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At least 73 records · Page 4

Progress on the Organic and Inorganic Modules of the Spacecraft Water Impurity Monitor, a Next Generation Complete Water Analysis System for Crewed Vehicles

The Spacecraft Water Impurity Monitor (SWIM) is a joint collaboration to develop an instrument platform that will perform in-flight measurements and deliver a more complete picture of water quality to decision makers. For exploration missions, returned water samples will not be an option, so spacecraft and habitats will need to be equipped with advanced water monitoring capabilities. Eventually, missions to the moon, Mars, and beyond should be equipped with analytical capabilities roughly analogous to those found in terrestrial labs. Based on what we know about current and future spacecraft environments, SWIM will seek to provide enhanced analytical capability that enables NASA to confidently send astronauts on distant missions without the possibility of returned water samples. The SWIM architecture can be broken down in an Organic Water Module (OWM) and an Inorganic Water Module (IWM), independent of each other but can be flown together if desired; an integrated system may share some commonality, e.g., single sample injection, sampling consumables, waste, etc. Each of these main modules can be broken down further into separation (if required) and detection modules. And, each separation module can be paired with one or more detection module depending on mission, spacecraft, customer needs, and size/mass/power constraints. This paper discusses the research and development progress toward the goal of a total water analysis system. For OWM, one of the analysis technologies that the SWIM team have been developing is a liquid-injection gas chromatograph mass spectrometer system; these systems are the workhorses of analytical chemistry laboratories world-wide. For IWM, the team is exploring a number of technologies ranging from traditional liquid chromatography technologies (e.g. ion chromatography, capillary electrophoresis) to flight-heritage technology such as ion-specific electrodes.

Stuart Pensinger↗

Hot Water, Cold Reality: Experimental Analysis of Sorption Constraints in Iodine Filtration Media Under Heated-Water Conditions

Iodine has been widely employed as a residual biocide in potable water applications during crewed missions. Unlike other biocides, it is essential to remove iodine from drinking water prior to consumption, as its biocidal concentration raises health concerns. Consequently, effectively removing iodine species from water is a critical step in potable water processing. Although the non-biocided heated leg has not violated microbial specifications on the International Space Station, any wetted volume lacking biocide presents potential risks for long‑duration exploration missions and for systems that are sensitive to microbial growth/contamination. Recent assessments indicate, however, that iodine‑removal performance may degrade under elevated temperature conditions, such as those required for dispensing hot water for food preparation. This reduction in efficacy appears to stem from both the potential physical degradation of filtration media and the temperature‑dependent behavior of adsorption processes. To investigate the influence of water temperature on the efficacy of filtration media for iodine removal, a series of adsorption capacity tests were conducted at both room temperature and elevated temperatures (90 °C). These experiments aimed to benchmark the performance of the adsorbents that constitute the ACTEX filter in the ISS’s potable water dispenser. The findings of this study provide critical insights into the iodine filtration process, verify the potential performance shortfall under elevated temperature conditions, and establish the basis for defining new absorbent requirements to ensure reliable iodine removal in future mission architectures.

iodine↗

Hot Water, Cold Reality: Experimental Analysis of Sorption Constraints in Iodine Filtration Media Under Heated-Water Conditions

Iodine has been widely employed as a residual biocide in potable water applications during crewed missions. Unlike other biocides, it is essential to remove iodine from drinking water prior to consumption, as its biocidal concentration raises health concerns. Consequently, effectively removing iodine species from water is a critical step in potable water processing. Although the non-biocided heated leg has not violated microbial specifications on the International Space Station, any wetted volume lacking biocide presents potential risks for long‑duration exploration missions and for systems that are sensitive to microbial growth/contamination. Recent assessments indicate, however, that iodine‑removal performance may degrade under elevated temperature conditions, such as those required for dispensing hot water for food preparation. This reduction in efficacy appears to stem from both the potential physical degradation of filtration media and the temperature‑dependent behavior of adsorption processes. To investigate the influence of water temperature on the efficacy of filtration media for iodine removal, a series of adsorption capacity tests were conducted at both room temperature and elevated temperatures (90 °C). These experiments aimed to benchmark the performance of the adsorbents that constitute the ACTEX filter in the ISS’s potable water dispenser. The findings of this study provide critical insights into the iodine filtration process, verify the potential performance shortfall under elevated temperature conditions, and establish the basis for defining new absorbent requirements to ensure reliable iodine removal in future mission architectures.

drinking water↗

Remote sensing of atmospheric water vapor and liquid water with the Nimbus 5 microwave spectrometer

The Nimbus 5 satellite is provided with a passive microwave spectrometer (NEMS) incorporating channels at 22.235 and 31.4 GHz to measure atmospheric water vapor and liquid water over ocean. The discussion covers principles of atmospheric water determination, accuracy of measurements, observations of specific storms and fronts, and observations of water vapor and liquid water on a global scale. The NEMS experiment has demonstrated the ability of a two-channel microwave spectrometer to determine integrated abundances of water vapor and liquid water with estimated rms accuracies of 0.2 and 0.01 g per sq cm, respectively. The data can be used to plot global maps or accumulate global statistics.

Staelin, D. H.↗

A Novel Ion Exchange System to Purify Mixed ISS Waste Water Brines for Chemical Production and Enhanced Water Recovery

Current International Space Station water recovery regimes produce a sizable portion of waste water brine. This brine is highly toxic and water recovery is poor: a highly wasteful proposition. With new biological techniques that do not require waste water chemical pretreatment, the resulting brine would be chromium-free and nitrate rich which can allow possible fertilizer recovery for future plant systems. Using a system of ion exchange resins we can remove hardness, sulfate, phosphate and nitrate from these brines to leave only sodium and potassium chloride. At this point modern chlor-alkali cells can be utilized to produce a low salt stream as well as an acid and base stream. The first stream can be used to gain higher water recovery through recycle to the water separation stage while the last two streams can be used to regenerate the ion exchange beds used here, as well as other ion exchange beds in the ISS. Conveniently these waste products from ion exchange regeneration would be suitable as plant fertilizer. In this report we go over the performance of state of the art resins designed for high selectivity of target ions under brine conditions. Using ersatz ISS waste water we can evaluate the performance of specific resins and calculate mass balances to determine resin effectiveness and process viability. If this system is feasible then we will be one step closer to closed loop environmental control and life support systems (ECLSS) for current or future applications.

Water Brines↗

General Circulation Models Simulate Negative Liquid Water Path­–Droplet Number Correlations, but Anthropogenic Aerosols Still Increase Simulated Liquid Water Path

General circulation models' (GCMs) estimates of the liquid water path adjustment to anthropogenic aerosol emissions differ in sign from other lines of evidence. This reduces confidence in estimates of the effective radiative forcing of the climate by aerosol–cloud interactions (ERFaci). The discrepancy is thought to stem in part from GCMs' inability to represent the turbulence–microphysics interactions in cloud-top entrainment, a mechanism that leads to a reduction in liquid water in response to an anthropogenic increase in aerosols. In the real atmosphere, enhanced cloud-top entrainment is thought to be the dominant adjustment mechanism for liquid water path, weakening the overall ERFaci. We show that the latest generation of GCMs includes models that produce a negative correlation between the present-day cloud droplet number and liquid water path, a key piece of observational evidence supporting liquid water path reduction by anthropogenic aerosols and one that earlier-generation GCMs could not reproduce. However, even in GCMs with this negative correlation, the increase in anthropogenic aerosols from preindustrial to present-day values still leads to an increase in the simulated liquid water path due to the parameterized precipitation suppression mechanism. This adds to the evidence that correlations in the present-day climate are not necessarily causal. We investigate sources of confounding to explain the noncausal correlation between liquid water path and droplet number. These results are a reminder that assessments of climate parameters based on multiple lines of evidence must carefully consider the complementary strengths of different lines when the lines disagree.

General circulation models↗

Northern Colorado Water Resources: Using Earth Observations to Assess Relationships between Snowpack and Wildfires for Water Utility Management

In recent years, wildfires in the western U.S. have increased in size, frequency, and severity. Colorado is no exception to this trend, with many recent wildfires raising concerns. The Cameron Peak and East Troublesome Fires, the two largest recorded wildfires in Colorado history, burned over 400,000 acres in 2020. Wildfires pose a significant threat to high-elevation ecosystems, especially in terms of disturbances to watershed resources. Colorado’s annual water supply is dependent upon the melt and runoff of high-elevation snowpack, thus understanding wildfire effects is crucial. This project partnered with Northern Water, a water management company in Colorado, to explore fire impacts on Colorado Front Range watersheds and water supply forecasts. We investigated the use of remote sensing to study the influences of wildfire on snow depth, as Northern Water had previously relied on field-based observations of snowpack for their water supply forecasts. This project utilized airborne LiDAR data from Airborne Snow Observatories, Inc., Landsat 8 OLI derived products, as well as in situ snow survey data from Colorado State University to assess and model changes in snowpack over time. We uncovered key drivers of change in snowpack such as burn severity and snow zone and created a random forest model to determine and investigate their relationships. Despite temporal data availability limitations, analysis also showed that remotely-sensed snow depth measurements were strongly correlated with in situ snow depth measurements, revealing the accuracy and feasibility of using remote sensing technologies to study landscape-scale snowpack characteristics for water utility management purposes.

airborne LiDAR↗

Water hyacinths for removal of phenols from polluted waters

Removal of phenol by water hyacinths (Eichhornia crassipes (Mart.) Solms) in static water was investigated. 2.75 g dry weight of this aquatic plant demonstrated the ability to absorb 100 mg of phenol per plant per 72 hours from distilled water, river water, and bayou water. One hectare of water hyacinth plants is shown to be potentially capable of removing 160 kg of phenol per 72 hours from waters polluted with this chemical.

Wolverton, B. C.↗

Airborne discrimination between ice and water - Application to the laser measurement of chlorophyll-in-water in a marginal ice zone

The concurrent active-passive measurement capabilities of the NASA Airborne Oceanographic Lidar have been used to (1) discriminate between ice and water in a large ice field within the Greenland Sea and (2) achieve the detection and measurement of chlorophyll-in-water by laser-induced and water-Raman-normalized pigment fluorescence. Passive upwelled radiances from sea ice are significantly stronger than those from the neighboring water, even when the optical receiver field-of-view is only partially filled with ice. Thus, weaker passive upwelled radiances, together with concurrently acquired laser-induced spectra, can rather confidently be assigned to the intervening water column. The laser-induced spectrum can then be processed using previously established methods to measure the chlorophyll-in-water concentration. Significant phytoplankton patchiness and elevated chlorophyll concentrations were found within the waters of the melting ice compared to ice-free regions just outside the ice field.

Hoge, Frank E.↗

A systems approach to water recovery testing for space life support - Initial biomedical results from the ECLSS Water Recovery Test and plans for testbed utilization

Among the challenges of designing and constructing Space Station Freedom is the development of the water system. A review of past efforts in reclaiming waste water in enclosed environments reveals that there are many gaps in the biomedical understanding of this process. Some of the key uncertainties of human interaction with a closed water system include determining potential contaminants and establishing safe levels of multiple compounds in the enclosed system of Space Station. Another uncertainty is the microbial constituency of such a system and what impact it could have on crew health and performance. The use of iodine as the passive biocide may have both an indirect and direct impact on the crew. In this paper the initial results of the Water Recovery Test are reviewed from a biomedical perspective, revealing areas where more information is needed to develop the ECLSS water system. By including the approach of 'man as a subsystem', consideration is given to how man interacts with the total water system. Taking this systems approach to providing the crew with a safe source of water gives useful insight into the most efficient design and utilization of closed system testbeds.

Aten, Laurie A.↗

Analysis of thrust augmentation of turbojet engines by water injection at compressor inlet including charts for calculating compression processes with water injection

A psychrometric chart having total pressure (sum of partial pressures of air and water vapor) as a variable, a Mollier diagram for air saturated with water vapor, and charts showing the thermodynamic properties of various air-water vapor and exhaust gas-water vapor mixtures are presented as aids in calculating the thrust augmentation of a turbojet engine resulting from the injection of water at the compressor inlet. Curves are presented that show the theoretical performance of the augmentation method for various amounts of water injected and the effects of varying flight Mach number, altitude, ambient-air temperature, ambient relative humidity, compressor pressure ratio, and inlet-diffuser efficiency. Numerical examples, illustrating the use of the psychrometric chart and the Mollier diagram in calculating both compressor-inlet and compressor-outlet conditions when water is injected at the compressor inlet, are presented.

Wilcox, E Clinton↗

Excess chemical potential of small solutes across water--membrane and water--hexane interfaces

The excess chemical potentials of five small, structurally related solutes, CH4, CH3F, CH2F2, CHF3, and CF4, across the water-glycerol 1-monooleate bilayer and water-hexane interfaces were calculated at 300, 310, and 340 K using the particle insertion method. The excess chemical potentials of nonpolar molecules (CH4 and CF4) decrease monotonically or nearly monotonically from water to a nonpolar phase. In contrast, for molecules that possess permanent dipole moments (CH3F, CH2F, and CHF3), the excess chemical potentials exhibit an interfacial minimum that arises from superposition of two monotonically and oppositely changing contributions: electrostatic and nonelectrostatic. The nonelectrostatic term, dominated by the reversible work of creating a cavity that accommodates the solute, decreases, whereas the electrostatic term increases across the interface from water to the membrane interior. In water, the dependence of this term on the dipole moment is accurately described by second order perturbation theory. To achieve the same accuracy at the interface, third order terms must also be included. In the interfacial region, the molecular structure of the solvent influences both the excess chemical potential and solute orientations. The excess chemical potential across the interface increases with temperature, but this effect is rather small. Our analysis indicates that a broad range of small, moderately polar molecules should be surface active at the water-membrane and water-oil interfaces. The biological and medical significance of this result, especially in relation to the mechanism of anesthetic action, is discussed.

NASA Center ARC↗

Determination of Ice Water Path in Ice-over-Water Cloud Systems Using Combined MODIS and AMSR-E Measurements

To provide more accurate ice cloud properties for evaluating climate models, the updated version of multi-layered cloud retrieval system (MCRS) is used to retrieve ice water path (IWP) in ice-over-water cloud systems over global ocean using combined instrument data from the Aqua satellite. The liquid water path (LWP) of lower layer water clouds is estimated from the Advanced Microwave Scanning Radiometer for EOS (AMSR-E) measurements. With the lower layer LWP known, the properties of the upper-level ice clouds are then derived from Moderate Resolution Imaging Spectroradiometer measurements by matching simulated radiances from a two-cloud layer radiative transfer model. Comparisons with single-layer cirrus systems and surface-based radar retrievals show that the MCRS can significantly improve the accuracy and reduce the over-estimation of optical depth and ice water path retrievals for ice over-water cloud systems. During the period from December 2004 through February 2005, the mean daytime ice cloud optical depth and IWP for overlapped ice-over-water clouds over ocean from Aqua are 7.6 and 146.4 gm(sup -2), respectively, significantly less than the initial single layer retrievals of 17.3 and 322.3 gm(sup -2). The mean IWP for actual single-layer clouds was 128.2 gm(sup -2).

Huang, Jianping↗

Design and Evaluation of a Water Recirculation Loop Maintenance Device for the Advanced Spacesuit Water Membrane Evaporator

A dual-bed device to maintain the water quality of the Advanced Spacesuit Water Membrane Evaporation (SWME) water recirculation loop has been designed and is undergoing testing. The SWME is a heat rejection device under development at the NASA Johnson Space Center to perform thermal control for advanced spacesuits. One advantage to this technology is the potential for a significantly greater degree of tolerance to contamination when compared to the existing Sublimator technology. The driver for the development of a water recirculation maintenance device is to further enhance this advantage through the leveraging of fluid loop management lessons-learned from the International Space Station (ISS). A bed design that was developed for a Hamilton Sundstrand military application, and considered for a potential ISS application with the Urine Processor Assembly, provides a low pressure drop means for water maintenance in a recirculation loop. The bed design is coupled with high capacity ion exchange resins, organic adsorbents, and a cyclic methodology developed for the Extravehicular Mobility Unit (EMU) Transport Water loop. The bed design further leverages a sorbent developed for ISS that introduces a biocide in a microgravity-compatible manner for the Internal Active Thermal Control System (IATCS). The leveraging of these water maintenance technologies to the SWME recirculation loop is a clear demonstration of applying the valuable lessons learned on the ISS to the next generation of manned spaceflight Environmental Control and Life Support System (ECLSS) hardware.

Steele, John W.↗

Design and Evaluation of a Water Recirculation Loop Maintenance Device for the Advanced Spacesuit Water Membrane Evaporator

A dual-bed device to maintain the water quality of the Advanced Spacesuit Water Membrane Evaporation (SWME) water recirculation loop has been designed and is undergoing testing. The SWME is a heat rejection device under development at the NASA Johnson Space Center to perform thermal control for advanced spacesuits. One advantage to this technology is the potential for a significantly greater degree of tolerance to contamination when compared to the existing sublimator technology. The driver for the development of a water recirculation maintenance device is to further enhance this advantage through the leveraging of fluid loop management lessons learned from the International Space Station (ISS). A bed design that was developed for a Hamilton Sundstrand military application, and considered for a potential ISS application with the Urine Processor Assembly, provides a low pressure drop means for water maintenance in a recirculation loop. The bed design is coupled with high-capacity ion exchange resins, organic adsorbents, and a cyclic methodology developed for the Extravehicular Mobility Unit Transport Water Loop. The bed design further leverages a sorbent developed for the ISS that introduces a biocide in a microgravity-compatible manner for the Internal Active Thermal Control System. The leveraging of these water maintenance technologies to the SWME recirculation loop is a unique demonstration of applying the valuable lessons learned on the ISS to the next generation of crewed spaceflight Environmental Control and Life Support System hardware.

Steele, John W.↗

Performance of a Water Recirculation Loop Maintenance Device and Process for the Advanced Spacesuit Water Membrane Evaporator

A dual-bed device to maintain the water quality of the Advanced Spacesuit Water Membrane Evaporation (SWME) water recirculation loop has been designed and is undergoing testing. The SWME is a heat rejection device under development at the NASA Johnson Space Center to perform thermal control for advanced spacesuits. One advantage to this technology is the potential for a significantly greater degree of tolerance to contamination when compared to the existing Sublimator technology. The driver for the development of a water recirculation maintenance device is to further enhance this advantage through the leveraging of fluid loop management lessons-learned from the International Space Station (ISS). A bed design that was developed for a Hamilton Sundstrand military application, and considered for a potential ISS application with the Urine Processor Assembly, provides a low pressure drop means for water maintenance in a recirculation loop. The bed design is coupled with high capacity ion exchange resins, organic adsorbents, and a cyclic methodology developed for the Extravehicular Mobility Unit (EMU) Transport Water loop. The bed design further leverages a sorbent developed for ISS that introduces a biocide in a microgravity-compatible manner for the Internal Active Thermal Control System (IATCS). The leveraging of these water maintenance technologies to the SWME recirculation loop is a unique demonstration of applying the valuable lessons learned on the ISS to the next generation of manned spaceflight Environmental Control and Life Support System (ECLSS) hardware.

Steele, John W.↗

A Novel Ion Exchange System to Purify Mixed ISS Waste Water Brines for Chemical Production and Enhanced Water Recovery

Current International Space Station water recovery regimes produce a sizable portion of waste water brine. This brine is highly toxic and water recovery is poor: a highly wasteful proposition. With new biological techniques that do not require waste water chemical pretreatment, the resulting brine would be chromium-free and nitrate rich which can allow possible fertilizer recovery for future plant systems. Using a system of ion exchange resins we can remove hardness, sulfate, phosphate and nitrate from these brines to leave only sodium and potassium chloride. At this point modern chlor-alkali cells can be utilized to produce a low salt stream as well as an acid and base stream. The first stream can be used to gain higher water recovery through recycle to the water separation stage while the last two streams can be used to regenerate the ion exchange beds used here, as well as other ion exchange beds in the ISS. Conveniently these waste products from ion exchange regeneration would be suitable as plant fertilizer. In this report we go over the performance of state of the art resins designed for high selectivity of target ions under brine conditions. Using ersatz ISS waste water we can evaluate the performance of specific resins and calculate mass balances to determine resin effectiveness and process viability. If this system is feasible then we will be one step closer to closed loop environmental control and life support systems (ECLSS) for current or future applications.

brine↗

Lunar Water ISRU Measurement Study (LWIMS): Establishing a Measurement Plan for Identification and Characterization of a Water Reserve

NASA’s Artemis program aims to achieve a sustainable lunar presence by 2028. To carry out sustained crewed surface operations, In-Situ Resource Utilization (ISRU), which would use lunar resources (e.g., water) to produce mission consumables, will be critical. Water-bearing materials have been identified at both lunar poles, butthe nature and extent of this resource is not well understood. Identification of the presence of water alone is not adequate for ISRU architecture planning and engineering design. The Lunar Water ISRU Measurement Study (LWIMS) assessed and defined the type, amount, and fidelity of the information and measurements needed to select mining locations for lunar water ISRU and to define requirements for ISRU hardware and architecture development. Current ISRU requirements were used to define a water ‘reserve’ in this context. A measurement plan to achieve these goals includes three key elements; a predictive ‘water favorability’ model to identify and map potential deposits, continued assessment of orbital data, and three types of landed missions to make direct ground measurements. Corresponding mission scenarios and instrument suites will depend on risk posture and timelines for ISRU implementation.

In situ resource utilization↗