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At least 73 records · Page 4

Neutral band gap of carbon by quantum Monte Carlo methods

We present a method of calculating the energy gap of a charge-neutral excitation using only ground-state calculations. We report Quantum Monte Carlo calculations of Γ→ Γ and Γ → X particle-hole excitation energies in diamond carbon. We analyze the finite-size effect and find the same 1/L decay rate as that in a charged excitation, where L is the linear extension of the supercell. This slow decay is attributed to the delocalized nature of the excitation in supercells too small to accommodate excitonic binding effects. At larger system sizes, the apparent 1/L decay crosses over to a 1/L 3 behavior. Estimation of the scale of exciton binding can be used to correct finite-size effects of neutral gaps.

36 MATERIALS SCIENCE↗

Design and Analysis of an Isokinetic Sampling Probe for Submicron Particle Measurements at High Altitude

An isokinetic dilution probe has been designed with the aid of computational fluid dynamics to sample sub-micron particles emitted from aviation combustion sources. The intended operational range includes standard day atmospheric conditions up to 40,000-ft. With dry nitrogen as the diluent, the probe is intended to minimize losses from particle microphysics and transport while rapidly quenching chemical kinetics. Initial results indicate that the Mach number ratio of the aerosol sample and dilution streams in the mixing region is an important factor for successful operation. Flow rate through the probe tip was found to be highly sensitive to the static pressure at the probe exit. Particle losses through the system were estimated to be on the order of 50% with minimal change in the overall particle size distribution apparent. Following design refinement, experimental testing and validation will be conducted in the Particle Aerosol Laboratory, a research facility located at the NASA Glenn Research Center to study the evolution of aviation emissions at lower stratospheric conditions. Particle size distributions and number densities from various combustion sources will be used to better understand particle-phase microphysics, plume chemistry, evolution to cirrus, and environmental impacts of aviation.

Heath, Christopher M.↗

Interstellar Broadening of Images in the Gravitational Lens Pks 1830-211

The remarkably strong radio gravitational lens PKS 1830-211 consists of a one arcsecond diameter Einstein ring with two bright compact (milliarcsecond) components located on opposite sides of the ring. We have obtained 22 GHz VLBA data on this source to determine the intrinsic angular sizes of the compact components. Previous VLBI observations at lower frequencies indicate that the brightness temperatures of these components are significantly lower than 10(exp 10) K (Jauncey, et al. 1991), less than is typical for compact synchrotron radio sources and less than is implied by the short timescales of flux density variations. A possible explanation is that interstellar scattering is broadening the apparent angular size of the source and thereby reducing the observed brightness temperature. Our VLBA data support this hypothesis. At 22 GHz the measured brightness temperature is at least 10(exp 11) K, and the deconvolved 2 size of the core in the southwest compact component is proportional to upsilon(sup -2) between 1.7 and 22 GHz. VLBI observations at still higher frequencies should be unaffected by interstellar scattering.

Jones, D. L.↗

Radio wave scattering in the outer heliosphere

Current models for the 2-3 kHz emissions observed by the Voyager spacecraft in the outer heliosphere involve 2f(p) radiation generated near the termination shock or the heliopause. Radio wave scattering by solar wind density irregularities strongly affects observed sources of f(p) and 2f(p) emission in the inner heliosphere and the characteristics of astrophysical sources. In particular, the angular size, brightness temperature, and time variability of the source are strongly affected by scattering, thereby having major implications for the inferred size, energy budget, time variability, location, and nature of the source if scattering is ignored. This paper addresses whether scattering is important for interpreting the Voyager 2-3 kHz emissions. Quantitative calculations (with and without diffraction) are performed for the angular broadening of an outer heliospheric source as a function of path length, radiation frequency relative to f(p) and the spectrum of density irregularities. The effects of scattering in both the solar wind and the heliosheath are considered. Predictions for radial gradients in the source's apparent angular size and in the source's modulation index are presented. The calculations are compared with observations and the results discussed. First estimates suggest that scattering plausibly dominates the observed source size. The observed trend in modulation index with heliocentric distance is consistent with scattering being important and the source being in the outer heliosphere. Additional arguments for scattering being important are summarized.

Cairns, Iver H.↗

Anion and Cation Size Effects on Viscoelasticity and Ion Transport of Imine Vitrimer Electrolytes

Vitrimers are a subclass of covalent adaptable networks where bond exchange occurs without breaking, thereby offering polymer materials with enhanced mechanical strength, thermal stability, and reprocessability compared to conventional electrolytes. Despite recent progress, we lack a complete understanding of the role of ions in controlling the physical and chemical properties of vitrimers. In this work, we study how different salts affect the viscoelasticity, morphology, and ionic conductivity of imine vitrimers. Our results show that addition of salt decreases relaxation times at elevated temperatures due to the catalytic effect of the cations, with smaller cations leading to faster relaxation. However, the activation energy for terminal relaxation increases with smaller cation size. This apparent discrepancy is attributed to the complex interplay among bond exchange kinetics, chain diffusion, and salt dissociation. Anions act as plasticizers by reducing the shear modulus, except lithium bromide. Ionic conductivity increases with larger anions due to smaller salt dissociation energies, whereas the cation type has a minor impact as polymer segmental dynamics dominate ionic transport. Imine-based vitrimers are reprocessable and recyclable, maintaining original mechanical properties and ionic conductivity after recovery. Mixed salt vitrimers exhibited tunable viscoelasticity and ionic conductivity intermediate to the analogous pure salt systems. Altogether, this work highlights the role of salt in the dynamic and conductive properties of imine vitrimers.

Anions↗

Fabric properties and electric efficiency limits of mechanical moisture extraction from fabrics

Residential clothes drying consume about 650 TBtu of primary energy per year in the United States, equivalent to 3% of primary residential energy consumption. There is a strong impetus to reduce the energy consumption of clothes dryers by both improving existing technology and developing alternatives that use fundamentally different drying mechanisms. Clothes drying technologies are broadly classified into either evaporative or mechanical drying. The focus of this paper is on mechanical drying, including vibrational, centrifugal, and press-based methods. In this work, the physical processes involved in these mechanical fabric drying processes were analyzed to develop general theories of mechanical cloth drying energy efficiency. Quantitative evaluation of the theories requires measured fabric properties. To accomplish this, a set of experiments was conducted on samples of a standard test fabric. The fabric was a cotton-polyester blend specified by the US Department of Energy to evaluate the standardized efficiency of all residential clothes dryers in the US. Mercury porosimetry experiments were conducted to determine the fabric pore size distribution, apparent density, and porosity. Elasticity experiments were conducted to determine the fabric’s Young’s modulus. Isostatic press experiments were conducted to establish a relationship between compression force and fabric moisture content. The data resulting from these experiments were combined with mathematical models developed in this work to calculate the theoretical maximum performance limits for mechanical drying of the standard fabric. The results of the analysis are used to make recommendations for the most promising technologies that offer the greatest potential energy savings for residential clothes drying.

36 MATERIALS SCIENCE↗

The Calar Alto Legacy Integral Field Area survey: extended and remastered data release

ABSTRACT This paper describes the extended data release (eDR) of the Calar Alto Legacy Integral Field Area (CALIFA) survey. It comprises science-grade quality data for 895 galaxies obtained with the Potsdam Multi Aperture Spectograph/PPak instrument at the 3.5-m telescope at the Calar Alto Observatory along the last 12 yr, using the V500 setup [3700–7500 Å, 6 Å/full-width at half-maximum (FWHM)] and the CALIFA observing strategy. It includes galaxies of any morphological type, star formation stage, a wide range of stellar masses (∼107–1012 M⊙), at an average redshift of ∼0.015 (90 per cent within 0.005 < z < 0.05). Primarily selected based on the projected size and apparent magnitude, we demonstrate that it can be volume corrected resulting in a statistically limited but representative sample of the population of galaxies in the nearby Universe. All the data were homogeneous re-reduced, introducing a set of modifications to the previous reduction. The most relevant is the development and implementation of a new cube-reconstruction algorithm that provides with an (almost) seeing-limited spatial resolution (FWHMPSF ∼ 1.0 arcsec). To illustrate the usability and quality of the data, we extracted two aperture spectra for each galaxy (central 1.5 arcsec and fully integrated), and analyse them using pyFIT3D. We obtain a set of observational and physical properties of both the stellar populations and the ionized gas, that have been compared for the two apertures, exploring their distributions as a function of the stellar masses and morphologies of the galaxies, comparing with recent results in the literature.

Sánchez, S. F. (ORCID:0000000164449307)↗

Long wavelength VLBI.

The application of very-long baseline interferometry (VLBI) techniques at meter and decameter wavelengths has proven to be a unique tool for studying a number of different phenomena. Because of the high angular resolution which we achieve with VLBI, candidate objects for study include the compact nuclei and 'jets' associated with quasars and radio galaxies, pulsars, small knots in galactic supernova remnants, and nonthermal planetary sources. Our investigations have been aimed at determining the emission spectra of these objects, measuring their apparent angular size, and mapping their structure. We expect that these properties will be interrelated, particularly at or below the frequencies at which their spectra peak.

Clark, T. A.↗

Meter-wavelength observations of pulsars using very long baseline interferometry

The results of an investigation of the angular structure imposed on pulsar radiation due to scattering in the interstellar medium are presented. The technique of very-long-baseline interferometry was used to obtain the necessary high angular resolution. The interferometers formed by the Arecibo, NRAO, and Sugar Grove telescopes were used at radio frequencies of 196, 111, and 74 MHz during seven separate observing sessions between November 1971 and February 1973. A crude visibility function for the Crab nebular pulsar was obtained along with the correlated pulse profile. The technique of differential fringe phase was used to show that the pulsar and the compact source in the Crab nebula are coincident to within 0.001 arcsec which corresponds to aproximately 2 a.u. at the distance to the nebula. The ratio of pulsing to total flux, and the fringe visibility of the time-averaged pulsing flux are also discussed, and apparent angular sizes of the pulsars were measured.

Vandenberg, N. R.↗

The MXB1916-053/4U1915-05: Burst properties and constraints on a 50 minute binary secondary

Results are presented from OSO-8 and HEAO-1 A2 observations of 34 bursts from the X-ray burster MXB1916-053/4U1915-05 recently discovered to show a 50 minute binary period. While 11 burst previously reported all had similar light curves, 22 observed two years later show a factor of 3 range of peak fluxes and decay times between 3 and 20 s. Recurrence times between successive bursts vary between 3 and 6 hours. A ratio of steady flux to average burst flux of equiv 120 is developed. A burst observed with the HEAO-1 A2 experiment showed an initial temperature rise to a peak black body temperature of equiv 3 keV followed by the cooling typical of type I bursts. The burst was unusual in that the apparent projected size of a blackbody source increased by a factor of 3 during the cooling phase.

Swank, J. H.↗

MXB 1916-053/4U 1915-05 - Burst properties and constraints on a 50 minute binary secondary

Results are presented from OSO-8 and HEAO-1 A2 observations of 34 bursts from the X-ray burster MXB 1916-053/4U 1915-05 recently discovered to show a 50 minute binary period. While 11 burst previously reported all had similar light curves, 22 observed two years later show a factor of 3 range of peak fluxes and decay times between 3 and 20 s. Recurrence times betweeen successive bursts vary between 3 and 6 hours. A ratio of steady flux to average burst flux of equiv 120 is developed. A burst observed with the HEAO-1 A2 experiment showed an initial temperature rise to a peak black body temperature of equiv 3 keV followed by the cooling typical of type I bursts. The burst was unusual in that the apparent projected size of a blackbody source increased by a factor of 3 during the cooling phase. Previously announced in STAR as N83-34872

Swank, J. H.↗

On the accuracy of recent Goddard gravity models

The Goddard Space Flight Center (GSFC) has occupied a central position within NASA with respect to the development of earth gravity models. The gravity models at Goddard, which are referred to as the Goddard earth models (GEM's) have been under development for more than 15 years. The fields have increased in size and (apparent) accuracy with the inclusion of new tracking data, better nongravitational force modeling, and more orbits over a wide range of inclinations and mean motions. The usefulness of the considered models depends largely on accuracy estimates. The present paper is concerned with a reevaluation of earlier accuracy assessments, taking into account the accuracies of the GEM 9 and the GEM-L2 models. It is found that GEM 9 is about 30 percent more accurate than originally estimated in 1979 from older gravimetry data.

Lerch, F. J.↗

The 27-28 October 1986 FIRE IFO cirrus case study - In situ observations of radiation and dynamic properties of a cirrus cloud layer

Observations are presented of cirrus cloud radiative, microphysical, and dynamic properties, their variability, and apparent scale sizes, as observed from NCAR Sabreliner on October 28, 1986. Broadband mass-absorption coefficients were deduced as a function of depth into the cirrus cloud and found to vary with particle dimension. Broadband volume absorption coefficients were deduced. By employing a diffusivity factor of 1.49 this agreement was maximized. Calculated infrared heating rates were typical of thin cirrus layers. The cloud top cooling and cloud base warming were observed to become more accentuated for the denser portions of cloud. The broadband emittances due to the cloud aerosol were found to approach 0.5 to 0.6. The cirrus clouds were observed to exhibit significant horizontal variability and a significant amount of scatter was evident when attempting to relate the broadband infrared and shortwave radiative properties. It is suggested that these radiative properties, which are modulated by the cloud elements, have their scales determined by the eddies detected in the analysis of wind components.

Smith, William L., Jr.↗

The Optical Counterpart to Gamma-Ray Burst GRB 970228 Observed Using the Hubble Space Telescope

Although more than 2,000 astronomical gamma-ray bursts (GRBS) have been detected, and numerous models proposed to explain their occurrence, they have remained enigmatic owing to the lack of an obvious counterpart at other wavelengths. The recent ground-based detection of a transient optical source in the vicinity of GRB970228 may therefore have provided a breakthrough. The optical counterpart appears to be embedded in an extended source which, if a galaxy, as has been suggested would lend weight to those models that place GRBs at cosmological distances. Here we report, observations using the Hubble Space Telescope of the transient counterpart and extended source 26 and 39 days after the initial gamma-ray outburst. We find that the counterpart has faded since the initial detection (and continues to fade), but the extended source exhibits no significant change in brightness between the two dates of the observations reported here. The size and apparent constancy of the extended source imply that it is extragalactic, but its faintness makes a definitive statement about its nature difficult. Nevertheless, the decay profile of the transient source is consistent with a popular impulsive-fireball model13, which assumes a merger between two neutron stars in a distant galaxy.

Sahu, K. C.↗

World-Wide Web Tools for Locating Planetary Images

The explosive growth of the World-Wide Web (WWW) in the past year has made it feasible to provide interactive graphical tools to assist scientists in locating planetary images. The highest available resolution images of any site of interest can be quickly found on a map or plot, and, if online, displayed immediately on nearly any computer equipped with a color screen, an Internet connection, and any of the free WWW browsers. The same tools may also be of interest to educators, students, and the general public. Image finding tools have been implemented covering most of the solar system: Earth, Mars, and the moons and planets imaged by Voyager. The Mars image-finder, which plots the footprints of all the high-resolution Viking Orbiter images and can be used to display any that are available online, also contains a complete scrollable atlas and hypertext gazetteer to help locating areas. The Earth image-finder is linked to thousands of Shuttle images stored at NASA/JSC, and displays them as red dots on a globe. The Voyager image-finder plots images as dots, by longitude and apparent target size, linked to online images. The locator (URL) for the top-level page is http: //ic-www.arc.nasa.gov/ic/projects/bayes-group/Atlas/. Through the efforts of the Planetary Data System and other organizations, hundreds of thousands of planetary images are now available on CD-ROM, and many of these have been made available on the WWW. However, locating images of a desired site is still problematic, in practice. For example, many scientists studying Mars use digital image maps, which are one third the resolution of Viking Orbiter survey images. When they douse Viking Orbiter images, they often work with photographically printed hardcopies, which lack the flexibility of digital images: magnification, contrast stretching, and other basic image-processing techniques offered by off-the-shelf software. From the perspective of someone working on an experimental image processing technique for super-resolution, the discovery that potential users are often not using the highest resolution already available, nor using conventional image processing techniques, was surprising. This motivated the present work.

Kanefsky, Bob↗

Operator Localization of Virtual Objects

Errors in the localization of nearby virtual objects presented via see-through, helmet mounted displays are examined as a function of viewing conditions and scene content. Monocular, biocular or stereoscopic presentation of the virtual objects, accommodation (required focus), subjects'age, and the position of physical surfaces are examined. Nearby physical surfaces are found to introduce localization errors that differ depending upon the other experimental factors. The apparent physical size and transparency of the virtual objects and physical surfaces respectively are also influenced by their relative position when superimposed. Design implications are discussed.

Ellis, Stephen R.↗

Localization of Virtual Objects in the Near Visual Field (Operator Interaction with Simple Virtual Objects)

Errors in the localization of nearby virtual objects presented via see-through, helmet mounted displays are examined as a function of viewing conditions and scene content in four experiments using a total of 38 subjects. Monocular, biocular or stereoscopic presentation of the virtual objects, accommodation (required focus), subjects' age, and the position of physical surfaces are examined. Nearby physical surfaces are found to introduce localization errors that differ depending upon the other experimental factors. These errors apparently arise from the occlusion of the physical background by the optically superimposed virtual objects. But they are modified by subjects' accommodative competence and specific viewing conditions. The apparent physical size and transparency of the virtual objects and physical surfaces respectively are influenced by their relative position when superimposed. The design implications of the findings are discussed in a concluding section.

Ellis, Stephen R.↗

The Enantiomeric Ratios of Meteoritic Organic Compounds: Their Possible Roles in the Origin of Life

This talk will give an overview of the enantiomer (mirror-image) ratios of organic compounds in meteorites and also describe the results of the present work in my lab. The primary focus will be on sugar derivatives (sugar acids) of carbonaceous meteorites. Our work begins to address questions associated with chirality, i.e., the origins of homochirality. On Earth, biological monomers (amino acids, sugars, etc.) are usually found with one of the enantiomers more abundant than the other. However, biological polymers (proteins, nucleic acids, etc.) are only composed of one enantiomer i.e., they are homochiral. There are hints in meteorites that some organic molecules may also exist in homochiral forms. The talk will address questions such as: did extraterrestrial sources aid in the beginning of this homochirality? Do the increasing size and apparent enantiomer excesses of some meteoritic compounds also extend to larger meteoritic compounds and polymers?

Cooper, George↗