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At least 73 records · Page 4

Temperature sensitivity of Eppley broadband radiometers

Broadband radiometers manufactured by Eppley Laboratories Inc. are commonly used to measure irradiance from both ground-based and aircraft platforms. Namely, the pyranometer (Model PSP) measures irradiance in the .3 to 3.0 micron spectral region while the pyrgeometer (Model PIR) senses energy in the 4 to 50 micron region. The two instruments have a similar thermopile construction but different filters to achieve the appropriate spectral selection. During the fall of 1986, the First ISCCP (International Satellite Cloud Climatology Project) Regional Experiment (FIRE) commenced with the first cirrus Intensive Field Observation (IFO) conducted in Central Wisconsin. Due to the nature of this field project, pyranometers and pyrgeometers manufactured by Eppley were flown on NCAR's high altitude research aircraft, the Sabreliner. Inherent in the construction of these radiometers is temperature compensation circuitry designed to make the instrument sensitivity nominally constant over a temperature range from -20 to +40 C. Because the Sabreliner flew at high altitudes where temperatures were as cold as -70 C, it was necessary to determine the radiometers relative sensitivity to temperatures below -20 C and apply appropriate corrections to the FIRE radiation data set. A procedure to perform this calibration is outlined. It is meant to serve as a supplement to calibration procedures.

Smith, William L., Jr.↗

Pressure and Temperature Sensitive Paint Measurements on Rotors

Luminescent molecular probes imbedded in a polymer binder form a temperature or pressure paint. On excitation by light of the proper wavelength, the luminescence, which is quenched either thermally or by oxygen, is detected by a camera or photodetector. From the detected luminescent intensity, temperature and pressure can be determined. The basic photophysics, calibration, accuracy and time response of luminescent paints is described followed by applications in wind tunnels and in rotating machinery.

Sullivan, John↗

Temperature sensitivity of the equilibrium neutronics and accident analysis of the HTR-10

Pebble-Bed High-Temperature Gas-cooled Reactors (PB-HTGR) are moderated by the graphite in the fuel pebbles and the graphite reflector surrounding the pebble-bed. Because graphite is by far the most abundant material in PB-HTGRs and the primary moderator, accurate modeling of the graphite material, including density, impurities, and temperatures, is crucial for accurate computational modeling and simulation of these reactors. While main characteristics of the graphite components are often known, the local temperature is less well known and often averaged over all components. Here, this work studies the impact of considering accurate temperature profiles in the graphite material on the generation of a small PB-HTGR model at the state of equilibrium operation and on short-term accident progression. The fuel compositions for the PB-HTGR were determined using a jump-in equilibrium modeling method, the Axial Radial Zone Equilibrium Modeling (AR-ZEM) method. In contrast to previous work, the AR-ZEM method was used considering thermal-hydraulic feedback from the MELCOR code to determine temperatures of the fuel pebbles and the surrounding graphite reflector. The consideration of an axial and radial temperature profile in the core and reflector, as opposed to uniform material temperatures, had an impact of almost 1,300 pcm on the equilibrium core eigenvalue and caused significant differences in the discharged plutonium fuel inventory with up to 4.9% and 11.0% for Pu-239 and Pu-242, respectively. To assess the impact on short-term accident progression, two Anticipated Transient Without SCRAM (ATWS) events, a Pressurized Loss of Forced Coolant (PLOFC) and a Control Rod Withdrawal (CRW) with loss of flow, were simulated with MELCOR. The use of temperature profiles in the equilibrium core models did not reveal a significant impact on the temperature, power, or reactivity responses during the transients. In conclusion, a need for consideration of accurate temperature profiles, in particular for the graphite reflector, was found for the generation of equilibrium PB-HTGRs core models using jump-in methods, but detailed temperature profiles may not be necessary when performing conservative transient analysis.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Pressure Effects on the Temperature Sensitivity of Fiber Bragg Gratings

A 3-dimensional physical model was developed to relate the wavelength shifts resulting from temperature changes of fiber Bragg gratings (FBGs) to the thermal expansion coefficients, Young s moduli of optical fibers, and thicknesses of coating polymers. Using this model the Bragg wavelength shifts were calculated and compared with the measured wavelength shifts of FBGs with various coating thickness for a finite temperature range. There was a discrepancy between the calculated and measured wavelength shifts. This was attributed to the refractive index change of the fiber core by the thermally induced radial pressure. To further investigate the pressure effects, a small diametric load was applied to a FBG and Bragg wavelength shifts were measured over a temperature range of 4.2 to 300K.

Wu, Meng-Chou↗

The mean ozone profile and its temperature sensitivity in the upper stratosphere and lower mesosphere - An analysis of LIMS observations

Multiple simultaneous LIMS (Limb Infrared Monitor of the Stratosphere) observations of both O3 and temperature T in the upper stratosphere and lower mesosphere are analyzed to derive O3-T correlations for comparisons with model calculations. The zonally averaged O3 profile is compared with results from a simplified photochemical model that assumes O3 to be in a photochemical steady state. The model profile is systematically lower than the observed profile. Key parameters are identified in which changes can systematically increase the O3 profile in both the stratosphere and the mesosphere. The LIMS-derived values for the sensitivity of O3 to changes in T are compared with equilibrium model calculations which include the T-driven opacity feedback effect on photodissociation rate constants. The theoretical O3 response to temperature perturbations is investigated. It is shown how the O3-T sensitivity coefficient is affected by zonal and vertical advection terms as well as by the photochemical coupling between O3 and T.

Froidevaux, Lucien↗

Uncertainty in Reconstructing Paleo‐Elevation of the Antarctic Ice Sheet From Temperature‐Sensitive Ice Core Records

Paleotemperature reconstructions from ice cores are mixed signals of changes in climate and ice‐surface elevation. A common, temperature‐based paleoaltimetry method suggests these signals can be disentangled by comparing two proxy locations with similar climates. The difference between the records is assumed to be due to elevation, which is estimated by scaling the temperature difference by a lapse rate. We investigate the uncertainty associated with this approach using a case study of the Antarctic Ice Sheet during the Last Glacial Maximum. From an ensemble of climate simulations, we extract modeled temperatures at locations of real ice cores. We find uncertainty on the order of hundreds of meters that results from spatial heterogeneity in non‐adiabatic temperature change, which itself stems in part from elevation‐induced atmospheric circulation change. Our findings suggest that caution is needed when interpreting temperature‐based paleoaltimetry results for ice sheets.

58 GEOSCIENCES↗

Transition Detection at Cryogenic Temperatures Using a Carbon-Based Resistive Heating Layer Coupled with Temperature Sensitive Paint

This paper will highlight the development and application of a carbon-based resistive heating layer for use in transition detection at cryogenic temperatures at the National Transonic Facility (NTF) for full-flight Reynolds number testing. This study builds upon previous work that was successfully demonstrated at the 0.3-m Transonic Cryogenic Tunnel on a smaller-scale airfoil shape of regular geometry. However, the test performed at the NTF involved a semispan wing with complex geometry and significantly larger than previous tests. This required the development of new coatings to provide suitable resistances to provide adequate heating rates for transition detection. Successful implementation of this technology has the ability to greatly enhance transition detection experiments at cryogenic temperatures as well as reducing perturbation in the tunnel caused by more traditional transition detection methods.

Watkins, A. Neal↗

Evaluation of Brightness Temperature Sensitivity to Snowpack Physical Properties Using Coupled Snow Physics and Microwave Radiative Transfer Models

There are multiple existing microwave radiative transfer models (RTMs) to simulate the brightness temperature (Tb) of snowpacks. It is still challenging to have consistent Tb responses from RTMs due to individual physical formulations of the snowpack scattering process. This article examines three of the widely-used multi-layer RTMs: 1) the microwave emission model of layered snowpacks (MEMLS); 2) the dense media radiative transfer based on the quasi-crystalline approximation (QCA) of Mie scattering of densely packed sticky spheres (DMRTQMS); and 3) the Helsinki University of Technology (HUT) model. Interestingly, these models yield slightly different Tb responses when driven by the same physical snowpack properties. Tb variations, dependent on the choice of RTMs, are then evaluated to improve the understanding of model differences in microwave emission from a snowpack. We first perform a sensitivity study of the Tb predictions from the three RTMs as a function of snow grain sizes, densities, and depths. While Tb from all three RTMs decreases with increasing snow grain sizes, it is found that a scaling factor is required to have the same amount of Tb attenuation for small grain sizes within the Rayleigh scattering regime. For larger grain sizes, however, a scaling coefficient is not enough to match the model outputs due to the different scattering assumptions of the RTMs. For a single snow layer with increasing snow depths and densities, all three RTMs exhibit Tb attenuations arising from the increase in path lengths and optical depths. Further evaluations are conducted by feeding the three RTMs with the output of a snow physics model driven by in situ weather forcing in a coupled simulation. Outputs of this coupled model include snowpack physical properties and Tbs. By using snow stratigraphy observations, another set of Tb simulation is also conducted with RTMs driven by in situ snowpit observations. The snow physics outputs from the coupled case are compared against in situ snow stratigraphy observations.

Do Hyuk Kang↗

Diverse sediment microbiota shape methane emission temperature sensitivity in Arctic lakes

Abstract Northern post-glacial lakes are significant, increasing sources of atmospheric carbon through ebullition (bubbling) of microbially-produced methane (CH 4 ) from sediments. Ebullitive CH 4 flux correlates strongly with temperature, reflecting that solar radiation drives emissions. However, here we show that the slope of the temperature-CH 4 flux relationship differs spatially across two post-glacial lakes in Sweden. We compared these CH 4 emission patterns with sediment microbial (metagenomic and amplicon), isotopic, and geochemical data. The temperature-associated increase in CH 4 emissions was greater in lake middles—where methanogens were more abundant—than edges, and sediment communities were distinct between edges and middles. Microbial abundances, including those of CH 4 -cycling microorganisms and syntrophs, were predictive of porewater CH 4 concentrations. Results suggest that deeper lake regions, which currently emit less CH 4 than shallower edges, could add substantially to CH 4 emissions in a warmer Arctic and that CH 4 emission predictions may be improved by accounting for spatial variations in sediment microbiota.

54 ENVIRONMENTAL SCIENCES↗

Expansion Valve With Temperature-Sensitive Flow Regulation

Joule-Thomson expansion valve designed so particles or condensed contaminants in vapor flowing through unlikely to clog orifice. In addition, new valve automatically adjusts flow of vapor. Allows high initial flow for rapid cooling, but gradually reduces flow as operating temperature reached. Flow adjusts manually when necessary. Developed for expansion of high-pressure vapors to condense them into low-pressure cryogenic liquids. Used to conserve helium coolant in superconducting system by condensing vapor boiling from liquid-helium bath.

Walker, Graham↗

Investigating Fundamental Principles of Nonequilibrium Assembly Using Temperature-Sensitive Copolymers

Both natural biomaterials and synthetic materials benefit from complex energy landscapes that provide the foundation for structure–function relationships and environmental sensitivity. Understanding these nonequilibrium dynamics is important for the development of design principles to harness this behavior. Using a model system of poly(ethylene glycol) methacrylate-based thermoresponsive lower critical solution temperature (LCST) copolymers, we explored the impact of composition and stimulus path on nonequilibrium thermal hysteretic behavior. Through turbidimetry analysis of nonsuperimposable heat–cool cycles, we observe that LCST copolymers show clear hysteresis that varies as a function of pendent side chain length and hydrophobicity. Hysteresis is further impacted by the temperature ramp rate, as insoluble states can be kinetically trapped under optimized temperature protocols. As a result, this systematic study brings to light fundamental principles that can enable the harnessing of out-of-equilibrium effects in synthetic soft materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Coarse-grained molecular dynamics integrated with convolutional neural network for comparing shapes of temperature sensitive bottlebrushes

Quantification of shape changes in nature-inspired soft material architectures of stimuli-sensitive polymers is critical for controlling their properties but is challenging due to their softness and flexibility. Here, we have computationally designed uniquely shaped bottlebrushes of a thermosensitive polymer, poly(N-isopropylacrylamide) (PNIPAM), by controlling the length of side chains along the backbone. Coarse-grained molecular dynamics simulations of solvated bottlebrushes were performed below and above the lower critical solution temperature of PNIPAM. Conventional analyses (free volume, asphericity, etc.) show that lengths of side chains and their immediate environments dictate the compactness and bending in these architectures. We further developed 100 unique convolutional neural network models that captured molecular-level features and generated a statistically significant quantification of the similarity between different shapes. Thus, our study provides insights into the shapes of complex architectures as well as a general method to analyze them. The shapes presented here may inspire the synthesis of new bottlebrushes.

36 MATERIALS SCIENCE↗

High-sensitivity cryogenic temperature sensors using pressurized fiber Bragg gratings

Cryogenic temperature sensing was studied using a pressurized fiber Bragg grating (PFBG). The PFBG was obtained by simply applying a small diametric load to a regular fiber Bragg grating (FBG), which was coated with polyimide of a thickness of 11 micrometers. The Bragg wavelength of the PFBG was measured at temperatures from 295 to 4.2 K. A pressure-induced transition occurred at 200 K during the cooling cycle. As a result the temperature sensitivity of the PFBG was found to be nonlinear but reach 24 pm/K below 200 K, more than three times the regular FBG. For the temperature change from 80 K to 10 K, the PFBG has a total Bragg wavelength shift of about 470 pm, 10 times more than the regular FBG. From room temperature to liquid helium temperature the PFBG gives a total wavelength shift of 3.78 nm, compared to the FBG of 1.51 nm. The effect of the coating thickness on the temperature sensitivity of the gratings is also discussed.

Wu, Meng-Chou↗

High-sensitivity Cryogenic Temperature Sensors using Pressurized Fiber Bragg Gratings

Cryogenic temperature sensing was studied using a pressurized fiber Bragg grating (PFBG). The PFBG was obtained by simply applying a small diametric load to a regular fiber Bragg grating (FBG), which was coated with polyimide of a thickness of 11 micrometers. The Bragg wavelength of the PFBG was measured at temperatures from 295 to 4.2 K. A pressure-induced transition occurred at 200 K during the cooling cycle. As a result the temperature sensitivity of the PFBG was found to be nonlinear but reach 24 pm/K below 200 K, more than three times the regular FBG. For the temperature change from 80 K to 10 K, the PFBG has a total Bragg wavelength shift of about 470 pm, 10 times more than the regular FBG. From room temperature to liquid helium temperature the PFBG gives a total wavelength shift of 3.78 nm, compared to the FBG of 1.51 nm. The effect of the coating thickness on the temperature sensitivity of the gratings is also discussed.

Wu, Meng-Chou↗