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Volcanoes and global catastrophes

The search for a single explanation for global mass extinctions has let to polarization and the controversies that are often fueled by widespread media attention. The historic record shows a roughly linear log-log relation between the frequency of explosive volcanic eruptions and the volume of their products. Eruptions such as Mt. St. Helens 1980 produce on the order of 1 cu km of tephra, destroying life over areas in the 10 to 100 sq km range, and take place, on the average, once or twice a decade. Eruptions producing 10 cu km take place several times a century and, like Krakatau 1883, destroy life over 100 to 1000 sq km areas while producing clear global atmospheric effects. Eruptions producting 10,000 cu km are known from the Quaternary record, and extrapolation from the historic record suggests that they occur perhaps once in 20,000 years, but none has occurred in historic time and little is known of their biologic effects. Even larger eruptions must also exist in the geologic record, but documentation of their volume becomes increasingly difficult as their age increases. The conclusion is inescapable that prehistoric eruptions have produced catastrophes on a global scale: only the magnitude of the associated mortality is in question. Differentiation of large magma chambers is on a time scale of thousands to millions of years, and explosive volcanoes are clearly concentrated in narrow belts near converging plate margins. Volcanism cannot be dismissed as a producer of global catastrophes. Its role in major extinctions is likely to be at least contributory and may well be large. More attention should be paid to global effects of the many huge eruptions in the geologic record that dwarf those known in historic time.

Simkin, Tom↗

Active Volcanoes of Kamchatka as Suitable Terrestrial Analogs for Future Landing Missions and for Change Detection Analysis on Venus

The next decade will see the return to Venus due to a number of missions which have been recently selected and proposed for launch. The selected missions NASA DAVINCI and VERITAS, Roscosmos Venera-D, and ESA EnVision, along with the proposed missions ISRO Shukrayaan- 1, and CNSA VOICE, will open a new era for the exploration of the Earth’s hellish twin planet. These missions will shed new light on the science questions such as: (a) whether recent volcanic activity is locally constrained, or active volcanism occurs on a global scale; (b) the rate of the present-day volcanic activity; (c) the styles of volcanism on Venus, including possible occurrences of pyroclastic/explosive volcanism; and (d) how does the extreme environment on Venus effect volcanic activity. In preparation for these future missions to Venus, the Analogs for VENus’ GEologically Recent Surfaces (AVENGERS) initiative has the scope to select and analyze a number of active terrestrial volcanoes as suitable analogs for the identification and analysis of active volcanism on Venus. The Roscosmos Venera-D is the only mission, among the currently selected or planned mission, equipped with a lander to analyze the elemental and mineralogical composition of the surface. Therefore, it is crucial to find applicable volcanic areas on Earth to perform operational tests such as surface drilling and in-situ elemental composition analysis. To this regard, we propose the analysis of active volcanoes of the Kamchatka Peninsula, which is in a geodynamic setting (subduction) contrasting to that of the volcanic rises on Venus (hot spot). Thus, Kamchatka may represent a helpful geodynamic endmember to put the expected landing site of the Venera-D mission within the context of the entire variety of volcanic landforms and surface chemistry. The Kamchatka Peninsula is located on the eastern margin of the Eurasian plate, in proximity to the Kuril-Kamchatka subduction zone. The frequent eruptions characterizing the volcanoes of the Kamchatka Peninsula make them a suitable terrestrial analog for the possible detection of ongoing eruptions on Venus by future missions, which can be achieved by comparing a sequence of radar images of the same volcano and its surroundings taken at different times. Moreover, it is possible to collect samples of both unweathered and weathered volcanic deposits, to analyze their near infrared spectra in the laboratory for direct comparison with the spectra to be provided by the future missions to Venus. The chemical analyses of Venusian surface materials from the previous Soviet Venera and Vega missions are consistent with that of tholeiitic basalts. Since the volcanism of the Kamchatka Peninsula is characterized by both basaltic lava flows eruptions and pyroclastic activity, performing operational tests in the Kamchatka Peninsula also offers the unique opportunity to provide us the tools to potentially interpret the diverse output given by both effusive and explosive volcanic products.

Piero D'Incecco↗

Mount Etna as A Terrestrial Laboratory to Investigate Recent Volcanic Activity on Venus By Future Missions: A Comparison With Idunn Mons, Venus

The recently selected missions to Venus have opened a new era for the exploration of this planet. These missions will provide information about the chemistry of the atmosphere, the geomorphology, local-to-regional surface composition, and the rheology of the interior. One key scientific question to be addressed by these future missions is whether Venus remains volcanically active, and if so, how its volcanism is currently evolving. Hence, it is fundamental to analyze appropriate terrestrial analog sites for the study of possibly active volcanism on Venus. To this regard, we propose Mount Etna - one of the most active and monitored volcanoes on Earth - as a suitable terrestrial laboratory for remote and in-situ investigations to be performed by future missions to Venus. Being characterized by both effusive and explosive volcanic products, Mount Etna offers the opportunity to analyze multiple eruptive styles, both monitoring active volcanism and identifying the possible occurrence of pyroclastic activity on Venus. We directly compare Mount Etna with Idunn Mons, one of the most promising potentially active volcanoes of Venus. Despite the two structures show a different topography, they also show some interesting points of comparison, and in particular: a) comparable morpho-structural setting, since both volcanoes interact with a rift zone, and b) morphologically similar volcanic fields around both Mount Etna and Idunn Mons. Given its ease of access, we also propose Mount Etna as an analog site for laboratory spectroscopic studies to identify the signatures of unaltered volcanic deposits on Venus.

P D DIncecco↗

The Active Volcanoes of Kamchatka as Suitable Terrestrial Analogs Within the AVENGERS Initiative: An Opportunity for In-Situ Operational Tests for Future Landing Venus Missions

The next decade will see the return to Venus thanks to a number of missions which have been recently selected and proposed for launch. The Roscosmos Venera-D mission, along with the NASA DAVINCI, NASA VERITAS, ESA EnVision, the ISRO Shukrayaan-1, and the CNSA VOICE missions will open a new era for the exploration of the Earth’s hellish twin planet. The next missions to Venus should be able to shed new light on the science questions such as: a) whether the volcanic activity on this planet is locally constrained, or volcanism acts on a global scale, b) the rate of the present-day volcanic activity, and c) the style of volcanism on Venus, whether it is predominantly effusive, or the occurrence of local episodes of pyroclastic volcanism is also possible. In preparation for the future missions to Venus, the Analogs for VENus’ Geologically Recent Surfaces (AVENGERS) initiative will select and analyze a number of active terrestrial volcanoes as suitable analogs for the identification and analysis of active volcanism on Venus. Among the future missions to Venus, the Roscosmos Venera-D is the only one to be equipped with a lander which will analyze the elemental and mineralogical composition of the surface. As the young topographic rises (areas characterized by recent volcano-tectonic activity) on Venus are being proposed as one of the possible terrain types for the Venera-D landing, it is crucial to look for volcanic areas on Earth where to perform operational tests such as surface drilling and in-situ elemental composition analysis. To this regard, we propose here the analysis of the active volcanoes of the Kamchatka Peninsula in Russia as a very suitable analog for the Venera-D mission, as well as for the analysis of surface change detection due to ongoing eruptions. The Kamchatka Peninsula is located on the eastern margin of the Eurasia plate, in proximity of the Kuril-Kamchatka subduction zone. The volcanoes of the Kamchatka Peninsula are among the most active volcanoes of the world, making them a suitable terrestrial analog in the search for active volcanism on Venus. Moreover, the volcanoes of Kamchatka are characterized by pyroclastic activity. Since the previous Soviet Venera and Vega missions landed over areas which elemental composition was most likely consistent with that of tholeiitic basalts, performing operational tests over areas characterized by pyroclastic activity also offers the unique opportunity to provide us the tools to potentially interpret the diverse output given by landing over portions of the surface of Venus possibly characterized by explosive volcanic products. Finally, the frequent eruptions characterizing the volcanoes of the Kamchatka Peninsula make them also a suitable terrestrial analog for the possible detection of ongoing eruptions on Venus by future missions, which can be achieved by comparing two (or more) radar images of the same volcano (and its surroundings) in two (or more) different moments of time.

Planetary Geology↗

Volatile metal deposits on lunar soils: Relation to volcanism

Parallel leaching and volatilization experiments conducted on lunar samples and similar experiments on sphalerite do not supply the information needed to resolve the question of the chemical nature of pb 204, Zn, Bi and Tl deposits on lunar soil surfaces. It is proposed that in Apollo 17 mare and terra soils and fractions of pb 204, Zn and Tl that are insoluble under mild, hot pH 5HNO3, leaching conditions and involatile at 600 C were originally surface deposits which became immobilized by migration into the silicate substrate or by chemisorption. Only Bi is predominantly indigenous. The implication is also that the soils over their respective times of evolution were exposed to heavy metal vapors or that an episodic exposure occurred after they had evolved. A sequence of events is proposed to account for orange 74220 and black 74001 glasses by lava fountaining and for soil 74241 as tephra from an explosive volcanic eruption.

Reed, G. W., Jr.↗

An Estimate of the Likelihood for a Climatically Significant Volcanic Eruption Within the Present Decade (2000-2009)

Since 1750, the number of cataclysmic volcanic eruptions (i.e., those having a volcanic explosivity index, or VEI, equal to 4 or larger) per decade is found to span 2-11, with 96% located in the tropics and extra-tropical Northern Hemisphere, A two-point moving average of the time series has higher values since the 1860s than before, measuring 8.00 in the 1910s (the highest value) and measuring 6.50 in the 1980s, the highest since the 18 1 0s' peak. On the basis of the usual behavior of the first difference of the two-point moving averages, one infers that the two-point moving average for the 1990s will measure about 6.50 +/- 1.00, implying that about 7 +/- 4 cataclysmic volcanic eruptions should be expected during the present decade (2000-2009). Because cataclysmic volcanic eruptions (especially, those having VEI equal to 5 or larger) nearly always have been associated with episodes of short-term global cooling, the occurrence of even one could ameliorate the effects of global warming. Poisson probability distributions reveal that the probability of one or more VEI equal to 4 or larger events occurring within the next ten years is >99%, while it is about 49% for VEI equal to 5 or larger events and 18% for VEI equal to 6 or larger events. Hence, the likelihood that a, climatically significant volcanic eruption will occur within the next 10 years appears reasonably high.

Wilson, Robert M.↗

Volatile metal deposits on lunar soils - Relation to volcanism

Parallel leaching and volatilization experiments conducted on lunar samples and similar experiments on sphalerite do not supply the information needed to resolve the question of the chemical nature of Pb-204, Zn, Bi, and Tl deposits on lunar soil surfaces. It is proposed that in Apollo 17 mare and terra soils the fractions of Pb-204, Zn, and Tl that are insoluble under mild, hot pH 5 HNO3, leaching conditions and involatile at 600 C were originally surface deposits which became immobilized by migration into the silicate substrate or by chemisorption. Most of the Bi does not seem to be the result of such a deposit. The implication is also that the soils, over their respective times of evolution, were exposed to heavy metal vapors or that an episodic exposure occurred after they had evolved. A sequence of events is proposed to account for orange 74220 and black 74001 glasses by lava fountaining and for soil 74241 as tephra from an explosive volcanic eruption.

Reed, G. W., Jr.↗

Sedimentological effects of tsunamis, with particular reference to impact-generated and volcanogenic waves

Impulse-generated waves (tsunamis) may be produced, at varying scales and global recurrence intervals (RI), by several processes. Meteorite-water impacts will produce tsunamis, and asteroid-scale impacts with associated mega-tsunamis may occur. A bolide-water impact would undoubtedly produce a major tsunami, whose sedimentological effects should be recognizable. Even a bolide-land impact might trigger major submarine landslides and thus tsunamis. In all posulated scenarios for the K/T boundary event, then, tsunamis are expected, and where to look for them must be determined, and how to distinguish deposits from different tsunamis. Also, because tsunamis decrease in height as they move away from their source, the proximal effects will differ by perhaps orders of magnitude from distal effects. Data on the characteristics of tsunamis at their origin are scarce. Some observations exist for tsunamis generated by thermonuclear explosions and for seismogenic tsunamis, and experimental work was conducted on impact-generated tsunamis. All tsunamis of interest have wave-lengths of 0(100) km and thus behave as shallow-water waves in all ocean depths. Typical wave periods are 0(10 to 100) minutes. The effect of these tsunamis can be estimated in the marine and coastal realm by calculating boundary shear stresses (expressed as U*, the shear velocity). An event layer at the K/T boundary in Texas occurs in mid-shelf muds. Only a large, long-period wave with a wave height of 0(50) m, is deemed sufficient to have produced this layer. Such wave heights imply a nearby volcanic explosion on the scale of Krakatau or larger, or a nearby submarine landslide also of great size, or a bolide-water impact in the ocean.

Bourgeois, Joanne↗

Diffusion in Melts and Magmas

Diffusion results from random motion of particles and entities. Diffusion in melts and magmas is due to thermally excited random motion of atoms, ions, and clusters, and plays a critical role in magmatic and volcanic processes. In melts and magmas, diffusion is one of the two mechanisms of mass transfer; the other being bulk flow (referred to as convection or advection). When both are present, diffusion refers to the dispersive motion relative to the mean bulk flow in a given reference frame (Richter et al. 1998). Diffusion plays critical roles in controlling magma mixing (Watson 1982; Koyaguchi 1985, 1989; Lesher 1994; Huber et al. 2009; Guo and Zhang 2020), mineral growth and dissolution rates in magmas (e.g., Watson 1982; Harrison and Watson 1983; Zhang et al. 1989; Newcombe et al. 2014; Macris et al. 2018), bubble growth and dissolution rate in magmas (Sparks 1978; Proussevitch and Sahagian 1998; Liu and Zhang 2000; Zhang 2013), and elemental and isotope fractionation during mineral 2 growth and dissolution (Jambon 1980; Richter et al. 1999, 2003; Watson and Muller 2009; Chopra et al. 2012; Watkins et al. 2014, 2017; Holycross et al. 2016, 2018). As a result, diffusion also plays an essential role in explosive volcanic eruptions and magma crystallization. Furthermore, diffusion has important applications in geospeedometry (Lasaga 1983, 1998; Zhang 1994, 2008; Trail et al. 2016; Zhang and Xu 2016). Experimental investigation of diffusion in geologically relevant silicate melts began to flourish in the 1970’s when micro-analytical measurements of diffusion profiles became available. In addition to the vast number of papers published since then, numerous books and reviews are available for diffusion in silicate melts. Hofmann et al. (1974) edited a book titled “Geochemical Transport and Kinetics” published by Carnegie Institution of Washington. This was the first landmark book summarizing the field. Lasaga and Kirkpatrick (1981) edited a book “Kinetics of Geochemical Processes” as volume 8 of the Reviews in Mineralogy (later becoming Reviews in Mineralogy and Geochemistry) series. Zhang and Cherniak (2010) edited “Diffusion in Minerals and Melts” as volume 72 of Reviews of Mineralogy and Geochemistry series, in which one chapter focused on diffusion theory, five chapters on diffusion in silicate melts (Behrens 2010; Lesher 2010; Liang 2010; Zhang and Ni 2010; Zhang et al. 2010), and other chapters were on experimental, analytical, and computational methods, and diffusion in minerals. Several textbooks covered the principles and applications of diffusion theories (Kirkaldy and Young 1987; Shewmon 1989; Cussler 1997; Lasaga 1998; Zhang 2008; Vrentas and Vrentas 2016), and two classic books covered the mathematics of diffusion (Carslaw and Jaeger 1959; Crank 1975). In preparing for this review chapter, we thought carefully about what to cover for this vast field, and decided to briefly go through the fundamentals of diffusion (more complete review can be found in Chakraborty 1995; Zhang 2008, 2010) and solutions to often-encountered 3 diffusion problems, and then focus on post-2010 diffusion studies on silicate melts and magmas. Here, melts refer to (mostly natural) silicate liquid, and magmas refer to crystal-bearing and/or bubble-bearing melts in which the continuous phase is the melt. There is a large body of work on diffusion in glasses, especially in the materials science literature, which is not covered in this review.

Youxue Zhang↗

An investigation of volcanic depressions. Part 4: Origin of Hole-in-the-ground, a maar in Central Oregon

Hole-in-the-Ground, a volcanic explosion crater, located in central Oregon is described. The morphology of the soil and rocks and the topography of the crater indicate the sequential happenings during the eruption. Geophysical measurements also indicate a domical intrusion below the crater floor, extending upward as a ring dike around the margins of the crater. The volume of ejecta was determined for four major eruptions. Varied analyses were made of the pyroclastic debris, rocks, cinders, and soil.

Lorenz, V.↗

The effect of volcanic activity on climate

Radiative transfer calculations of the global energy balance were performed to estimate the change in mean surface temperature that results from the addition of volcanic aerosols to the stratosphere. Results of the calculations are consistent with stratospheric warming observed in the last few months following the eruption of Mt. Agung and the average surface temperature decrease found for the two year period following major volcanic explosions.

Pollack, J. B.↗

Stratospheric aerosols and climatic change

Generated primarily by volcanic explosions, a layer of submicron silicate particles and particles made of concentrated sulfuric acids solution is present in the stratosphere. Flights through the stratosphere may be a future source of stratospheric aerosols, since the effluent from supersonic transports contains sulfurous gases (which will be converted to H2SO4) while the exhaust from Space Shuttles contains tiny aluminum oxide particles. Global heat balance calculations have shown that the stratospheric aerosols have made important contributions to some climatic changes. In the present paper, accurate radiative transfer calculations of the globally-averaged surface temperature (T) are carried out to estimate the sensitivity of the climate to changes in the number of stratospheric aerosols. The results obtained for a specified model atmosphere, including a vertical profile of the aerosols, indicate that the climate is unlikely to be affected by supersonic transports and Space Shuttles, during the next decades.

Baldwin, B.↗

Climatic effects of atmospheric aerosols

It is shown quantitatively how radiative climatic forcing by aerosols depends on the physical properties of the aerosols. The special case of atmospheric aerosols produced by volcanic explosions is considered, and evidence is presented which indicates that even the simple climate models available today may be able to capture some of the basic effects of aerosols on global climate. Possible effects of anthropogenic aerosols are briefly examined. It is noted that additional evidence for the significant influence of aerosols on climate may be found in data obtained from recent spacecraft missions to Venus and Mars.

Hansen, J. E.↗

Part 2: Sedimentary geology of the Valles, Marineris, Mars and Antarctic dry valley lakes

Detailed mapping of the layered deposits in the Valles Marineris, Mars from high-resolution Viking orbiter images revealed that they from plateaus of rhythmically layered material whose bases are in the lowest elevations of the canyon floors, and whose tops are within a few hundred meters in elevation of the surrounding plateaus. Four hypotheses for the origin of the layered deposits were considered: that they are eolian deposits; that they are remnants of the same material as the canyon walls; that they are explosive volcanic deposits; or that they were deposited in standing bodies of water. There are serious morphologic objections to each of the first three. The deposition of the layered deposits in standing bodies of water best explains their lateral continuity, horizontality, great thickness, rhythmic nature, and stratigraphic relationships with other units within the canyons. The Martian climatic history indicated that any ancient lakes were ice covered. Two methods for transporting sediment through a cover of ice on a martian lake appear to be feasible. Based on the presently available data, along with the theoretical calculations presented, it appears most likely that the layered deposits in the Valles Marineris were laid down in standing bodies of water.

Nedell, Susan S.↗

Abundance and distribution of ultramafic microbreccia in Moses Rock Dike: Quantitative application of AIS data

Moses Rock dike is a Tertiary diatreme containing serpentinized ultramafic microbreccia (SUM). Field evidence indicates the SUM was emplaced first followed by breccias derived from the Permian strata exposed in the walls of the diatreme and finally by complex breccias containing basement and mantle derived rocks. SUM is found primarily dispersed throughout the matrix of the diatreme. Moses Rock dike was examined with Airborne Imaging Spectrometer (AIS) to map the distribution and excess of SUM in the matrix and to better understand the nature of the eruption which formed this explosive volcanic feature. AIS data was calibrated by dividing the suite of AIS data by data from an internal standard area and then multiplying this relative reflectance data by the absolute bidirectional reflectance of a selected sample from the standard area which was measured in the lab. From the calibrated AIS data the minerals serpentine, gypsum, and illite as well as desert varnish and the lithologies SUM and other sandstones were identified. SUM distribution and abundance in the matrix of the diatreme were examined in detail and two distinct styles of SUM dispersion were observed. The two styles are discussed in detail.

Mustard, John F.↗

Iridium, shocked minerals, and trace elements across the Cretaceous/Tertiary boundary at Maud Rise, Wedell Sea, and Walvis Ridge, South Atlantic Ocean

Sediments spanning a 5 meter section across the Cretaceous-Tertiary boundary at ODP holes 689B and 690D, Maud Rise, Wedell Sea and hole 527, Walvis Ridge, are being analyzed for shock deformation, PGE's and other trace elements (including REE's). Mineral separates from each sample were studied with optical microscopy to determine the distribution and microstructural state of quartz and feldspar present in the sediments. Samples from Maud Rise were taken of the K/T transition and at about 50 cm intervals above and below it. These samples consist of carbonate-rich sediments, with the K/T transition marked by a change from white Maastrichtian oozes to a greenish ooze with higher concentrations of altered volcanic clay and vitric ash. The Walvis Ridge site is characterized by more clay-rich sediments with average carbonate content about 60 to 70 percent. Initial results from RNAA studies indicate that iridium is present in all the Maud Rise samples in concentrations equal to or greater than 0.01 ppb (whole-rock basis). Preliminary results from optical microscopy indicate the occurrence of shock mosaicism in quartz and feldspar in all of the samples studied. The pervasiveness of shock mosaicism and presence of planar features to 2 meters from the K/T boundary indicates that a single impact or volcanic explosion 66 ma may be ruled out as responsible for the K/T event. A similar conclusion may be drawn independently from the distribution of iridium and other trace elements. Regardless of the source of the shock waves and sediment contamination, multiple events are required over a ca.0.5 my timespan; currently we favor endogenous sources.

Huffman, Alan R.↗

The impact cratering record on Triton

Impact craters on Triton are scarce owing to the relatively recent resurfacing by icy melts. The most heavily cratered surface has a crater density about the same as the lunar maria. The transition diameter from simple to complex craters occurs at a diameter of about 11 kilometers, and the depth-diameter relationship is similar to that of other icy satellites when gravity is taken into account. The crater size-frequency distribution has a differential -3 slope (cumulative -2 slope) and is the same as that for the fresh crater population on Miranda. The most heavily cratered region is on the leading hemisphere in Triton's orbit. Triton may have a leading-trailing asymmetry in its crater population. Based primarily on the similarity of size distributions on Triton and Miranda and the relatively young surface on Triton, the source of Triton's craters is probably comets. The very peculiar size distribution of sharp craters on the 'cantaloupe' terrain and other evidence suggests thay are volcanic explosion craters.

Strom, Robert G.↗

Fingerprinting the K/T impact site and determining the time of impact by U-Pb dating of single shocked zircons from distal ejecta

U-Pb isotopic dating of single 1 - 3 micrograms zircons from K/T distal ejecta from a site in the Raton Basin, Colorado provides a powerful new tool with which to determine both the time of the impact event and the age of the basement at the impact site. Data for the least shocked zircons are slightly displaced from the 544 +/- 5 Ma primary age for a component of the target site, while those for highly shocked and granular grains are strongly displaced towards the time of impact at 65.5 +/- 3.0 Ma. Such shocked and granular zircons have never been reported from any source, including explosive volcanic rocks. Zircon is refractory and has one of the highest thermal blocking temperatures; hence, it can record both shock features and primary and secondary ages without modification by post-crystallization processes. Unlike shocked quartz, which can come from almost anywhere on the Earth's crust, shocked zircons can be shown to come from a specific site because basement ages vary on the scale of meters to kilometers. With U-Pb zircon dating, it is now possible to correlate ejecta layers derived from the same target site, test the single versus multiple impact hypothesis, and identify the target source of impact ejecta. The ages obtained in this study indicate that the Manson impact site, Iowa, which has basement rocks that are mid-Proterozoic in age, cannot be the source of K/T distal ejecta. The K/T distal ejecta probably originated from a single impact site because most grains have the same primary age.

Krogh, T. E.↗