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At least 73 records · Page 4

Pentaerythritol structure-directing agents bias aluminum siting in MFI zeolites to increase para -xylene selectivity during toluene methylation

MFI zeolites contain ten-membered ring channels (∼0.55 nm diameter) that intersect to form larger voids (∼0.70 nm diameter). The distribution of framework Al sites dictates the void environments that confine active H + sites. MFI synthesized with pentaerythritol (PET) and Na + as structure-directing agents are interrogated using kinetically controlled toluene methylation rates and xylene isomer selectivities. High para-xylene selectivity and low toluene methylation rates indicate that MFI-PET samples contain H + sites predominantly in smaller channels. As-synthesized samples contain more framework Al than Na + , indicating that some charge compensation is provided by protonated PET-solvent complexes that bias Al siting towards these smaller channels.

36 MATERIALS SCIENCE↗

B-periodic oscillations in the Hall-resistance induced by a dc-current-bias under combined microwave-excitation and dc-current bias in the GaAs/AlGaAs 2D system

We report the observation of dc-current-bias-induced B-periodic Hall resistance oscillations and Hall plateaus in the GaAs/AlGaAs 2D system under combined microwave radiation- and dc bias excitation at liquid helium temperatures. The Hall resistance oscillations and plateaus appear together with concomitant oscillations also in the diagonal magnetoresistance. The periods of Hall and diagonal resistance oscillations are nearly identical, and source power (P) dependent measurements demonstrate sub-linear relationship of the oscillation amplitude with P over the span 0 < P ≤ 20 mW.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Bias in the effective field theory of large scale structures

We study how to describe collapsed objects, such as galaxies, in the context of the Effective Field Theory of Large Scale Structures. The overdensity of galaxies at a given location and time is determined by the initial tidal tensor, velocity gradients and spatial derivatives of the regions of dark matter that, during the evolution of the universe, ended up at that given location. Similarly to what was recently done for dark matter, we show how this Lagrangian space description can be recovered by upgrading simpler Eulerian calculations. We describe the Eulerian theory. We show that it is perturbatively local in space, but non-local in time, and we explain the observational consequences of this fact. We give an argument for why to a certain degree of accuracy the theory can be considered as quasi time-local and explain what the operator structure is in this case. Furthermore, we describe renormalization of the bias coefficients so that, after this and after upgrading the Eulerian calculation to a Lagrangian one, the perturbative series for galaxies correlation functions results in a manifestly convergent expansion in powers of k/k NL and k/k M , where k is the wavenumber of interest, k NL is the wavenumber associated to the non-linear scale, and k M is the comoving wavenumber enclosing the mass of a galaxy.

79 ASTRONOMY AND ASTROPHYSICS↗

Unexpected magnetism, Griffiths phase, and exchange bias in the mixed lanthanide Pr 0.6 Er 0.4 Al 2

We report an unusual coexistence of ferromagnetism and ferrimagnetism, and metamagnetism in Pr 0.6 Er 0.4 Al 2 . In addition, this compound retains a clear Griffiths phase behavior even at 1 kOe magnetic field and shows a large exchange bias after field cooling from the paramagnetic state. The crystal-field excitations and opposite exchange interactions between nearest-neighbor and next-nearest-neighbor rare earth sites explain these behaviors.

Pathak, Arjun K.↗

Epitaxial niobium dioxide thin films by reactive-biased target ion beam deposition

Epitaxial NbO{sub 2} thin films were synthesized on Al{sub 2}O{sub 3} (0001) substrates via reactive bias target ion beam deposition. X-ray diffraction and Raman spectra were used to confirm the tetragonal phase of pure NbO{sub 2}. Through XPS, it was found that there was a ∼1.3 nm thick Nb{sub 2}O{sub 5} layer on the surface and the bulk of the thin film was NbO{sub 2}. The epitaxial relationship between the NbO{sub 2} film and the substrate was determined. Electrical transport measurement was measured up to 400 K, and the conduction mechanism was discussed.

36 MATERIALS SCIENCE↗

ASSESSMENT OF NORMALITY FOR CRITICALITY SAFETY BIAS AND BIAS UNCERTAINTY CALCULATION

The single-sided lower tolerance factors frequently used for non-trending assessment of the validation bias and bias uncertainty are sensitive to departures from normality. When used properly, the tolerance limits ensure that an appropriate fraction of the true population of applicable critical experiments lies above the calculated lower tolerance limit with the required statistical confidence level. One condition necessary to ensure that the appropriate proportion of the true population of keff values in the validation suite lies above the lower tolerance limit is that the assumption that the normality of the underlying population of critical experiments is valid or conservative.This paper discusses various methods used to assess whether the assumption that the validation suite may be treated as a random sample drawn from a normal distribution is acceptable. Techniques for assessing the validity of this underlying assumption include common omnibus hypothesis tests for normality, assessment of sample skewness and kurtosis of the validation suite, and graphical techniques. These techniques are used to assess the nature and potential conservatism/nonconservatism imparted by various departures from normality where possible. A review of hypothesis testing is also presented to frame the discussion of omnibus normality tests. Additionally, two cases are analysed with these techniques to provide an example of how they should be implemented.

Clarity, Justin↗

Exposing Process‐Level Biases in a Global Cloud Permitting Model With ARM Observations

The emergence of global convective‐permitting models (GCPMs) represents a significant advancement in climate modeling, offering improved representation of deep convection and complex precipitation patterns. In this study, we evaluate the performance of the Simple Cloud‐Resolving E3SM Atmosphere Model (SCREAM) using its doubly periodic configuration (DP‐SCREAM) against large eddy simulations and modern observational data sets from the Atmospheric Radiation Measurement program. We introduce several new transitional cloud regime cases, such as the transition from shallow to deep convection and from stratocumulus to cumulus, as well as cold‐air outbreak scenarios. The results reveal both strengths and limitations of SCREAM, particularly in the accurate simulation of cloud transitions and midlevel convection, with varying degrees of sensitivity to horizontal and vertical resolution. Despite improvements at higher resolutions, key biases remain, including the abrupt transition from shallow to deep convection and the lack of congestus clouds. These findings underscore the need for further refinement in turbulence parameterizations and vertical grid resolution in GCPMs.

Bogenschutz, Peter A. [Lawrence Livermore National↗

Clustering of quasars in SDSS-IV eBOSS: study of potential systematics and bias determination

Here, we study the first year of the eBOSS quasar sample in the redshift range 0.9 Q = 2.45 ± 0.05 at $\bar{z}$=1.55, together with its evolution with redshift. We use this information to determine the minimum mass of the halo hosting the quasars and the characteristic halo mass, which we find to be both independent of redshift within statistical error. Using a recently-measured quasar-luminosity-function we also determine the quasar duty cycle. Lastly, the size of this first year sample is insufficient to detect any luminosity dependence to quasar clustering and this issue should be further studied with the final ~500,000 eBOSS quasar sample.

79 ASTRONOMY AND ASTROPHYSICS↗

Phase slips in a current-biased narrow superconducting strip

The theory of current transport in a narrow superconducting strip is revisited taking the effect of thermal fluctuations into account. The value of voltage drop across the sample is found as a function of temperature (close to the transition temperature, T $-$ T c << T c ) and bias current J < J c (J c is the critical current calculated in the framework of the BCS approximation, neglecting thermal fluctuations). It is shown that careful analysis of vortices crossing the strip results in considerable increase of the activation energy.

Ovchinnikov, Yu. N.↗

Brightest Cluster Galaxy ellipticity as proxy for halo shape: Orientation bias, assembly bias, and potential selection effects in SZ-selected clusters

The orientation of triaxial galaxy clusters with respect to the line-of-sight is expected to be one of the prime sources of scatter and potential bias in optical observables (e.g., richness and weak-lensing signal) of galaxy clusters. In this work, we use the observed shape of the central Brightest Cluster Galaxy (BCG) as proxy for the orientation along the line-of-sight for clusters selected via the Sunyaev-Zel'dovich (SZ) effect from the South Pole Telescope (SPT) and Atacama Cosmology Telescope (ACT) surveys, matched to optically selected clusters from the Dark Energy Survey Year 3 (DES). We construct two samples of clusters that are designed to be identical in SZ mass estimate and redshift but with the roundest vs. the most elliptical BCGs, which we expect to correspond to BCGs (and clusters) with major axes aligned along the line-of-sight vs. in the plane of the sky, respectively. We find that the optical richness of round-BCG clusters is $\sim 10$% larger than that of elliptical-BCG clusters, in agreement with the expectation from projection effects and presenting the first such detection in data. The density profiles, however, are not in agreement with the expectation from projection effects: the 1-halo term (below $6~h^{-1}\rm{Mpc}$) of both the weak-lensing and galaxy density profiles are the same for the subsamples, contrary to previous studies based on X-ray selected clusters. In the 2-halo regime (above $6~h^{-1}\rm{Mpc}$), we find a significant excess of the elliptical-BCG cluster profiles compared to the round-BCG cluster profiles, which is the opposite of the expectation from numerical simulations. We hypothesize that the intrinsic shape of the BCG reflects not just the orientation angle, but also intrinsic properties of the cluster which can affect both the SZ signal and the amplitude of the 2-halo term.

Srinivasan, Radhakrishnan [SUNY, Stony Brook] (ORC↗