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At least 73 records · Page 4

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NASA NTRS1983

Geochemical constraints on the origin of the moon

Hypothesis for the origin of the moon involve variants on capture, double-planet, and fission processes. Double-planet and fission hypotheses are examined in the light of siderophile trace elements. The siderophile trace elements chosen (W, Re, Mo, P, Ga, Ge) have well understood geochemical behavior such that appropriate metal/silicate partition coefficients are available and their abundances in the lunar and terrestrial mantles 4.4-4.5 Gyr ago may be reasonably inferred. The fission hypothesis of Ringwood (1979) is not consistent with the behavior of Re, Mo, and P. The hybrid fission hypothesis of Wanke et al. (1983) overcomes many of the deficiencies of Ringwood's hypothesis, but is not readily reconcilable with the behavior of Re and Ir. The double-planet hypothesis as most recently advanced by Newsom and Drake (1982, 1983) appears to be consistent with siderophile-element behavior in the moon.

Drake, M. J.↗

NASA NTRS1983

Digital image processing applied to analysis of geophysical and geochemical data for southern Missouri

Digital image-processing techniques have been used to analyze a variety of geophysical and geochemical map data covering southern Missouri, a region with important basement and strata-bound mineral deposits. Gravity and magnetic anomaly patterns, which have been reformatted to image displays, indicate a deep crustal structure cutting northwest-southeast through southern Missouri. In addition, geologic map data, topography, and Landsat multispectral scanner images have been used as base maps for the digital overlay of aerial gamma-ray and stream sediment chemical data for the 1 x 2-deg Rolla quadrangle. Results indicate enrichment of a variety of elements within the clay-rich alluvium covering many of the interfluvial plains, as well as a complicated pattern of enrichment for the sedimentary units close to the Precambrian rhyolites and granites of the St. Francois Mountains.

Guinness, E. A.↗

NASA NTRS1984

The geochemical behavior of refractory noble metals and lithophile trace elements in refractory inclusions in carbonaceous chondrites

Recent models of Ca, Al-rich (CAI) inclusion petrogenesis, and the recent availability of thermodynamic data have led to the reexamination of the geochemical behavior of the refractory noble metals (RNM) and several lithophile refractory trace elements in CAI's in the context of distillation models. Here, pertinent chemical and mineralogical properties of the various classes of refractory inclusions are reviewed, and calculations of the stability of LRTE-RNM alloys and several LRTE oxides under nebular conditions are presented. The calculations, observations and experimental results are applied to a new model of the origin of refractory metal nuggets, and a specific mechanism is identified for producing Group II chemical patterns in a cold star nebula by fractionating interstellar dust at low temperature on the basis of physical differences between different populations of pre-solar grains.

Fegley, B., Jr.↗

NASA NTRS1984

Geophysical and geochemical constraints favoring the capture hypothesis

The early fractionation of the Moon as a result of melting the outer layer of the Moon is discussed. This melting can be attributed to the accretional heating of the moon. Computations of the early thermal evolution of the Earth and Moon based on the assumption that these bodies accreted independently were carried out. The results are consistent with many observations. The concept of geochemical reservoirs was also applied to the Moon.

Turcotte, D. L.↗

NASA NTRS1985

Petrogenetic modeling of Hawaiian tholeiitic basalts - A geochemical approach

The abundances of 29 elements in 33 samples of tholeiitic basalts from five volcanoes in Hawaii are determined by neutron-activation analysis; the results are presented in tables and graphs with the data of Murali et al. (1977) for a sixth volcano and characterized in detail; and geochemical partial-melting models are constructed to explain the origin of these basalts. The models proposed are based on olivine crystallization from three distinct source compositions (determined from the REE and Sc partitioning) and correspond to the volcano groups Mauna Kea, Kohala, and Kilauea; Mauna Loa and Lanai; and Koolau.

Budahn, J. R.↗

NASA NTRS1984

Comments on the BLAG model - The carbonate-silicate geochemical cycle and its effect on atmospheric carbon dioxide over the past 100 million years

A self-consistent method of determining initial conditions for the model presented by Berner, Lasaga, and Garrels (1983) (henceforth, the BLAG model) is derived, based on the assumption that the CO2 geochemical cycle was in steady state at t = -100 m.y. (million years). This initialization procedure leads to a dissolved magnesium concentration higher than that calculated by Berner, Lasaga, and Garrels and to a low ratio of dissolved calcium to bicarbonate prior to 60 m.y. ago. The latter prediction conflicts with the geologic record of evaporite deposits, which requires that this ratio remain greater than 0.5. The contradiction is probably caused by oversimplifications in the BLAG model, such as the neglect of the cycles of organic carbon and sulfur.

Kasting, J. F.↗

NASA NTRS1985

Geochemical and petrological sampling and studies at the first moon base

Strategic sampling appropriate to the first-order lunar base can advance a variety of first-order lunar geochemical and petrological problems. Field observation and collection of samples would be done on the lunar surface, but detailed analysis would be done mainly in terrestrial laboratories. Among the most important areas of investigation for which field observations can be made and samples can be collected at the initial base are regolith studies, studies of mare and highlands stratigraphy, and a search for rare materials such as mantle nodules. Since the range of exploration may be limited to a radius of about 20 km from the first lunar base, locating the base near a mare-highlands boundary would enable the greatest latitude in addressing these problems.

Haskin, L. A.↗

NASA NTRS1986

A hybrid model of the CO2 geochemical cycle and its application to large impact events

The effects of a large asteriod or comet impact on modern and ancient marine biospheres are analyzed. A hybrid model of the carbonate-silicate geochemical cycle, which is capable of calculating the concentrations of carbon dioxide in the atmosphere, ocean, and sedimentary rocks, is described. The differences between the Keir and Berger (1983) model and the hybrid model are discussed. Equilibrium solutions are derived for the preindustrial atmosphere/ocean system and for a system similar to that of the late Cretaceous Period. The model data reveal that globl darkening caused by a stratospheric dust veil could destroy the existing phytoplankton within a period of several weeks or months, nd the dissolution of atmospheric NO(x) compounds would lower the pH of ocean surface waters and release CO2 into the atmosphere. It is noted that the surface temperatures could be increased by several degrees and surface oceans would be uninhabitable for calcaerous organisms for approximately 20 years.

Kasting, J. F.↗

NASA NTRS1987

Mutual interactions of redox couples via electron exchange in silicate melts - Models for geochemical melt systems

The mutual interactions via electron exchange of redox couples in glass-forming melts were investigated both theoretically and experimentally. A thermodynamic approach for considering the mutual interactions leads to conclusion that the degree of mutual interaction in the melt should be proportional in part to the difference in relative reduction potentials of the interacting redox couples. Experimental studies verify this conclusion for numerous redox couples in several composition/temperature/oxygen fugacity regimes. Geochemical systems simultaneously possess many potentially multivalent elements; the stabilized redox states in the resulting magmas can be explained in part by mutual interactions and by redox buffering through the central Fe(III)- Fe(II) couples in the melts. The significance of these results for basaltic magmas of the earth, moon, and meteorites is addressed.

Schreiber, Henry D.↗

NASA NTRS1988

Geochemical comparison of K-T boundaries from the Northern and Southern Hemispheres

Closely spaced (cm-scale) traverses through the K-T boundary at Stevns Klint (Denmark), Woodside Creek (New Zealand) and a new Southern Hemisphere site at Richards Bay (South Africa) were subjected to trace element and isotopic (C, O, Sr) investigation. Intercomparison between these data-sets, and correlation with the broad K-T database available in the literature, indicate that the chemistry of the boundary clays is not globally constant. Variations are more common than similarities, both of absolute concentrations, and interelement ratios. For example, the chondrite normalized platinum-group elements (PGE) patterns of Stevns Klint are not like those of Woodside Creek, with the Pt/Os ratios showing the biggest variation. These differences in PGE patterns are difficult to explain by secondary alteration of a layer that was originally chemically homogeneous, especially for elements of such dubious crustal mobility as Os and Ir. The data also show that enhanced PGE concentrations, with similar trends to those of the boundary layers, occur in the Cretaceous sediments below the actual boundary at Stevns Klint and all three the New Zealand localities. This confirms the observations of others that the geochemistry of the boundary layers apparently does not record a unique component. It is suggested that terrestrial processes, eg. an extended period of Late Cretaceous volcanism can offer a satisfactory explanation for the features of the K-T geochemical anomaly. Such models would probably be more consistent with the observed stepwise, or gradual, palaeontological changes across this boundary, than the instant catastrophe predicated by the impact theory.

Tredous, M.↗

NASA NTRS1988

Geochemical characteristics of charnockite and high grade gneisses from Southern Peninsular Shield and their significance in crustal evolution

Presented here are the results of detailed investigations encompassing externsive structural mapping in the charnockite-high grade gneiss terrain of North Arcot district and the type area in Pallavaram in Tamil Nadu supported by petrography, mineral chemistry, major, minor and REE distribution patterns in various lithounits. This has helped in understanding the evolutionary history of the southern peninsular shield. A possible tectonic model is also suggested. The results of these studies are compared with similar rock types from parts of Andhra Pradesh, Kerala, Sri Lanka, Lapland and Nigeria which has brought about a well defined correlation in geochemical characteristics. The area investigated has an interbanded sequence of thick pile of charnockite and a supracrustal succession of shelf type sediments, layered igneous complex, basic and ultrabasic rocks involved in a complex structural, tectonic, igneous and metamorphic events.

Sugavanam, E. B.↗

NASA NTRS1988

Geochemical cycles of atmospheric gases

The processes that control the atmosphere and atmospheric changes are reviewed. The geochemical cycles of water vapor, nitrogen, carbon dioxide, oxygen, and minor atmospheric constituents are examined. Changes in atmospheric chemistry with time are discussed using evidence from the rock record and analysis of the present atmosphere. The role of biological evolution in the history of the atmosphere and projected changes in the future atmosphere are considered.

Walker, J. C. G.↗

NASA NTRS1989

Geological and geochemical record of 3400-million-year-old terrestrial meteorite impacts

Beds of sand-sized spherules in the 3400-million-year-old Fig Tree Group, Barberton Greenstone belt, South Africa, formed by the fall of quenched liquid silicate droplets into a range of shallow- to deep-water depositional environments. The regional extent of the layers, their compositional complexity, and lack of included volcanic debris suggest that they are not products of volcanic activity. The layers are greatly enriched in iridium and other platinum group elements in roughly chondritic proportions. Geochemical modeling based on immobile element abundances suggests that the original average spherule composition can be approximated by a mixture of fractionated tholeiitic basalt, komatiite, and CI carbonaceous chondrite. The spherules are thought to be the products of large meteorite impacts on the Archean earth.

Lowe, Donald R.↗

NASA NTRS1990

Geochemical evolution of the northern plains of Mars - Early hydrosphere, carbonate development, and present morphology

An equilibrium geochemical model of the primitive Martian atmosphere-regolith-ocean system that could have existed early in the history of Mars is developed. The results of this model are used to examine the evolution of the volatile budget of Mars and the processes occurring in the Martian ocean that may have contributed to the deposition of large carbonate beds on the northern plains. Results of this model are compared to those of the Pollack et al. (1987) model.

Schaefer, Martha W.↗

NASA NTRS1991

A geochemical assessment of possible lunar ore formation

The Moon apparently formed without appreciable water or other relatively volatile materials. Interior concentrations of water or other volatile substances appear to be extremely low. On Earth, water is important to the genesis of nearly all types of ores. Thus, some have reasoned that only abundant elements would occur in ore concentrations. The definition and recognition of ores on the Moon challenge the imaginations and the terrestrial perceptions of ore bodies. Lunar ores included solar-wind soaked soils, which contain abundant but dilute H, C, N, and noble gases (including He-3). Oxygen must be mined; soils contain approximately 45 percent (wt). Mainstream processes of rock formation concentrated Si, Mg, Al, Fe, and Ca, and possibly Ti and Cr. The highland surface contains approximately 70 percent (wt) feldspar (mainly CaAl2Si2O8), which can be separated from some highland soils. Small fragments of dunite were collected; dunite may occur in walls and central peaks of some craters. Theoretical extensions of observations of lunar samples suggest that the Moon may have produced ores of trace elements. Some small fragments have trace-element concentrations 10(exp 4) times higher than the lunar average, indicating that effective geochemical separations occurred; processes included fractional crystallization, silicate immiscibility, vaporization and condensation, and sulfide metamorphism. Operations of these processes acting on indigenous materials and on meteoritic material in the regolith could have produced ores. Infalling carbonaceous meteorites and comets have added water and hydrocarbons that may have been cold-trapped. Vesicles in basalts, pyroclastic beads, and reported transient events suggest gag emission from the lunar interior; such gas might concentrate and transport rare elements. Large impacts may disperse ores or produce them through deposition of heat at depth and by vaporization and subsequent condensation. The main problem in assessing lunar resources is the ignorance about the largely unexplored Moon.

Haskin, Larry A.↗

NASA NTRS1991

Geochemical stratigraphy of two regolith cores from the Central Highlands of the moon

High-resolution concentration profiles are presented for 20-22 chemical elements in the under 1-mm grain-size fractions of 60001-7 and 60009/10. Emphasis is placed on the stratigraphic features of the cores, and the fresh results are compared with those of previous petrographic and geochemical studies. For elements associated with major mineral phases, the variations in concentration in both cores exceed that observed in some 40 samples of surface and trench soils. Most of the variation in lithophile element concentrations at depths of 18 to 21 cm results from the mixing of two components - oil that is relatively mafic and rich in incompatible trace elements (ITEs), and coarse-grained anorthosite. The linearity of mixing lines on two-element concentration plots argues that the relative abundances of these various subcomponents are sufficiently uniform from sample to sample and from region to region in the core that the mixture behaves effectively as a single component. Soils at depths of 52-55 cm exhibit very low concentrations of ITEs.

Korotev, R. L.↗

NASA NTRS1991

Sources and geochemical evolution of cyanide and formaldehyde

The major source of cyanide has, in current paleoatmospheric models, been assumed to be the reaction of photodissociated thermospheric nitrogen with a limiting supply of stratospheric methane. Formaldehyde may be produced with more ease from an atmosphere of carbon dioxide as the dominant carbon species, and from carbonate in solution or sorbed in double layer hydroxide minerals. Potentially more important sources for cyanide and other carbon containing molecules are the partially photoprotected northern and southern auroral ovals where continuous currents reaching several mega-amperes induce ion-molecule reactions, extending into the lower stratosphere. In simulated environments of this kind, the cyanide ion is known to be produced from oxidized carbon species potentially more abundant than methane. Rainout of cyanide and formaldehyde place them in two different geochemical reaction reservoirs. In the anoxic Archean hydrosphere, about 1mM in Fe2(+), the cyanide ion would have been efficiently converted to the stable ferrocyanide complex Fe(CN) sub 6(4-), protecting it from the commonly considered fate of decomposition by hydrolysis, and eventually incorporating it in pyroaurite type minerals, most efficiently in green rust where it converts to insoluble ferriferrocyanide, prussian blue.

Arrhenius, G.↗

NASA NTRS1992

Early Archean spherule beds of possible impact origin from Barberton, South Africa: A detailed mineralogical and geochemical study

The Barberton Greenstone belt is a 3.5- to 3.2-Ga-old formation situated in the Swaziland Supergroup near Barberton, northeast Transvaal, South Africa. The belt includes a lower, predominantly volcanic sequence, and an upper sedimentary sequence (e.g., the Fig Tree Group). Within this upper sedimentary sequence, Lowe and Byerly identified a series of different beds of spherules with diameters of around 0.5-2 mm. Lowe and Byerly and Lowe et al. have interpreted these spherules to be condensates of rock vapor produced by large meteorite impacts in the early Archean. We have collected a series of samples from drill cores from the Mt. Morgan and Princeton sections near Barberton, as well as samples taken from underground exposures in the Sheba and Agnes mines. These samples seem much better preserved than the surface samples described by Lowe and Byerly and Lowe et al. Over a scale of just under 30 cm, several well-defined spherule beds are visible, interspaced with shales and/or layers of banded iron formation. Some spherules have clearly been deposited on top of a sedimentary unit because the shale layer shows indentions from the overlying spherules. Although fresher than the surface samples (e.g., spherule bed S-2), there is abundant evidence for extensive alteration, presumably by hydrothermal processes. In some sections of the cores sulfide mineralization is common. For our mineralogical and petrographical studies we have prepared detailed thin sections of all core and underground samples (as well as some surface samples from the S-2 layer for comparison). For geochemical work, layers with thicknesses in the order of 1-5 mm were separated from selected core and underground samples. The chemical analyses are being performed using neutron activation analysis in order to obtain data for about 35 trace elements in each sample. Major elements are being determined by XRF and plasma spectrometry. To clarify the history of the sulfide mineralization, sulfur isotopic compositions are being determined.

Koeberl, Christian↗