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At least 73 records · Page 4

Measurement of material parameters that limit the open-circuit voltage in P-N-junction silicon solar cells

The greatest gains in solar energy conversion efficiency of p-n-junction silicon solar cells come from increasing the open-circuit voltage V sub OC; it is important to understand and characterize the material parameters that limit the V sub OC. Strong experimental evidence exists to support the assertion that either an anomalously large minority carrier charge storage or an anomalously small minority carrier lifetime in the quasi-neutral emitter region limits the open circuit voltage. A method is presented for measuring charge storage and effective lifetime. Static and transient measurements are analyzed using physical models of the solar cell characteristics. This analysis yields the emitter charge storage and life-time, which then can be related to the various physical mechanisms, such as energy band gap shrinkage, that have been proposed earlier as responsible for limiting V sub OC.

Lindholm, F. A.↗

Space Environmental Effects on the Optical Properties of Selected Transparent Polymers

Transparent polymer films are currently considered for use as solar concentrating lenses for spacecraft power and propulsion systems. These polymer films concentrate solar energy onto energy conversion devices such as solar cells and thermal energy systems. Conversion efficiency is directly related to the polymer transmission. Space environmental effects will decrease the transmission and thus reduce the conversion efficiency. This investigation focuses on the effects of ultraviolet and charged particle radiation on the transmission of selected transparent polymers. Multiple candidate polymer samples were exposed to near ultraviolet (NUV) radiation to screen the materials and select optimum materials for further study. All materials experienced transmission degradation of varying degree. A method was developed to normalize the transmission loss and thus rank the materials according to their tolerance of NUV. Teflon(Tm) FEP and Teflon(Tm) PFA were selected for further study. These materials were subjected to a combined charged particle dose equivalent to 5 years in a typical geosynchronous Earth orbit (GEO). Results from these NUV screening tests and the 5 year GEO equivalent dose are presented.

Edwards, David L.↗

Photocell heat engine solar power systems

A combined photocell heat engine concept is proposed for high efficiency solar energy conversion in space. In this concept the short wavelength portion of the solar spectrum is split by a dichroic filter and sent to a bank of photocells. The long wave-length remainder of the spectrum is used by the heat engine. This technique allows the photocells to operate with the minimum amount of waste heat, increasing their efficiency and reducing the amount of cooling required. The heat engine operates by direct absorption in a working fluid containing broadband absorber molecules or particulates. A window in the heat engine admits the long wave-lengths from the solar spectrum. The window may also reflect a portion of the internal gaseous reradiation spectrum (e.g., a heat mirror) to help reduce radiation losses. Flow-induced thermal gradients may also reduce reradiation losses in the case of optically thick working fluids. The efficiencies computed for the photocell heat engine solar energy converter can be as high as 42 percent.

Taussig, R. T.↗

Solar house system interfaced with the power utility grid

Photovoltaic cells may be used to convert sunlight directly into electrical energy and into low-grade heat to be used for large scale terrestrial solar energy conversion. Both forms of energy can be utilized if such cells are deployed in close proximity to the consumer (rooftop). CdS/Cu2S solar cells are an example of cells which may be produced inexpensively enough to become economically attractive. Cell parameters relevant for combined solar conversion are presented. Critical issues, such as production yield, life expectancy, stability of performance, are discussed. Systems design parameters related to operating temperatures are analyzed. First results obtained on Solar One, the experimental solar house of the University of Delaware, are given. Economic aspects are discussed.

Boeer, K. W.↗

Solar radiation measurement - Techniques and instrumentation

A general survey is presented of solar radiation measurement, techniques, and instrumentation. The importance of determining the total and spectral irradiance of the sun is examined in the context of the energy crisis and utilization of solar energy. The survey includes the extraterrestrial solar fluxes, their possible variations, problems relating to energy received by collecting surfaces on the ground, major types of instrumentation, and the radiation scales to which the measurements are referred. The type of insolation data available is reviewed. Alternate techniques of deriving insolation data with high space-time resolution are discussed with reference to solar energy conversion requirements. Energy received on the ground can be computed from known values of the extraterrestrial solar spectrum and of the spectral absorption parameters of the atmosphere. Another technique is based on measurements made by meteorological satellites of the cloud-cover and of the solar energy reflected and scattered back to space by the earth-atmosphere system.

Thekaekara, M. P.↗

Solar cell array design handbook - The principles and technology of photovoltaic energy conversion

Photovoltaic solar cell array design and technology for ground-based and space applications are discussed from the user's point of view. Solar array systems are described, with attention given to array concepts, historical development, applications and performance, and the analysis of array characteristics, circuits, components, performance and reliability is examined. Aspects of solar cell array design considered include the design process, photovoltaic system and detailed array design, and the design of array thermal, radiation shielding and electromagnetic components. Attention is then given to the characteristics and design of the separate components of solar arrays, including the solar cells, optical elements and mechanical elements, and the fabrication, testing, environmental conditions and effects and material properties of arrays and their components are discussed.

Rauschenbach, H. S.↗

Optical Analysis of Transparent Polymeric Material Exposed to Simulated Space Environment

Transparent polymeric materials are being designed and utilized as solar concentrating lenses for spacecraft power and propulsion systems. These polymeric lenses concentrate solar energy onto energy conversion devices such as solar cells and thermal energy systems. The conversion efficiency is directly related to the transmissivity of the polymeric lens. The Environmental Effects Group of the Marshall Space Flight Center's Materials, Processes, and Manufacturing Department exposed a variety of materials to a simulated space environment and evaluated them for an, change in optical transmission. These materials include Lexan(TM), polyethylene terephthalate (PET). several formulations of Tefzel(TM). and Teflon(TM), and silicone DC 93-500. Samples were exposed to a minimum of 1000 Equivalent Sun Hours (ESH) of near-UV radiation (250 - 400 nm wavelength). Data will be presented on materials exposed to charged particle radiation equivalent to a five-year dose in geosynchronous orbit. These exposures were performed in MSFC's Combined Environmental Effects Test Chamber, a unique facility with the capability to expose materials simultaneously or sequentially to protons, low-energy electrons, high-energy electrons, near UV radiation and vacuum UV radiation.Prolonged exposure to the space environment will decrease the polymer film's transmission and thus reduce the conversion efficiency. A method was developed to normalize the transmission loss and thus rank the materials according to their tolerance to space environmental exposure. Spectral results and the material ranking according to transmission loss are presented.

Edwards, David L.↗

Solar heating system final design package

The system is composed of a warm air collector, a logic control unit and a universal switching and transport unit. The collector was originally conceived and designed as an integrated roof/wall system and therefore provides a dual function in the structure. The collector serves both as a solar energy conversion system and as a structural weather resistant skin. The control unit provides totally automatic control over the operation of the system. It receives input data from sensor probes in collectors, storage and living space. The logic was designed so as to make maximum use of solar energy and minimize use of conventional energy. The transport and switching unit is a high-efficiency air-handling system equipped with gear motor valves that respond to outputs from the control system. The fan unit was designed for maximum durability and efficiency in operation, and has permanently lubricated ball bearings and excellent air-handling efficiency.

Source record↗

Issues and opportunities in space photovoltaics

Space power sources are becoming a central focus for determining man's potential and schedule for exploring and utilizing the benefits of space. The ability to search, probe, survey, and communicate throughout the universe will depend on providing adequate power to the instruments to do these jobs. Power requirements for space platforms are increasing and will continue to increase into the 21st century. Photovoltaics have been a dependable power source for space for the last 30 years and have served as the primary source of power on virtually all DOD and NASA satellites. The performance of silicon (Si) solar cells has increased from 10 percent air mass zero (AM0) solar energy conversion efficiency in the early 60's to almost 15 percent on today's spacecraft. Some technologists even think that the potential for solar photovoltaics has reached a plateau. However, present and near-future Air Force and NASA requirements show needs that, if the problems are looked upon as opportunities, can elevate the photovoltaic power source scientist and array structure engineer into the next technological photovoltaic growth curve.

Francis, Robert W.↗

Issues and opportunities in space photovoltaics

Space power sources are becoming a central focus for determining man's potential and schedule for exploring and utilizing the benefits of space. The ability to search, probe, survey, and communicate throughout the universe will depend on providing adequate power to the instruments to do these jobs. Power requirements for space platforms are increasing and will continue to increase into the 21st century. Photovoltaics have been a dependable power source for space for the last 30 years and have served as the primary source of power on virtually all DOD and NASA satellites. The performance of silicon (Si) solar cells has increased from 10 percent air mass zero (AM0) solar energy conversion efficiency in the early 60's to almost 15 percent on today's spacecraft. Some technologists even think that the potential for solar photovoltaics has reached a plateau. However, present and near-future Air Force and NASA requirements show needs that, if the problems are looked upon as opportunities, can elevate the photovoltaic power source scientist and array structure engineer into the next technological photovoltaic growth curve.

Francis, Robert W.↗

Methods for the photochemical utilization of solar energy

The paper considers the 'ground rules' which govern the efficiency of photochemical solar energy conversion and then summarizes the most promising approaches in each of three categories: photochemically assisted thermal systems for the heating and/or cooling of structures; photogalvanic systems for the production of electrical power in applications, such as photorechargeable batteries or inexpensive 'solar cells'; and photochemical formation of fuels for combustion and for use as chemical feedstocks or foods. Three concepts for the photochemical utilization of solar energy in space are found to be particularly promising: (1) photochemical trans-cis isomerization of indigold dyes for photoassisted heating or cooling, (2) the redox stabilized photoelectrolysis cell for the production of hydrogen (and/or oxygen or other useful chemicals), and (3) the liquid-junction photovoltaic cell for the production of electrical power.

Schwerzel, R. E.↗

Picosecond kinetics of excited state decay processes in internally hydrogen-bonded polymer photostabilizers

A construction of economically practical solar energy conversion devices could be based on the employment of inexpensive, visible-radiation transparent, durable, light-fast materials. Difficulties arise in connection with the availability of such materials. Plastics which are not particularly susceptible to solar ultraviolet degradation are, in general, expensive, while less expensive optically transparent films are susceptible to deterioration when exposed to solar radiation. However, techniques are known for protecting polymers from photochemical degradation. According to these techniques, the composition or structure of polymeric material is modified by incorporation of photostabilizers. Two classes of ultraviolet absorbers are used as commercial photostabilizers. These classes include 2-hydroxybenzophenone (HB) and 2-(2-prime -hydroxyphenyl)benzotriazole (HPB). The present investigation is concerned with the results of spectroscopic and kinetics measurements related to the study of the mechanism of excited-state relaxation of polymer photostabilizers in the class HB and HPB.

Huston, A. L.↗

Dynamic RPS Path to Flight

NASA Glenn Research Center has been pursuing the development of dynamic power conversion for several decades. Candidate NASA missions involve mutli-year travel to far away destinations, or to extreme environments where sunlight does not exist. Human-base mission studies also show that power needs would be beyond the capabilities of solar energy conversion, and instead would require nuclear reactor energy sources, for which the thermal energy must be converted to electricity. Dynamic power conversion technology has developed sufficiently to make a sound engineering argument that it is suitable for these NASA missions. Dynamic conversion power sources have yet to be flown in space, and thus suffer a disadvantage owing to their lack of heritage data on flight missions. One of the largest obstacles for adoption is the uncertainty in reliability of a device with moving parts. However, significant progress has been made toward demonstrating the technology capable in all relevant environments, with the necessary long life. Another hurdle for adoption is the lack of mission, which would drive specific requirements, and provide a solid timeline for technology development endpoint. Until a mission is identified, an alternative approach is necessary to advance a dynamic power conversion system towards flight.

Oriti, Sal↗

Dynamic RPS Path to Flight - Nuclear and Emerging Technologies for Space

NASA Glenn Research Center has been pursuing the development of dynamic power conversion for several decades. Candidate NASA missions involve mutli-year travel to far away destinations, or to extreme environments where sunlight does not exist. Human-base mission studies also show that power needs would be beyond the capabilities of solar energy conversion, and instead would require nuclear reactor energy sources, for which the thermal energy must be converted to electricity. Dynamic power conversion technology has developed sufficiently to make a sound engineering argument that it is suitable for these NASA missions. Dynamic conversion power sources have yet to be flown in space, and thus suffer a disadvantage owing to their lack of heritage data on flight missions. One of the largest obstacles for adoption is the uncertainty in reliability of a device with moving parts. However, significant progress has been made toward demonstrating the technology capable in all relevant environments, with the necessary long life. Another hurdle for adoption is the lack of mission, which would drive specific requirements, and provide a solid timeline for technology development endpoint. Until a mission is identified, an alternative approach is necessary to advance a dynamic power conversion system towards flight.

Oriti, Salvatore↗

Modeling of high efficiency solar cells under laser pulse for power beaming applications

Solar cells have been used to convert sunlight to electrical energy for many years and also offer great potential for non-solar energy conversion applications. Their greatly improved performance under monochromatic light compared to sunlight, makes them suitable as photovoltaic (PV) receivers in laser power beaming applications. Laser beamed power to a PV array receiver could provide power to satellites, an orbital transfer vehicle, or a lunar base. Gallium arsenide (GaAs) and indium phosphide (InP) solar cells have calculated efficiencies of more than 50 percent under continuous illumination at the optimum wavelength. Currently high power free-electron lasers are being developed which operate in pulsed conditions. Understanding cell behavior under a laser pulse is important in the selection of the solar cell material and the laser. An experiment by NAsA lewis and JPL at the AVLIS laser facility in Livermore, CA presented experimental data on cell performance under pulsed laser illumination. Reference 5 contains an overview of technical issues concerning the use of solar cells for laser power conversion, written before the experiments were performed. As the experimental results showed, the actual effects of pulsed operation are more complicated. Reference 6 discusses simulations of the output of GaAs concentrator solar cells under pulsed laser illumination. The present paper continues this work, and compares the output of Si and GaAs solar cells.

Jain, Raj K.↗

Investigation of direct solar-to-microwave energy conversion techniques

Identification of alternative methods of producing microwave energy from solar radiation for purposes of directing power to the Earth from space is investigated. Specifically, methods of conversion of optical radiation into microwave radiation by the most direct means are investigated. Approaches based on demonstrated device functioning and basic phenomenologies are developed. There is no system concept developed, that is competitive with current baseline concepts. The most direct methods of conversion appear to require an initial step of production of coherent laser radiation. Other methods generally require production of electron streams for use in solid-state or cavity-oscillator systems. Further development is suggested to be worthwhile for suggested devices and on concepts utilizing a free-electron stream for the intraspace station power transport mechanism.

Chatterton, N. E.↗

Parallel-processing with surface plasmons, a new strategy for converting the broad solar spectrum

A new strategy for efficient solar-energy conversion is based on parallel processing with surface plasmons: guided electromagnetic waves supported on thin films of common metals like aluminum or silver. The approach is unique in identifying a broadband carrier with suitable range for energy transport and an inelastic tunneling process which can be used to extract more energy from the more energetic carriers without requiring different materials for each frequency band. The aim is to overcome the fundamental 56-percent loss associated with mismatch between the broad solar spectrum and the monoenergetic conduction electrons used to transport energy in conventional silicon solar cells. This paper presents a qualitative discussion of the unknowns and barrier problems, including ideas for coupling surface plasmons into the tunnels, a step which has been the weak link in the efficiency chain.

Anderson, L. M.↗

Modular thermoelectric cell is easily packaged in various arrays

Modular thermoelectric cells are easily packaged in various arrays to form power supplies and have desirable voltage and current output characteristics. The cells employ two pairs of thermoelectric elements, each pair being connected in parallel between two sets of aluminum plates. They can be used as solar energy conversion devices.

Epstein, J.↗