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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Challenges and future perspectives on sodium and potassium ion batteries for grid-scale energy storage

The energy crisis and environmental pollution require the advancement of large-scale energy storage techniques. Among the various commercialized technologies, batteries have attracted enormous attention due to their relatively high energy density and long cycle life. Nevertheless, the limited supply and uneven distribution of lithium minerals, as well as their high cost, has greatly hindered the application of lithium-ion batteries in large-scale energy storage. Therefore, building next-generation alternative rechargeable batteries that feature low cost, long service life, and high safety is of the utmost importance. Over the past several years, we have witnessed many successful research outcomes for sodium and potassium ion batteries (SIBs and PIBs) in regard to electrode and electrolyte materials. In this Perspective, we summarize the current developments on SIBs/PIBs and their challenges when facing practical applications, including their cost, energy density, ion diffusivity in solids/electrolytes/interphases, cycle life, and safety concerns. Furthermore, we provide an overview of strategies to overcome the remaining challenges for achieving better electrochemical performance. Finally, we outline several possible directions for the future development of these two battery chemistries, with the hope of aiding the transition from the laboratory to next-generation practical applications for SIBs/PIBs batteries in grid-scale energy storage.

Energy Storage↗
DOE OSTI2020

Mathematical Models for Optimization of Grid-Integrated Energy Storage Systems

Energy storage has been proven to yield positive effects on planning, operation and control of electric grids. It has become a crucial task to properly model the energy storage systems (ESS) under the framework of grid optimization on transmission and distribution networks including microgrids. This paper presents a review on mathematical models and test cases of ESSs used for grid optimization studies, where the network constraints of power systems are included. The existing ESS models are mainly classified into two categories – linear and nonlinear models. The two main categories are further divided into several subcategories respectively; such as mixed-integer linear and convex nonlinear sub-categories. Based on the review and discussions, this paper aims at providing suggestions for choosing proper ESS models for specific grid optimization studies considering the chosen power network model.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2024

Energy Storage

This Energy Exchange 2024 session explores Energy Storage, from currently available to cutting edge systems, and explores benefits and shortcomings related to key mission goals of sustainment, resilience, and emissions reduction. Specifically, this session will explore advancements in long-duration energy storage, organic flow batteries, and rechargeable/non-rechargeable storage. Additionally, we will explore usage advantages (DoD, Commercial, Utility, Residential), system sustainment issues and challenges, and advantages/disadvantages in the integration into existing and legacy electrical systems. The Panel will have a mix of DoD, commercial, and lab/academic experts.

emissions↗
DOE OSTI2020

Redox-active oxide materials for thermal energy storage

Thermochemical storage materials having the general formula A x A′ 1-x B y B′ 1-y O 3-δ , where A=La, Sr, K, Ca, Ba, Y and B=Mn, Fe, Co, Ti, Ni, Cu, Zr, Al, Y, Cr, V, Nb, Mo, are disclosed. These materials have improved thermal storage energy density and reaction kinetics compared to previous materials. Concentrating solar power thermochemical systems and methods capable of storing heat energy by using these thermochemical storage materials are also disclosed.

14 SOLAR ENERGY↗
DOE OSTI2020

Redox-active oxide materials for thermal energy storage

Thermochemical storage materials having the general formula AxA′1-xByB′1-yO3-δ, where A=La, Sr, K, Ca, Ba, Y and B=Mn, Fe, Co, Ti, Ni, Cu, Zr, Al, Y, Cr, V, Nb, Mo, are disclosed. These materials have improved thermal storage energy density and reaction kinetics compared to previous materials. Concentrating solar power thermochemical systems and methods capable of storing heat energy by using these thermochemical storage materials are also disclosed.

14 SOLAR ENERGY↗
DOE OSTI2021

Process for fabrication of enhanced β″-alumina solid electrolytes for energy storage devices and energy applications

A dense β″-alumina/zirconia composite solid electrolyte and process for fabrication are disclosed. The process allows fabrication at temperatures at or below 1600° C. The solid electrolytes include a dense composite matrix of β″-alumina and zirconia, and one or more transition metal oxides that aid the conversion and densification of precursor salts during sintering. The composite solid electrolytes find application in sodium energy storage devices and power-grid systems and devices for energy applications.

Lu, Xiaochuan↗
DOE OSTI2022

Multilevel Analysis, Design, and Modeling of Coupling Advanced Nuclear Reactors and Thermal Energy Storage in an Integrated Energy System

This report discusses the different options for coupling thermal energy storage (TES) systems to advanced nuclear power plants (A-NPPs) in order to enable flexible and hybrid plant operation. An advanced light-water reactor (A LWR), a high-temperature gas-cooled reactor (HTGR) and a liquid-metal fast reactor (LMFR) were selected as the initial use cases for demonstrating a thermally balanced energy storage coupling design for thermal power extraction. The models presented herein showcase several design considerations, focusing on optimal deployment methodologies for achieving steady-state and transient-state operation with minimum disruption to the nuclear power cycle. This first part of the study presents steady-state models developed using Aspen HYSYS®, with the thermal energy bypass for NPP-TES coupling being varied at up to 50%. The various components were sized using the Aspen Process Economic Analyzer (APEA) and Aspen Exchanger Design and Rating (EDR), when applicable. Cost functions from these models were developed using the latest publicly available data obtained from APEA V11. The TES-coupled A-NPP steady-state models and cost functions then provided a baseline for dynamic operation and process optimization by using Idaho National Laboratory (INL)’s Framework for Optimization of Resources and Economics (FORCE) tools. A stochastic optimization of the various energy storage systems coupled to the A-NPPs was then performed using the Risk Analysis Virtual Environment (RAVEN) and its dispatch optimization plugin, the Holistic Energy Resource Optimization Network (HERON). The signal processing and synthetic history capabilities of RAVEN were used to account for the unpredictable behavior of electricity markets. An autoregressive moving average (ARMA) model was used to analyze price signals from the Pennsylvania-New Jersey-Maryland (PJM) market and were applied to the HERON analysis in order to optimize a system with the best economics. Transient modeling evaluation was then performed using Modelica models within the HYBRID repository, which was developed at INL for the Department of Energy Integrated Energy Systems program for the characterization of dynamic integrated system behavior and feedback. This includes evaluation of the TES-coupled A-LWR systems’ impact on physical and thermal system response during imposed system demands. Additional TES-coupled reactor types, coupling approaches, markets, and TES technologies will be evaluated in future work.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2021

2021 Thermal Energy Storage Systems for Buildings Workshop: Priorities and Pathways to Widespread Deployment of Thermal Energy Storage in Buildings

The 2021 U.S. Department of Energy's (DOE) "Thermal Energy Storage Systems for Buildings Workshop: Priorities and Pathways to Widespread Deployment of Thermal Energy Storage in Buildings" was hosted virtually on May 11 and 12, 2021. This report provides an overview of the workshop proceedings. Organized by DOE's Building Technologies Office (BTO), the National Renewable Energy Laboratory, Lawrence Berkeley National Laboratory, and Oak Ridge National Laboratory, the workshop convened more than 600 stakeholders from around the world to discuss the need for advancing the deployment of thermal energy storage (TES) in buildings. This workshop was designed to build on BTO's webinar series and 2019 workshop. The goals of this workshop were to promote discussion on TES related to: 1. Market adoption and deployment barriers, 2. Key applications and value drivers, 3. System cost, performance, and market requirements, and 4. End-use specific needs. The workshop took place over two days and consisted of keynote presentations, moderated panels, breakout sessions, and open discussion forums. The keynote presentations introduced opportunities for building TES, barriers to widespread deployment, and future visions. Moderated panel discussions presented diverse perspectives, breakout sessions provided opportunities for more intimate conversations, and open discussions captured feedback from the entire workshop group. Over the course of the two days, attendees exchanged experiences and ideas surrounding multiple aspects of TES in buildings. The first section of this report provides background on the motivations behind advancing TES for residential and commercial buildings and elaborates on the workshop objectives. The second section details the workshop structure and participant demographics. The third section provides key findings of the discussions that took place during the breakout sessions. Finally, this report details recommendations and actions to increase the TES deployment. Several recommendations from workshop attendees are presented in Table ES-1. TES holds significant potential to help increase building efficiency, grid-interactivity, and energy resilience, as well as reduce associated carbon emissions. The outputs generated from this workshop will aid stakeholders in advancing TES in buildings through a deeper understanding of the opportunities and barriers surrounding widespread deployment.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2023

Improving Frequency Stability and Minimizing Load Shedding Events by Adopting Grid-Scale Energy Storage with Grid Forming Inverters

The upward adoption trend of renewable generation not only means cleaner energy integrated into modern power grids, but also that most new generation sources are based on front-end inverter bridges, used as interfaces to most wind generation and all the solar PV. It is well known that due to their power electronics-based construction rather than rotational shafts, these sources do not provide inertia inherently, nor substantial amounts of short-circuit currents. However, stable energy such as what can be stored in energy storage systems, although interfaced via inverters, can be controlled to respond to system disturbances in a manner that emulates inertial behavior. This paper focuses on the application of such energy storage systems to augment inertia in the island of Puerto Rico. To do so, a user defined inverter model that contains grid forming capabilities and fast frequency response is modeled and integrated into the real transmission system in power flow and dynamics software. Energy storage is then connected to two selected areas so that it not only provides frequency regulation to avoid widespread load shedding events, but also other tangible benefits. The simulated cases suggest that even relatively small energy storage systems can avert load shedding events if adequately placed in the transmission network.

Grid-forming inverters, IBR, Inertia↗
DOE OSTI2024

Regional Power System Black Start with Run-of-river Hydropower Plant and Battery Energy Storage

Battery energy storage systems (BESSs) are an important asset for power systems with high integration levels of renewable energy, and they can be controlled to provide various critical services to the power grid. This paper presents the real-world experience of using a megawatt-scale BESS with grid-following (GFL) and grid-forming (GFM) controls and a run-of-river (ROR) hydropower plant to restore a regional power system. To demonstrate this, we carry out power-hardware-in-the-loop experiments integrating an actual GFL- or GFM-controlled BESS and a load bank. Both the simulation and experimental results presented in this paper show the different roles of GFL- or GFM-controlled BESS in power system black starts. The results provide further insight for system operators on how GFL- or GFM-controlled BESS can enhance grid stability and how an ROR hydropower plant can be converted into a black-start-capable unit with the support of a small-capacity BESS. The results show that an ROR hydropower plant combined with a BESS has the potential of becoming one of enabling elements to perform bottom-up black-start schemes as opposed to conventional bottom-down method, thus enhancing the system resiliency and robustness.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2023

Neural Network-Enhanced Reproducing Kernel Particle Method for Image-Based Multiphysics Damage Modeling of Energy Storage Materials

Energy storage materials undergo significant stresses during charge/discharge cycling, which makes understanding their reliability and durability fundamental in predicting performance and service life. Strong electrochemical-mechanical coupling and highly anisotropic material properties contribute to the formation and propagation of micro-cracking, largely along material interfaces and grain boundaries. With microstructural images supplied by the National Renewable Energy Laboratory (NREL), image-based modeling techniques are used to represent the complex material microstructures that dictate the coupled physics of these systems. Traditional electrochemical-mechanical models rely on mesh-based finite element methods, which can lead to difficulties in capturing crack propagation due to mesh dependency. Additionally, commonly used damage models, such as the continuous damage model and the cohesive zone model, often have steep tradeoffs between discontinuous field accuracy and computational expense. In this work, a neural network-enhanced reproducing kernel particle method (NN-RKPM) [1] is leveraged to accurately capture damage and crack propagation throughout the material by learning the location, orientation, and sharpness of discontinuity while allowing for a coarser nodal distribution than that necessary for capturing sharp solution transitions using traditional mesh-based methods. NN-RKPM is used to inform how crack opening and closure in turn affect the coupled chemical equations and material microstructure. Reference: [1] Baek, J., Chen, J. S., Susuki, K., "Neural Network enhanced Reproducing Kernel Particle Method for Modeling Localizations," International Journal for Numerical Methods in Engineering, Vol. 123, pp 4422-4454, https://doi.org/10.1002/nme.7040, 2022.

damage modeling↗
DOE OSTI2023

Neural Network Enhanced RKPM for Electrochemical-Mechanical Coupled Damage Modeling of Energy Storage Materials

Energy storage materials undergo significant charge cycling, which makes understanding their reliability and durability fundamental in predicting performance and service life. Strong electrochemical-mechanical coupling and highly anisotropic material properties contribute to the formation and propagation of micro-cracking, largely along material interfaces and grain boundaries. For Li-ion batteries, for example, lithium moving between electrodes during charging and discharging process causes expansion and contraction of grains, and the strongly anisotropic and nonlinearly [Li]-dependent grain material properties can cause grains to expand into and contract away from each other, leading to chemo-mechanical cracking. In the first part of this work, a RKPM based computational framework for solving the coupled solid-phase lithium conservation with Fickian diffusion and the lithium concentration dependent anisotropic mechanical problem subjected to a highly nonlinear Butler-Volmer boundary condition is introduced. The choice of RKPM completeness conditions for lithium concentration and mechanical deformation fields, and the variational consistency condition for the domain integration of the coupled problem is first determined. In the second part of this work, a neural network-enhanced reproducing kernel particle method (NN-RKPM) [1] is leveraged to accurately capture damage and crack propagation throughout the material, by learning the location, orientation, and sharpness of discontinuity while allowing for a coarser nodal distribution than that is necessary for capturing sharp solution transitions using traditional mesh-based methods. NN-RKPM is used to inform how crack opening and closure in turn affect the coupled chemical equations and material microstructure.

damage modeling↗
DOE OSTI2021

Dynamic tunability of phase-change material transition temperatures using ions for thermal energy storage

Thermal energy storage (TES) based on phase-change materials (PCMs) has many current and potential applications, such as climate control in buildings, thermal management for batteries and electronics, thermal textiles, and transportation of pharmaceuticals. Despite its promise, the adoption of TES has been limited, in part due to limited tunability of the transition temperature, which hinders TES performance for varying use temperatures. Transition temperature tuning of a material using an external stimulus, such as pressure or an electric field, typically requires very large stimuli. To circumvent this problem, here, we report on the dynamic transition temperature tunability of a PCM using ions. We achieve a transition temperature tunability up to 6°C in polyethylene glycol (PEG) by using the salt lithium oxalatodifluoroborate at a low voltage of 2.5 V, which may enable simpler and safer devices/system designs. We also explain the thermal properties of the salt/PCM solution using the Flory-Huggins theory.

25 ENERGY STORAGE↗
DOE OSTI2023

A ranking methodology for the coupling of pressurized water nuclear reactors and molten salt thermal energy storage

Thermal energy storage (TES) systems are a proposed solution to electricity market demand fluctuations and can be coupled to nuclear power plants to enable load following. Here, this work focuses on developing a methodology for evaluating potential designs for integrating a TES system into an existing pressurized water nuclear power plant. The proposed ranking methodology allows a group of experts to postulate and weigh designs based on ranking criteria derived from literature. The methodology developed in this study can aid in the final selection of a TES design for an existing nuclear power plant. The same process could be used to analyze other TES and nuclear reactor designs. The determined optimum design from this methodology was to place the TES system after the steam generator and to utilize the steam generated from the nuclear power plant to heat a molten salt TES unit. Another conclusion of this research was that human bias is prevalent during design selection, and actions such as standardized ranking criteria and large groups of experts should be used to minimize this error.

25 ENERGY STORAGE↗
DOE OSTI2021

Performance evaluation of a dynamic wall integrated with active insulation and thermal energy storage systems

Thermal energy storage systems in buildings can store cooling/heating energy during non-peak load hours or when renewable energy sources are available for later use when demanded. Using the building envelope as a thermal battery can help to shave the peak load, reduce the burden in electric grids, and enhance the occupant's thermal comfort. Sensible energy storage on wall systems such as thermally activated building systems can provide an active thermal storage strategy. However, most of the stored energy is used through passive means directed by the thermal lag, which can impede the on-demand release of the stored energy. Integrating active insulation systems with building thermal storage systems can increase the flexibility of charging and discharging time and duration. In this study, a wall system equipped with an active insulation system and thermally activated storage system was designed, and its performance on active cooling energy contribution was studied. The performances of energy storage (charging), release (discharging) of the thermal energy storage energy, and the active insulation system were studied separately and together as an integrated system. Results showed that the thermal properties of the thermal energy storage core material and the pipe spacing of both embedded pipes in the thermal energy storage and hydronic pipes used in the active insulation system affected the wall performance the most out of all the tested wall system parameters. During discharging, the heat flux into the wall was as high as 81.92 W/m 2 . This active insulation system's dynamic R-value varied between less than 1ft 2 •°F•h/BTU (0.18 m 2 •K/W) to 98% of the equally thick foam insulation's R-value.

25 ENERGY STORAGE↗
DOE OSTI2022

Redox-active oxide materials for thermal energy storage

Thermochemical storage materials having the general formula AxA′1-xByB′1-yO3-δ, where A=La, Sr, K, Ca, Ba, Y and B=Mn, Fe, Co, Ti, Ni, Cu, Zr, Al, Y, Cr, V, Nb, Mo, are disclosed. These materials have improved thermal storage energy density and reaction kinetics compared to previous materials. Concentrating solar power thermochemical systems and methods capable of storing heat energy by using these thermochemical storage materials are also disclosed.

Babiniec, Sean M.↗