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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Simultaneous 100-kHz Acetone Planar Laser-Induced Fluorescence and OH* Chemiluminescence in a Linear Non-Premixed Detonation Channel

Reactant mixing and combustion are investigated in an optically accessible, self-excited linear detonation combustor. The mixing field is captured using 100 kHz planar laser-induced fluorescence (PLIF) imaging of acetone as a tracer in the fuel supply, while 100 kHz chemiluminescence imaging of excited-state hydroxyl (OH*) radicals simultaneously resolves the evolution of the detonation wave. Time sequences are acquired over multiple detonation cycles in each test, with acetone-PLIF images collected along multiple orthogonal planes to reveal the complex three-dimensional topography of the fuel distribution. The instantaneous and phase averaged acetone-PLIF images enable measurement of key fuel injection characteristics, such as the injector recovery time, fuel jet velocity, and refill height for a range of operating conditions. Instantaneous and phase-averaged measurements of acetone-PLIF with the time-coincident OH* chemiluminescence images also reveal a number key features, such as fuel stratification and weak detonation in the injector near field, incomplete combustion and deflagration behind the detonation wave, vitiation and deflagration of reactants ahead of the detonation wave, and fuel and oxidizer recovery time mismatch leading to combustion inefficiency. These measurements significantly enhance the ability to obtain detailed information on the intracycle and intercycle spatiotemporal evolution of the reactant refill process and its coupled effects on the detonation wave structure and propagation.

Propulsion↗

NASA IKONOS Multispectral Radiometric Calibration and 3-Year Temporal Stability Assessment

Radiometric calibration of commercial imaging satellite products is required to ensure that science and application communities can place confidence in the imagery they use and can fully understand its properties. Inaccurate radiometric calibrations can lead to erroneous decisions and invalid conclusions and can limit intercomparisons with other system. In addition, the user community has little or no insight into the design and operation of commercial sensors or into the methods involved in generating commercial products. To address this calibration need, the NASA Stennis Space Center (SSC) Earth Science Applications (ESA) Directorate established a commercial satellite imaging radiometric calibration team consisting of three independent groups: NASA, SSC,ESA, the University of Arizona Remote Sensing Group, and South Dacota State University. Each group determined the absolute radiometric calibration coefficients of the Space Imaging IKONOS 4-band, 4 m multispectral product covering the visible through near-infrared spectral region. For a three year period beginning in 2000, each team employed some variant of a reflectance-based vicarious calibration approach, requiring ground-based measurements coincident with IKONOS image acquisitions and radiative transfer calculations. Several study sites throughout the United States were employed that covered nearly the entire dynamic range of the IKONOS sensor. IKONOS at-sensor radiance values were compared to those estimated by each independent group to determine the IKONOS sensor's radiometric accuracy and stability. Over 10 individual vicariously determined at-sensor radiance estimates were used each year. When combined, these estimates provided a high-precision radiometric gain calibration coefficient. No significant calibration offset was observed. The results of this evaluation provide the scientific community with an independent assessment of the IKONOS sensor's absolute calibration and temporal stability over the 3-year period. While the techniques and method described in this paper reflect those developed at the NASA SSC, the results of the entire team are included.

Pagnutti, Mary↗

Passive Microwave Spectral Imaging of Amospheric Structure

The primary objective of this research was to improve the scientific foundation necessary to full realization of the meteorological potential of the NOAA Advanced Microwave Sounding Unit (AMSU) recently first launched on the NOAA-15 satellite in May, 1998. These advances were made in four main areas: (1) improvements, based on aircraft observations, in the atmospheric transmittance expressions used for interpreting AMSU and similar data; (2) development of neural network retrieval methods for cloud top altitude estimates of approximately 1-km accuracy under cirrus shields--the altitude is that of the larger ice particles aloft, which is related to precipitation rate; (3) analysis of early AMSU flight data with respect to its precipitation sensitivity and fine-scale thermal structure; and (4) improvements to the 54-GHz and 118-GHz MTS aircraft imaging spectrometer now operating on the NASA ER-2 aircraft. More specifically, the oxygen transmittance expressions near 118 GHz were in better agreement with aircraft data when the temperature dependence exponent of the 118.75-GHz linewidth was increased from the MPM92 value (Liebe et al., 1992) of 0.8 to 0.97+/-0.03. In contrast, the observations 52.5-55.8 GHz were consistent with the MPM92 model. Neural networks trained on comparisons of 118-GHz spectral data and coincident stereoscopic video images of convective cells observed from 20-km altitude yielded agreement in their peak altitudes within as little as 1.36 km rms, much of which is stereoscopic error. Imagery using these methods produced useful characterizations for Cyclone Oliver in 1993 and other storms (Schwartz et al., 1996; Spina et al., 1998). Similar neural network techniques yielded simulated rms errors in relative humidity retrievals of 6-14 percent over ocean and 6-15 percent over land at pressure levels from 1013 to 131 mbar (Cabrera-Mercader and Staelin, 1995).

Staelin, David H.↗

Radiometric Characterization of IKONOS Multispectral Imagery

A radiometric characterization of Space Imaging's IKONOS 4-m multispectral imagery has been performed by a NASA funded team from the John C. Stennis Space Center (SSC), the University of Arizona Remote Sensing Group (UARSG), and South Dakota State University (SDSU). Both intrinsic radiometry and the effects of Space Imaging processing on radiometry were investigated. Relative radiometry was examined with uniform Antarctic and Saharan sites. Absolute radiometric calibration was performed using reflectance-based vicarious calibration methods on several uniform sites imaged by IKONOS, coincident with ground-based surface and atmospheric measurements. Ground-based data and the IKONOS spectral response function served as input to radiative transfer codes to generate a Top-of-Atmosphere radiance estimate. Calibration coefficients derived from each vicarious calibration were combined to generate an IKONOS radiometric gain coefficient for each multispectral band assuming a linear response over the full dynamic range of the instrument. These calibration coefficients were made available to Space Imaging, which subsequently adopted them by updating its initial set of calibration coefficients. IKONOS imagery procured through the NASA Scientific Data Purchase program is processed with or without a Modulation Transfer Function Compensation kernel. The radiometric effects of this kernel on various scene types was also investigated. All imagery characterized was procured through the NASA Scientific Data Purchase program.

Pagnutti, Mary↗

JACIE Radiometric Assessment of QuickBird Multispectral Imagery

Radiometric calibration of commercial imaging satellite products is required to ensure that science and application communities can place confidence in the imagery they use and can fully understand its properties. Inaccurate radiometric calibrations can lead to erroneous decisions and invalid conclusions and can limit intercomparisons with other systems. To address this calibration need, the NASA Stennis Space Center (SSC) Earth Science Applications (ESA) directorate,through the Joint Agency for Commercial Imagery Evaluation (JACIE) framework, established a commercial imaging satellite radiometric calibration team consisting of two groups: 1) NASA SSC ESA, supported by South Dakota State University, and 2) the University of Arizona Remote Sensing Group. The two groups determined the absolute radiometric calibration coefficients of the Digital Globe 4-band, 2.4-m QuickBird multispectral product covering the visible through near-infrared spectral region. For a 2-year period beginning in 2002, both groups employed some variant of a reflectance-based vicarious calibration approach, which required ground-based measurements coincident with QuickBird image acquisitions and radiative transfer calculations. The groups chose several study sites throughout the United States that covered nearly the entire dynamic range of the QuickBird sensor. QuickBird at-sensor radiance values were compared with those estimated by the two independent groups to determine the QuickBird sensor's radiometric accuracy. Approximately 20 at-sensor radiance estimates were vicariously determined each year. The estimates were combined to provide a high-precision radiometric gain calibration coefficient. The results of this evaluation provide the user community with an independent assessment of the QuickBird sensor's absolute calibration and stability over the 2-year period. While the techniques and method described reflect those developed at the NASA SSC, the results of both JACIE team groups are included in this paper.

Pagnutti, Mary↗

Improved field assessments of chemicals and explosives using high-resolution gamma-ray spectroscopy with a tagged neutron interrogation system

A fi eld-portable tagged neutron interrogation system is being developed for detection of explosives and chemical warfare agents by prompt gamma-ray neutron activation analysis. The system combines an associated particle imaging deuterium-tritium neutron generator with a high-purity germanium gamma-ray detector. Fine spatial resolution neutron and alpha detectors enable precise mapping of characteristic gamma-ray emission distributions onto high-clarity neutron radiographic images. A narrow coincidence gate associated with each tagged neutron ensures a large signal-to-background ratio, thus signifi cantly improving sensitivity to the chemical compositions of the items being assessed. Recent experimental results recorded from test objects involving mock explosives and other chemicals are presented.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

Two complimentary methods for aligning linear arrays

Two approaches are presented for implementing a simple method for aligning the object and image planes of linear arrays of elemental detectors. Both variants begin by firing a laser beam into cubic beamsplitters which change the direction of the resulting parallel beams to one perpendicular to the array. A neutral density filter is located along the beam path and an optical microscope is located beyond the exit plane of the beamsplitters. In the first variant, the beam is tuned to the spectral sensitivity of the elements. In the second version, a lens and a microscope are situated outside the exit plane of the beamsplitters, and spectral tuning is unnecessary. Subsequent rotations of the array are shown to reveal the coincidence or lack of coincidence of the image plane and the linear array.

Finkel, Mitchell W.↗

Centroid Detector Assembly for the AXAF-I Alignment Test System

The High Resolution Mirror Assembly (HRMA) of the Advanced X-ray Astrophysics Facility (imaging) (AXAF-I) consists of four nested paraboloids and four nested hyperboloids, all of meter-class size, and all of which are to be assembled and aligned in a special 15 meter tower at Eastman Kodak Company in Rochester, NY. The goals of the alignment are (1) to make the images of the four telescopes coincident; (2) to remove coma from each image individually; and (3) to control and determine the final position of the composite focus. This will be accomplished by the HRMA Aligment Test System (HATS) which is essentially a scanning Hartmann test system. The scanning laser source and the focal plane of the HATS are part of the Centroid Detector Assembly (CDA) which also includes processing electronics and software. In this paper we discuss the design and the measured performance of the CDA.

Glenn, Paul↗

Multiangle Imaging Spectroradiometer (MISR) Global Aerosol Optical Depth Validation Based on 2 Years of Coincident Aerosol Robotic Network (AERONET) Observations

Performance of the Multiangle Imaging Spectroradiometer (MISR) early postlaunch aerosol optical thickness (AOT) retrieval algorithm is assessed quantitatively over land and ocean by comparison with a 2-year measurement record of globally distributed AERONET Sun photometers. There are sufficient coincident observations to stratify the data set by season and expected aerosol type. In addition to reporting uncertainty envelopes, we identify trends and outliers, and investigate their likely causes, with the aim of refining algorithm performance. Overall, about 2/3 of the MISR-retrieved AOT values fall within [0.05 or 20% x AOT] of Aerosol Robotic Network (AERONET). More than a third are within [0.03 or 10% x AOT]. Correlation coefficients are highest for maritime stations (approx.0.9), and lowest for dusty sites (more than approx.0.7). Retrieved spectral slopes closely match Sun photometer values for Biomass burning and continental aerosol types. Detailed comparisons suggest that adding to the algorithm climatology more absorbing spherical particles, more realistic dust analogs, and a richer selection of multimodal aerosol mixtures would reduce the remaining discrepancies for MISR retrievals over land; in addition, refining instrument low-light-level calibration could reduce or eliminate a small but systematic offset in maritime AOT values. On the basis of cases for which current particle models are representative, a second-generation MISR aerosol retrieval algorithm incorporating these improvements could provide AOT accuracy unprecedented for a spaceborne technique.

global meaurement↗

Improved field assessments of chemicals and explosives using high-resolution gamma-ray spectroscopy with a tagged neutron interrogation system

A fi eld-portable tagged neutron interrogation system is being developed for detection of explosives and chemical warfare agents by prompt gamma-ray neutron activation analysis. The system combines an associated particle imaging deuterium-tritium neutron generator with a high-purity germanium gamma-ray detector. Fine spatial resolution neutron and alpha detectors enable precise mapping of characteristic gamma-ray emission distributions onto high-clarity neutron radiographic images. A narrow coincidence gate associated with each tagged neutron ensures a large signal-to-background ratio, thus signifi cantly improving sensitivity to the chemical compositions of the items being assessed. Recent experimental results recorded from test objects involving mock explosives and other chemicals are presented.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

It’s Not What You Take Up, It’s What You Keep: How Discoveries from Diverse Disciplines Directed the Development of the FDG PET/CT Scan

Although imaging glucose metabolism with positron emission tomography combined with X-ray CT (FDG-PET/CT) has become a standard diagnostic modality for the discovery and surveillance of malignant tumors and inflammatory processes, its origins extend back to more than a century of notable discoveries in the fields of inorganic and organic chemistry, nuclear physics, mathematics, biochemistry, solute transport physiology, metabolism, and imaging, accomplished by pioneering and driven investigators, of whom at least ten were recipients of the Nobel Prize. These tangled and diverse roots eventually coalesced into the FDG-PET/CT method, that through its many favorable characteristics inherent in the isotope used ( 18 F), the accurate imaging derived from coincidence detection of positron annihilation radiation combined with computed tomography, and the metabolic trapping of 2-deoxy-2-[ 18 F] fluoro-d-glucose (FDG) in tissues, provides safety, sensitivity, and specificity for tumor and inflammation detection. Here, the authors hope that this article will increase the appreciation among its readers of the insight, creativity, persistence, and drive of the many investigators who made this technique possible. This article is followed by a review of the many applications of FDG-PET/CT to the gastrointestinal tract and hepatobiliary system (Mandelkern in Dig Dis Sci 2022)

2-DG↗

Initial-site characterization of hydrogen migration following strong-field double-ionization of ethanol

Abstract An essential problem in photochemistry is understanding the coupling of electronic and nuclear dynamics in molecules, which manifests in processes such as hydrogen migration. Measurements of hydrogen migration in molecules that have more than two equivalent hydrogen sites, however, produce data that is difficult to compare with calculations because the initial hydrogen site is unknown. We demonstrate that coincidence ion-imaging measurements of a few deuterium-tagged isotopologues of ethanol can determine the contribution of each initial-site composition to hydrogen-rich fragments following strong-field double ionization. These site-specific probabilities produce benchmarks for calculations and answer outstanding questions about photofragmentation of ethanol dications; e.g., establishing that the central two hydrogen atoms are 15 times more likely to abstract the hydroxyl proton than a methyl-group proton to form H $${}_{3}^{+}$$ 3 + and that hydrogen scrambling, involving the exchange of hydrogen between different sites, is important in H 2 O + formation. The technique extends to dynamic variables and could, in principle, be applied to larger non-cyclic hydrocarbons.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Hydrogen migration in inner-shell ionized halogenated cyclic hydrocarbons

Abstract We have studied the fragmentation of the brominated cyclic hydrocarbons bromocyclo-propane, bromocyclo-butane, and bromocyclo-pentane upon Br(3 d ) and C(1 s ) inner-shell ionization using coincidence ion momentum imaging. We observe a substantial yield of CH 3 + fragments, whose formation requires intramolecular hydrogen (or proton) migration, that increases with molecular size, which contrasts with prior observations of hydrogen migration in linear hydrocarbon molecules. Furthermore, by inspecting the fragment ion momentum correlations of three-body fragmentation channels, we conclude that CH x + fragments (with x = 0, …, 3) with an increasing number of hydrogens are more likely to be produced via sequential fragmentation pathways. Overall trends in the molecular-size-dependence of the experimentally observed kinetic energy releases and fragment kinetic energies are explained with the help of classical Coulomb explosion simulations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Improved field assessments of chemicals and explosives using high-resolution gamma-ray spectroscopy with a tagged neutron interrogation system

A field-portable tagged neutron interrogation system is being developed for detection of explosives and chemical warfare agents by prompt γ-ray neutron activation analysis. The system combines an associated particle imaging deuterium-tritium neutron generator with a high-purity germanium γ-ray detector. Fine spatial resolution neutron and α detectors enable precise mapping of characteristic γ-ray emission distributions onto high-clarity neutron radiographic images. A narrow coincidence gate associated with each tagged neutron ensures a large signal-to-background ratio, thus significantly improving sensitivity to the chemical compositions of the items being assessed. Recent experimental results recorded from test objects involving mock explosives and other chemicals are presented.

Bucher, Brian [Idaho National Laboratory (INL)]↗

Radar detection of surface oil accumulations

The United States Coast Guard is developing AIREYE, an all weather, day/night airborne surveillance system, for installation aboard future medium range surveillance aircraft. As part of this program, a series of controlled tests were conducted off southern California to evaluate the oil slick detection capabilities of two Motorola developed, side looking radars. The systems, a real aperture AN/APS-94D and a synthetic aperture coherent on receive (COR) were flown over the Santa Barbara Channel on May 19, 1976. Targets imaged during the coincident overflights included natural oil seepage, simulated oil spills, oil production platforms, piers, mooring buoys, commercial boats and barges at other targets. Based on an analysis of imagery from the coincident radar runs, COR provides better detection of natural and man made oil slicks, whereas the AN/APS-94D consistently exhibited higher surface target detection results. This and other tests have shown that active microwave systems have considerable potential for aiding in the detection and analysis of surface oil accumulations.

Estes, J. E.↗

Relations between water vapor imagery, vertical motion, and tropopause folds

The atmospheric processes associated with the movement and development of a pronounced dry feature in a series of 6.7-micron images from March, 1982 are examined. It is found that the dark, warm image bands are due to subsidence. The advective band is produced by descent associated with the entrance region of a polar jet streak. The evolution of the development image component is coincident with a tropopause fold and associated intrusion of dry stratospheric air into the middle troposphere. The increasing brightness temperatures are simulated by altering upwind soundings based on trajectory-determined vertical motion and using both the original and altered profiles as input to a radiative transfer model.

Moore, Steven R.↗

Radiometric Calibration of the AWiFS Sensor and a Cross-calibration Enhanced Vicarious Calibration Technique

Using vicarious calibration validation of moderate resolution sensors such as AWiFS is complicated by requiring more land area to ensure proper registration and sufficient pixel numbers. A trial AWiFS calibration was performed on a grass site that consisted of two dramatically different grass heights. Ground truth data was collected over relatively small areas representing only a few pixels. The radiometric gain results for each of these areas will be reported. To enhance this analysis, since a near coincidence high resolution image was collected, the high resolution data was effectively resized to produce pixels comparable to AWiFS and the atmospheric model was used to produce a top of canopy radiance map. Multiple uniform vegetated areas of several radiances were then identified and subsequently propagated to the top of atmosphere viewpoint of the moderate resolution (AWiFS) satellite. The radiometric gain was then calculated based on the vendor high resolution satellite gains (for the 3 bands with comparable wavelengths). Band-to-band conversion was performed assuming a hyperspectral reflectance based on the standard vegetated site. The initial comparison produces AWiFS radiometric gain values that agree to better than 10% of the values measured using the standard vicarious gain technique.

Aaron, David↗