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DOE OSTI2023

Low-Temperature Geothermal Geospatial Datasets: An Example from Alaska

This project is a component of a broader effort focused on geothermal heating and cooling (GHC) with the aim of illustrating the numerous benefits of incorporating GHC and geothermal heat exchange (GHX) into community energy planning and national decarbonization strategies. To better assist private sector investment, it is currently necessary to define and assess the potential of low-temperature geothermal resources. For shallow GHC/GHX fields, there is no formal compilation of subsurface characteristics shared among industry practitioners that can improve system design and operations. Alaska is specifically noted in this work, because heretofore, it has not received a similar focus in geothermal potential evaluations as the contiguous United States. The methodology consists of leveraging relevant data to generate a baseline geospatial dataset of low-temperature resources (less than 150 degrees C) to compare and analyze information accessible to anyone trying to understand the potential of GHC/GHX and small-scale low-temperature geothermal power in Alaska (e.g., energy modelers, communities, planners, and policymakers). Importantly, this project identifies data related to (1) the evaluation of GHC/GHX in the shallow subsurface, and (2) the evaluation of low-temperature geothermal resource availability. Additionally, data is being compiled to assess repurposing of oil and gas wells to contribute co-produced fluids toward the geothermal direct use and heating and cooling resource potential. In this work we identified new data from three different datasets of isolated geothermal systems in Alaska and bottom-hole temperature data from oil and gas wells that can be leveraged for evaluation of low-temperature geothermal resource potential. The goal of this project is to facilitate future deployment of GHC/GHX analysis and community-led programs and update the low-temperature geothermal resources assessment of Alaska. A better understanding of shallow potential for GHX will improve design and operations of highly efficient GHC systems. The deployment and impact that can be achieved for low-temperature geothermal resources will contribute to decarbonization goals and facilitate widespread electrification by shaving and shifting grid loads.

15 GEOTHERMAL ENERGY↗

DOE OSTI2022

Reduced diffusion and enhanced retention of multiple radionuclides from pore structure characterization of barrier materials for enhanced repository performance

Fluid flow and chemical transport in porous media are the macroscopic consequences of pore structure, which integrates geometry (e.g., pore size and surface area, pore-size distribution) and topology (e.g., pore connectivity). Low-permeability geological media whose pores are poorly interconnected will exhibit the characteristics of anomalous diffusion and sample size-dependent effective porosity, which will strongly impact long-term net diffusion and retention of radionuclides in geological repository settings involving different host rocks and barrier materials. A suite of innovative and complementary experimental approaches is utilized to study the microscopic pore structure and macroscopic fluid flow & chemical transport for a range of host rocks and barrier materials, in addition to standard clay minerals and reference rocks. With a particular focus on quantifying the presence and magnitude of “isolated” pores for a reduced effective porosity in low-permeability geomedia, the integrated methodologies for basic properties and pore structure characterization of these geomedia include X-ray diffraction, thin section petrography, grain size distribution, water immersion porosimetry after vacuum-pulling for full saturation, mercury intrusion porosimetry, nitrogen physisorption, scanning electron microscopy, X-ray computed tomography, and (ultra-)small angle neutron (X-ray) scattering. In addition, custom-designed gas diffusion, tracer recipe involving a range of anionic and cationic chemicals with subsequent analyses by laser ablation and inductively coupled plasma-mass spectrometry, along with batch sorption, column transport, and imbibition tests were conducted for coupled effects of pore structure and chemical retention/transport. From the perspectives of pore structure in conjunction with multiple and complementary approaches to examining a range of sample sizes under different observational scales, we find that the poor pore connectivity is prevalent in low-permeability media (mudstone and crystalline rock) that is related to geological processes (e.g., compaction, diagenesis and thermal maturation). For example, the deep and organic matter-rich mudstones have a much smaller effective porosity than the total porosity (as a result of poor pore connectivity) and associated diffusion coefficient, and the effective porosity & diffusion coefficients are also dependent upon the sample sizes used in the measurement. Similarly, most of the pore space in the shallow mudstone is also controlled by pore-throat diameters in the 5-50 nm range of intergranular pore types from its fine-grained nature, but with an overall good pore connectivity. However, the nm-sized pore space (physically pore-network architecture) and strong sorption capacities (chemical retention from clay minerals) of both shallow and deep mudstones lead to the synergistic retention of cationic radionuclides and their utilities as effective host rocks and barrier materials. Our unique approaches of studying how the micro-scale pore structure affect macro-scale fluid flow, diffusion & retention, and chemical transport produce improved mechanistic understanding, and realistic quantification, of diffusion and retention of typical radionuclides in a range of generic host rocks and barrier materials (clay/shale, salt, crystalline rock, and tuff), with the overall results leading to scientifically-based understanding of enhanced isolation (from both diffusion and retention) of radionuclides and improved confidence on the long-term performance of geological repository to store high-level radioactive wastes. In addition to the training of 25 undergraduates, graduates, and postdocs of UTA, the scientists (organizations) involved in performing this work (e.g., discussion, sample sharing, and operation of SANS and SAXS instruments) include Ed Matteo, Yifeng Wang, and Kristopher Kuhlman (Sandia National Laboratories), Jens Birkholzer, Liange Zheng, Tim Kneafsey, and Sharon Borglin (Lawrence Berkeley National Laboratory), Mavrik Zavarin (Lawrence Livermore National Laboratory), Yukio Tachi and Yuta Fukatsu (Japan Atomic Energy Agency), Mieke de Craen (Euridice, Belgium), Markus Bleuel (NIST), Wei-Ren Chen, Gergely Nagy, Changwoo Do, William Heller, Larry Anovitz, and Kenneth Littrell (ORNL), as well as Jan Illvsky, Ivan Kuzmenko, Ju-Sang Park and Jon Almers (ANL). Key deliverables include a total of 13 peer-reviewed journal articles (nine published and three under review), 23 presentations at scientific conferences (AAPG, AAPG Southwest Section, AGU, Asian Clay Conference, GSA, GSA South-Central Section, IHLRWM, InterPore, International Conference on Chemistry and Migration Behavior of Actinides and Fission Products in the Geosphere, International Conference on Coupled Processes in Fractured Geological Media: Observation, Modeling and Application), and academic institutions (UTA, New Mexico State University; University of Poitiers, France; University of Helsinki, Finland; Uppsala University, Sweden; Istanbul Technical University, Turkey) and other organizations (Andra, France; Posiva Oy, Finland).

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2021

High-Temperature Heat Transfer Fluid Circulator for Concentrating Solar Power Systems How Mohawk and Velo3Dare Printing the Future of Energy

A high temperature Heat Transfer Fluid circulator compressor with wide turn down ratio aerodynamic performance was designed, fabricated and tested for application with high pressure super Critical CO2 fluid capable of temperatures and pressures to >750°C and 25 MPa respectively. The modular system decoupled the drive motor system from an independent compressor shaft to provide thermal isolation between the high temperature compressor shaft and the lower temperature capable motor elements. While the thermal management approach appears to be viable there are potential losses in the secondary cooling flows that need to be taken into account and fine-tuned during operation in order to achieve desired overall system efficiencies. The system was also shown to be viable and dynamically stable throughout the entire operating speed range, thereby validating the overall system configuration and structural design approach used. Finally, while it was not possible to achieve specific PTC-10 test points, the compressor performance tests provide sufficient data to indicate that the compressor has the ability to achieve the required performance in practice. The two key factors affecting compressor design and cost are the maximum expected temperature and pressure. The maximum allowable temperatures for current state-of-the-art (SOA) motor driven compressor technology is limited to of approximately 150-200°C, but inlet temperatures >750 °C may be encountered. While the optimal efficiency of compression is in the transcritical region, some concepts require inlet pressures to 225 bar.

14 SOLAR ENERGY↗

DOE OSTI2020

High-Temperature Heat Transfer Fluid Circulator for Concentrating Solar Power Systems

14 SOLAR ENERGY↗

DOE OSTI2022

Modified Lucas-Washburn theory for fluid filling in nanotubes

Ultrafast water transport in carbon nanotubes (CNTs) has drawn a great deal of attention in a number of applications, such as water desalination, power generation, and biomolecule detection. With the recent experimental advances in water filling of isolated CNTs, the Lucas-Washburn theory for capillary rise in tubes needs to be revisited for a better understanding of the physics and dynamics of water filling in CNTs. Here, the Lucas-Washburn theory is corrected for the hydrodynamic entrance effects as well as the variation of capillary pressure and hydrodynamic properties with the radius and length of CNTs. Due to the large slippage in CNTs, inclusion of the entrance effects is important particularly for the initial stages of filling where a L ∝ t scaling, as opposed to L 2 ∝ t , is observed in our molecular dynamics (MD) simulations. The corrected Lucas-Washburn theory is shown to predict the water filling dynamics in CNTs as observed in MD simulations. With the corrected theory, we achieve a better understanding of capillary rise and water filling dynamics in CNTs.

74 ATOMIC AND MOLECULAR PHYSICS↗

DOE OSTI2022

Development of the TREAT M2 experiment as a transient benchmark

A transient benchmark based on the Transient Reactor Test Facility (TREAT) M2 Calibration experiment (M2-CAL) is under development. TREAT, at Idaho National Laboratory, is a graphite moderated air-cooled research reactor which has been used extensively for fuel material testing under extreme and accident conditions. Accurate benchmark models are a beneficial component in the operations, experimental planning, and development of TREAT. In this work, we present a transient benchmark model for the M2-CAL experiment core loading. The benchmark model incorporates the coupling between the Monte Carlo Code SERPENT and the computational fluid dynamics code OpenFOAM to capture the temperature feedback mechanism. The M2-CAL transient 2580 was simulated in this work. A pre-transient analysis was performed to determine the optimum core composition and conditions before the beginning of the transient. The analysis was validated against historic TREAT kinetic measurements and the worth of the transient rod T-2. The axial power distribution in the flux wire for the M2-CAL experiment was determined and contrasted with the experiment. The model was then used to simulate the M2-CAL transient 2580 experiment based on the reported pre-transient and transient conditions. Several transient observables were calculated and compared to the experiment. The model shows good agreement with the experimental power traces, period, and average increase of power at the power ramp (time > 7.8 s). Inverse point kinetics analysis was performed during the period of the power ramp for the model and the experiment based on that, the temperature feedback component was isolated and contrasted with the experimental feedback. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

DOE OSTI2023

Utah FORGE 1-2551: Multi-Stage Fracturing System and Well Tractor to Enable Zonal Isolation During Stimulation and EGS Operations in Horizontal Wellbores - Workshop Presentation and Report

Included here are a presentation recording, slides, and report on the Multi-Stage Fracturing System and Well Tractor to Enable Zonal Isolation During Stimulation and EGS Operations in Horizontal Wellbores project by Colorado School of Mines, presented by Dr. William W. Fleckenstein. One goal of the project is to develop and demonstrate the use of low-cost, rapid multistage fracture stimulation technology with cemented casing frac sleeves that eliminates packers used in both conventional stimulation and injection flow control. The second goal is to develop and demonstrate the devices to effectively detect and control the flow of heat-carrier fluid solely from a long-reach injector through the network of induced and existing fractures and produced from an open-hole long-reach well to improve heat recovery. This presentation was featured in the Utah FORGE R&D Annual Workshop on September 7, 2023. The workshop provided a valuable opportunity to explore the progress made in each of the 17 Research and Development projects funded under Solicitation 2020-1 which aim to enhance our understanding of the crucial factors influencing the development of Enhanced Geothermal Systems (EGS) reservoirs and resources.

15 GEOTHERMAL ENERGY↗

DOE OSTI2020

Volumetric efficiency and pressure pulsations of a triplex reciprocating supercritical CO 2 pump

A reciprocating triplex pump has been integrated into a closed-loop supercritical carbon dioxide test facility. The pump is designed to compress liquid or supercritical carbon dioxide and has a maximum volumetric flow rate of 51 L/min. A sweep across the pump’s speed range of 100–1000 rev/min was performed with inlet conditions between 60 and 160 bar. The volumetric efficiency was found to increase as pump speed increased from 10 to 40 % before it plateaued at higher pump speeds. The mechanical efficiency increased linearly with pump speed and was not affected by system pressure. Pressure pulsations caused by the plungers and valves were also measured at each speed. Additionally, a 35-liter buffer volume, connected near the pump’s discharge was isolated at each speed to determine its effectiveness as a pulsation dampener. Overall the reciprocating pump was shown to perform exceptionally with liquid or supercritical inlet conditions applicable to many supercritical fluid applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2021

Active liquid crystals powered by force-sensing DNA-motor clusters

Significance Single-molecule techniques have elucidated how isolated molecular motors generate piconewton forces with unprecedented detail. However, in diverse biological and synthetic settings, force-generating proteins collectively power nonequilibrium dynamics, including continuous large-scale rearrangements and persistent fluid flows. Characterizing motor-generated forces in these dense and dynamical environments remains a challenge. We assembled a reversible DNA-based force-sensing probe that, by an optical readout, reveals the molecular arrangements and the force loads experienced by kinesin motors. These probes provide insight into motor-generated forces that collectively power the unique dynamics of microtubule-based active nematics, a noteworthy example of an internally driven active matter system. DNA-based force probes can be extended to study forces and stresses in various synthetic systems as well as diverse cellular environments.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2022

Transient mixing behavior of a supercritical fluid injected into supercritical and subcritical environments

Transient, near-field mixing of a supercritical fluid injected into supercritical and subcritical environments is investigated experimentally. Fuel (propane) from a 100 μm diameter Bosch diesel injector is injected into a high-pressure test rig with a steady flow of heated, low-velocity nitrogen to control the ambient pressure and temperature. The fuel supply pressure is approximately 190 bar, allowing short injections lasting 3–4 ms to be performed in quick succession to acquire statistically significant datasets to represent the unsteady fuel–air mixing. Two test cases with the same ambient density and injector inlet pressure and temperature were chosen in an attempt to isolate effects of mixture phase behavior. Microscopic rainbow Schlieren deflectometry (RSD) is used for visualization and quantitative data acquisition. In the case of the supercritical ambient, the injector inlet and exit and ambient conditions are all supercritical. The RSD analysis reveals a mixing process similar to the single phase fluid mixing, though condensation is also observed locally, and can be explained by the adiabatic mixing theory presented in the paper. For the subcritical ambient case, the injector inlet is supercritical, but the injector exit and ambient conditions are both subcritical. The results show a rapid expansion in the near-field promoting mixing between propane and nitrogen. At downstream locations, significant condensation is also observed as predicted by the adiabatic mixing theory. As a result, the supercritical ambient case exhibited longer and narrower jet penetration compared to the subcritical ambient case.

02 PETROLEUM↗

DOE OSTI2022

Well-Controlled Hydro-thermo-chemical Stimulation of a Coso Geothermal Well to Enhance Productivity

The goal of this project was to demonstrate controlled fracturing and permeability increase to enhance resource production and power generation at Coso. It was planned to stimulate at least two intervals in the Well 73-18RD with zonal isolation using advanced high-temperature packer technology. The anticipation was that a hydraulic fracture would form in one zone and in the second zone natural fractures would reopen, shear and extend, thereby increasing fluid communication in the field. In both cases, the intent was to carefully design the stimulation to take advantage of the relative roles of hydraulic pressure, thermal stress and chemical (“hydro-thermo-chemical”) dissolution. The project had planned to use the Welltec Annular Barrier (WAB) system developed as part of another DOE-funded project which was on schedule to be ready for field deployment. If successful, the Coso Operating Company would incorporate this approach into their ongoing well maintenance in other wells increasing the total MWs produced. The project had multiple tasks and the objective of Task 1 was to develop a workover plan, to build a geologic model, to design a stimulation program, and to work with the operating and services companies to develop a detailed budget and obtain the necessary permits and sundry notices. In Phase 2 the workover plan would be implemented, the designed stimulation would be carried out, and subsequently the well would logged and tested to measure the impact of stimulation. Per sponsor request, a Pre-Task 1 activity with a Go/No Go decision point was scheduled in Task 1.

02 PETROLEUM↗

DOE OSTI2023

Exploring for Superhot Geothermal Targets in Magmatic Settings: 2022 Field Campaign at Newberry Volcano

This paper presents preliminary results from a subset of work carried out as part of a multinational research project entitled DErisking Exploration for multiple geothermal Plays in magmatic ENvironments (DEEPEN), supported by the U.S. Department of Energy (DOE) and Geothermica, a joint effort by EU member states and associated countries. The DEEPEN project will develop a customized approach to exploration for supercritical and superhot geothermal plays in magmatic systems, which will be applied to two demonstration sites. This paper summarizes field activities carried out at the U.S. demonstration site, Newberry Volcano in central Oregon. The objective of this work effort is to refine the subsurface model of Newberry Volcano, with special focus on deeper zones including the magmatic plumbing system and other key geologic elements. New data collection included gravity and wideband magnetotelluric (MT) surveys, as well as reinstallation of a seismic network. The National Renewable Energy Laboratory (NREL) and Enthalpion Energy LLC (Enthalpion) worked with the Deschutes National Forest Fort Rock District to use a low ground disturbance method of MT deployment to collect MT data inside the caldera and other restricted areas inside the National Volcanic Monument. This opened these areas to geophysical exploration for the first time in decades. Sites along and adjacent to the south rim of the volcano constituted the primary survey objectives. A team from Lawrence Berkeley National Laboratory (LBNL), the U.S. Geological Survey (USGS), and AltaRock also began the process of reinstalling the seismic network from the AltaRock enhanced geothermal system (EGS) demonstration in anticipation of further development activities at the site. The data ingestion, reduction, and analysis phase of the project is ongoing. We are currently processing the MT and gravity data and are developing a new, highly GPU-accelerated, 3D joint MT and gravity inversion to better localize the south rim/south flank conductive target and better understand its relationship to deep heat, fluid sources, and surface extrusive features. Joint inversions, which have not yet been undertaken at Newberry, will allow us to obtain constraints on the geologic model that cannot be determined from each method in isolation, improving our ability to image key geologic features at depth.

geophysics↗

DOE OSTI2026

A decade of progress in understanding and managing legacy well integrity for geologic carbon storage

This study reviews a decade of research progress in legacy well integrity and risk management for geologic carbon storage (GCS) to commemorate the 20 th anniversary of the Intergovernmental Panel on Climate Change’s 2005 Special Report on Carbon Capture and Storage. In the past ten years, legacy well research has benefited from global efforts to constrain emissions from abandoned oil and gas wells, a continued focus on well materials performance in the presence of CO 2 -rich fluids, and practical experience gained through GCS implementation. Field measurements of abandoned well emissions show that leakage is not universal or catastrophic but forms a continuum of low-to-moderate fluxes that depend on isolation integrity and environmental attenuation. Materials research has constrained the conditions under which Portland cements exhibit self-sealing and non-sealing behaviors, and has identified the impact of geomechanical properties, non-uniform pathway apertures, multi-phase flow, and impurities in the CO 2 stream, on leakage pathways as important new areas for investigation. GCS projects at brownfield sites have inspired the creation of new workflows that integrate various tools and technologies to manage legacy well leakage risks. GCS implementation has also motivated a push towards scenario-based well modeling that directly informs permit applications. These advances inspire new research questions for the coming decade, particularly around the level of legacy well leakage risk that is environmentally acceptable and tolerable to stakeholders when sequestering millions of tonnes of CO 2 annually.

Carbon capture and storage↗

DOE OSTI2022

Beware of fake ν ’s: The effect of massive neutrinos on the nonlinear evolution of cosmic structure

Massive neutrinos suppress the growth of cosmic structure on small, nonlinear scales. It is thus often proposed that using statistics beyond the power spectrum can tighten constraints on the neutrino mass by extracting additional information from these nonlinear scales. We study the information content regarding neutrino mass at the field level, quantifying how much of this information arises from the difference in nonlinear evolution between a cosmology with one fluid [cold dark matter (CDM)] and two fluids ( CDM + neutrinos ). We do so by running two N -body simulations, one with and one without massive neutrinos, both with the same phases, and matching their linear power spectrum at a given low redshift. This effectively isolates the information encoded in the linear initial conditions from the nonlinear cosmic evolution. We demonstrate that, for k ≲ 1 h / Mpc , and for a single redshift, there is negligible difference in the real-space CDM field between the two simulations. This suggests that all the information regarding neutrino mass is in the linear power spectrum set by the initial conditions. Thus, any probe based on the CDM field alone will have negligible constraining power beyond that which exists at the linear level over the same range of scales. Consequently, any probe based on the halo field will contain little information beyond the linear power. We find similar results for the matter field responsible for weak lensing. We also demonstrate that there may be much information beyond the power spectrum in the 3D matter field; however, this is not observable in modern surveys via dark matter halos or weak lensing. Finally, we show that there is additional information to be found in redshift space.

79 ASTRONOMY AND ASTROPHYSICS↗

DOE OSTI2020

Methods of combined bioprocessing and related microorganisms, thermophilic and/or acidophilic enzymes, and nucleic acids encoding said enzymes

A genetically modified organism comprising: at least one nucleic acid sequence and/or at least one recombinant nucleic acid isolated from Alicyclobacillus acidocaldarius and encoding a polypeptide involved in at least partially degrading, cleaving, transporting, metabolizing, or removing polysaccharides, cellulose, lignocellulose, hemicellulose, lignin, starch, sugars, sugar oligomers, carbohydrates, complex carbohydrates, chitin, heteroxylans, glycosides, xylan-, glucan-, galactan-, or mannan-decorating groups; and at least one nucleic acid sequence and/or at least one recombinant nucleic acid encoding a polypeptide involved in fermenting sugar molecules to a product. Additionally, enzymatic and/or proteinaceous extracts may be isolated from one or more genetically modified organisms. The extracts are utilized to convert biomass into a product. Further provided are methods of converting biomass into products comprising: placing the genetically modified organism and/or enzymatic extracts thereof in fluid contact with polysaccharides, cellulose, lignocellulose, hemicellulose, lignin, starch, sugars, sugar oligomers, carbohydrates, complex carbohydrates, chitin, heteroxylans, glycosides, and/or xylan-, glucan-, galactan-, or mannan-decorating groups.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2019

Performance Analysis and Tank Test Validation of a Hybrid Wave-Current Energy Converter with a Single Power Takeoff

Marine and hydrokinetic (MHK) energy, including ocean waves, tidal current, ocean current and river current, has been recognized as a promising power source due to its full-day availability and high energy potential. At this stage, ocean current energy, tidal energy and ocean wave energy are currently the most competitive sourves among all the categories of MHK. The state of art MHK energy harvesting technology mainly focus on harvesting either ocean wave energy or current energy, but not both. However, a significant amount of ocean waves and tidal/ ocean current coexist in many sites and traditional devices that harvest from a single form of MHK energy, cannot make full use of the coexisting ocean energy. Furthermore, MHK energy harvesting devices need to advance to be cost-effective and competitive with other energy sources. This is difficult to achieve. Ocean wave excitation is irregular, which means that ocean wave height and wave periods are unpredictable and excitation forces on energy harvesting devices can have large variance in amplitude and frequency. Such problems/ restrictions can be possibly addressed by the concept of a hybrid energy converter. In this sense, a hybrid wave-current ocean energy conveter (HWCEC) that simutaneously harvests energy from current and wave with one single power takeoff (PTO) is designed.The wave energy is extracted through relative heaving motion between a floating buoy and a submerged second body, while the current energy is extracted using a marine current turbine (MCT). Energy from both sources are integrated by a hybrid PTO whose concept is based on a mechanical motion rectifier (MMR). In this study, different working modes are investigated together with switching criteria.Simulations were conducted with hydrodynamic coefficients obtained from computational fluid dynamics analysis and boundary element method. Tank tests were conducted for a HWCEC under coexisting wave and current inputs. For comparison, separate baseline tests of a turbine and a two-body point absorber, each acting in isolation, are conducted. Experimental results validate the dynamic modeling and show that a HWCEC can increase the output power with a range between 29-87 percent over either current turbine and wave energy converter acting individually, and it can reduce by up to 70 percent the peak-to-average power ratio compared with the wave energy converter on the tested conditions.Such results demonstrate the potential of the HWCEC as an efficient and cost-effective design.

16 TIDAL AND WAVE POWER↗

DOE OSTI2024

Efficient recovery processes for the black mass from spent lithium-ion batteries

A method of recycling lithium-ion batteries is disclosed. The method includes isolating a composite electrode that comprises an electrode material adhered to a current collector with a polyvinylidene difluoride (PVDF) binder from a spent lithium-ion battery. The method also includes contacting the composite electrode in a polyol fluid capable of releasing the PVDF binder from the current collector without substantially altering either component. The composite electrode may be a cathode or an anode. The method also includes rapidly delaminating the electrode material from the current collector to give a free electrode material and a free current collector, and recovering each of the free electrode material and the free current collector from the mixture. The free electrode material may be reused to prepare another composite electrode, as well as a lithium-ion battery comprising the same, which are also disclosed.

Belharouak, Ilias↗

DOE OSTI2021

Multiscale Assessment of Caprock Integrity for Geologic Carbon Storage in the Pennsylvanian Farnsworth Unit, Texas, USA

Leakage pathways through caprock lithologies for underground storage of CO2 and/or enhanced oil recovery (EOR) include intrusion into nano-pore mudstones, flow within fractures and faults, and larger-scale sedimentary heterogeneity (e.g., stacked channel deposits). To assess multiscale sealing integrity of the caprock system that overlies the Morrow B sandstone reservoir, Farnsworth Unit (FWU), Texas, USA, we combine pore-to-core observations, laboratory testing, well logging results, and noble gas analysis. A cluster analysis combining gamma ray, compressional slowness, and other logs was combined with caliper responses and triaxial rock mechanics testing to define eleven lithologic classes across the upper Morrow shale and Thirteen Finger limestone caprock units, with estimations of dynamic elastic moduli and fracture breakdown pressures (minimum horizontal stress gradients) for each class. Mercury porosimetry determinations of CO2 column heights in sealing formations yield values exceeding reservoir height. Noble gas profiles provide a “geologic time-integrated” assessment of fluid flow across the reservoir-caprock system, with Morrow B reservoir measurements consistent with decades-long EOR water-flooding, and upper Morrow shale and lower Thirteen Finger limestone values being consistent with long-term geohydrologic isolation. Together, these data suggest an excellent sealing capacity for the FWU and provide limits for injection pressure increases accompanying carbon storage activities.

58 GEOSCIENCES↗