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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

Complex magmatic processes on Mars - Inferences from the SNC meteorites

Published data on the elemental and isotopic abundances in the shergottites-nakhlites-Chassigny (SNC) meteorites, considered to be of Martian origin, are compared with those for eucritic, lunar, and terrestrial basalt samples, with a focus on their implications for magmatic processes in the parent bodies. The major elements, the REEs and isotopes, and the other lithophile incompatible elements (such as high-field-strength elements, HFSEs) are discussed separately, and it is concluded that Mars had a magmatic history significantly different from that of the other bodies. The Martian pattern of HFSE and REE anomalies suggests extraction of carbonatic melts and remelting of the depleted source material, while the Nd isotopic constraints on the melting of Nakhla indicate very high fractionation of REEs, requiring exceedingly efficient porous flow down to depths of over 350 km.

Longhi, J.↗
NASA NTRS1992

Martian parent craters for the SNC meteorites

Information on the petrology and ages of the SNC meteorites, together with geological data derived from Viking Orbiter images, are used to identify 25 candidate impact craters in the Tharsis region of Mars that could possibly be the source craters for these meteorites. The craters chosen as candidate source craters had diameters greater than 10 km, morphologies indicative of young craters, and satisfied both the petrological criteria of the SNCs and the proposed 1.3 Ga crystallization ages. On the basis of the constraints implied by the identification of the candidate source craters, interpretations of the absolute chronology of Mars are proposed.

Mouginis-Mark, P. J.↗
NASA NTRS1992

Soil mineralogy and chemistry on Mars - Possible clues from salts and clays in SNC meteorites

If the shergottite, nakhlite, and chassignite (SNC) meteorites' parent planet is Mars, then the aqueous precipitates found in them imply that oxidizing, water-based solutions may have been chemically active on that planet over the past 200-1300 million yrs. It is suggested that the mixture of aqueous precipitates found in the SNCs furnish a self-consistent model for the bulk elemental composition of surface sediments at the Viking Lander sites. Further mineralogical and stable-isotope studies of the secondary minerals may establish the limits for biological activity over the last 1300 million years of Mars' water-based chemistry.

Gooding, James L.↗
NASA NTRS1993

Mars volatile evolution - Implications of the recent measurement of O-17 in water from the SNC meteorites

Escape of oxygen to space on Mars is capable of producing a fractionation of oxygen isotopes in the remaining oxygen which is off of the fractionation line produced by the usual mass-dependent exchange processes. The magnitude of fractionation which can occur can be larger than that which was measured in oxygen in water derived from the SNC meteorites (thought to have come from Mars). In conjunction with the apparent lack of fractionation of O-18 in the atmosphere, this result suggests that less than 25 percent of the oxygen in the Martian climate system has been lost over geologic time. Other mechanisms also might be able to produce such a fractionation, so that this conclusion is not unique; however, it is consistent with other lines of evidence. There is no requirement for an initial volatile inventory with an isotopic composition different from that of the bulk planet (as might be the case for a late veneer of volatile-rich material).

Jakosky, Bruce M.↗
NASA NTRS1993

Martian carbon dioxide: Clues from isotopes in SNC meteorites

Attempts to unravel the origin and evolution of the atmosphere and hydrosphere on Mars from isotopic data have been hampered by the impreciseness of the measurements made by the Viking Lander and by Earth-based telescopes. The SNC meteorites which are possibly pieces of the Martian surface offer a unique opportunity to obtain more precise estimates of the planet's volatile inventory and isotopic composition. Recently, we reported results on oxygen isotopes of water extracted by pyrolysis from samples of Shergotty, Zagami, Nakhla, Chassigny, Lafayette, and EETA-79001. Now we describe complementary results on the stable isotopic composition of carbon dioxide extracted simultaneously from those same samples. We will also report on C-14 abundances obtained by accelerator mass spectrometry (AMS) for some of these CO2 samples.

Karlsson, H. R.↗
NASA NTRS1993

Wet inside and out? Constraints on water in the Martian mantle and on outgassed water, based on melt inclusions in SNC meteorites

Constraints on the volatile inventory and outgassing history of Mars are critical to understanding the origin of ancient valley systems and paleoclimates. Planetary accretion models for Mars allow either a volatile-rich or volatile-poor mantle, depending on whether the accreted materials were fully oxidized or whether accretion was homogeneous so that water was lost through reaction with metallic iron. The amount of water that has been outgassed from the interior is likewise a contentious subject, and estimates of globally distributed water based on various geochemical and geological measurements vary from a few meters to more than a thousand meters. New data on SNC meteorites, which are thought to be Martian igneous rocks, provide constraints on both mantle and outgassed water.

Mcsween, H. Y., Jr.↗
NASA NTRS2004

The First Billion Years of Martian History as Seen from the SNC Meteorites: A Review

There are currently 28 known, distinct samples of Mars that have been liberated from that planet by impacts and subsequently delivered to the Earth. The formation ages of these samples range from 4.5 b.y. to 180 m.y. Collectively, these samples are called SNC meteorites after the major petrologic subdivisions: Shergottite, Nakhlite, Chassigny. Texturally, most of these meteorites are cumulates or partial cumulates. However, a few may represent real melt compositions: EET79001B, Y9800459, QUE94201, and the groundmass of EET79001A.

Jones, J. H.↗
NASA NTRS2010

Mineralogy of SNC Meteorite EET79001 by Simultaneous Fitting of Moessbauer Backscatter Spectra

We have acquired M ssbauer spectra for SNC meteorite EET79001 with a MIMOS II backscatter M ssbauer spectrometer [1] similar to those now operating on Mars as part of the Mars Exploration Rover (MER) missions. We are working to compare the Fe mineralogical composition of martian meteorites with in-situ measurements on Mars. Our samples were hand picked from the >1 mm size fraction of saw fines on the basis of lithology, color, and grain size (Table 1). The chips were individually analyzed at approx.300K by placing them on a piece of plastic that was in turn supported by the contact ring of the instrument (oriented vertically). Tungsten foil was used to mask certain areas from analysis. As shown in Figure 1, a variety of spectra was obtained, each resulting from different relative contributions of the Fe-bearing minerals present in the sample. Because the nine samples are reasonably mixtures of the same Fe-bearing phases in variable proportions, the nine spectra were fit simultaneously (simfit) with a common model, adjusting parameters to a single minimum chi-squared convergence criterion [2]. The starting point for the fitting model and values of hyperfine parameters was the work of Solberg and Burns [3], who identified olivine, pyroxene, and ferrous glass as major, and ilmenite and a ferric phase as minor (<5%), Fe-bearing phases in EET79001.

Morris, Richard V.↗
DOE OSTI2021

Observation of pressure-induced electron transfer in SnC 2 O 4

We examined the high pressure behavior of stannous oxalate via Raman and X-ray absorption spectroscopy (XAS) inside a diamond anvil cell. Phase transitions were observed to occur near 2.6 and 15 GPa which were reversible upon decompression to ambient conditions. When further pressurized above 15 GPa, the colorless material sustains irreversible chemical alterations and becomes bright red colored – darkening at higher pressures. Another irreversible phase transition occurred above 20 GPa. Concomitant with color change of the sample, we observed a softening of the ν(C–C) modes of the C 2 O 4 2- anion via Raman spectroscopy. We performed a separate XAS experiment which indicates that the Sn 2+ cation undergoes a partial reduction of the 2+ oxidation state with pressure which persists when the sample was depressurized to ambient conditions. Thus, electron density within the C–C bond in the oxalate anion appears to migrate toward the tin cation with pressure. This observation suggests that pressure can offer a very controllable means to vary cation–anion and unit cell dimensions (and thus the electric interactions causing electron movement) and thus the pressure-induced synthesis of novel materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1983

The origin of SNC meteorites - An alternative to Mars

The possibility that certain very young meteorites originated as impact melts on a large asteroid or asteroids is investigated. Calculations of the thermal evolution of impact melt show that the solidification time should be long enough to produce igneous or quasi-cumulate textures within rocks if the crater is large enough and if the initial clast concentration is low, at least in some portion of the melt sheet. The number of collisions within the asteroid belt which would produce craters of the requisite size is calculated. Using an estimate of the current size distribution of asteroids, it is found that over 3000 such collisions should have occurred during the lifetime of the solar system. Excavation and ejection of the solidified melt by a subsequent impact would be dynamically easy because of the low escape velocities of even the largest asteroids but improbable because of the depth that must be sampled. A second, sufficiently large impact is rare, so only the products of one such double event have been obtained up to now.

Vickery, A. M.↗
NASA NTRS1987

Mars regolith versus SNC meteorites: Evidence for abundant crustal carbonates

Viking XRF analyses are compared with those for terrestrial and lunar basalt samples, and eucritic meteorites (of possible Mars origin). The comparison indicates depletion of Ca relative to Si in the Mars regolith. It is suggested that carbonate formation during a warmer, wetter epoch early in Mars' history could have been responsible.

Warren, Paul H.↗
NASA NTRS1988

Speculations on the igneous history of Mars: Inferences from the SNC meteorites

In general, attempts to delineate an a priori sampling strategy for missions to terrestrial planets must be simple. In the case of the Moon, for example, the simplest and most obvious plan that to sample both the highly-cratered, high-albedo highlands and less-cratered, low-albedo mare--has proven very useful. However in the case of Mars, multiple missions and/or roving samplers may prove expensive or infeasible. Thus, we may be limited to collecting samples from a single site, and, consequently, consideration of sampling strategies for a Mars mission is more critical than for the more-accessible Moon.

Jones, John H.↗
NASA NTRS1989

Iron Mossbauer spectral study of weathered Antarctic and SNC meteorites

Mossbauer spectral measurements were made on suites of finds from Antarctica and falls collected elsewhere in order to distinguish preterrestrial oxidation products formed on parent meteorite bodies from secondary minerals derived from chemical weathering on earth. Ferric iron is shown to be present throughout the interiors of all the specimens, in amounts ranging from less than 1 to greater than 30 percent Fe(3+). The results indicate that achondrites found to date did not originate from the outermost surface of Mars.

Solberg, T. C.↗
NASA NTRS1991

Proposed planning and scheduling services for the SNC in the CDOS era

Studies indicate that the current NCC mode of operation needs to be enhanced to meet the needs of the mid to late 19990's. There is a need to simplify the request interface for Space Network services. This is because there are more complex missions, more flexible spacecraft operations, more scheduling data volume, and more events per spacecraft and scheduling period.

Welden, Todd↗
NASA NTRS1992

Mars volatile evolution: Implications of the recent measurement of O-17 in water from the SNC meteorites

Oxygen, carbon, and hydrocarbon isotopes in water and carbon dioxide in the Martian environment can fractionate due to processes involving escape to space, exchange between atmospheric and non-atmospheric species, and exchange of atoms between different molecules. As a result, the ratios of O-18/O-17/O-16, C-13/C-12 and D/H in atmospheric and surface species are sensitive indicators of the integrated effects of outgassing and volatile evolution over geologic time. Previously, I summarized all of the available observations of isotopic abundances and compared them with models of fractionation in order to see which scenarios of volatile evolution were most plausible. Presently, I have included in the models the possible evolution of O-17 due to loss to space in order to see whether these measurements are consistent with various scenarios for atmospheric evolution.

Jakosky, Bruce M.↗
NASA NTRS1992

Distribution of water on Mars: Implications from SNC meteorites

There has been much speculation about the abundance of water and other volatiles on Mars. Attempts to calculate abundances of water on Mars indicate that Mars contains approx. 10-100 m of water. Numerous models have been put forth to determine the amount of water on Mars more closely. Some researchers infer that Chassigny parent magma contained greater than 1.5 percent water by weight and that the Martian mantle contained greater than 1000 parts per million water. This is too much water for a depleted region. Perhaps some of the water in Chassigny was assimilated at shallow depths, either in a crustal magma chamber or by interaction with superficial permafrost. Either is possible and provides an alternative to the dilemma of water-rich to depleted regions.

Jones, J. H.↗