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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Advanced Gas Turbine (AGT) Technology Project

Engine testing, ceramic component fabrication and evaluation, component performance rig testing, and analytical studies comprised AGT 100 activities during the 1985 year. Ten experimental assemblies (builds) were evaluated using two engines. Accrued operating time was 120 hr of burning and 170 hr total, bringing cumulative total operating time to 395 hr, all devoid of major failures. Tests identified the generator seals as the primary working fluid leakage sources. Power transfer clutch operation was demonstrated. An alpha SiC gasifier rotor engine test resulted in blade tip failures. Recurring case vibration and shaft whip have limited gasifier shaft speeds to 84%. Ceramic components successfully engine tested now include the SiC scroll assembly, Si3N3 turbine rotor, combustor assembly, regenerator disk bulkhead, turbine vanes, piston rings, and couplings. A compressor shroud design change to reduce heat recirculation back to the inlet was executed. Ceramic components activity continues to focus on the development of state-of-the-art material strength characteristics in full-scale engine hardware. Fiber reinforced glass-ceramic composite turbine (inner) backplates were fabricated by Corning Glass Works. The BMAS/III material performed well in engine testing. Backplates of MAS material have not been engine tested.

Source record↗
NASA NTRS1988

Heat transfer measurements on biconics at incidence in hypersonic high enthalpy air and nitrogen flows

Heat transfer rate measurements have been obtained at 0, 5, 15, and 21 deg angles-of-attack for a straight biconic scale model of an aeroassisted orbital vehicle proposed for planetary probe missions. Heat-transfer distributions were measured using palladium thin-film resistance gauges deposited on a glass-ceramic substrate. The windward heat transfer correlations were based on equilibrium flow in the shock layer of the model, although the flow may depart from equilibrium in the flow-field.

Gai, S. L.↗
NASA NTRS1989

High-temperature testing of glass/ceramic matrix composites

Recent advances in ceramic and other high-temperature composites have created a need for test methods that can be used at 1000 C and above. Present test methods usually require adhesively bonded tabs that cannot be used at high temperatures. This paper discusses some of the difficulties with high-temperature test development and describes several promising test methods. Stress-strain data are given for Nicalon ceramic fiber reinforced glass and glass-ceramic matrix composites tested in air at temperatures up to 1000 C.

Mandell, John F.↗
NASA NTRS1990

Crystallization behavior and properties of BaO-Al2O3-2SiO2 glass matrices

Glass of stoichiometric celsian composition, BaO-Al2O3-2SiO2, is a potential glass-ceramic matrix for high-temperature composites. The glass has a density of 3.39 g/cu cm, thermal expansion coefficient of 6.6 x 10(exp -6)/deg C glass transition temperature of 910 C, and dilatometric softening point of 925 C. On heat treatment, only hexacelsian crystallized out on the surface, but both celsian and hexacelsian were present in the bulk. Effects of cold isostatic pressing (CIP), sintering, and hot pressing, in the presence and absence of an additive, on the formation of the celsian phase in the glass were studied. CIP'ed samples, after appropriate heat treatments, always crystallized out as celsian whereas the presence of 5 to 10 weight percent of an additive was necessary for formation of celsian in sintered as well as hot pressed specimens. Green density increased with CIP'ing pressure but had no effect on sintered density. Hot pressing resulted in fully dense samples.

Drummond, Charles H., III↗
NASA NTRS1991

Effects of water on the strength of Zerodur

An experimental design matrix was constructed to determine the effects of time and temperature water soak on the strength of Zerodur glass-ceramic. It was found that strength does increase in a nonlinear manner which is consistent with existing theories of crack tip blunting and residual stress reduction.

Tucker, Dennis S.↗
NASA NTRS1990

Effect of thermal cycling on stress in metallic films on ceramic substrates

The hydrogen maser is the most stable frequency standard currently available for averaging intervals of hours to weeks. A major contributor to maser frequency variations is the maser's microwave resonant cavity: by means of the cavity pulling effect, a change in the cavity's resonance frequency produces a proportional change in the maser's output frequency. To minimize variations in the cavity's dimensions, and thus in its resonance frequency, maser cavities are often constructed of a low-expansivity glass-ceramic material coated on its surface with a conductive metallic film. It was previously shown that silver films like those used in SAO maser cavities develop tensile stress when cooled to room temperature after being fired onto the cavity, and that the stress in such films relaxes with time at a rate proportional to the level of stress. Stress relaxation in maser cavity coatings can alter the shape, and hence the resonance frequency, of the cavity, resulting in a slow variation in the maser's output frequency. The possibility was investigated of reversing the initial tensile stress by precooling the coated cavity material. It was hypothesized that cooling the material well below its normal working temperature and then warming it to its normal temperature would result in a lower tensile stress or even a compressive stress. Under such a condition stress relaxation, and thus any consequent frequency drifts, might be reduced or reversed.

Mattison, Edward M.↗
NASA NTRS1991

Structural characterization of high temperature composites

Glass, ceramic, and carbon matrix composite materials have emerged in recent years with potential properties and temperature resistance which make them attractive for high temperature applications such as gas turbine engines. At the outset of this study, only flexural tests were available to evaluate brittle matrix composites at temperatures in the 600 to 1000 C range. The results are described of an ongoing effort to develop appropriate tensile, compression, and shear test methods for high temperature use. A tensile test for unidirectional composites was developed and used to evaluate the properties and behavior of ceramic fiber reinforced glass and glass-ceramic matrix composites in air at temperatures up to 1000 C. The results indicate generally efficient fiber reinforcement and tolerance to matrix cracking similar to polymer matrix composites. Limiting properties in these materials may be an inherently very low transverse strain to failure, and high temperature embrittlement due to fiber/matrix interface oxidation.

Mandell, J. F.↗
NASA NTRS1992

Flight-vehicle materials, structures, and dynamics - Assessment and future directions. Vol. 3 - Ceramics and ceramic-matrix composites

The present volume discusses ceramics and ceramic-matrix composites in prospective aerospace systems, monolithic ceramics, transformation-toughened and whisker-reinforced ceramic composites, glass-ceramic matrix composites, reaction-bonded Si3N4 and SiC composites, and chemical vapor-infiltrated composites. Also discussed are the sol-gel-processing of ceramic composites, the fabrication and properties of fiber-reinforced ceramic composites with directed metal oxidation, the fracture behavior of ceramic-matrix composites (CMCs), the fatigue of fiber-reinforced CMCs, creep and rupture of CMCs, structural design methodologies for ceramic-based materials systems, the joining of ceramics and CMCs, and carbon-carbon composites.

Levine, Stanley R.↗
NASA NTRS1992

Environmental durability of ceramics and ceramic composites

An account is given of the current understanding of the environmental durability of both monolithic ceramics and ceramic-matrix composites, with a view to the prospective development of methods for the characterization, prediction, and improvement of ceramics' environmental durability. Attention is given to the environmental degradation behaviors of SiC, Si3N4, Al2O3, and glass-ceramic matrix compositions. The focus of corrosion prevention in Si-based ceramics such as SiC and Si3N4 is on the high and low sulfur fuel combustion-product effects encountered in heat engine applications of these ceramics; sintering additives and raw material impurities are noted to play a decisive role in ceramics' high temperature environmental response.

Fox, Dennis S.↗
NASA NTRS1993

Cratering in glasses impacted by debris or micrometeorites

Mechanical strength measurements on five glasses and one glass-ceramic exposed on LDEF revealed no damage exceeding experimental limits of error. The measurement technique subjected less than 5 percent of the sample surface area to stresses above 90 percent of the failure strength. Seven micrometeorite or space debris impacts occurred at locations which were not in that portion of the sample subjected to greater than 90 percent of the applied stress. As a result of this, the impact events on the sample were not detected in the mechanical strength measurements. The physical form and structure of the impact sites was carefully examined to determine the influence of those events upon stress concentration associated with the impact and the resulting mechanical strength. The size of the impact site, insofar as it determines flaw size for fracture purposes, was examined. Surface topography of the impacts reveals that six of the seven sites display impact melting. The classical melt crater structure is surrounded by a zone of fractured glass. Residual stresses arising from shock compression and from cooling of the fused zone cannot be included in the fracture mechanics analyses based on simple flaw size measurements. Strategies for refining estimates of mechanical strength degradation by impact events are presented.

Wiedlocher, David E.↗
NASA NTRS1992

Low-earth-orbit effects on strength of glasses

The effects of a 5.8-y exposure to low-earth-orbit environment upon the mechanical properties of five commercial glasses and a low-expansion-coefficient glass-ceramic have been examined. The radiation components of the earth-orbit environment did not degrade the mechanical strength of the samples examined within the limits of experimental error. Statistical problems arising from the low frequency of micrometeorite or space debris impacts upon the samples precluded statistically valid measurement of impacted sample strengths. Upper bounds for the magnitude of the impact event damage upon the strengths for impacted samples have been determined.

Wiedlocher, David E.↗
NASA NTRS1993

Physical properties of glasses exposed to Earth-facing and trailing-side environments on LDEF

The exposure of 108 glass samples and 12 glass-ceramic samples to Earth-orbit environments permitted measurements which establish the effects of each environment. Examination of five glass types and one glass ceramic located on both the Earth-facing side and the trailing edge revealed no reduction in strength within experimental limits. Strength measurements subjected less than 5 percent of the sample surface area to stresses above 90 percent of the glass's failure strength. Seven micrometeorite or space debris impacts occurred on trailing edge samples. One of those impacts occurred in a location which was subjected to 50 percent of the applied stress at failure. Micrometeorite or space debris impacts were not observed on Earth-facing samples. The physical shape and structure of the impact sites were carefully examined using stereographic scanning electron microscopy. These impacts induce a stress concentration at the damaged region which influences mechanical strength. The flaw size produced by such damage was examined to determine the magnitude of strength degradation in micrometeorite or space-debris impacted glasses. Scanning electron microscopy revealed topographical details of impact sites which included central melt zones and glass fiber production. The overall crater structure is similar to much larger impacts of large meteorite on the Moon in that the melt crater is surrounded by shocked regions of material which fracture zones and spall areas. Residual stresses arising from shock compression and cooling of the fused zone cannot currently be included in fracture mechanics analyses based on simple flaw size examination.

Wiedlocher, David E.↗
NASA NTRS1994

Kinetics of phase transformations in glass forming systems

A nucleation rate like curve for a glass can be determined from the functional dependence of the maximum height of its DTA crystallization peak, (delta T)(sub p), on the nucleation temperature, T(sub n). This nucleation rate curve provides information for the temperature range where nucleation for the glass can occur and the temperature where the nucleation rate is a maximum. However, this curve does not provide information for the nucleation rate, I, for the glass at different temperatures. A method for estimating I at different temperatures from (delta T)(sub p) was developed using a Li2O.2SiO2 (LS2) glass. Also, the dielectric constant (epsilon) and the loss factor (tan delta) of a glass-ceramic depend, in part, upon the amount of crystallinity which, in turn, depends upon the nucleation density in the starting glass. It is therefore expected that epsilon and tan delta should have a relationship with nucleation density and hence on the nucleation rate.

Ray, Chandra S.↗
NASA NTRS1996

Investigation Into Radiation-Induced Compaction of Zerodur (trademark)

Zerodur is a low coefficient of thermal expansion glass-ceramic material. This property makes Zerodur an excellent material for high precision optical substrates. Functioning as a high precision optical substrate, a material must be dimensionally stable in the system operating environment. Published data indicate that Zerodur is dimensionally unstable when exposed to large doses of ionizing radiation. The dimensional instability is discussed as an increase in Zerodur density. This increase in density is described as a compaction. Experimental data showing proton-induced compaction of Zerodur is presented. The dependence of compaction on proton dose was determined to be a power law relationship.

Edwards, D. L.↗
NASA NTRS2000

The Effects of Gravity on the Combustion Synthesis of B2O3-Al2O3-MgO Glass Ceramic Composites

Glass ceramic composites based on B2O3-Al2O3-MgO have been produced by combustion synthesis in a Self-propagating mode. The gravitational effects on the combustion characteristics such as combustion wave velocity (V), and combustion temperature (T(sub c)) were studied. The results showed that the gravitational effects on these parameters were inconclusive. The microstructure of this system has also been analyzed with X-ray Diffraction and light microscopy. These results showed a higher amount of divitrification occurs under both reduced gravity and high gravity conditions. The gravitational effects on formation of pores, overall porosity and apparent porosity for this family of glass-ceramics also shows to be inconclusive. Possible reasons for these results are discussed.

Manerbino, A. R.↗
NASA NTRS2001

Accelerated Testing Methodology in Constant Stress-Rate Testing for Advanced Structural Ceramics: A Preloading Technique

Preloading technique was used as a means of an accelerated testing methodology in constant stress-rate ('dynamic fatigue') testing for two different brittle materials. The theory developed previously for fatigue strength as a function of preload was further verified through extensive constant stress-rate testing for glass-ceramic and CRT glass in room temperature distilled water. The preloading technique was also used in this study to identify the prevailing failure mechanisms at elevated temperatures, particularly at lower test rate in which a series of mechanisms would be associated simultaneously with material failure, resulting in significant strength increase or decrease. Two different advanced ceramics including SiC whisker-reinforced composite silicon nitride and 96 wt% alumina were used at elevated temperatures. It was found that the preloading technique can be used as an additional tool to pinpoint the dominant failure mechanism that is associated with such a phenomenon of considerable strength increase or decrease.

Choi, Sung R.↗
NASA NTRS2001

Accelerated Testing Methodology in Constant Stress-Rate Testing for Advanced Structural Ceramics: A Preloading Technique

Preloading technique was used as a means of an accelerated testing methodology in constant stress-rate (dynamic fatigue) testing for two different brittle materials. The theory developed previously for fatigue strength as a function of preload was further verified through extensive constant stress-rate testing for glass-ceramic and CRT glass in room temperature distilled water. The preloading technique was also used in this study to identify the prevailing failure mechanisms at elevated temperatures, particularly at lower test rates in which a series of mechanisms would be associated simultaneously with material failure, resulting in significant strength increase or decrease. Two different advanced ceramics including SiC whisker-reinforced composite silicon nitride and 96 wt% alumina were used at elevated temperatures. It was found that the preloading technique can be used as an additional tool to pinpoint the dominant failure mechanism that is associated with such a phenomenon of considerable strength increase or decrease.

Choi, Sung R.↗
DOE OSTI2026

Atomistic understanding of interdependence of crystal growth of two seeds embedded in glass

Recent results showed that during growth, a crystal seed embedded in glass experiences nonuniform forces from the host matrix. This result raised the possibility that during devitrification of glass, the growth of a crystal can be affected by the presence of neighboring crystals. To investigate the nature of any such interdependence of growth of neighboring crystals, atomic scale morphology of two seeds growing in a glass matrix was simulated as a function of their separation and relative misorientation. The results show a coupled rotation of seeds driven by (1) non-uniform forces from the surrounding glass, and (2) mutual interactions between the seeds. At small separations and low misorientation, each seed rotates toward perfect alignment, ultimately forming a single crystal. The onset and rate of alignment, as well as subsequent crystal growth, are strongly dependent on the growth temperature. In contrast, at larger separations and higher misorientation, the seeds cannot achieve full alignment before coalescing, resulting in polycrystalline structures.

36 MATERIALS SCIENCE↗