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At least 73 records · Page 4

SiC Fiber-Reinforced Celsian Composites

Celsian is a promising matrix material for fiber-reinforced composites for high temperature structural applications. Processing and fabrication of small diameter multifilament silicon carbide tow reinforced celsian matrix composites are described. Mechanical and microstructural properties of these composites at ambient and elevated temperatures are presented. Effects of high-temperature exposures in air on the mechanical behavior of these composites are also given. The composites show mechanical integrity up to ~1100 C but degrade at higher temperatures in oxidizing atmospheres. A model has been proposed for the degradation of these composites in oxidizing atmospheres at high temperatures.

Bansal, Narottam P.↗

Cryogenic Insulation Standard Data and Methodologies Project

Extending some recent developments in the area of technical consensus standards for cryogenic thermal insulation systems, a preliminary Inter-Laboratory Study of foam insulation materials was performed by NASA Kennedy Space Center and LeTourneau University. The initial focus was ambient pressure cryogenic boil off testing using the Cryostat-400 flat-plate instrument. Completion of a test facility at LETU has enabled direct, comparative testing, using identical cryostat instruments and methods, and the production of standard thermal data sets for a number of materials under sub-ambient conditions. The two sets of measurements were analyzed and indicate there is reasonable agreement between the two laboratories. Based on cryogenic boiloff calorimetry, new equipment and methods for testing thermal insulation systems have been successfully developed. These boiloff instruments (or cryostats) include both flat plate and cylindrical models and are applicable to a wide range of different materials under a wide range of test conditions. Test measurements are generally made at large temperature difference (boundary temperatures of 293 K and 78 K are typical) and include the full vacuum pressure range. Results are generally reported in effective thermal conductivity (ke) and mean heat flux (q) through the insulation system. The new cryostat instruments provide an effective and reliable way to characterize the thermal performance of materials under subambient conditions. Proven in through thousands of tests of hundreds of material systems, they have supported a wide range of aerospace, industry, and research projects. Boiloff testing technology is not just for cryogenic testing but is a cost effective, field-representative methodology to test any material or system for applications at sub-ambient temperatures. This technology, when adequately coupled with a technical standards basis, can provide a cost-effective, field-representative methodology to test any material or system for applications at sub-ambient to cryogenic temperatures. A growing need for energy efficiency and cryogenic applications is creating a worldwide demand for improved thermal insulation systems for low temperatures. The need for thermal characterization of these systems and materials raises a corresponding need for insulation test standards and thermal data targeted for cryogenic-vacuum applications. Such standards have a strong correlation to energy, transportation, and environment and the advancement of new materials technologies in these areas. In conjunction with this project, two new standards on cryogenic insulation were recently published by ASTM International: C1774 and C740. Following the requirements of NPR 7120.10, Technical Standards for NASA Programs and Projects, the appropriate information in this report can be provided to the NASA Chief Engineer as input for NASA's annual report to NIST, as required by OMB Circular No. A-119, describing NASA's use of voluntary consensus standards and participation in the development of voluntary consensus standards and bodies.

Technology Portfolio System↗

Radiation effects on selected electronics parts from the solar max satellite

The Solar Maximum Satellite was launched on February 14, 1980. Problems with the Main Electronics Box (MEB) were experienced in the period July 10 to September 30, 1980. Failure occurred in the October to November time frame. Replacement of the Main Electronic Box (MEB) was performed in April 1984. The failed original MEB was returned to Earth and offered an opportunity to study some electronic parts which had spent 50 months in the natural radiation environment of a low Earth orbit (LEO) spacecraft. Spare parts were annealed at ambient temperatures on the ground. Dose rate effects between the flight and laboratory environments were compared.

R H Maurer↗

Effects of microgravity on urinary osteopontin

Increased risk of renal stone formation during space flight has been linked primarily to increased calcium excretion from bone demineralization induced by space flight. Other factors contributing to increased risk include increased urinary calcium oxalate supersaturation, while urinary citrate, magnesium and volume are all decreased. The aim of this study was to increase the predictive value of stone risk profiles for crew members during space flight by evaluating the excretion of urinary protein inhibitors of calcium crystallization so that more comprehensive stone risk profiles could relate mineral saturation to the concentrations of inhibitor proteins. Levels of urinary osteopontin (uropontin) are reported in a series of 14 astronauts studied before, during, and after space flights. During space flight, a compensatory increase in uropontin excretion was not observed. However, the uropontin excretion of a majority of astronauts was increased during the period after space flight and was maximal at 2 wk after landing. The downward shift in the molecular size of uropontin observed in samples obtained during space flight was shown to result from storage at ambient temperature during flight, rather than an effect of microgravity on uropontin synthesis.

NASA Experiment Number 9401651↗

Two-dimensional thermal modeling of power monolithic microwave integrated circuits (MMIC's)

Numerical simulations of the two-dimensional temperature distributions for a typical GaAs MMIC circuit are conducted, aiming at understanding the heat conduction process of the circuit chip and providing temperature information for device reliability analysis. The method used is to solve the two-dimensional heat conduction equation with a control-volume-based finite difference scheme. In particular, the effects of the power dissipation and the ambient temperature are examined, and the criterion for the worst operating environment is discussed in terms of the allowed highest device junction temperature.

Fan, Mark S.↗

Thermal Insulation System for Non-Vacuum Applications Including a Multilayer Composite

The thermal insulation system of the present invention is for non-vacuum applications and is specifically tailored to the ambient pressure environment with any level of humidity or moisture. The thermal insulation system includes a multilayered composite including i) at least one thermal insulation layer and at least one compressible barrier layer provided as alternating, successive layers, and ii) at least one reflective film provided on at least one surface of the thermal insulation layer and/or said compressible barrier layer. The different layers and materials and their combinations are designed to provide low effective thermal conductivity for the system by managing all modes of heat transfer. The thermal insulation system includes an optional outer casing surrounding the multilayered composite. The thermal insulation system is particularly suited for use in any sub-ambient temperature environment where moisture or its adverse effects are a concern. The thermal insulation system provides physical resilience against damaging mechanical effects including compression, flexure, impact, vibration, and thermal expansion/contraction.

Fesmire, James E.↗

Laminar Diffusion Flame Studies (Ground- and Space-Based Studies)

Laminar diffusion flames are of interest because they provide model flame systems that are far more tractable for analysis and experiments than more practical turbulent diffusion flames. Certainly, understanding flame processes within laminar diffusion flames must precede understanding these processes in more complex turbulent diffusion flames. In addition, many properties of laminar diffusion flames are directly relevant to turbulent diffusion flames using laminar flamelet concepts. Laminar jet diffusion flame shapes (luminous flame boundaries) have been of particular interest since the classical study of Burke and Schumann because they are a simple nonintrusive measurement that is convenient for evaluating flame structure predictions. Thus, consideration of laminar flame shapes is undertaken in the following, emphasizing conditions where effects of gravity are small, due to the importance of such conditions to practical applications. Another class of interesting properties of laminar diffusion flames are their laminar soot and smoke point properties (i.e., the flame length, fuel flow rate, characteristic residence time, etc., at the onset of soot appearance in the flame (the soot point) and the onset of soot emissions from the flame (the smoke point)). These are useful observable soot properties of nonpremixed flames because they provide a convenient means to rate several aspects of flame sooting properties: the relative propensity of various fuels to produce soot in flames; the relative effects of fuel structure, fuel dilution, flame temperature and ambient pressure on the soot appearance and emission properties of flames; the relative levels of continuum radiation from soot in flames; and effects of the intrusion of gravity (or buoyant motion) on emissions of soot from flames. An important motivation to define conditions for soot emissions is that observations of laminar jet diffusion flames in critical environments, e.g., space shuttle and space station facilities, cannot involve soot emitting flames in order to ensure that test chamber windows used for experimental observations are not blocked by soot deposits, thereby compromising unusually valuable experimental results. Another important motivation to define conditions where soot is present in diffusion flames is that flame chemistry, transport and radiation properties are vastly simplified when soot is absent, making such flames far more tractable for detailed numerical simulations than corresponding soot-containing flames. Motivated by these observations, the objectives of this phase of the investigation were as follows: (1) Observe flame-sheet shapes (the location of the reaction zone near phi=1) of nonluminous (soot free) laminar jet diffusion flames in both still and coflowing air and use these results to develop simplified models of flame-sheet shapes for these conditions; (2) Observe luminous flame boundaries of luminous (soot-containing) laminar jet diffusion flames in both still and coflowing air and use these results to develop simplified models of luminous flame boundaries for these conditions. In order to fix ideas here, maximum luminous flame boundaries at the laminar smoke point conditions were sought, i.e., luminous flame boundaries at the laminar smoke point; (3) Observe effects of coflow on laminar soot- and smoke-point conditions because coflow has been proposed as a means to control soot emissions and minimize the presence of soot in diffusion flames.

Dai, Z.↗

Foreign Object Damage Behavior of a SiC/SiC Composite at Ambient and Elevated Temperatures

Foreign object damage (FOD) behavior of a gas-turbine grade SiC/SiC ceramic matrix composite (CMC) was determined at 25 and 1316 C, employing impact velocities from 115 to 440 meters per second by 1.59-mm diameter stell-ball projectiles. Two different types of specimen support were used at each temperature: fully supported and partially supported. For a given temperature, the degree of post-impact strength degradation increased with increasing impact velocity, and was greater in a partially supported configuration than in a fully supported one. The elevated-temperature FOD resistance of the composite, particularly under partially supported loading at higher impact velocities greater than or equal to 350 meters per second, was significantly less than the ambient-temperature counterpart, attributed to a weakening effect of the composite. For fully supported loading, frontal contact stress played a major role in generating composite damage; whereas, for partially supported loading, both frontal contact and backside bending stresses were combined sources of damage generation. The SiC/SiC composite was able to survive higher energy impacts without complete structural failure but suffered more strength affecting damage from low energy impacts than AS800 and SN282 silicon nitrides.

Bhatt, Ramakrishna T.↗

Cryogenic Storage Tank Non-Destructive Evaluation

This slide presentation reviews the work in non-destructive evaluation (NDE) of cryogenic storage tanks. Four large cryogenic tanks, constructed in 1965 with perlite insulation in the annular regions, are of concern. The construction of the tanks, two Liquid Oxygen (LOX) and two Liquid Hydrogen (LH2), are described. The loss rate for the LOX tank at Pad A is slightly higher than that for the one at Pad B. The concerns for the LH2 tank at Pad B are that there is a significantly higher boil-off rate than that at Pad A, that there is mold growth, indicative of increased heat flow, that there is a long down-time needed for repairs, and that 3 of 5 full thermal cycles have been used on the Pad B LH2 tank. The advantages and disadvantages of thermal imaging are given. A detailed description of what is visible of the structures in the infra-red is given and views of the thermal images are included. Missing Perlite is given as the probable cause of the cold spot on the Pad B LH2 tank. There is no indications of problematic cold regions on the Pad A LH2 tank, as shown by the thermal images given in the presentation. There is definite indication of a cold region on the Pad A LOX tank. There is however concerns with thermal imaging, as thermal images can be significantly effected by environmental conditions, image differences on similar days but with different wind speeds. Other effects that must be considered include ambient temperature, humidity levels/dew, and cloud reflections

Arens, Ellen↗

Digital control of diode laser for atmospheric spectroscopy

A system is described for remote absorption spectroscopy of trace species using a diode laser tunable over a useful spectral region of 50 to 200 cm(-1) by control of diode laser temperature over range from 15 K to 100 K, and tunable over a smaller region of typically 0.1 to 10 cm(-1) by control of the diode laser current over a range from 0 to 2 amps. Diode laser temperature and current set points are transmitted to the instrument in digital form and stored in memory for retrieval under control of a microprocessor during measurements. The laser diode current is determined by a digital to analog converter through a field effect transistor for a high degree of ambient temperature stability, while the laser diode temperature is determined by set points entered into a digital to analog converter under control of the microprocessor. Temperature of the laser diode is sensed by a sensor diode to provide negative feedback to the temperature control circuit that responds to the temperature control digital to analog converter.

Menzies, R. T.↗

Response of cloud supersaturation to radiative forcing

Time-dependent solutions are obtained for droplet temperatures and supersaturation, in a study of the diffusional growth or evaporation of cloud droplets due to net emission or absorption of radiation, taking into account the partitioning of the net radiation budget between the droplets and the ambient air. Radiative perturbations are noted to result in very high rates of change in droplet temperatures. As the droplets evaporate or grow due to radiative effects, the saturation ratio of the ambient air adjusts in keeping with changes in the water vapor density and temperature of the air.

Davies, R.↗

Effects of thermal and environmental exposure on the mechanical properties of graphite/polyimide composites.

Composites were exposed in circulating and static air environments up to 600 F for a maximum of 1000 hours. Composites of HT-S, HM-S, Thornel 50S, and Fortafil 5-Y fiber and a new addition type polyimide resin were laminated in a matched-die mold. Flexural strength, flexural modulus, and interlaminar shear strengths were determined at 75, 500 and 600 F after various durations of exposure. Composite and fiber weight loss characteristics were determined by isothermal gravimetric analysis in air. Properties of composites exposed and tested at the environment temperatures are compared with those determined under short-term exposure. A new short beam interlaminar shear fixture is described. Environmental effects of long-term (up to one year) ambient temperature exposure on the elevated temperature mechanical properties of graphite/polyimide composites are presented.

Hanson, M. P.↗

Liquid oxygen-compatible filament-winding matrix resin

Polyurethanes derived from hydroxy terminated polyperfluoro propylene oxide prepolymers were evaluated as matrix resins for filament wound composites which would be exposed to liquid (and 100% gaseous) oxygen environments. A number of structural modifications were brought about by variations in prepolymer molecular weight, and alternative curing agents which allowed retention of the oxygen compatibility. Although satisfactory performance was achieved at sub-ambient temperatures, the derived composites suffered considerable property loss at ambient or slightly elevated temperatures. To attain overall effectiveness of the composite system, upgrading of the polymer thermomechanical properties must first be achieved.

Harrison, E. S.↗

Experimental evaluation of the tensor polynomial failure criterion for the design of composite structures

The experimental measures and techniques are described which are used to obtain the strength tensor components, including cubic terms. Based on a considerable number of biaxial pressure tests together with specimens subjected to a constant torque and internal pressure, a modified form of the plane stress tensor polynomial failure equation was obtained that was capable of predicting ultimate strength results well. Preliminary data were obtained to determine the effect of varying post cure times and ambient temperatures (-80 F to 250 F) on the change in two tensor strength terms, F sub 2 and F sub 22. Other laminate configurations yield corresponding variations for the remaining strength parameters.

Tennyson, R. C.↗

Alcohol cold starting - A theoretical study

Two theoretical computer models have been developed to study cold starting problems with alcohol fuels. The first model, a droplet fall-out and sling-out model, shows that droplets must be smaller than 50 microns to enter the cylinder under cranking conditions without being slung-out in the intake manifold. The second model, which examines the fate of droplets during the compression process, shows that the heat of compression can be used to vaporize small droplets (less than 50 microns) producing flammable mixtures below freezing ambient temperatures. While droplet size has the greater effect on startability, a very high compression ratio can also aid cold starting.

Browning, L. H.↗

Transition to unstable ion flow in parallel electric fields

The stability of ionospheric O(+)-H(+) outflows accelerated by a nonambipolar parallel electric field is considered under conditions where the ion motion initially develops adiabatically and the ambient plasma is vertically stratified with an effective temperature that increases with altitude. Such conditions are expected near the bottom of the auroral acceleration region where ion and electron streaming instabilities first develop. It is shown for a particular equilibrium profile that the differentially accelerated ion flows become unstable within about 100 km from their entry point in the acceleration region. At O(+)/H(+) density ratios less than about 9, the instability is dominated by a violent H(+)-O(+) two-stream interaction which couples the O(+) and H(+) acoustic modes, and which mediates a transition to nonadiabatic acceleration. At higher altitudes and/or larger O(+)/H(+) density ratios, a much weaker resonant instability exists, which is driven by the relative drift between electrons and O(+) or H(+) ions. The results suggest that the H(+)-O(+) two-stream instability may be a viable mechanism for heating upflowing auroral ions.

Bergmann, R.↗

Advanced Catalysts for the Ambient Temperature Oxidation of Carbon Monoxide and Formaldehyde

The primary applications for ambient temperature carbon monoxide (CO) oxidation catalysts include emergency breathing masks and confined volume life support systems, such as those employed on the Shuttle. While Hopcalite is typically used in emergency breathing masks for terrestrial applications, in the 1970s, NASA selected a 2% platinum (Pt) on carbon for use on the Shuttle since it is more active and also more tolerant to water vapor. In the last 10-15 years there have been significant advances in ambient temperature CO oxidation catalysts. Langley Research Center developed a monolithic catalyst for ambient temperature CO oxidation operating under stoichiometric conditions for closed loop carbon dioxide (CO2) laser applications which is also advertised as having the potential to oxidize formaldehyde (HCHO) at ambient temperatures. In the last decade it has been discovered that appropriate sized nano-particles of gold are highly active for CO oxidation, even at sub-ambient temperatures, and as a result there has been a wealth of data reported in the literature relating to ambient/low temperature CO oxidation. In the shorter term missions where CO concentrations are typically controlled via ambient temperature oxidation catalysts, formaldehyde is also a contaminant of concern, and requires specially treated carbons such as Calgon Formasorb as untreated activated carbon has effectively no HCHO capacity. This paper examines the activity of some of the newer ambient temperature CO and formaldehyde (HCHO) oxidation catalysts, and measures the performance of the catalysts relative to the NASA baseline Ambient Temperature Catalytic Oxidizer (ATCO) catalyst at conditions of interest for closed loop trace contaminant control systems.

Nalette, Tim↗

Effect of temperature coupling on ozone depletion prediction

The effects of chlorine perturbations on both the temperature and the ozone distribution in the stratosphere have been studied using a simplified radiative-photochemical model. The model solves the hydrostatic equation for total density in a self-consistent manner as the temperature is changed. Radiative coupling is found to have a significant effect on both the thermal structure and the ozone distribution, particularly in the 35-50-km region. By increasing the ClX mixing ratio by 5.0 ppbv, the temperature in this region is decreased by 5 to 10 K with a slight increase below 30 km. The local ozone depletion around 40 km due to added ClX is smaller compared with the estimate made by keeping the temperature fixed to the ambient condition. However, the integrated effect of radiative coupling is to increase the calculated column ozone depletion by 15% to 25% in this model.

Chandra, S.↗