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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS2015

Solar Thermal Upper Stage Liquid Hydrogen Pressure Control Testing

High-energy cryogenic propellant is an essential element in future space exploration programs. Therefore, NASA and its industrial partners are committed to an advanced development/technology program that will broaden the experience base for the entire cryogenic fluid management community. Furthermore, the high cost of microgravity experiments has motivated NASA to establish government/aerospace industry teams to aggressively explore combinations of ground testing and analytical modeling to the greatest extent possible, thereby benefitting both industry and government entities. One such team consisting of ManTech SRS, Inc., Edwards Air Force Base, and Marshall Space Flight Center (MSFC) was formed to pursue a technology project designed to demonstrate technology readiness for an SRS liquid hydrogen (LH2) in-space propellant management concept. The subject testing was cooperatively performed June 21-30, 2000, through a partially reimbursable Space Act Agreement between SRS, MSFC, and the Air Force Research Laboratory. The joint statement of work used to guide the technical activity is presented in appendix A. The key elements of the SRS concept consisted of an LH2 storage and supply system that used all of the vented H2 for solar engine thrusting, accommodated pressure control without a thermodynamic vent system (TVS), and minimized or eliminated the need for a capillary liquid acquisition device (LAD). The strategy was to balance the LH2 storage tank pressure control requirements with the engine thrusting requirements to selectively provide either liquid or vapor H2 at a controlled rate to a solar thermal engine in the low-gravity environment of space operations. The overall test objective was to verify that the proposed concept could enable simultaneous control of LH2 tank pressure and feed system flow to the thruster without necessitating a TVS and a capillary LAD. The primary program objectives were designed to demonstrate technology readiness of the SRS concept at a system level as a first step toward actual flight vehicle demonstrations. More specific objectives included testing the pressure and feed control system concept hardware for functionality, operability, and performance. Valuable LH2 thermodynamic and fluid dynamics data were obtained for application to both the SRS concept and to future missions requiring space-based cryogen propellant management.

Moore, J. D.↗
NASA NTRS2003

Test Rig for Evaluating Active Turbine Blade Tip Clearance Control Concepts

Improved blade tip sealing in the high pressure compressor and high pressure turbine can provide dramatic improvements in specific fuel consumption, time-on-wing, compressor stall margin and engine efficiency as well as increased payload and mission range capabilities of both military and commercial gas turbine engines. The preliminary design of a mechanically actuated active clearance control (ACC) system for turbine blade tip clearance management is presented along with the design of a bench top test rig in which the system is to be evaluated. The ACC system utilizes mechanically actuated seal carrier segments and clearance measurement feedback to provide fast and precise active clearance control throughout engine operation. The purpose of this active clearance control system is to improve upon current case cooling methods. These systems have relatively slow response and do not use clearance measurement, thereby forcing cold build clearances to set the minimum clearances at extreme operating conditions (e.g., takeoff, re-burst) and not allowing cruise clearances to be minimized due to the possibility of throttle transients (e.g., step change in altitude). The active turbine blade tip clearance control system design presented herein will be evaluated to ensure that proper response and positional accuracy is achievable under simulated high-pressure turbine conditions. The test rig will simulate proper seal carrier pressure and temperature loading as well as the magnitudes and rates of blade tip clearance changes of an actual gas turbine engine. The results of these evaluations will be presented in future works.

Lattime, Scott B.↗
NASA NTRS2018

Helium Pressurization Modeling of the EDU Submerged Diffuser Using Thermal Desktop

NASA is currently working on developing its predictive modeling capabilities to support future missions that require long term storage of cryogenic propellants. Through the Evolvable Cryogenics project, Development and Validation of Analysis Tools (DVAT) task, both CFD and multi-node fluid modeling tools are being validated against to increase the following cryogenic fluid management technologies: Self-Pressurization, Pressure Control, Helium Pressurization, de-stratification, jet mixing, Tank and transfer line chill-down, tank filling and transfer. NASA is using previous and future micro-gravity experiments to validate both types of models. Recent activities include: Validation of the Tank Pressure Control Experiment (TPCE), Hydrogen and Helium pressurization, and Completion of the Zero Boil Off Tank (ZBOT) experiment on ISS. Future activities include validation of the ZBOT experiment with both CFD and multi-node analysis tools, validation of the Cryogenic Demonstration System of the Robotic Refueling Mission (RRM3).

low-gravity fluid modeling↗
NASA NTRSDate not supplied

Liquid Hydrogen and other Cryogenic Instrumentation Experience at NASA Glenn

NASA has learned extensive lessons on instrumentation of hydrogen systems during technology developments activities focused on the development of in-space cryogenic fluid management technologies. A subset of these lessons that are useful for aircraft and terrestrial applications using liquid hydrogen are presented to help disseminate the information learned. Discussion includes temperature, pressure, flow, and mass gauging options.

Liquid Hydrogen↗
DOE OSTI2020

Predicting and Managing Risk to Bats at Commercial Wind Farms using Acoustics

Bat populations in North America face novel threats from white-nose syndrome and widespread turbine-related mortality related to the rapidly expanding wind power industry in addition to long-standing pressures from habitat loss and degradation. Bats, unlike most small mammals, are long-lived and slow to reproduce, highlighting the importance of understanding and managing anthropogenic sources of mortality. My dissertation research used acoustic bat detectors to measure bat activity at commercial wind projects, predict patterns in risk, and design strategic measures to reduce fatality rates by curtailing turbine operation during periods when bats are most active. Bats collide with wind turbines only when their rotors are spinning, and risk of turbine-related fatality is therefore a dynamic factor that can be manipulated by curtailing turbine operation when bats are active. We first measured inter-detector variation in metrics of acoustic bat activity to understand how the acoustic detection process may affect inferences related to spatial and temporal variation in bat activity. Using acoustic detectors mounted on top of wind turbines at two commercial wind farms in West Virginia, we then demonstrated that the amount of bat activity recorded when turbines were operating aligned closely with bat fatality rates on multiple scales. Accordingly, the metric of bat activity exposed to turbine operation provides a meaningful, quantitative indicator of turbine-related bat fatality risk. Further, bats responded consistently to changing wind speed and temperature at turbines in both wind farms across multiple years, enabling exposed bat activity to be predicted accurately among turbines and years. Building on these results, we simulated exposure of bats to turbine operation and energy loss for curtailment strategies recommended by state and federal agencies in the United States and Canada. By adjusting parameters such as cut-in wind speeds and temperature thresholds, we demonstrated the ability to design strategic curtailment programs that achieve equivalent or greater predicted reductions in bat activity exposure for substantially less energy-production loss. Characterizing fatality risk on a finer scale using acoustics will help regulatory agencies and the wind industry alike reduce risks of population-level impacts to vulnerable bat species while continuing to expand large-scale renewable energy generation.

17 WIND ENERGY↗
DOE OSTI2022

Geothermal Hydraulic Stimulation: Overview of Methods and Best Practices

This paper outlines important information related to the hydraulic stimulation of geothermal wells and considerations for regulators responsible for evaluating applications to conduct these operations. Hydraulic stimulation applied to geothermal wells is an evolving technology that is different from the hydraulic fracturing process widely used to complete unconventional oil and gas wells. Important differences relate to operating pressures, variations in rock and fracture processes, and characteristics and disposal of hydraulic fracture fluids. Hydraulic stimulation is not widely used in the geothermal industry; however, future development of enhanced geothermal systems (EGS) will require hydraulic stimulation in order to enhance and create fracture permeability to allow wells to deliver sufficient heat and fluid to power plants. Gigawatts of EGS potential have been identified (U.S. Department of Energy 2019), so it is expected that the use of hydraulic stimulation of geothermal wells will be more common in the future. At present, there are no formal regulations guiding drilling programs or sundry notices that propose hydraulic stimulation of geothermal wells. On federal lands, important constraints and oversight are embedded in the process for obtaining Geothermal Drilling Permits outlined in the Code of Federal Regulations (43 CFR Section 3262.11); in Geothermal Resource Order 2 (GRO 2) guidance for assessment and mitigation of impacts of geothermal operations as well as construction and testing of geothermal wells; and in a Bureau of Land Management (BLM) Induced Seismicity Instruction Memorandum (BLM 2018). Additionally, local knowledge from BLM field offices and expertise of BLM engineers, or that of state regulators for operations on private and state lands, will be applied to fully assess operator applications to conduct geothermal hydraulic stimulation activities. Significant research effort has been directed toward EGS, so geothermal hydraulic stimulation techniques, impacts, and results are evolving and becoming better understood, including adaptation of decades of oil and gas industry experience with hydraulic fracturing of unconventional reservoirs. Recent EGS activities in the United States provide details about hydraulic stimulation with respect to oversight, stimulation design, execution, and results. Based on experience to date, the important issues to address when hydraulically stimulating a geothermal well include the following: 1. Wellbore construction and integrity must be appropriate to protect groundwater and manage stimulation pressures. 2. Understanding of lithology, faults, fractures, and subsurface stress state is necessary to design stimulation plans and predict results. 3. Seismic monitoring allows for observation and mitigation of induced seismicity.

geothermal↗
NASA NTRS2019

Monolithic Trace-Contaminant Sorbents Fabricated from 3D-Printed Polymer Precursors

The current trace-contaminant (TC) removal technology for use in Extravehicular Activities (EVAs) involves the use of a packed bed of acid-impregnated granular charcoal, which is difficult to regenerate. In this paper, results are presented on the development of vacuum-regenerable TC sorbents for use in the Portable Life Support System (PLSS). The sorbents are derived from 3D-printed polymer monoliths (e.g., honeycomb structures), which are then carbonized and activated in order to develop porosity, and also to enhance the TC-sorption capacity. Results are presented on the following aspects of carbon-sorbent development: (1) precursor selection; (2) monolith fabrication; (3) shape retention and strength; (4) carbon surface and porosity characterization; (5) TC-sorption capacity and vacuum-regeneration; (6) pressure drop; and (7) sub-scale sorbent prototype. The use of predominantly microporous monolithic carbon is associated with the following benefits: (a) high TC-sorption capacity; (b) low pressure drop; (c) rapid vacuum (pressure-swing) desorption due to thin monolith walls and low pressure drop; (d) good thermal management (high thermal conductivity and low adsorption/desorption thermal effects associated with physisorption); and (e) good resistance to dusty environments.

Portable Life Support System (PLSS)↗
DOE OSTI2024

Managing Subsurface Pressure Buildup and Interference in Commercial-Scale CO 2 Storage Project with Proximal Injection Wells

Large-scale decarbonization using carbon capture and storage (CCS) is likely to involve many commercial-scale CO 2 storage projects located in close proximity to each other. This close proximity raises concerns over pressure interference among the storage projects. Pressure interference between injection and storage efforts can reduce the practicable CO 2 storage resource and force wells to inject CO 2 at a lower rate to avoid the fracture pressure thresholds per United States Environmental Protection Agency (EPA) Class VI well regulations to preserve injection and confining zone integrity and potentially mitigate against inducing seismic activity. These analyses employ numerical full-physics reservoir modeling to evaluate how pressure buildup fronts and CO 2 plumes evolve under commercial-scale injection volumes of CO 2 in which multiple storage sites located in close proximity occur in tandem. The simulation models mimic injection at pseudo basin-scale and assume homogeneous saline formation(s) as storage targets with a pair of upper and lower homogeneous seal layer/s. These analyses specifically investigate the efficacy of two basin-wide reservoir pressure management strategies in addressing the technical challenges associated with pressure buildup and CO 2 plume commingling. The strategies explored include: 1) enlarging the area of injection well spacing (WS) and 2) storing CO 2 in a stacked sequence (SSS) of saline formations compared to a single formation. The storage and confining zones properties assumed were held common across the scenarios, unless specified otherwise. Analyses results show that after injecting 4 million tons per year for 30 years using 4 separate wells (each injecting 1 million metric tons per year), the radius of CO 2 plume extends to a mere 3 km or less from injection wells. Meanwhile, the radius of pressure buildup ranges on the order of tens to a few hundreds of kilometers, depending on the magnitude of pressure buildup threshold that one would use to define the front. CO 2 plume commingling from different injection wells appears to occur 50 years post-injection, especially under scenarios with narrowly spaced (i.e., < 5 km apart) injection well locations. Findings from sensitivity cases on the well spacing suggest that storage formations modeled would require different well spacing to avoid fracture pressure thresholds. For instance, modeled storage formations with high fracture gradients (i.e., 0.8 psi/ft) would need less than 5–km well spacing, whereas those with lower fracture gradients (i.e., 0.7 psi/ft) would need approximately 20–km well spacing, based on assumed modeling parameters. Under stacked injection, the pressure challenges (described above) still exist but are more alleviated due to distributing the same injection volume across more available reservoir volume. These analyses demonstrate that stacked-sequence storage can effectively address the challenges, while still providing the same target CO 2 storage volumes and allowing a large number of storage projects to be deployed in the same basin by better utilizing the available storage resource across different reservoir depths. Among cases modeled, the resulting pressure buildup front is most suppressed when each storage project distributes injection volumes over several wells, each of which injects a portion of the total CO 2 across the stacked sequence. This strategy results in the smallest CO 2 aerial footprint amongst scenarios evaluated but also shows the largest reduction in the pressure buildup at the top of perforation at the injection wells (upwards of approximately 42 percent compared to the commercial-scale single-formation storage), the result of which is crucial to maintain caprock integrity. The findings presented by this research draw attention to the importance of greater coordination among storage operators and regulatory stakeholders to foster the upscaling and deployment of CCS. These analyses provide insights into required decision-making when considering multi-project deployment in a shared basin. Because these analyses evaluate a very specific geologic situation, they bear further investigations across other geologic situations.

42 ENGINEERING↗
DOE OSTI2021

NETL Well Integrity Workshop: Identifying Well Integrity Research Needs for Subsurface Energy Infrastructure

Wells are a critical component of subsurface energy infrastructure. Ensuring the integrity of wells as engineered pathways for the safe extraction, injection, and storage of fluids in the subsurface is key to maximizing the effectiveness and resilience of that infrastructure. Addressing well integrity issues in a technically robust manner that promotes environmental sustainability and social equity is also an important focus of the United States (U.S.) Department of Energy’s (DOE) Office of Fossil Energy and Carbon Management. Industry best practices, regulatory standards, modern monitoring data acquisition and control systems, and decades of research and development have dramatically improved the performance and reliability of wells for hydrocarbon extraction and underground injection in the oil and gas industry. Yet, important innovation is required to improve and ensure well integrity performance in engineered geologic systems where operational environments (fluid composition, temperature, pressure, and/or stress conditions) and long functional life cycles of well systems present unique challenges. Additionally, work is needed to understand and manage the long-term integrity and risks associated with legacy wells—especially those located adjacent to and presenting hazards for new subsurface activity.

02 PETROLEUM↗
DOE OSTI2021

NRAP-Open-IAM Multisegmented Wellbore Reduced-Order Model

Geologic carbon storage is one of the promising strategies to mitigate climate change by reducing the emission of carbon dioxide to the atmosphere. As part of the National Risk Assessment Partnership (NRAP), a systems-level stochastic analysis tool called the open source integrated assessment model, NRAP-Open-IAM, has been developed to estimate and manage the risk of containment loss at a geological carbon sequestration site. NRAP-Open-IAM contains several wellbore leakage model components that estimate the fluid leak rate that may occur through compromised legacy wells due to the increase in pressure resulting from CO 2 injection activities. Coupled to a reservoir component model, these components estimate the leakage of CO 2 and/or brine from a storage reservoir to overlying aquifer layers and the atmosphere through legacy wells. This report presents the theoretical framework and quality testing of the multisegmented wellbore reduced-order model. The model allows for segmenting of the legacy wells passing through the overlying stratigraphy into several intervals to simulate a site’s specific stratigraphic and hydrogeologic properties. For quality assurance, the analytical model is validated against numerical reservoir flow simulations for single and multiple aquifer(s) models. The results indicate that the model accurately predicts the transport of two-phase fluids (brine and injected CO 2 ) through the well over time. A detailed description of the model helps users to understand the model and provides a basis for future improvements.

58 GEOSCIENCES↗
NASA NTRS2009

Survey of Software Problems with Impacts to 'Campout' Protocol Extravehicular Activity (EVA) Prebreathe

During International Space Station campout protocol ExtraVehicular Activity (EVA) preparations, the crew is isolated overnight in the small airlock volume in a reduced pressure, oxygen enriched atmosphere. As such, there are special considerations for the software in terms of air composition, pressure control and emergency responses. For one, the ISS software must monitor and manage two distinct atmospheres. Also, the small airlock volume is especially sensitive to small changes in the environment, and what would be a minor emergency in the larger vehicle volume can have catastrophic results in the isolated airlock. Finally, in cases of emergency, the crew needs to rapidly egress the airlock, which requires an aggressive automatic repressurization to equalize pressure on the hatch. This paper will describe the software which is modified for the airlock campout protocol. In addition, the paper will describe the software problems and hardware problems with software workarounds which have affected campout protocol.

Diderich, Greg↗
NASA NTRS2002

Demonstration of a Spoken Dialogue Interface for Planning Activities of a Semi-autonomous Robot

Planning and scheduling in the face of uncertainty and change pushes the capabilities of both planning and dialogue technologies by requiring complex negotiation to arrive at a workable plan. Planning for use of semi-autonomous robots involves negotiation among multiple participants with competing scientific and engineering goals to co-construct a complex plan. In NASA applications this plan construction is done under severe time pressure so having a dialogue interface to the plan construction tools can aid rapid completion of the process. But, this will put significant demands on spoken dialogue technology, particularly in the areas of dialogue management and generation. The dialogue interface will need to be able to handle the complex dialogue strategies that occur in negotiation dialogues, including hypotheticals and revisions, and the generation component will require an ability to summarize complex plans. This demonstration will describe a work in progress towards building a spoken dialogue interface to the EUROPA planner for the purposes of planning and scheduling the activities of a semi-autonomous robot. A prototype interface has been built for planning the schedule of the Personal Satellite Assistant (PSA), a mobile robot designed for micro-gravity environments that is intended for use on the Space Shuttle and International Space Station. The spoken dialogue interface gives the user the capability to ask for a description of the plan, ask specific questions about the plan, and update or modify the plan. We anticipate that a spoken dialogue interface to the planner will provide a natural augmentation or alternative to the visualization interface, in situations in which the user needs very targeted information about the plan, in situations where natural language can express complex ideas more concisely than GUI actions, or in situations in which a graphical user interface is not appropriate.

Dowding, John↗
NASA NTRS2015

Zero Boil-Off System Testing

Cryogenic propellants such as liquid hydrogen (LH2) and liquid oxygen (LO2) are a part of NASA's future space exploration plans due to their high specific impulse for rocket motors of upper stages. However, the low storage temperatures of LH2 and LO2 cause substantial boil-off losses for long duration missions. These losses can be eliminated by incorporating high performance cryocooler technology to intercept heat load to the propellant tanks and modulating the cryocooler temperature to control tank pressure. The technology being developed by NASA is the reverse turbo-Brayton cycle cryocooler and its integration to the propellant tank through a distributed cooling tubing network coupled to the tank wall. This configuration was recently tested at NASA Glenn Research Center in a vacuum chamber and cryoshroud that simulated the essential thermal aspects of low Earth orbit, its vacuum and temperature. This test series established that the active cooling system integrated with the propellant tank eliminated boil-off and robustly controlled tank pressure.

Reverse turbo-Brayton cycle↗
NASA NTRSDate not supplied

Cryogenic Fluid Management Using CFD - Development and Applications

The Fluid Dynamics Branch has positioned itself to support a wide range of customers in need of Cryogenic Fluid Management (CFM) analysis. A computational fluid dynamics (CFD) tool used for all manner of internal and external propulsion applications has been extended and refined to better model cryogenic propellant storage and tanking operations. Through the CFM Portfolio project, several validation activities were initiated. Validation of propellant tank self-pressurization, autogenous pressurization, slosh-induced ullage collapse, and jet-induced mixing all aid in defining model accuracy. The on-going validation effort has enabled confident application of the tool to in-line design and evaluation of CFM hardware and operations. Recent project support included design of no-vent fill operations using various techniques for the Human Landing System (HLS). Propellant transfer dynamics were predicted to ensure complete propellant delivery. Many more activities in support of HLS and other projects and programs were supported. The branch has engaged the CFM community to share recent findings and capabilities through conferences. To reach the wider community, a consolidation of fundamental findings from work on in-space pulsed settling maneuvers was distilled in an AIAA paper. Development and demonstration of CFM modeling capabilities continues in order to meet the needs of the agency and its industry partners in the endeavor to sustainably reach the Moon and beyond.

Jacob Brodnick↗
NASA NTRSDate not supplied

Updated Analysis of the Trash Compaction and Processing System: Water Collected from Trash, Evaluation of the Source Contaminant Control System, and Zotek® F30 Foam Processing

The Trash Compaction and Processing System (TCPS) aims to reduce volume, biologically safen, physically stabilize, manage effluents, and recover resources from astronaut trash in the International Space Station (ISS). At NASA Ames Research Center (ARC), there are two test systems: the Heat Melt Compactor (HMC), which compacts the trash into a tile with temperature and pressure, and the Source Contaminant Control System (SCCS), which is the gas management subsystem aimed to reduce contaminants by converting them into carbon dioxide (CO 2 ) and water (H 2 O) vapor. Both the HMC and SCCS serve as test systems that support TCPS development by conducting risk reduction activities associated with an ISS technology demonstration. In this paper, the risk reduction activities discussed are the testing of different trash models for operational scenarios in the HMC, investigating the water extracted from those trash models, and managing the gaseous effluents from the trash via contaminant conversion through the SCCS. The HMC has undergone several tests of different trash models and cases in which a containment bag is used or not. For the first topic, this paper will analyze the water collected and recovered from these tests and analyze the effect of specific trash containment bags. For the second topic, this paper will individually evaluate the carbon bed and catalytic oxidizer (CatOx) to understand what components the carbon bed removes and what contaminants are converted in the CatOx. For the third and final topic, this paper will discuss Zotek® F30 foam processing in the HMC unit and testing verification in correlation to defined TCPS requirements. A foam model was added to reduce the volume of foam that take up space in the ISS. Overall, this paper is a compilation and an updated analysis of tests conducted in the lab-scale TCPS at ARC within the past year.

TCPS↗
NASA NTRSDate not supplied

Validation of Cryogenic Propellant Tank Filling using Computational Fluid Dynamics Simulation

The Fluid Dynamics Branch at MSFC has positioned itself to support a wide range of customers in need of Cryogenic Fluid Management (CFM) analysis. A computational fluid dynamics (CFD) tool used for all manner of internal and external propulsion applications has been extended and refined to better model cryogenic propellant storage and tanking operations. Through the CFM Portfolio project, several validation activities were initiated. Validation of propellant tank self-pressurization, autogenous pressurization, slosh-induced ullage collapse, and jet-induced mixing all aid in defining model accuracy. The on-going validation effort has enabled confident application of the tool to in-line design and evaluation of CFM hardware and operations. Recent project support included defining the impact of in-space slosh dynamics on reaction control system mass for Space Launch System (SLS) upper stages. Propellant mixing strategies were defined to improve performance of a thermal vent system for a Commercial Lunar Payload Services (CLPS) partner. Design support of in-space maneuvers, tank hardware, and autogenous pressurization operations was also provided through Human Landing System (HLS) collaboration work. The branch has engaged the CFM community to share recent findings and capabilities through several forums including conferences, technical interchange meetings, and workshops. Development and demonstration of CFM modeling capabilities continues in this work on the no-vent fill of propellant tank in micro-gravity to meet the needs of NASA and its industry partners in the endeavor to sustainably reach the Moon and beyond.

CFD↗
DOE OSTI2022

EERC Final Topical Report – Findings on Subtask 3.2 – Produced Water Management Through Geologic Homogenization, Conditions, and Reuse

The Energy & Environmental Research Center (EERC) was awarded a contract by the North Dakota Industrial Commission (NDIC) Oil and Gas Research Program (NDIC No. G-051-101) to conduct a study on the recycling of water used in oil and gas operations, also known as produced water, from oil- and gas-producing regions of North Dakota as directed by Section 19 of North Dakota House Bill 1014. This final report provides a compilation of results of the study, which include regulatory, scientific, technological, and feasibility methods and considerations associated with North Dakota produced water management. The report provides a synopsis of this project’s previously submitted produced water assessment report entitled “Produced Water Management and Recycling Options in North Dakota” (Energy & Environmental Research Center, 2020), with updated values provided as appropriate. The report provides the results from the investigation of a novel produced water management strategy, referred to as geologic homogenization, conditioning, and reuse (GHCR), which aims to use a subsurface geologic formation as a natural medium for managing produced water recycling and reuse. Water management is a significant technical and economic challenge for sustainable oil and gas production, and water volumes are intrinsically linked to oil production volumes. North Dakota oil production rose to over 1.5 million barrels (MMbbl)/day in 2019, and despite a downturn in oil price in early 2020, North Dakota oil production has recovered to 1.1 MMbbl/day as of August 2021. Bakken petroleum system development between 2008 and 2020 has resulted in a nearly fourfold increase in produced water volumes to 642 MMbbl/yr in 2020 after peaking at 740 MMbbl/yr in 2019 and a fivefold increase in saltwater disposal (SWD) volumes to 565 MMbbl/yr in 2020 after a peak of 682 MMbbl/yr in 2019. Produced water and SWD volumes are forecasted to double by 2030. SWD is the primary method of produced water management used in North Dakota, with approximately 95% of the SWD volume occurring through subsurface injection into sandstones of the Dakota Group (Dakota). Localized pressurization of the Dakota resulting from SWD and projected increases in produced water volumes could impact the economics of North Dakota oil production. As a result, there is an emerging need to pursue alternative produced water management approaches, including recycling and reuse. While produced water recycling is not yet widespread, commercial operators are making strides in overcoming the technical challenges of using high salinity produced water in completion operations (Marathon Oil, 2020). As water management continues to be a key focal point in companies’ environmental, social, and governance (ESG) initiatives, focus on water management, including recycling, will likely continue to increase. Laboratory column testing, field sample collection, geologic modeling and numerical simulation, and techno-economic analysis all indicate that GHCR could feasibly be implemented as a potential water management option. Laboratory column testing and field sample collection indicate that the Inyan Kara sandstone and native formation fluid are capable of homogenizing with the Bakken produced water to a point where the fluid composition appears to stabilize. Extracting that stabilized fluid could be considered homogeneous and capable of providing individual batches of hydraulic fracturing fluid. Numerical simulation results indicate that extraction of fluids from the Inyan Kara in a GHCR implementation scenario is capable of reducing formation pressure, which would help ease localized pressurization of the Inyan Kara and extend the available capacity for nearby existing SWD wells. Economic analysis indicates that there are scenarios where GHCR implementation can be a competitive or even lower-cost option than a conventional water management approach. Site-specific conditions will dictate the economic potential of GHCR, but potentially attractive sites for GHCR implementation will be those that are located above a pressurized zone of the Inyan Kara, need six or more Bakken infill wells, and face high costs for conventional SWD and/or freshwater. Based on the regulatory review, drilling into the Inyan Kara for SWD and to harness as a source water for industrial use have precedent in North Dakota, and a workable regulatory solution for GHCR seems likely. However, restrictions in the state regarding surface storage and transport of produced fluids may limit some activities, which will affect how GHCR could ultimately be implemented. In summary, this study reveals pursuing GHCR can be a viable approach to water management in North Dakota. The GHCR concept addresses some of the challenges that hinder the more traditional approaches to recycling in the industry. Furthermore, an assessment of the current landscape of water management within the state reveals the ongoing trend of increasing volumes of produced water and SWD. Projections reveal that the volumes of produced water that need to be managed are expected to double over the next decade (Energy & Environmental Research Center, 2020). With the continued development of the Bakken and continuing driving factors related to ESG initiatives, implementing a practice such as GHCR is a feasible approach to adding recycling of produced water to industry within the state. This subtask was cofunded through the EERC–U.S. Department of Energy Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FE0024233. Nonfederal funding was provided by the North Dakota Industrial Commission Oil and Gas Research Program. References Energy & Environmental Research Center, 2020, Produced water management and recycling options in North Dakota: Final Report for North Dakota Legislative Management Energy Development and Transmission Committee and North Dakota Industrial Commission. Marathon Oil, 2020, Sustainability report: https://cdn.sanity.io/files/ghcnw9z2/website/ 91744eb6ef8fbe59505a911c6b8d2e8dd9a537fa.pdf?dl (accessed November 2021).

02 PETROLEUM↗
DOE OSTI2021

Vapor-Liquid Partitioning of Methylmercury Compounds: Fundamental Data to Support the Savannah River Site Liquid Waste System: Henry's Law, Solubility and Vapor Pressure Determination for Representative Methylmercury Compounds

The Savannah River Site (SRS) Liquid Waste System (LWS) contains approximately 66 tons of mercury within the liquids, salts, and sludges that are currently being processed into final wasteforms for disposal. Mercury concentrations within the system exceed those typically experienced in environmental or industrial systems; thus, management of mercury compounds continues to be a priority for SRS. In the LWS, waste is vitrified into a borosilicate glass wasteform that contains most of the radioactivity, while the lower activity solutions are dispositioned in a low-level grout wasteform, or “saltstone”. The alkaline, high ionic strength caustic wastes are pumped, evaporated, and otherwise managed throughout the LWS and Defense Waste Processing Facility (DWPF) as they are stored and prepared for conversion to the final wasteforms. Because of the complexity of this system, a key component of effective mercury management in the LWS requires analysis of mercury in various physical phases. The high concentration of mercury within the SRS LWS has the potential to generate vapor-phase contamination. Elemental mercury (Hg 0 ), dimethylmercury ((CH 3 ) 2 Hg), and methylmercury (CH 3 Hg + ) are among species known or suspected to contribute to the flux of mercury from liquid to vapor phase (Iverfeldt and Lindquist, 1982). Chemical speciation affects not only mercury behavior in LWS operations but may also affect the performance of mercury treatment and removal technologies in the LWS.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗