Gas analysis for LANL weapons surveillance
Gas analysis is performed at LANL as one part of weapons surveillance conducted to identify stockpile aging concerns and to predict the lifetime of weapon components and materials. These analyses include gas dissolved in and evolved from polymeric materials. Radiolysis and thermal decomposition of polymers are examples of processes which lead to gas production. These are accessed using canister aging studies with gas analysis typically performed using gas chromatography and gas chromatography/mass spectrometry. More recently we have developed methods to measure dissolved gases in polymeric materials suspect in the failure of potting materials. This talk provides a brief overview of recent work.