

Formation of dust grains with impurities in red giant winds

Among the several proposed carriers of diffuse interstellar bands (DIB's) are impurities in small dust grains, especially in iron oxide grains (Huffman 1977) and silicate grains (Huffman 1970). Most promising are single ion impurities since they can reproduce the observed band widths (Whittet 1992). These oxygen-rich grains are believed to originate mostly in the mass flows from red giants and in supernovae ejecta (e.g. Gehrz 1989). A question of considerable impact for the origin of DIB's is therefore, whether these grains are produced as mainly clean crystals or as some dirty materials. A formalism has been developed that allows tracking of the heterogeneous growth of a dust grain and its internal structure during the dust formation process. This formalism has been applied to the dust formation in the outflow from a red giant star.

Dominik, Carsten↗