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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

Evaluation of Selected Chemical Processes for Production of Low-cost Silicon, Phase 3

The construction and operation of an experimental process system development unit (EPSDU) for the production of granular semiconductor grade silicon by the zinc vapor reduction of silicon tetrachloride in a fluidized bed of seed particles is presented. The construction of the process development unit (PDU) is reported. The PDU consists of four critical units of the EPSDU: the fluidized bed reactor, the reactor by product condenser, the zinc vaporizer, and the electrolytic cell. An experimental wetted wall condenser and its operation are described. Procedures are established for safe handling of SiCl4 leaks and spills from the EPSDU and PDU.

Blocher, J. M., Jr.↗
NASA NTRS1981

Evaluation of selected chemical processes for production of low-cost silicon, phase 3

A Process Development Unit (PDU), which consisted of the four major units of the process, was designed, installed, and experimentally operated. The PDU was sized to 50MT/Yr. The deposition took place in a fluidized bed reactor. As a consequences of the experiments, improvements in the design an operation of these units were undertaken and their experimental limitations were partially established. A parallel program of experimental work demonstrated that Zinc can be vaporized for introduction into the fluidized bed reactor, by direct induction-coupled r.f. energy. Residual zinc in the product can be removed by heat treatment below the melting point of silicon. Current efficiencies of 94 percent and above, and power efficiencies around 40 percent are achievable in the laboratory-scale electrolysis of ZnCl2.

Blocher, J. M., Jr.↗
NASA NTRS1982

Simulation studies of the physical and chemical processes occurring in the stratospheric clouds of the Mount St. Helens eruptions of May and June 1980

The large and diverse set of observational data collected in the high-altitude clouds of May 18, May 25, and June 13, 1980 was organized and analyzed for trends which reveal the processes at work. The data were used to guide and constrain model simulations of the volcanic eruptions. A comprehensive one-dimensional model of stratospheric sulfate aerosols, sulfur precursor gases, and volcanic ash and dust particles is utilized which accounts for homogeneous and heterogeneous chemistry in the clouds, aerosol nucleation and growth, and cloud expansion. Computational results are given for the time histories of the gaseous species concentrations, sulfate aerosol size dispersions, and ash burdens in the eruption clouds. The long-term buildup of stratospheric aerosols in the Northern Hemisphere and the persistent effects of injected chlorine and water vapor on ozone are discussed. It is concluded that SO2, water vapor, and ash are the most important substances injected by the volcano into the stratosphere, with respect to both the widespread effects on composition and the impact on climate. It is found that the volcano probably had little influence on the climate ( 0.05 K global surface cooling) or on stratospheric ozone ( 0.2 percent maximum hemispherical reduction).

Turco, R. P.↗
NASA NTRS1983

Coupling of Transport and Chemical Processes in Catalytic Combustion

Catalytic combustors have demonstrated the ability to operate efficiently over a much wider range of fuel air ratios than are imposed by the flammability limits of conventional combustors. Extensive commercial use however needs the following: (1) the design of a catalyst with low ignition temperature and high temperature stability, (2) reducing fatigue due to thermal stresses during transient operation, and (3) the development of mathematical models that can be used as design optimization tools to isolate promising operating ranges for the numerous operating parameters. The current program of research involves the development of a two dimensional transient catalytic combustion model and the development of a new catalyst with low temperature light-off and high temperature stablity characteristics.

Bracco, F. V.↗
NASA NTRS1983

The 1980 eruptions of Mount St. Helens - Physical and chemical processes in the stratospheric clouds

The large and diverse set of observational data collected in the high-altitude plumes of the May 18, May 25, and June 13, 1980 eruptions is organized and analyzed with a view to discerning the processes at work. The data serve to guide and constrain detailed model simulations of the volcanic clouds. For this purpose, use is made of a comprehensive one-dimensional model of stratospheric sulfate aerosols, sulfur precursor gases, and volcanic ash and dust. The model takes into account gas-phase and condensed-phase (heterogeneous) chemistry in the clouds, aerosol nucleation and growth, and cloud expansion. Computational results are presented for the time histories of the gaseous species concentrations, aerosol size distributions, and ash burdens of the eruption clouds. Also investigated are the long-term buildup of stratospheric aerosols in the Northern Hemisphere and the persistent effects of injected chlorine and water vapor on stratospheric ozone. It is concluded that SO2, water vapor, and ash were probably the most important substances injected into the stratosphere by the Mount St. Helens volcano, both with respect to their widespread effects on composition and their effect on climate.

Turco, R. P.↗
NASA NTRS1984

Analysis of physical-chemical processes governing SSME internal fluid flows

The efforts to adapt CHAM's computational fluid dynamics code, PHOENICS, to the analysis of flow within the high pressure fuel turbopump (HPFTP) aft-platform seal cavity of the SSME are summarized. In particular, the special purpose PHOENICS satellite and ground station specifically formulated for this application are listed and described, and the preliminary results of the first part two-dimensional analyses are presented and discussed. Planned three-dimensional analyses are also briefly outlined. To further understand the mixing and combustion processes in the SSME fuelside preburners, a single oxygen-hydrogen jet element was investigated.

Singhal, A. K.↗
NASA NTRS1987

Chemical processes in Triton's atmosphere and surface

The Neptune moon Triton may have an appreciable atmosphere; the preliminary calculations of Delitsky (1983) have suggested that there should be a significant resultant chemistry in a possible N2 ocean with dissolved CH4, given charged-particle radiolysis of gaseous mixtures and gamma radiolysis of N2-CH4 solutions. The latter will yield substantial quantities of organic products which will be partially soluble in any N2-CH4 liquid present. Attention is presently given to the energy sources available for Triton, in order to estimate rates of synthesis and ascertain the possible history of such simple and complex organic products on Triton's surface.

Delitsky, M. L.↗
NASA NTRS1989

The roles of dynamical and chemical processes in determining the stratospheric concentration of ozone in one-dimensional and two-dimensional models

The two-dimensional model of Ko et al. (1985) was used to calculate the stratospheric concentrations of ozone, to determine the principal modes of balance for different stratospheric regions. The results of this analysis show that the local concentration of ozone in different regions of stratosphere is determined by balances between different mechanisms. In the upper stratosphere, the ozone concentration is dominated by photochemical processes, whereas in the mid-lower stratosphere, the bulk of ozone appears to be controlled by an interaction between the transport and the photochemical processes. The results point to the limitations of one-dimensional models, which fail to properly account for the effect of transport in the lower stratosphere.

Ko, Malcolm K. W.↗
NASA NTRS1994

Evolution of chemically processed air parcels in the lower stratosphere

Aircraft, ground-based, and satellite measurements indicate large concentrations of ClO in the lower stratosphere in and near the polar vortex. The amount of local ozone depletion caused by these large ClO concentrations will depend on the relative rates of ozone loss and ClO recovery. ClO recovery occurs when NO(x), from HNO3 photolysis, reacts with ClO to form ClONO2. We show that air parcels with large amounts of ClO will experience a subsequent ozone depletion that depends on the solar zenith angle. When the solar zenith angle is large in the middle of winter, the recovery of the ClO concentration in the parcel is slow relative to ozone depletion. In the spring, when the solar zenith angle is smaller, the ClO recovery is much faster. After ClO recovery, the chlorine chemistry has not returned to normal. The ClO has been converted to ClONO2. ClO production from further encounters with PSCs will be limited by the heterogeneous reaction of ClONO2 with water. Large ozone depletions, of the type seen in the Antarctic, occur only if there is significant irreversible denitrification in the air parcel.

Stolarski, Richard S.↗
NASA NTRS2009

Chemical Processing of Non-Crop Plants for Jet Fuel Blends Production

The use of Biofuels has been gaining in popularity over the past few years due to their ability to reduce the dependence on fossil fuels. Biofuels as a renewable energy source can be a viable option for sustaining long-term energy needs if they are managed efficiently. We describe our initial efforts to exploit algae, halophytes and other non-crop plants to produce synthetics for fuel blends that can potentially be used as fuels for aviation and non-aerospace applications. Our efforts have been dedicated to crafting efficient extraction and refining processes in order to extract constituents from the plant materials with the ultimate goal of determining the feasibility of producing biomass-based jet fuel from the refined extract. Two extraction methods have been developed based on communition processes, and liquid-solid extraction techniques. Refining procedures such as chlorophyll removal and transesterification of triglycerides have been performed. Gas chromatography in tandem with mass spectroscopy is currently being utilized in order to qualitatively determine the individual components of the refined extract. We also briefly discuss and compare alternative methods to extract fuel-blending agents from alternative biofuels sources.

Kulis, M. J.↗
NASA NTRS2011

Experimental Testing and Modeling of a Pneumatic Regolith Delivery System for ISRU

Excavating and transporting planetary regolith are examples of surface activities that may occur during a future space exploration mission to a planetary body. Regolith, whether it is collected on the Moon, Mars or even an asteroid, consists of granular minerals, some of which have been identified to be viable resources that can be mined and processed chemically to extract useful by-products, such as oxygen, water, and various metals and metal alloys. Even the depleted "waste" material from such chemical processes may be utilized later in the construction of landing pads and protective structures at the site of a planetary base. One reason for excavating and conveying planetary regolith is to deliver raw regolith material to in-situ resource utilization (ISRU) systems. The goal of ISRU is to provide expendable supplies and materials at the planetary destination, if possible. An in-situ capability of producing mission-critical substances such as oxygen will help to extend the mission and its success, and will greatly lower the overall cost of a mission by either eliminating, or significantly reducing, the need to transport the same expendable materials from the Earth. In order to support the goals and objectives of present and future ISRU projects, NASA seeks technology advancements in the areas of regolith conveying. Such systems must be effective, efficient and provide reliable performance over long durations while being exposed to the harsh environments found on planetary surfaces. These conditions include contact with very abrasive regolith particulates, exposure to high vacuum or dry (partial) atmospheres, wide variations in temperature, reduced gravity, and exposure to space radiation. Regolith conveying techniques that combine reduced failure modes and low energy consumption with high material transfer rates will provide significant value for future space exploration missions to the surfaces of the moon, Mars and asteroids. Pneumatic regolith conveying has demonstrated itself to be a viable delivery system through testing under terrestrial and reduced gravity conditions in recent years. Modeling and experimental testing have been conducted at NASA Kennedy Space Center to study and advance pneumatic planetary regolith delivery systems in support of NASA's ISRU project. The goal of this work is to use the model to predict solid-gas flow patterns in reduced gravity environments for ISRU inlet gas line allowing the eductor inlet gas flow to vary and depend on the flow pattern developed at the eductor as inferred by the experimental observations.

Santiago-Maldonado, Edgardo↗
NASA NTRS1989

Heterogeneous physicochemistry of the polar ozone hole

Processes occurring in the polar winter stratosphere, which involve polar stratospheric clouds (PSCs), are investigated using observations from the Airborne Antarctic Ozone Experiment. In particular, data on the properties of PSCs and their physical chemistry, the microphysical processes and time constants for cloud processes, the heterogeneous chemical processes and their time constants, and nonlinearities in the long-term ozone trend associated with physical and chemical processes are examined. The chemical reactions leading to the depletion of the inert chlorine reservoir in a presence of type I PSCs are established, and it is shown that type II PSCs contribute to chemical processing that sustains the chemical imbalance of the polar stratosphere. It is shown that, using a simple model, the decadal evolution of the Antarctic ozone hole may be understood through nonlinearities in the heterogeneous chemistry, with possible contributing effects of variations in stratospheric temperatures and water vapor concentrations.

Turco, Richard P.↗
NASA NTRS2004

Chemical models for simulating single-walled nanotube production in arc vaporization and laser ablation processes

Chemical kinetic models for the nucleation and growth of clusters and single-walled carbon nanotube (SWNT) growth are developed for numerical simulations of the production of SWNTs. Two models that involve evaporation and condensation of carbon and metal catalysts, a full model involving all carbon clusters up to C80, and a reduced model are discussed. The full model is based on a fullerene model, but nickel and carbon/nickel cluster reactions are added to form SWNTs from soot and fullerenes. The full model has a large number of species--so large that to incorporate them into a flow field computation for simulating laser ablation and arc processes requires that they be simplified. The model is reduced by defining large clusters that represent many various sized clusters. Comparisons are given between these models for cases that may be applicable to arc and laser ablation production. Solutions to the system of chemical rate equations of these models for a ramped temperature profile show that production of various species, including SWNTs, agree to within about 50% for a fast ramp, and within 10% for a slower temperature decay time.

Nanotubes, Carbon/chemistry↗
NASA NTRS1997

Interstellar and Cometary Dust

'Interstellar dust' forms a continuum of materials with differing properties which I divide into three classes on the basis of observations: (a) diffuse dust, in the low-density interstellar medium; (b) outer-cloud dust, observed in stars close enough to the outer edges of molecular clouds to be observed in the optical and ultraviolet regions of the spectrum, and (c) inner-cloud dust, deep within the cores of molecular clouds, and observed only in the infrared by means of absorption bands of C-H, C=O, 0-H, C(triple bond)N, etc. There is a surprising regularity of the extinction laws between diffuse- and outer-cloud dust. The entire mean extinction law from infrared through the observable ultraviolet spectrum can be characterized by a single parameter. There are real deviations from this mean law, larger than observational uncertainties, but they are much smaller than differences of the mean laws in diffuse- and outer-cloud dust. This fact shows that there are processes which operate over the entire distribution of grain sizes, and which change size distributions extremely efficiently. There is no evidence for mantles on grains in local diffuse and outer-cloud dust. The only published spectra of the star VI Cyg 12, the best candidate for showing mantles, does not show the 3.4 micro-m band which appreciable mantles would produce. Grains are larger in outer-cloud dust than diffuse dust because of coagulation, not accretion of extensive mantles. Core-mantle grains favored by J. M. Greenberg and collaborators, and composite grains of Mathis and Whiffen (1989), are discussed more extensively (naturally, I prefer the latter). The composite grains are fluffy and consist of silicates, amorphous carbon, and some graphite in the same grain. Grains deep within molecular clouds but before any processing within the solar system are presumably formed from the accretion of icy mantles on and within the coagulated outer-cloud grains. They should contain a mineral/carbonaceous matrix, without organic refractory mantles, in between the ices. Unfortunately, they may be significantly processed by chemical processes accompanying the warming (over the 10 K of the dark cloud cores) which occurs in the outer solar system. Evidence of this processing is the chemical anomalies present in interplanetary dust particles collected in the stratosphere, which may be the most primitive materials we have obtained to date. The comet return mission would greatly clarify the situation, and probably provide samples of genuine interstellar grains.

Mathis, John S.↗
NASA NTRS1980

Extraterrestrial materials processing and construction

Three different chemical processing schemes were identified for separating lunar soils into the major oxides and elements. Feedstock production for space industry; an HF acid leach process; electrorefining processes for lunar free metal and metal derived from chemical processing of lunar soils; production and use of silanes and spectrally selective materials; glass, ceramics, and electrochemistry workshops; and an econometric model of bootstrapping space industry are discussed.

Criswell, D. R.↗