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Recent Progress in Laboratory Astrophysics and Astrochemistry Achieved with the COSmIC Facility

We describe the characteristics and the capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to generate, process and analyze interstellar, circumstellar and planetary analogs in the laboratory. COSmIC stands for "Cosmic Simulation Chamber" and is dedicated to the study of neutral and ionized molecules and nanoparticles under the low temperature and high vacuum conditions that are required to simulate various space environments such as diffuse interstellar clouds, circumstellar outflows and planetary atmospheres. COSmIC integrates a variety of state-of-the-art instruments that allow recreating simulated space conditions to generate, process and monitor cosmic analogs in the laboratory. The COSmIC experimental setup is composed of a Pulsed Discharge Nozzle (PDN) expansion, that generates a plasma in the stream of a free supersonic jet expansion, coupled to high-sensitivity, complementary in situ diagnostics: cavity ring down spectroscopy (CRDS) and laser induced fluorescence (LIF) systems for photonic detection, and Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent results obtained using COSmIC will be highlighted. In particular, the progress that has been achieved in the domain of the diffuse interstellar bands (DIBs) and in monitoring, in the laboratory, the formation of circumstellar dust grains and planetary atmosphere aerosols from their gas-phase molecular precursors. Plans for future laboratory experiments on interstellar and planetary molecules and grains will also be addressed, as well as the implications of the studies underway for astronomical observations and past and future space mission data analysis.

Salama, Farid↗

Determination of the Complex Refractive Indices of Aerosol Analogs Formed at Low Temperatures with the NASA Ames Optical Constants Facility (OCF)

The NASA Ames COsmic SImulation Chamber (COSmIC) [1] is a unique experimental facility that allows: 1) cooling a gas mixture to low temperature (150 K) in a jet expansion before inducing chemistry by plasma; and 2) controlling the extent of the chemical reactions by employing a pulsed plasma discharge. This enables the study of the early stages of aerosol production, as well as specific chemical pathways in planetary environments (e.g. Titan’s and Pluto’s atmospheres). Both the gas and solid products can be studied. For a decade COSmIC has been used to simulate Titan’s atmospheric chemistry at low, Titan-like temperature [2]. New developments on the COSmIC facility are investigating formation of aerosols in tenuous, or transitory, atmospheres of other icy bodies [3-5], as well as cool exoplanets atmospheres having a hydrocarbon component, that results in formation of hazes and/or surface deposits of refractory materials. The new Ames Optical Constants Facility enables determination of the aerosol analogs' complex refractive indices, n and k, from 0.59 to 200 μm [2]. Here we report efforts of determining n and k from ex-situ transmission measurements of solid samples produced from binary N-CH and Ar-CH, and tertiary N-CH-CH and Ar-CH-CHgas mixtures in COSmIC, and deposited onto various substrates. A computational technique [6] that addresses interference fringes observed in the laboratory transmission data, particularly at wavelengths < 3 μm, has been implemented and applied to determine n and k for the samples. At visible and near-infrared wavelengths(0.4-1.6 μm) the deposit thickness, and its variation, as well as n and k were determined by a commercial entity. These data provide the ability to compare results, from independent methods, in the region of overlap between the two approaches.

Ella M Sciamma-O'Brien↗

The Hyperluminous Infrared Quasar 3C 318 and Its Implications for Interpreting Sub-MM Detections of High-Redshift Radio Galaxies

We present near-infrared spectroscopy and imaging of the compact steep-spectrum radio source 3C 318 which shows it to be a quasar at redshift z = 1.574 (the z = 0.752 value previously reported is incorrect). 3C 318 is an IRAS, ISO and SCUBA source so its new redshift makes it the most intrinsically luminous far-infrared (FIR) source in the 3C catalogue (there is no evidence of strong gravitational lensing effects). Its bolometric luminosity greatly exceeds the 10(exp 13) solar luminosity level above which an object is said to be hyperluminous. Its spectral energy distribution (SED) requires that the quasar heats the dust responsible for the FIR flux, as is believed to be the case in other hyperluminous galaxies, and contributes (at the greater than 10% level) to the heating of the CIA dust responsible for the sub-mm emission. We cannot determine whether a starburst makes an important contribution to the heating of the coolest dust, so evidence for a high star-formation rate is circumstantial being based on the high dust, and hence gas, C-1 mass required by its sub-mm detection. We show that the current sub-mm and FIR data available for the highest-redshift radio galaxies are consistent with SEDs similar to that of 3C 318. This indicates that at least some of this population may be detected in the sub-mm because of dust heated by the quasar nucleus, and that interpreting sub-mm detection as evidence for very high (approx. less than 1000 solar mass/yr) star-formation rates may not always be valid. We show that the 3C318 quasar is slightly reddened (A(sub v) approx. = 0.5), the most likely cause of which is SMC-type dust in the host galaxy. If very distant radio galaxies are reddened in a similar way then we show that only slightly greater amounts of dust could obscure the quasars in these sources. We speculate that the low fraction of quasars amongst the very high redshift (z approx. greater than 3) objects in low-frequency radio-selected samples is the result of such obscuration. The highest-z objects might be preferentially obscured because like 3C318 they are inevitably observed very shortly after the jet-triggering event, or because their host galaxies are richer in dust and gas at earlier cosmic epochs, or because of some combination of these two effects.

Willott, Chris J.↗

Laser Induced Fluorescence Spectroscopy of Neutral and Ionized Polycyclic Aromatic Hydrocarbons in the Cosmic Simulation Chamber

Polycyclic aromatic hydrocarbon (PAH) molecules are considered the best carriers to account for the ubiquitous infrared emission bands. PAHs have also been proposed as candidates to explain the diffuse interstellar bands (DIBs), a series of absorption features seen on the interstellar extinction curve and are plausible carriers for the extended red emission (ERE), a photoluminescent process associated with a wide variety of interstellar environments. Extensive efforts have been devoted over the past two decades to characterize the physical and chemical properties of PAH molecules and ions in space. Absorption spectra of PAH molecules and ions trapped in solid matrices have been compared to the DIBs. Absorption spectra of several cold, isolated gas-phase PAHs have also been measured under experimental conditions that mimic the interstellar conditions. The purpose of this study is to provide a new dimension to the existing spectroscopic database of neutral and single ionized PAHs that is largely based on absorption spectra by adding emission spectroscopy data. The measurements are based on the laser induced fluorescence (LIF) technique and are performed with the Pulsed Discharge Nozzle (PDN) of the COSmIC laboratory facility at NASA Ames laboratory. The PDN generates a plasma in a free supersonic jet expansion to simulate the physical and the chemical conditions in interstellar environments. We focus, here, on the fluorescence spectra of large neutral PAHs and their cations where there is a lack of fluorescence spectroscopy data. The astronomical implications of the data (e.g., ERE) are examined.

Laboratory↗

Preliminary Analysis of the Multisphere Neutron Spectrometer

Crews working on present-day jet aircraft are a large occupationally exposed group with a relatively high average effective dose from galactic cosmic radiation. Crews of future high-speed commercial aircraft flying at higher altitudes would be even more exposed. To help reduce the significant uncertainties in calculations of such exposures, the Atmospheric Ionizing Radiation (AIR) Project, an international collaboration of 15 laboratories, made simultaneous radiation measurements with 14 instruments on five flights of a NASA ER-2 high-altitude aircraft. The primary AIR instrument was a highly sensitive extended-energy multisphere neutron spectrometer with lead and steel shells placed within the moderators of two of its 14 detectors to enhance response at high energies. Detector responses were calculated for neutrons and charged hadrons at energies up to 100 GeV using MCNPX. Neutron spectra were unfolded from the measured count rates using the new MAXED code. We have measured the cosmic-ray neutron spectrum (thermal to greater than 10 GeV), total neutron fluence rate, and neutron effective dose and dose equivalent rates and their dependence on altitude and geomagnetic cutoff. The measured cosmic-ray neutron spectra have almost no thermal neutrons, a large "evaporation" peak near 1 MeV and a second broad peak near 100 MeV which contributes about 69% of the neutron effective dose. At high altitude, geomagnetic latitude has very little effect on the shape of the spectrum, but it is the dominant variable affecting neutron fluence rate, which was 8 times higher at the northernmost measurement location than it was at the southernmost. The shape of the spectrum varied only slightly with altitude from 21 km down to 12 km (56 - 201 grams per square centimeter atmospheric depth), but was significantly different on the ground. In all cases, ambient dose equivalent was greater than effective dose for cosmic-ray neutrons.

Goldhagen, P.↗

A Dissection of Spatially Resolved AGN Feedback across the Electromagnetic Spectrum

We present optical SuperNova Integral Field Spectrograph integral field spectroscopy, Hubble Space Telescope optical imaging, Chandra X-ray imaging, and Very Large Array radio interferometry of the merging galaxy 2MASX J04234080+0408017, which hosts a Seyfert 2 active galactic nucleus (AGN) at z = 0.046. Our observations reveal that radiatively driven, ionized gas outflows are successful to distances >10 kpc due to the low mass of the host system, encompassing the entirety of the observed optical emission. We also find that at large radii, where observed velocities cannot be reproduced by radiative driving models, high-velocity kinematics are likely due to mechanical driving from AGN winds impacting high-density host material. This impacting deposits sufficient energy to shock the host material, producing thermal X-ray emission and cosmic rays, which in turn promote the formation of in situ radio structure in a pseudo-jet morphology along the high-density lanes.

Travis Fischer↗

The Evolution of Galaxies and Clusters at High Spatial Resolution with Advanced X-ray Imaging Satellite (AXIS)

Stellar and black hole feedback heat and disperse surrounding cold gas clouds, launching gas flows off circumnuclear and galactic disks, producing a dynamic interstellar medium. On large scales bordering the cosmic web, feedback drives enriched gas out of galaxies and groups, seeding the intergalactic medium with heavy elements. In this way, feedback shapes galaxy evolution by shutting down star formation and ultimately curtailing the growth of structure after the peak at redshift 2–3. To understand the complex interplay between gravity and feedback, we must resolve both the key physics within galaxies and map the impact of these processes over large scales, out into the cosmic web. The Advanced X-ray Imaging Satellite (AXIS) is a proposed X-ray probe mission for the 2030s with arcsecond spatial resolution, large effective area, and low background. AXIS will untangle the interactions of winds, radiation, jets, and supernovae with the surrounding interstellar medium across the wide range of mass scales and large volumes driving galaxy evolution and trace the establishment of feedback back to the main event at cosmic noon. This white paper is part of a series commissioned for the AXIS Probe mission concept; additional AXIS white papers can be found at the AXIS website.

47 OTHER INSTRUMENTATION↗

COSMIC: Carbon Monoxide and Soot in Microgravity Inverse Combustion

Almost seventy percent of deaths in accidental fires are caused by inhalation of toxins such as carbon monoxide (CO) and smoke (soot) that form during underventilated burning. The COSMIC project examines the formation mechanisms of CO and soot during underventilated combustion, achieved presently using laminar, inverse diffusion flames (IDFs) formed between an air jet and surrounding fuel. A major hypothesis of the project is that the IDF mimics underventilated combustion because carbon-containing species that form on the fuel side of the flame (such as CO and soot) can escape without passing through an oxidizing flame tip. An IDF literature review was presented at the last microgravity workshop, and a few additional IDF papers have appeared since that meeting. The COSMIC project is entering the third year of its four-year funding cycle. The first two years have been devoted to designing and constructing a rig for use in the NASA 2.2-second drop tower. A few computations and laboratory experiments have been performed. The goals of this paper are to discuss the use of numerical simulation during burner design, to present computational and experimental results that support the hypothesis that IDFs are similar to underventilated flames, and to delineate future plans.

Blevins, L. G.↗

First Optical Constants from 0.4 to 1.6 µm of Titan Aerosol Analogs Produced in the NASA Ames COSmIC Facility and Their Use in a New Analysis of Cassini VIMS Observations

We have determined the real and imaginary refractive indices (n and k, respectively), from the visible to the near infrared (0.4 to 1.6 μm), of five laboratory-generated organic refractory materials produced from gas-phase chemistry with the NASA Ames COSmIC facility. The solid samples were produced using a plasma discharge in the stream of a 200-K supersonic jet-cooled expansion of different gas mixtures to study the impact of the molecular precursors on the solid sample optical properties. Three samples were produced from N2:CH4 (95:5) gas mixtures using three different high voltages (700V, 800V and 1000V) to vary the energy in the plasma discharge. One sample was produced from a N2:CH4:C2H2 (94:5:5:0.5) gas mixture, with a high voltage of 1000 V. The fifth sample was produced in an Ar:CH4 (95:5) gas mixture with a high voltage of 1000 V to produce a nitrogen-free hydrocarbon sample. The optical constants, n and k, of these five samples were determined using spectral reflectance measurements. They appear to be positively correlated with the nitrogen content in the solid sample, i.e., a sample with larger nitrogen content exhibits higher n and k values. We have used these refractive indices as input parameters in a radiative transfer model to analyze Cassini Visible Infrared Mapping Spectrometer (VIMS) observations of Titan’s atmosphere. The results show that using the tholin samples with higher n and k values (higher nitrogen content) provides a better fit to the observational data than using the samples with lower n and k values (lower nitrogen content). The Titan tholins with higher nitrogen content therefore appear to be more representative of the Titan aerosols observed by VIMS.

Titan Aerosol Analogs↗

Clementine Engineering Experiments Program.

Spacecraft must survive and operate reliably in the space environment for long periods of time. Radiation, temperature variations, spacecraft charging, surface contamination, and micrometeoroids/space debris all present environmental challenges to spacecraft missions. The environmental issues associated with these effects require in-situ space experiments to properly quantify the environment and its effects. To obtain data on specific microelectronic and sensor systems in the space environment, several engineering experiments were developed for the Clementine spacecraft and the Clementine lunar transfer booster or Interstage Adapter Satellite (ISAS). These platforms allowed testing of advanced spacecraft microelectronic and sensor devices in a lunar transfer orbit that intersects Earth's radiation belts and debris environment and in interplanetary space where direct exposure to solar flares, Galactic Cosmic Rays, and micrometeoroids was possible. A suite of experiments was developed by the Naval Research Laboratory (NRL), the Jet Propulsion Laboratory (JPL), NASA Langley Research Center (LaRC), the Aerospace Corporation, and NASA Goddard Space Flight Center (GSFC) to investigate in detail specific radiation and environmental reliability issues. This paper presents an introduction to the issues being investigated, the instruments provided for the mission, and the rationale for the engineering program.

Spacecraft↗

Low-Temperature Production of Cosmic Grains Analogs From Gas-Phase Molecular Precursors with the NASA Ames' COSmIC Facility

Complex carbon molecules and ions are ubiquitous in space and form the building blocks of carbonaceous cosmic dust grains, ultimately contributing to the formation of planets. Here, we report the first experimental investigations of the low temperature chemical pathways leading to the production of cosmic grain analogs from gas phase molecular precursors in order to better understand the evolution of cosmic carbon. The experiments were performed using the COsmic SImulation Chamber (COSmIC) to generate and characterize grains formed from gas phase precursors under controlled conditions representative of astrophysical environments [1]. Using COSmIC, it is possible to investigate the evolution of cosmic carbon from the formation of neutral and ionized gas phase hydrocarbons and PAHs [2], to carbon grains [3, 4]. This is achieved by using a discharge nozzle to (1) produce an adiabatic jet expansion and cool down Ar-hydrocarbon/PAH gas mixtures to astrophysically relevant temperature (150 K) before inducing chemistry by generating a plasma discharge in the stream of the expansion. This plasma-induced chemistry results in the formation of complex molecules and solid particles, analogs of cosmic grains. Solid grains are produced in-situ in the plasma expansion, carried by the accelerated gas in the expansion, and collected on substrates placed a few centimeters downstream of the electrodes. The results of a preliminary solid phase ex-situ analysis of cosmic grain analogs produced at low temperature in COSmIC from gas mixtures including molecular precursors of cosmic carbon grains, i.e., such as CH4 and C2H2 found in circumstellar ejecta of late C stars [3] as well as PAHs ubiquitously detected in IR emission bands seen in galactic and extragalactic environments [4] will be discussed. Scanning Electron Microscopy imaging was used to provide insight on the morphology and growth structure of the grains produced in COSmIC, and to investigate how the precursors used to produce the grains affect these parameters [3]. Laser desorption mass spectrometry was used to identify the molecules making up the main structures within the condensed grains [4]. NIR to FIR optical properties are characterized to provide critical information (functional groups, optical constants) to the scientific community, for use in radiative transfer models in particular, and to help decipher and enhance the return data from space observations.

F. Salama↗

Low Temperature Formation of Carbonaceous Grains from Hydrocarbons and PAHs with the COSmIC Facility

Complex carbon molecules and ions are ubiquitous in space and form the building blocks of the carbonaceous components of cosmic dust grains, ultimately contributing to the formation of planets. We report experimental investigations of the low temperature chemical pathways leading to the formation of cosmic grain analogs from gas phase molecular precursors to better understand the evolution of cosmic carbon. The study of the formation of dust is essential to understand and to quantify the budget of extraterrestrial organic molecules. Although dust plays an important role in the evolution of interstellar chemistry and in the formation of organic molecules, little is known on the formation and destruction processes of carbonaceous dust. The experiments were performed using the Cosmic Simulation Chamber (COSmIC) to generate and characterize solid grains formed from gas phase precursors under controlled conditions representative of astrophysical environments [1]. Using COSmIC, it is possible to investigate the evolution of cosmic carbon from the formation of neutral and ionized hydrocarbons and PAHs in the gas phase [2], to solid carbon grains [3, 4, 5]. This is achieved by using a pulsed slit discharge nozzle to produce an adiabatic jet expansion and cool down Ar-hydrocarbon and PAH gas mixtures to astrophysically relevant temperature before inducing chemistry by generating a plasma discharge in the stream of the expansion. This plasma induced chemistry results in the formation of complex molecules and solid particles, analogs of cosmic grains in situ in the plasma expansion (i.e., without wall effects) that are carried by the accelerated gas in the expansion, and collected on substrates placed a few centimeters downstream of the electrodes. The results of a preliminary solid phase ex-situ analysis of cosmic grain analogs produced from a series of gas mixtures including hydrocarbons such as CH4 and C2H2 [3] and PAHs [4, 5] found in circumstellar ejecta of late C stars will be discussed. SEM imaging was used to provide insight on the impact of the precursors on the morphology and growth structure of the grains produced [3]. Laser desorption mass spectrometry was used to identify the molecules making up the main structures within the condensed grains [4] while X-ray irradiation and X-ray photoemission spectroscopy were used to investigate the impact the impact of stellar X-rays on cosmic dust.

Carbonaceous Grains↗

NASA Ames' COSmIC Laboratory Astrophysics Facility: Recent Results and Progress

The COSmIC facility was developed at NASA Ames to study interstellar, circumstellar and planetary analogs in the laboratory]. COSmIC stands for "Cosmic Simulation Chamber" and is dedicated to the study of neutral and ionized molecules and nanoparticles under the low temperature and high vacuum conditions that are required to simulate space environments. COSmIC integrates a variety of instruments that allow generating; processing and monitoring simulated space conditions in the laboratory. It is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a plasma in a free supersonic jet expansion coupled to high-sensitivity, complementary in situ diagnostic tools, used for the detection and characterization of the species present in the expansion: a Cavity Ring Down Spectroscopy (CRDS) and fluorescence spectroscopy systems for photonic detection, and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS) for mass detection. Recent advances achieved in laboratory astrophysics using COSmIC will be presented, in particular in the domain of the diffuse interstellar bands (DIBs) and the monitoring, in the laboratory, of the formation of dust grains and aerosols from their gasphase molecular precursors in environments as varied as circumstellar outflows and planetary atmospheres. Plans for future laboratory experiments on cosmic molecules and grains in the growing field of laboratory astrophysics (NIR-MIR CRDS, Laser Induced Fluorescence spectra of cosmic molecule analogs and the laser induced incandescence spectra of cosmic grain analogs) will also be addressed as well as the implications of the on-going studies for astronomy.

Laboratory Astrophysics↗

The Chemical Evolution of Cosmic Carbon: Laboratory Studies with the COSmIC Facility

Cosmic dust plays an essential role in our understanding of the chemical and physical evolution of the universe. Our understanding of cosmic dust relies on a combination of astronomical observations (either remote or on extraterrestrial dust samples), astrophysical modeling and laboratory studies of realistic analogs of cosmic dust grains. The COSmIC facility was developed at NASA Ames to study the evolution of cosmic carbon from circumstellar outflows to interstellar clouds to planetary atmospheres in the laboratory [1]. COSmIC stands for “Cosmic Simulation Chamber” and is dedicated to the study of neutral and ionized molecules and grain particles under the low temperature and density conditions that are required to simulate space environments. COSmIC integrates a variety of instruments that allow generating, processing, and monitoring simulated space conditions in the laboratory. It is composed of a Pulsed Discharge Nozzle (PDN) expansion that generates a plasma in a free supersonic jet expansion, coupled to high-sensitivity, complementary in situ diagnostic tools used for the detection and characterization of the species present in the expansion: Cavity Ring Down Spectroscopy (CRDS) and fluorescence spectroscopy systems for photonic detection and an orthogonal Reflectron Time-Of-Flight Mass Spectrometer (oReTOF-MS) for mass detection. Recent advances achieved in laboratory astrophysics using COSmIC’s laboratory data in synergy with observational data will be presented. These results include the formation of dust grains and aerosols from gas-phase molecular precursors in environments as varied as circumstellar outflows of late AGB stars [2] and planetary atmospheres [3] and the evolution of our understanding of the diffuse interstellar bands (DIBs) with applications to the ESO Diffuse Interstellar Bands Large Exploration Survey (EDIBLES [4, 5]). Plans for future laboratory developments and techniques to study the evolution of cosmic carbon molecules and grains (including NIR-MIR CRDS, laser induced fluorescence (LIF) and incandescence (LII)) will also be addressed as well as their astronomical applications.

Salama, F.↗

An experimental measurement of galactic cosmic radiation dose in conventional aircraft between San Francisco and London compared to theoretical values for conventional and supersonic aircraft

These direct measurements are in fair agreement with computations made using a program which considers both basic cosmic ray atmospheric physics and the focusing effect of the earth's magnetic field. These measurements also agree with those made at supersonic jet aircraft altitudes in Rb-57 aircraft. It is concluded that experiments and theory show that the doses received at conventional jet aircraft altitudes are slightly higher than those encountered in supersonic flights at much higher altitudes.

Wallace, R.↗

Emulsion chamber observations and interpretation (HE 3)

Experimental results from Emulsion Chamber (EC) experiments at mountain altitudes or at higher levels using flying carriers are examined. The physical interest in this field is concentrated on the strong interaction at the very high energy region exceeding the accelerator energy, also on the primary cosmic ray intensity and its chemical composition. Those experiments which observed cosmic ray secondaries gave information on high energy interaction characteristics through the analyses of secondary spectra, gamma-hadron families and C-jets (direct observation of the particle production occuring at the carbon target). Problems of scaling violation in fragmentation region, interaction cross section, transverse momentum of produced secondaries, and some peculiar features of exotic events are discussed.

Shibata, M.↗

Interstellar and Planetary Analogs in the Laboratory

We present and discuss the unique capabilities of the laboratory facility, COSmIC, that was developed at NASA Ames to investigate the interaction of ionizing radiation (UV, charged particles) with molecular species (neutral molecules, radicals and ions) and carbonaceous grains in the Solar System and in the Interstellar Medium (ISM). COSmIC stands for Cosmic Simulation Chamber, a laboratory chamber where interstellar and planetary analogs are generated, processed and analyzed. It is composed of a pulsed discharge nozzle (PDN) expansion that generates a free jet supersonic expansion in a plasma cavity coupled to two ultrahigh-sensitivity, complementary in situ diagnostics: a cavity ring down spectroscopy (CRDS) system for photonic detection and a Reflectron time-of-flight mass spectrometer (ReTOF-MS) for mass detection. This setup allows the study of molecules, ions and solids under the low temperature and high vacuum conditions that are required to simulate some interstellar, circumstellar and planetary physical environments providing new fundamental insights on the molecular level into the processes that are critical to the chemistry in the ISM, circumstellar and planet forming regions, and on icy objects in the Solar System. Recent laboratory results that were obtained using COSmIC will be discussed, in particular the progress that have been achieved in monitoring in the laboratory the formation of solid particles from their gas-phase molecular precursors in environments as varied as circumstellar outflow and planetary atmospheres.

Salama, Farid↗