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Our studies are highly interdisciplinary, but are focused on the processes and products of early planetary and asteroidal differentiation, especially the genesis of the ancient lunar crust. The compositional diversity that we explore is the residue of process diversity, which has strong relevance for comparative planetology.
Although silicic rocks (i.e. granites and rhyolites) comprise a minor component of the sampled portion of the lunar crust, recent remote sensing studies [e.g., 1-4] indicate that several un-sampled regions of the Moon have significantly higher concentrations of silicic material (also high in [K], [U], and [Th]) than sampled regions. Within these areas are morphological features that are best explained by the existence of chemically evolved volcanic rocks. Observations of silicic domes [e.g., 1-5] suggest that sizable networks of silicic melt were present during crust formation. Isotopic data indicate that silicic melts were generated over a prolonged timespan from 4.3 to 3.9 Ga [e.g., 6-8]. The protracted age range and broad distribution of silicic rocks on the Moon indicate that their petrogenesis was an important mechanism for secondary crust formation. Understanding the origin and evolution of such silicic magmas is critical to determining the composition of the lunar crustal highlands and will help to distinguish between opposing ideas for the Moon's bulk composition and differentiation. The two main hypotheses for generating silicic melts on Earth are fractional crystallization or partial melting. On the Moon silicic melts are thought to have been generated during extreme fractional crystallization involving end-stage silicate liquid immiscibility (SLI) [e.g. 9, 10]. However, SLI cannot account for the production of significant volumes of silicic melt and its wide distribution, as reported by the remote global surveys [1, 2, 3]. In addition, experimental and natural products of SLI show that U and Th, which are abundant in the lunar granites and seen in the remote sensing data of the domes, are preferentially partitioned into the depolymerized ferrobasaltic magma and not the silicic portion [11, 12]. If SLI is not the mechanism that generated silicic magmas on the Moon then alternative processes such as fractional crystallization (only crystal-liquid separation) or partial melting should be considered as viable possibilities to be tested.
Measurements of elemental chemistry are fundamental for exploring geology Almost every mars surface mission has had this capability But previous instruments have not been able to accurately correlate chemistry with texture.
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Igneous and metamorphic rocks as simulated lunar rocks, determining elastic and attenuation symmetry by quasi-longitudinal pulse velocity and amplitude measurements on spherical specimens
Apollo 14 breccias show a mixture of high and low track densities at most interior positions, indicating that the majority of the tracks have been inherited from the parent ingredients of the breccias. Using the lowest of these track densities as indicative of maximum postbrecciation surface residence times, we find a median 1.35 m.y., much younger than the less friable Apollo 11 and 12 igneous rocks. The igneous rock 14310 is studied as a part of a consortium, the results indicating a complex irradiation history. Soils are extremely variable, median track densities ranging over at least a factor of 200. Individual high density soil grains yield track density gradients having variable slopes, most of which are lower than expected from the Surveyor III filter glass results.
The alpha particle x-ray spectrometer (APXS) on all four Mars Rovers returned geochemical data from about 1000 rocks and soils along the combined traverses of over 50 kilometers. Here we discuss rocks likely of igneous origin, which might represent source materials for the soils and sediments identified along the traverses. Adirondack-type basalts, abundant in the plains of Gusev Crater, are primitive, olivine bearing basalts. They resemble in composition the basaltic soils encountered at all landing sites, except the ubiquitous elevated S, Cl and Zn in soils. They have been postulated to represent closely the average Martian crust composition. The recently identified new Martian meteorite Black Beauty has similar overall geochemical composition, very distinct from the earlier established SNC meteorites. The rim of the Noachian crater Endeavour, predating the sulfate-bearing Burns formation at Meridiani Planum, also resembles closely the composition of Adirondack basalts. At Gale Crater, the MSL Curiosity rover identified a felsic rock type exemplified by the mugearitic float rock JakeM, which is widespread along the traverse at Gale. While a surprise at that time, possibly related more evolved, alkaline rocks had been previously identified on Mars. Spirit encountered the Wishstone rocks in the Columbia Hills with approx. 6% Na2O+K2O, 15 % Al2O3 and low 12% FeO. Pathfinder rocks with elevated K and Na and >50% SiO2 were postulated to be andesitic. Recently Opportunity encountered the rock JeanBaptisteCharbonneau with >15% Al2O3, >50% SiO2 and approx. 10% FeO. A common characteristic all these rocks is the very low abundance of Cr, Ni and Zn, and an Fe/Mn ratio of about 50, indicating an unaltered Fe mineralogy. Beside these likely igneous rock types, which occurred always in several rocks, a few unique rocks were encountered, e.g. Bounce Rock, a pyroxene-bearing ejecta rock fragment resembling the Shergottite EETA 79001B meteorite. The APXS data can be used to relate the findings of all 4 landing sites, constrain the water to rock ratio of sediments or imply source rock provenance. Beyond that the capability to quantify important volatile elements like P, S, Cl, and Br have provided new insights into the chemistry and the environment present during the formation of the sediments.
Concentrations of Li, K, Rb, Sr, Na, rare-earths, Zr and Hf have been determined for some Luna 16 core materials by mass-spectrometric isotope-dilution. Two regolith fines samples from different depths in the core, and four rock-chips, including both igneous rocks and breccias, have similar trace-element concentrations. The Luna 16 materials have general lunar trace-element characteristics but differ from other returned lunar samples in a manner that suggests the presence of excess feldspar. Unless the Luna 16 igneous rocks are fused soils, they appear to represent either partial plagioclase cumulates or the least differentiated igneous material yet returned from the moon. The similarity in trace-element concentrations of the igneous rocks and the fines would then suggest largely local derivation of the Luna 16 regolith.
Continental flood basalts and mid-ocean ridge (MOR) tholeiitic basalts have distinctly different Nd-143/Nd-144 which may permit a priori distinction between continental and oceanic igneous rocks. Initial Nd-143/Nd-144 of continental igneous rocks through time fall on a Sm/Nd evolution curve with chondritic REE abundance ratio. These observations indicate that many continental igneous rocks are derived from a reservoir with chondritic REE pattern which may represent primary material remaining since the formation of the earth. Oceanic igneous rocks are derived from a different ancient reservoir which has Sm/Nd higher than chondritic. Initial Nd-143/Nd-144 and Sr-87/Sr-86 in young basalts from both oceans and continents show a strong correlation suggesting that Sm-Nd and Rb-Sr fractionation events in the mantle may be correlative and caused by the same process. From this correlation Rb/Sr for the earth is inferred to be 0.029.
The author has identified the following significant results. Significant results of the Wyoming investigation during the first six months include: (1) successful segregation of Precambrian metasedimentary/metavolcanic rocks from igneous rocks; (2) discovery of iron formation within the metasedimentary sequence; (3) mapping of previously unreported tectonic elements of major significance; (4) successful mapping of large scale fractures of the Wind River Mountains; (5) sucessful distinction of some metamorphic, igneous, and sedimentary lithologies by color-additive viewing of ERTS images; (6) mapping and interpretation of glacial features in western Wyoming; and (7) development of techniques for mapping small urban areas.
The author has identified the following significant results. Significant results of the Wyoming ERTS-1 investigation during the first six months (July-December 1972) included: (1) successful segregation of Precambrian metasedimentary/metavolcanic rocks from igneous rocks, (2) discovery of iron formation within the metasedimentary sequence, (3) mapping of previously unreported tectonic elements of major significance, (4) successful mapping of large scale fracture systems of the Wind River Mountains, (5) successful distinction of some metamorphic, igneous, and sedimentary lithologies by color additive viewing, (6) mapping of large scale glacial features, and (7) development of techniques for mapping small urban areas.
Apollo 11 lunar igneous rocks mineralogical, chemical and petrological features by optical and electron microscopy and X ray spectrometry
The howardite, eucrite and diogenite (HED) clan of meteorites forms the largest suite of achondrites with over 900 named members. The HEDs are igneous rocks and breccias of igneous rocks from a differentiated asteroid [1]. The consensus view is that these rocks hail from the asteroid 4 Vesta, which will be the first target of NASA's Dawn mission. When Dawn arrives at Vesta, she will begin remote imagery and spectroscopy of the surface. The surface she will observe will be dominated by rocks and soils mixed through impact gardening. To help with the interpretation of the remotely sensed data, we have begun a project on the petrologic and compositional study of a suite of HED polymict breccias. Here we report on the preliminary findings of this project.
We present a sample handling system, a subsystem of the proposed Dragon landed Mars Sample Return (MSR) mission [1], that can return to Earth orbit a significant mass of frozen Mars samples potentially consisting of: rock cores, subsurface drilled rock and ice cuttings, pebble sized rocks, and soil scoops. The sample collection, storage, retrieval and packaging assumptions and concepts in this study are applicable for the NASA's MPPG MSR mission architecture options [2]. Our study assumes a predecessor rover mission collects samples for return to Earth to address questions on: past life, climate change, water history, age dating, understanding Mars interior evolution [3], and, human safety and in-situ resource utilization. Hence the rover will have "integrated priorities for rock sampling" [3] that cover collection of subaqueous or hydrothermal sediments, low-temperature fluidaltered rocks, unaltered igneous rocks, regolith and atmosphere samples. Samples could include: drilled rock cores, alluvial and fluvial deposits, subsurface ice and soils, clays, sulfates, salts including perchlorates, aeolian deposits, and concretions. Thus samples will have a broad range of bulk densities, and require for Earth based analysis where practical: in-situ characterization, management of degradation such as perchlorate deliquescence and volatile release, and contamination management. We propose to adopt a sample container with a set of cups each with a sample from a specific location. We considered two sample cups sizes: (1) a small cup sized for samples matching those submitted to in-situ characterization instruments, and, (2) a larger cup for 100 mm rock cores [4] and pebble sized rocks, thus providing diverse samples and optimizing the MSR sample mass payload fraction for a given payload volume. We minimize sample degradation by keeping them frozen in the MSR payload sample canister using Peltier chip cooling. The cups are sealed by interference fitted heat activated memory alloy caps [5] if the heating does not affect the sample, or by crimping caps similar to bottle capping. We prefer cap sealing surfaces be external to the cup rim to prevent sample dust inside the cups interfering with sealing, or, contamination of the sample by Teflon seal elements (if adopted). Finally the sample collection rover, or a Fetch rover, selects cups with best choice samples and loads them into a sample tray, before delivering it to the Earth Return Vehicle (ERV) in the MSR Dragon capsule as described in [1] (Fig 1). This ensures best use of the MSR payload mass allowance. A 3 meter long jointed robot arm is extended from the Dragon capsule's crew hatch, retrieves the sample tray and inserts it into the sample canister payload located on the ERV stage. The robot arm has capacity to obtain grab samples in the event of a rover failure. The sample canister has a robot arm capture casting to enable capture by crewed or robot spacecraft when it returns to Earth orbit
Viking XRF data of the Martian regolith are compared with data of typical igneous rocks of the earth, Moon, eucrite parent asteroid, and shergottite, nakhlite, and Chassigny (SNC) meteorites. It is suggested that regolith's low Ca/Si ratio, with respect to igneous rocks with similar (Mg + Fe)/Si ratios, is not a result of simple mixing of SNC-like rocks with other igneous rocks, but rather is due to the removal of Ca from the regolith as Ca-carbonate. Formation of a mass of carbonate equivalent to a 20-m-thick global shell could account for the removal of 1000 mbar of CO2 from the Martian atmosphere. This Ca/Si ratio is consistent with the hypothesis that the Martian climate was once far warmer and wetter than at present.
The return to Earth of geological and atmospheric samples from the surface of Mars is among the highest priority objectives of planetary science. The MEPAG Mars Sample Return (MSR) End-to-End International Science Analysis Group (MEPAG E2E-iSAG) was chartered to propose scientific objectives and priorities for returned sample science, and to map out the implications of these priorities, including for the proposed joint ESA-NASA 2018 mission that would be tasked with the crucial job of collecting and caching the samples. The E2E-iSAG identified four overarching scientific aims that relate to understanding: (A) the potential for life and its pre-biotic context, (B) the geologic processes that have affected the martian surface, (C) planetary evolution of Mars and its atmosphere, (D) potential for future human exploration. The types of samples deemed most likely to achieve the science objectives are, in priority order: (1A). Subaqueous or hydrothermal sediments (1B). Hydrothermally altered rocks or low temperature fluid-altered rocks (equal priority) (2). Unaltered igneous rocks (3). Regolith, including airfall dust (4). Present-day atmosphere and samples of sedimentary-igneous rocks containing ancient trapped atmosphere Collection of geologically well-characterized sample suites would add considerable value to interpretations of all collected rocks. To achieve this, the total number of rock samples should be about 30-40. In order to evaluate the size of individual samples required to meet the science objectives, the E2E-iSAG reviewed the analytical methods that would likely be applied to the returned samples by preliminary examination teams, for planetary protection (i.e., life detection, biohazard assessment) and, after distribution, by individual investigators. It was concluded that sample size should be sufficient to perform all high-priority analyses in triplicate. In keeping with long-established curatorial practice of extraterrestrial material, at least 40% by mass of each sample should be preserved to support future scientific investigations. Samples of 15-16 grams are considered optimal. The total mass of returned rocks, soils, blanks and standards should be approximately 500 grams. Atmospheric gas samples should be the equivalent of 50 cubic cm at 20 times Mars ambient atmospheric pressure.
The objectives were to: explain the abundances of siderophile elements in the SNC meteorite suite, of putative Martian origin; discover the magmatic origins and possibly magma compositions behind the Nakhla meteorite, one of the SNC meteorites; and a re-evaluation of the petrology of Angra dos Reis, a unique meteorite linked to the earliest planetary bodies of the solar nebula. A re-evaluation of its petrography showed that the accepted scenario for its origin, as a cumulate igneous rock, was not consistent with the meteorite's textures (Treiman). More likely is that the meteorite represents a prophyritic igneous rock, originally with magma dominant. Studies of the Nakhla meteorite, of possible Martian origin, although difficult, were successful. It became necessary to reject the basic categorization of Nakhla: that is was a cumulate igneous rock. Detailed studies of the chemical zoning of Nakhlas' minerals, coupled with the failure of experimental studies to yield expected results, forced the conclusion that Nakhla is not a cumulate rock in the usual sense: a rock composed of igneous crystals and intercrystal magma. Study of the siderophile element abundances in the SNC meteorite groups involved trying to find reasonable core formation processes and parameters that would reproduce the observed abundances. Modelling was successful, and delimited a range of models which overlap with those reasonable from geophysical constraints.
It is assumed that most of the igneous rocks on the lunar surface are the product of partial melting in the lunar interior, followed by segregation and upward transport of an igneous liquid. An attempt is made to determine constraints on the composition of the lunar interior that derive from the chemical composition of the lunar igneous rocks. The salient chemical characteristics of igneous rocks from the lunar surface are summarized, and are compared to analogous characteristics of terrestrial volcanic rocks so that major similarities and differences between terrestrial and lunar basaltic rocks can be established.