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All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Calculation of Groundwater Pathway Radiological Dose for the Hanford Site Composite Analysis Null-Space Model Carlo Flow Model Set

The purpose of this environmental calculation file (ECF) is to present the results of the exposure route-specific and total radiological dose assessments for the groundwater pathway based on the null space Monte Carlo (NSMC) groundwater concentrations as a part an uncertainty analysis for the updated Hanford Site Composite Analysis (CA). The Plateau-to River (P2R) Groundwater Model (CP-57037, Model Package Report: Plateau to River Groundwater Model Version 8.3) is the CA base case that simulates the fate and transport of radiological contaminants within the saturated zone of the uppermost aquifer beneath the Central Plateau and downgradient to the Columbia River. An NSMC analysis was performed to identify and quantify the potential uncertainties associated with the P2R Model. The result of the NSMC analysis is a set of flow and transport simulations that provide an estimated range of possible outcomes that are used to quantify the uncertainty associated with the simulated base case concentrations.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Development of a Conditioned System-Level Groundwater Model to Evaluate Long-Term Groundwater Impacts within a Performance Assessment - 20115

A preliminary performance assessment (PA) of single-shell tank Waste Management Area (WMA) A-AX located at the U.S. Department of Energy (DOE)'s Hanford Site in southeastern Washington is being conducted to satisfy the requirements of DOE Order 435.1 [1] as it relates to closure of the single-shell radioactive waste tanks in the WMA A-AX tank farms. A PA assesses the fate, transport, and impacts of radionuclides within a low-level radioactive waste disposal facility in its assumed closure configuration and the subsequent potential doses to humans over a 1,000-year compliance period and a 10,000-year performance evaluation period. The WMA A-AX preliminary PA evaluation is structured around the complementary use of process-level and system-level models to calculate the facility performance against established DOE Order 435.1 [1] performance objectives. Process-level models are those that represent a detailed phenomenological representation of processes of concern in the PA. Process models typically only represent one or a few of the components of the PA, such as groundwater flow and transport, and must be integrated with other modeling elements to perform PA calculations. System-level models are those that are abstracted from the process models, retaining the essential features of the process model, while allowing integration of all aspects of the PA in a single modeling framework. System-level models are often characterized by coarser numerical discretization, lower dimensionality, or other similar simplifications compared to the process-level model. Traditionally, a three-dimensional (3-D) process-level model is utilized primarily to evaluate the long-term impact on groundwater and the potential doses to individuals who consume contaminated groundwater. System-level models are also utilized to evaluate the groundwater pathway in PAs. These models typically have reduced dimensionality (1-D) and are conditioned utilizing flow fields (Darcy fluxes) and moisture content distributions that are abstracted from the process level models. The abstraction approach assures that the flow field in both models is consistent for a specific set of input parameters for flow, differing only in the discretization and dimensionality of the two models. The preliminary WMA A-AX PA incorporates a detailed representation of the geological system and hydraulic properties within the 3-D model STOMP{sup C} numerical code so that the effects of relevant features and processes on water flow and radionuclide transport in the subsurface can be evaluated. The complementary system-level model is developed utilizing the GoldSim{sup C} code to implement a simplified, 1-D equivalent model to represent the groundwater pathway. Contaminant transport through the vadose zone and unconfined aquifer for Tc-99 and I-129 were evaluated in each of the models. Adjustments to the saturated portion of the GoldSim{sup C} 1-D model were required to mimic the dispersion effect captured with the 3-D STOMP{sup C} model. Once this conditioning was conducted, highly similar results for the transport of Tc-99 and I-129 were achieved at the point of calculation, located 100 m downgradient from the WMA A-AX fenceline. These radionuclides represent elements that are regarded as primary dose drivers in the PA groundwater pathway analysis. The high degree of conformance between the two models suggests that the use of the equivalent 1-D system model is suitable for evaluating the full suite of radionuclides that will be released from the tank sources within WMA A-AX over the 1,000-year compliance period and over the 10,000-year evaluation period. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Groundwater characterization and monitoring at a complex industrial waste site using electrical resistivity imaging

A contaminated industrial waste site in Washington State (USA) containing buried, metallic-waste storage tanks, pipes, and wells, was evaluated to determine the feasibility of monitoring groundwater remediation activities associated with an underlying perched aquifer system using electrical resistivity tomography. The perched aquifer, located ~65 m below ground surface and ~10 m above the regional water table, contains high concentrations of nitrate, uranium, and other contaminants of concern from past tank leaks and intentional releases of wastes to surface disposal sites. The extent of the perched water aquifer is not well known, and the effectiveness of groundwater extraction for contaminant removal is uncertain, so supplemental characterization and monitoring technologies are being evaluated. Numerical simulations of subsurface flow and contaminant transport were performed with a highly resolved model of the hydrogeologic system and waste site infrastructure, and these simulations were used as the physical basis for electrical resistivity tomography modeling. The modeling explicitly accounted for metallic infrastructure at the site. The effectiveness of using surface electrodes versus surface and horizontal subsurface electrodes, for imaging groundwater extraction from the perched water aquifer, was investigated. Although directional drilling is a mature technology, its use for electrode emplacement in the deep subsurface under a complex industrial waste site via horizontal wells has not yet been demonstrated. Results from this study indicate that using horizontal subsurface electrode arrays could significantly improve the ability of electrical resistivity tomography to image deep subsurface features and monitor remediation activities under complex industrial waste sites.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Application of a Null-Space Monte Carlo Flow Model Set to the Composite Analysis Base Case Fate and Transport Modeling

The Plateau to River Groundwater Model (P2R Model) is a groundwater flow and contaminant fate and transport (F&T) simulation model used to support remedial activities conducted by CH2M HILL Plateau Remediation Company at the Hanford Site in Washington State. Figure 1-1 illustrates the P2R Model extents, discretization, and boundary conditions. The P2R Model is utilized in the Composite Analysis (CA) for the Hanford Site as the computational engine for computing F&T predictions as described in CP-60406, Hanford Site Composite Analysis Technical Approach Description: Groundwater. The model simulates contaminants of concern within the saturated zone of the uppermost aquifer beneath the Central Plateau and downgradient to the Columbia River. CP-57037, Model Package Report for the Plateau to River Model Version 8.3, documents the current version of the P2R Model including a description of the conceptual site model, model development and calibration, and limitations to the model application. The overall objective of the saturated zone modeling effort is to provide a basis for making informed remedial action decisions based on descriptions of current and expected future contaminant concentrations in groundwater at decision points within and downgradient of the Central Plateau of the Hanford Site. Specifically, the purpose of this environmental calculation is to describe the application of the hydraulic property fields and recharge parameters documented in ECF-HANFORD-20-0027, Null Space Monte Carlo Evaluation of the Plateau to River Model, to the CA flow and fate and transport simulation results to quantify the uncertainty in the simulated results due to input parameter selection. Use of numerical groundwater models is always accompanied with uncertainty in the results produced by a model because models are approximations of reality. Thus, by definition, models lack the detail to fully represent observed behavior. Use of numerical techniques, such as a NSMC analysis, can help in identifying and quantifying the potential uncertainties associated with a numerical model such as the P2R Model. The result of NSCM analysis is a set of F&T simulations that provide an estimate of the range of possible outcomes that are used to quantify the uncertainty in simulated concentrations produced using the base case simulations. The simulated concentrations from all simulations will support calculation of the uncertainty of the total dose calculated in a separate calculation.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2022

Predictive Contaminant Transport Simulation with P2R Model for the Composite Analysis Limited Source Sensitivity Case.

The Plateau to River (P2R) is a groundwater flow and contaminant fate and transport (F&T) simulation model used to support remedial activities conducted by the Central Plateau Cleanup Company at the Hanford Site in Washington State. Figure 1 illustrates the P2R Model extents, discretization, and boundary conditions. The P2R Model is utilized in the Composite Analysis (CA) for the Hanford Site as the computational engine for computing F&T predictions as described in CP-60406, Hanford Site Composite Analysis Technical Approach Description: Groundwater. The model simulates contaminants of concern within the saturated zone of the uppermost aquifer beneath the Central Plateau and downgradient to the Columbia River. CP-57037, Model Package Report for the Plateau to River Model Version 8.3 documents the current version of the P2R Model including a description of the conceptual site model, model development and calibration, and limitations to the model application. Simulations conducted to support the dose calculations required by the CA are documented in ECF-HANFORD-19-0119, Predictive Flow Simulation with the P2R Model for the Composite Analysis Base Case and ECF-HANFORD-19-0120, Contaminant Transport Simulation with the P2R Model for the Composite Analysis Base Case.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Performance Assessment for the E-Area Low-Level Radioactive Waste Disposal Facility at the Savannah River Site: Chapter 5

This chapter presents selected GW flow and radionuclide contaminant transport results from PORFLOW for the VZ and aquifer zone for each type of DU (STs, ETs, LAWV, ILV, and NRCDAs). Results for the nominal PA compliance case and various sensitivity cases are given. Results for the VZ include water saturation spatial profiles and radionuclide flux-to-the-water- table time profiles. Aquifer zone results include maximum concentration spatial contours; radionuclide concentration time profiles at the 100-meter POA; and peak concentrations at the 100-meter POA and time of occurrence for each modeled radionuclide.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2021

Adaptive Site Management Strategies for the Hanford Central Plateau Groundwater

Adaptive site management (ASM) is a systematic and iterative management approach that can be used to expedite the remediation of large and/or complex sites. ASM is defined as a formal and systematic project or site management approach centered on rigorous site planning and a firm understanding of site conditions and uncertainties, using science and technology to routinely re-evaluate and prioritize site remedial actions and characterization activities. The goal of the approach is to create a framework of structured and continuous planning, implementation, and assessment processes that accommodates new information and changing site conditions to develop effective and efficient cleanup approaches that achieves the required outcome(s) while optimizing costs, cleanup timeframe, and performance. Central to ASM is an evolving conceptual site model (CSM). Over time, incremental reductions in uncertainty associated with the CSM will occur, while supporting continued progress toward site cleanup and closure through remedy optimization and evaluation. ASM has the potential to expedite cleanup for the Central Plateau area at Hanford through a planned and systematic approach for reducing uncertainty with targeted characterization activities, while continuing remediation activities that advance cleanup for key risk-driving contaminants. A core component of cleanup within the Central Plateau is the 200 West Pump-and-Treat (P&T) system. Even with an active P&T remedy, uncertainty exists with respect to plume distributions, total mass in the aquifer, and currently known continuing sources. Additional uncertainty is associated with multiple contaminant source locations in the vadose zone, which have the potential to create new groundwater plumes in the absence of any source control measures, although not all contaminant fluxes to groundwater will result in contaminant concentrations above cleanup levels. Collectively, these uncertainties need to be addressed in the CSM to support effective and efficient site progress toward cleanup goal(s). Other nontechnical factors that may warrant an ASM approach at the Hanford Central Plateau are associated with the formation of operable units (OUs) used to manage cleanup. With the exception of the 200-ZP-1 OU, the three remaining groundwater OUs only have interim action records of decision. Nine vadose zone source area OUs are also in the early stages of the remedial investigation and feasibility study process, with pending characterization and technology identification activities. A set of proposed site objectives for the Central Plateau are provided in this document as an initial consideration/example and basis for discussion for ASM implementation. These example site objectives were selected with the goal of maintaining protectiveness at the Columbia River through confinement of contaminant plumes within an administratively controlled area below existing surface waste sites and waste disposal facilities. Although site decision makers and regulators need to provide concurrence, these site objectives are used in this document to describe the elements of an ASM approach, including selection of interim objectives and a long-term adaptive management plan. Interim objectives are also defined to yield measurable incremental progress toward the overall site goals. This document identifies initial technical considerations for developing an ASM framework for the Central Plateau cleanup decisions. These considerations are intended to facilitate more specific decisions, such as objectives, near- and long-term actions, and performance metrics, to develop an overall approach that maintains protectiveness but recognizes the uncertainty, long timeframe, and technical challenges that need to be considered in selecting, implementing, and managing remediation at the Hanford Central Plateau.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2022

Application of a Null-Space Monte Carlo Flow Model Set to the Composite Analysis Base Case Fate and Transport Modeling

The Plateau-to-River (P2R) Model is a groundwater flow and contaminant fate and transport (F&T) simulation model used to support remedial activities conducted by Central Plateau Cleanup Company (CPCCo) at the Hanford Site in Washington State. Figure 1 illustrates the P2R Model extents, discretization, and boundary conditions. The P2R Model is utilized in the composite analysis (CA) for the Hanford Site as the computational engine for computing F&T predictions as described in CP-60406, Hanford Site Composite Analysis Technical Approach Description: Groundwater. The model simulates contaminants of concern within the saturated zone of the uppermost aquifer beneath the Central Plateau and downgradient to the Columbia River. CP-57037, Model Package Report for the Plateau to River Model Version 8.3 documents the current version of the P2R Model including a description of the conceptual site model, model development and calibration, and limitations to the model application.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

New Insights from Legacy Seismic Data regarding Basalt Elevations and Variability on the Hanford Site

Migration of groundwater contaminants in the Gable Gap area of the Hanford Site in southeastern Washington State is strongly influenced by the distribution and permeability of basalts that lie beneath an unconfined aquifer. Locally, folding and faulting of the Columbia River Basalt associated with the Yakima fold and thrust belt followed by erosion due to the Lake Missoula floods resulted in a complex basalt surface that represents either an impermeable lower boundary to the unconfined aquifer system or localized regions of increased permeability that potentially promote communication between the unconfined aquifer system and deeper, confined aquifer systems. Paleo-channels carved into the basalt by floodwaters are thought to provide preferential flow paths for groundwater contaminants. In 2011, a seismic landstreamer campaign was carried out to image the basalt surface and produced pre-stack depth migrated p-wave reflection images. The reflection images identified two large troughs that may represent paleo-channels and several areas of possible faulting. Here, the streamer data are re-analyzed using refraction travel-time and Rayleigh wave dispersion analyses to obtain images of compressional and shear wave velocities within the suprabasalt sediment sections and the upper basalt surface. The combined interpretation of reflection and seismic velocity images shows complexity in the basalt velocity and elevation, which varies by 50 m or more within the study area. These results, along with other ongoing geophysical investigations, will be used to inform the site geologic model and potentially guide placement of future boreholes needed to quantify vertical flow between the confined and unconfined aquifers.

58 GEOSCIENCES↗
DOE OSTI2020

Using Strain in the Vadose Zone During Sinusoidal-Rate Well Tests to Characterize an Aquifer

Well tests with sinusoidal variation in pumping rate are appealing because of the ability to filter competing signals and they also can be set up with no net removal of water, which is an advantage at contaminated sites. Current methods of interpreting sinusoidal-rate well tests analyze the phase lag and amplitude of pressure signals in the aquifer. This approach is restricted by the availability of monitoring wells. An alternative approach could be to measure the stain in the vadose zone instead of pressure in the aquifer. The goal of this research is to evaluate the feasibility of using signals from in-situ sensors in the vadose zone to characterize sinusoidal-rate well tests. Well tests with a variety of periods and amplitudes were performed using a well completed in an unconfined saprolite aquifer with a water table at 9m depth at our test site near Clemson, South Carolina. Vertical strain was measured every meter between 1 to 7 m using a distributed optical fiber sensing technique called coherence length gated microwave photonics interferometry (CMPI). A novel packaging system was designed to couple the optical fiber to the saprolite. The results show that strain measured in the vadose zone during sinusoidal-rate pumping varies periodically with amplitudes from 0.1 to 3 microstrain, depending on the amplitude of the sinusoidal pumping rate. Hydraulic heads at similar radial distances were also periodic with changing amplitudes ranging up to ±0.2 meters. The strain in the vadose zone responds to pressure in the underlying aquifer—the strain is tensile when the pressure is falling, and compressive when the pressure is rising. The phase lag between the pumping rate and the strain was 3 min with a pumping period of 15 minutes, and this gives a hydraulic diffusivity of 0.06 m2/s. This is the same diffusivity obtained by analyzing a constant rate pumping test, and it is slightly larger than the diffusivity (0.044 m2/s) obtained by analyzing the phase lag of the pressure in a nearby monitoring well. Strain measurements in the vadose zone could be made with much less cost and effort than installing a deep monitoring well. These results suggest that strain measurements in the vadose zone could be used to supplement monitoring wells, thereby increasing the resolution, and reducing costs of analyzing well tests.

well test, sinusoidal, periodic pumping, strain↗
DOE OSTI2023

Assessment of Baseline Monitoring Data for the Remote-Handled Low-Level Waste Disposal Facility at Idaho National Laboratory

The purpose of this document is to summarize environmental monitoring data collected at the Remote-Handled Low-Level Waste (RHLLW) Disposal Facility during the first four years of facility operations (FY 2019 through FY 2022). This summary provides a “baseline” condition for the facility, which can be used to distinguish contaminant releases from the RHLLW Disposal Facility from pre existing contamination as well as potential future releases from other sources (i.e., upgradient aquifer sources), as specified in the facility monitoring plan. Sufficient data has been collected over the first four years of operation of the RHLLW Disposal Facility to establish baseline conditions for future compliance monitoring of aquifer wells and performance monitoring of vadose zone lysimeters. Except for seven elevated tritium measurements from lysimeter HFEF-South believed to have been impacted by waste disposals, all data was deemed appropriate for establishing baseline concentrations. Monitoring of the aquifer detected indicator analytes gross alpha and gross beta and target analytes tritium and C-14. There were a few C-14 detections prior to an increase in the required detection level (RDL) after the first round of sampling. I-129 and Tc-99 were not detected above RDLs in aquifer samples. Lysimeter samples detected indicator analytes gross alpha and gross beta and target analyte tritium. Target analytes C-14, I-129, and Tc-99 were not detected above RDLs in lysimeter samples. Except for tritium, baseline concentrations of indicator and target analytes measured during the first four years of RHLLW facility operations are expected to represent conditions through the expected 20 year operating period of the facility. Elevated tritium in the aquifer, a result of past discharges of tritium at upgradient facilities, showed a decline over the first four years of operations, and levels are expected to continue to decline with time as a result of dilution and decay. Current tritium levels in lysimeter samples may be elevated due to tritium in the water applied during construction and infiltration testing of the facility. As a result, tritium concentrations in lysimeters may decline with time as a result of dilution and decay. Statistical measures (i.e., mean, standard deviation, and 99% upper confidence level [UCL]) were calculated for all detected analytes using the four years of concentration data. These measures will be used to evaluate future monitoring results and to demonstrate the facility is performing, or not performing, as established in the facility performance assessment (PA). Future monitoring results will also be combined with the baseline data in this report to further establish temporal trends and natural variability in the measurements. Based on the data collected during the baseline period, it is recommended the gross alpha action level for performance monitoring increase from 10 to 20 pCi/L due to several baseline measurements exceeding the preliminary action level of 10. An action level of 20 pCi/L is slightly greater than the 99% UCL, is protective of the aquifer, and would reduce unnecessary sampling. It is also recommended that tritium be added to the lysimeter analyte list for post-baseline period monitoring. Tritium, while not a dose concern, is a good tracer that can provide valuable information on water flow in and around the RHLLW Disposal Facility. Recommendations for a tritium action level are provided if considered necessary.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2025

Machine Learning Models for Mapping Groundwater Pollution Risk: Advancing Water Security and Sustainable Development Goals in Georgia, USA

The widespread use of pesticides, such as atrazine and malathion, in agricultural systems raises significant concerns regarding the contamination of groundwater, which serves as a critical resource for drinking water. This study applies machine learning techniques to predict the concentrations of atrazine and malathion in groundwater across Georgia, USA, using 2019 data. A Random Forest classifier was employed to integrate various environmental and demographic factors, including pesticide application rates, precipitation, lithology, and population density, to predict pesticide contamination in groundwater. The models demonstrated high training accuracies of 100% and moderate average testing accuracy of 55% for atrazine and 60% for malathion across five iterations. The low test accuracy of the model, ranging from 50% to 75%, is likely due to overfitting, which can be attributed to the small dataset size and the complex nature of pesticide-contamination patterns, making it challenging for the model to generalize to unseen data. Feature importance analysis revealed that average pesticide usage emerged as the most influential factor for atrazine, while aquifer lithology and precipitation played crucial roles in both models. These results provide valuable insights into the dynamics of pesticide contamination, highlighting areas at greater risk of contamination. The findings underscore the importance of integrating environmental, geological, and agricultural variables for more effective groundwater management and sustainable agricultural practices, contributing to the protection of water resources and public health.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Selection of Vadose Zone Flow and Transport Properties with Gravel Fraction Corrections for the Hanford Site Composite Analysis and Cumulative Impact Evaluation

This environmental calculation file (ECF) is a compilation of hydrologic and radiological/chemical properties to be used for the updated Hanford Site Composite Analysis (CA) and Cumulative Impact Evaluation (CIE) vadose zone (VZ) modeling. The CA will provide an all-pathways dose projection to a hypothetical future member of the public from all planned low-level radioactive waste disposal facilities and potential contributions from all other projected end-state sources of radioactive material left at the Hanford Site following site closure. Its primary purpose is to support the decision-making process of the U.S. Department of Energy (DOE) under DOE O 435.1 Chg 1, Radioactive Waste Management, related to managing low-level waste disposal facilities at the Hanford Site. The CIE evaluates the effects of cleanup decisions regarding groundwater quality in the Hanford Site Central Plateau (DOE/RL-2018-69, Cumulative Impact Evaluation Technical Approach Document). Due to the complexity and large number of waste sites in source operable units (OUs), the computational tools used for the CIE must be capable of representing a range of site conditions and source terms in the VZ while also efficiently computing the impact that cleanup decisions have on the underlying aquifer. Waste-site proximity between and within source OUs has resulted in contaminants commingling in the vadose and saturated zones in complex ways. Plume commingling requires cleanup decisions to be evaluated considering the surrounding waste sites and existing groundwater contamination, therefore demonstrating the need to evaluate cumulative impacts from the VZ to groundwater.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Discrete Fracture Network Modeling to Estimate Upscaled Parameters for the Topopah Spring, Lava Flow, and Tiva Canyon Aquifers at Pahute Mesa, Nevada National Security Site

This report describes the results of Discrete Fracture Network (DFN) simulations for the Topopah Spring Aquifer (TSA), Lava Flow Aquifer, and Tiva Canyon Aquifer (TCA), at Pahute Mesa on the Nevada National Security Site (NNSS), formerly the Nevada Test Site. The research focuses on calculating upscaled groundwater flow and contaminant transport parameters using DFNs generated according to fracture characteristics observed in the TSA, LFA and TCA at Pahute Mesa. The highly fractured and heterogeneous nature of these aquifers makes them candidates for stochastic DFN modeling of radionuclide transport on a small scale with subsequent upscaling. One hundred independent DFN realizations are generated for each aquifer, and the upscaled parameters for continuum simulations of subsurface flow and transport in fractured media at Pahute Mesa are calculated. Our goal is to implement a modeling approach that can translate parameters to larger-scale models that account for local-scale flow and transport processes, such as channelization of flow and transport along a few well connected, large fractures. Additionally, to simulate advective and advective-diffusive transport through the fracture networks, the Time Domain Random Walk (TDRW) approach is applied to account for matrix diffusion into a finite half-space. Moreover, a novel approach to calculate dynamic (active) fracture surface area to reflect flow channeling is implemented. This work will improve the representation of radionuclide transport processes in largescale, regulatory-focused models by providing estimates of hard-to-measure flow and contaminant transport parameters at large scales. In this report, we (1) show recent results of flow and transport simulations on multiple DFN realizations of the TSA, LFA, TCA; (2) discuss the resulting distributions of estimated upscaled parameters; (3) describe the estimation of upscaled parameters for an equivalent parallel-plate continuum model and (4) present a comparison between simulated transport from the equivalent continuum model and an actual DFN.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Groundwater Remediation with Pump-and-Treat Technology

Pump-and-treat (P&T) is a widely used remediation technology that involves pumping groundwater from extraction wells in the subsurface, removing contaminants of concern from the groundwater in an aboveground treatment system, reintroducing treated water into the environment – often by injection back into the groundwater aquifer or by discharge to the surface–, and groundwater monitoring to evaluate performance. In this chapter we explore how the Hanford Site uses the P&T remediation approach to treat contaminated groundwater. Six P&T facilities currently operate at the Hanford Site; however, this chapter uses the 100 Area DX and HX P&T facilities' treatment of hexavalent chromium as a case study to discuss this remediation approach. Located in the River Corridor, HX and DX P&T facilities are much closer to reaching closure than the younger 200W P&T facility located in the Central Plateau’s 200W Area. As such, one can follow the historical design, operation, and optimization steps that have led these facilities closer to closure.

Saslow, Sarah A.↗
DOE OSTI2026

Carbon Tetrachloride Degradation Results for 200-ZP-1 Operable Unit

Carbon tetrachloride (CT) contamination in the 200-ZP-1 Operable Unit (OU) at the Hanford Site originated from large-volume discharges to the subsurface during plutonium production operations between 1955 and 1973. Contamination migrated through more than 70 meters of unsaturated sediment to reach the underlying unconfined aquifer, where it persists as a large and complex groundwater plume. The 200-ZP-1 OU Record of Decision (ROD) requires that groundwater CT concentrations be reduced to 3.4 µg/L within 125 years. Current groundwater modeling projections estimate that the existing pump-and-treat, even when combined with monitored natural attenuation (specifically hydrolysis), will not achieve this target within the designated timeframe. A fundamental contributor to this shortfall is the extremely slow rate of CT hydrolysis under Hanford aquifer conditions, which has been estimated to have a half-life of 630 years. If faster-acting biotic and abiotic degradation processes are operating within the aquifer, their contribution to CT mass reduction could have a meaningful impact. However, site-specific measurements of these processes and their rates have not previously been performed. This report documents the results of a two-phase laboratory investigation designed to characterize and quantify the capacity of site-specific 200-ZP-1 OU sediments and groundwater to support natural attenuation of CT through biotic and abiotic pathways. In this context, degradation capacity is defined as the intrinsic potential of the subsurface matrix to transform CT under optimized, controlled conditions. System capacity is evaluated in two ways: (1) as rate-limited capacity, which establishes the maximum kinetic velocity of CT transformation and is measured using half-lives and first order rate constants; and (2) as mass limited capacity, which defines the total contaminant mass the batch experimental system can degrade before reactants are exhausted, representing the maximum amount of contaminant the microbial community and reactive mineral phases can transform under the experimental conditions.

abiotic degradation↗
DOE OSTI2025

Humate Amendment Injection Viability Testing – Supplementary Batch Mixture and Soil Column Studies

Groundwater in the Lost Lake Aquifer Zone (LLAZ) in the Southern Sector of the M-Area Hazardous Waste management Facility (HWMF) is contaminated with chlorinated ethenes, including trichloroethylene (TCE) and tetrachloroethylene (PCE). Treatment of contaminated groundwater with humic acid is being evaluated as a potential corrective action for these volatile organic compounds (VOCs) in the LLAZ in Southern Sector (SRNS, 2019). Pilot scale injections of Huma-K brand humic acid for groundwater treatment were previously performed in M-Area between 2017 and 2020 (Amidon, 2023). Groundwater was extracted from the Lost Lake Aquifer Zone (LLAZ), then a solution of humate was mixed with recovered groundwater and subsequently re-injected into the same aquifer unit. Operations of the historical humate pilot testing were discontinued in 2020 due to COVID-19 restrictions, low injection rates, and recirculation fluid spillage. No further field scale or laboratory research to investigate humate amended groundwater injection was performed at the SRS until 2024. At the request of Area Completion Projects (ACP), the Savannah River National Laboratory (SRNL) performed supplementary testing to help determine the viability of further injection of humate as a remedial option for VOCs within the LLAZ in the Southern Sector of the M-Area HWMF.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2023

Assessment of Potential Dose and Environmental Impacts from Proposed Testing at the INL Radiological Response Training Range

This assessment uses screening-level models to calculate potential environmental impacts from proposed tests at the Idaho National Laboratory (INL) Radiological Response Training Range (RRTR) site. Proposed tests could be conducted using 11 different radioactive material types that include K2O, LaBr3, KBr, Cu, Zr, F, Ga, Ga2O3, NaNO2, Ga-68, and Tc-99m. The tests could potentially release radioactive material to the atmosphere and radionuclides and other contaminants to the soil, which could leach into the unsaturated zone and migrate to the aquifer. Atmospheric transport of radionuclides to potential human receptors and time-integrated air concentrations were calculated with a Gaussian plume model and three years of hourly meteorological data. Potential surface-soil impacts were calculated with the computer program mixing-cell model (MCM). Groundwater impacts were calculated with the computer programs MCM and GWSCREEN. Radiological doses from potential atmospheric releases were calculated for public receptors off the INL Site and for workers at nearby INL facilities. Results were compared to regulatory dose limits. Maximum potential groundwater concentrations were estimated in the aquifer below the NSTR site and compared to drinking water standards or risk-based screening levels for resident tap water. Soil concentrations were calculated and compared to risk-based screening levels for workers and potential future residents. All impacts were estimated assuming 12 tests are conducted annually using all 11 material types for a period of 15 years. This document provides the resources to enable a subject matter expert in the field of environmental assessments to replicate the modeling and calculations. The methodology and parameters are presented in the text. All electronic files, including computer-code input, output, executable files, batch files, scripts, and spreadsheet files are contained in a zip file that can be accessed by selecting “Additional Information” (select Native File) in the INL Electronic Document Management System (EDMS). It is highly unlikely the test scenarios evaluated in this ECAR will adversely impact human health based on comparisons of calculated dose and concentration against regulatory standards and risk-based screening levels. Conservative estimates of dose to workers and the public from atmospheric transport of possible radionuclide releases are far below federal radiation protection standards. Conservative estimates of potential contaminant concentrations in groundwater are less than federal drinking water standards or screening levels. Predicted radionuclide concentrations in surface soils are below risk-based screening levels, except for Ge-68 (material Ga-68) for the worker. The Ge-68 soil concentration can be made less than the worker PRG, if the number of annual tests using Ga-68 is reduced from 12 to 6. However, the sum of ratios still exceeds one because of the high K-40 ratio. If the EF of the worker (number of days the worker is in the contaminated testing area) is reduced from 225 days/yr (default value for full time worker) to 112 days/yr, the Ge-68 ratio is less than one and the sum of ratios is less than one. Actual radiation doses and groundwater and surface-soil concentrations are likely to be much less than those calculated because of the conservative assumptions and parameters employed in the modeling. For example, atmospheric-transport calculations assume the entire inventory of each material type is readily released to the atmosphere and no plume deposition, depletion, or radioactive decay occurs during transport. The calculations also assume the same meteorological conditions (e.g., wind velocity, wind direction, stability class) that produce the maximum 95th percentile concentration (i.e., concentration representing the 95th percentile of a distribution of concentrations derived from 3 years of hourly meteorological data) at each receptor location are the same for all 12 tests during the year, and each receptor is assumed to be present during all 12 tests. The surface-soil assessment assumes the entire inventory of each test is deposited in the top 5 cm of soil. No atmospheric dispersal is assumed, and the radionuclides are subject only to leaching and radioactive decay. The groundwater-pathway modeling is conservative in that it is one-dimensional in the unsaturated zone (no lateral spreading/dilution) and assumes the entire inventory of contaminants infiltrates into the ground at the same location for every test. This is especially conservative for particulate radionuclides because they would have to dissolve or corrode first and some would be dispersed into the atmosphere. The groundwater receptor is also assumed to consume water directly from a hypothetical well positioned in the location of maximum concentration. In addition, conservative degradation rates were used, and volatilization was not considered for the nonradioactive chemical

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