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Results for “STATIC STABILITY”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Nanoscale TiO 2 coating improves water stability of Cs 2 SnCl 6

To improve the stability of Cs 2 SnCl 6 under aqueous/moisture environments, we applied a concept of artificial passivation by depositing a protective TiO 2 coating of 10 nm on the surface of Cs 2 SnCl 6 . Static leaching experiments results indicate that the initial release rates of Cs + and Cl - are decreased by 20–30 times with TiO 2 coating, suggesting its possibility to improve the short-term water/environmental stability of Cs 2 SnCl 6 . An amorphous-to-crystalline phase transition in TiO 2 film was observed, possibly resulting in degradation of Cs 2 SnCl 6 . However, the crystalline TiO 2 film still remains after 21 days water exposure and can still act as an effective passivation layer to reduce the release rates of Cs + and Cl - by as much as about 17 and 7 times, respectively, relative to static leaching without artificial coatings. Therefore, the water/environmental stability of metal halide perovskite Cs 2 SnCl 6 , which is a highly soluble molecular salt, can be enhanced by the nanoscale TiO 2 coating as an artificial passivation film.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2021

Interface-Driven Chiral Magnetism in Ultrathin Metallic Ferromagnets: Towards Skyrmion Spintronics

Magnetic skyrmions are localized chiral magnetic textures in the form of nanoscale vortices or bubbles that are topologically protected from being ‘unwound’. Their topological nature gives rise to rich behaviors including ordered lattice formation, emergent electrodynamics and robust current-driven displacement at remarkably low current densities. However, magnetic skyrmions have so far been restricted to just a few materials and observed only at low temperatures, limiting the experimental accessibility and technological application of these unique topological objects. This project aimed to realize magnetic skyrmions at room temperature in a new class of engineered chiral ferromagnets that exploit broken mirror symmetry at interfaces to generate helical magnetic order. Ultrathin magnetic heterostructures were engineered and patterned into laterally-confined nanostructures in which skyrmions were stabilized, manipulated, and detected for the first time under ambient conditions. Static and dynamic properties were examined using advanced x-ray imaging to provide a fundamental understanding of topological magnetic phases. The interactions between magnetic skyrmions and electron charge and spin currents were studied to identify fundamental new physics and enable device applications. These experimental studies, supported by detailed modeling, will help launch a new subfield of skyrmion-based spintronics in which individual skyrmions can be used to encode, store, and transport information in high-performance, low power memory and logic devices.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Real-Time High-Accuracy Digital Wireless Time, Frequency, and Phase Calibration for Coherent Distributed Antenna Arrays

his work presents a fully-digital high-accuracy real-time calibration procedure for frequency and time alignment of open-loop wirelessly coordinated coherent distributed antenna array (CDA) modems, enabling radio frequency (RF) phase coherence of spatially separated commercial off-the-shelf (COTS) software-defined radios (SDRs) without cables or external references such as the global navigation satellite system (GNSS). Building on previous work using high-accuracy spectrally-sparse time of arrival (ToA) waveforms and a multistep ToA refinement process, a high-accuracy two-way time transfer (TWTT)-based time–frequency coordination approach is demonstrated. Due to the two-way nature of the high-accuracy TWTT approach, the time and frequency estimates are Doppler and multipath tolerant, so long as the channel is reciprocal over the synchronization epoch. This technique is experimentally verified using COTS SDRs in a lab environment in static and dynamic scenarios and with significant multipath scatterers. Time, frequency, and phase stability were evaluated by beamforming over coaxial cables to an oscilloscope which achieved time and phase precisions of ~60– 70 ps , with median coherent gains above 99% using optimized coordination parameters, and a beamforming frequency root-mean-square error (RMSE) of 3.73 ppb in a dynamic scenario. Finally, experiments were conducted to compare the performance of this technique with previous works using an analog continuous-wave two-tone (CWTT) frequency reference technique in both static and dynamic settings.

Clock synchronization↗
DOE OSTI2020

Unraveling the Effects of Cobalt on Crystal Growth and Solution Behavior of Nb 6 P 2 W 12 -based Dimeric Clusters

We report the synthesis, characterization, and solution self-assembly of plenary Nb 6 P 2 W 12 -based transition-metal substituted polyoxometalate, which is obtained by simply adding transition metals (Co 2+ ) into aqueous solution containing cluster [(NbO 2 ) 6 P 2 W 12 O 56 ] 12- , which is obtained by an in situ synthetic method. The incorporation of Co 2+ ions significantly affects the crystal structure, resulting in the formation of a 1D chain-like crystal and the first example of a niobotungstate-based cobalt derivative cluster. The behavior and stability of this cluster in solution are confirmed by time-resolved static light scattering, dynamic light scattering, small-angle X-ray scattering, and electrospray mass spectrometry studies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Stability Enhancement in Na 0.67 Fe 0.2 Mn 0.8 O 2 Positive Electrodes via Spherical Coprecipitated Hydroxide Precursor Synthesis for Na-Ion Batteries

Mn/Fe-based layered transition metal oxides (LTMOs) are promising positive electrode materials for sodium-ion batteries (SIBs) due to their high abundance, low cost, and stable price fluctuations. At commercial scale, the fabrication of these materials commonly employs coprecipitation of hydroxide precursors, which allows for the scalable synthesis of uniform, dense particles with a tunable morphology. However, the common chelating agent (ammonia) forms unstable complexes with Fe 2+ ions, resulting in uncontrollable particle morphology and poor electrochemical properties. Here, in this study, three chelation strategies (no chelation, ammonia, oxalate) for Fe/Mn-based hydroxides are evaluated. It was found that oxalate chelation produced uniform, dense spherical hydroxide particles while particles via ammonia / no chelate routes exhibited no morphological control. The LTMOs synthesized from the oxalate-chelated hydroxide precursor formed uniform spherical particles, while the other two LTMOs showed greater variation in particle morphology. The oxalate-chelated LTMO electrode exhibited increased cycling stability due to reduced parasitic reactions with the electrolyte, as characterized by static leakage current measurements and electrochemical impedance spectroscopy.

25 ENERGY STORAGE↗
DOE OSTI2020

Electrostatic generator electrode-centering and seismic-isolation system for flywheel-based energy storage modules

Robust electro-static (ES) device embodiments, with application to energy storage flywheels as an example, are described that provide reliable, high-efficiency operation in the presence of thermal and mechanical perturbations, as well as seismic events. Electro-static generators and motors, when augmented with magnetic bearings, passive three-dimensional stabilization techniques and dynamic touch-down bearings, enable robust performance in the face of these environmental concerns, as well as efficient operation during typical operational sequences, including spin-up and steady-state modalities.

25 ENERGY STORAGE↗
DOE OSTI2021

Electrostatic generator electrode-centering and seismic-isolation system for flywheel-based energy storage modules

Robust electro-static (ES) device embodiments, with application to energy storage flywheels as an example, are described that provide reliable, high-efficiency operation in the presence of thermal and mechanical perturbations, as well as seismic events. Electro-static generators and motors, when augmented with magnetic bearings, passive three-dimensional stabilization techniques and dynamic touch-down bearings, enable robust performance in the face of these environmental concerns, as well as efficient operation during typical operational sequences, including spin-up and steady-state modalities.

Post, Richard F.↗
DOE OSTI2021

Multiplexable intrinsic Fabry-Pérot interferometers inscribed by femtosecond laser for vibration measurement in high temperature environments

This article reports fabrication technique and demodulation algorithm developments to use multiplexable intrinsic Fabry-Pérot interferometer (IFPI) fiber sensor array for distributed vibration measurements at high temperatures. Using femtosecond laser direct writing scheme, IFPI array were fabricated through laser-induced Type II scattering points in single mode fiber cores. Reflection spectra of IFPI array were demodulated in real-time using modified Bunemen frequency analysis. The demodulation algorithm, which was implemented using a photodetector-array spectrometer, achieves 64-nε dynamic strain resolution at 1-kHz spectral acquisition rate and 2-kHz maximum vibration bandwidth. Performance and stabilities of IFPI sensor array were characterized from room temperatures to 800 °C. The static strain resolution was 0.6 με and the minimum detectable dynamic strain amplitude was 23 nε/√Hz at 800 °C. The multiplex performance was also tested by measuring dynamic strain in time domain through six IFPI sensor array fabricated in one fiber. This paper presents an integrated and low-cost sensing solution to perform distributed vibration measurements in harsh environments.

42 ENGINEERING↗
DOE OSTI2023

A Process Model for ITCZ Narrowing under Warming Highlights Clear-Sky Water Vapor Feedbacks and Gross Moist Stability Changes in AMIP Models

Tropical areas with mean upward motion—and as such the zonal-mean intertropical convergence zone (ITCZ)—are projected to contract under global warming. To understand this process, a simple model based on dry static energy and moisture equations is introduced for zonally symmetric overturning driven by sea surface temperature (SST). Processes governing ascent area fraction and zonal mean precipitation are examined for insight into Atmospheric Model Intercomparison Project (AMIP) simulations. Bulk parameters governing radiative feedbacks and moist static energy transport in the simple model are estimated from the AMIP ensemble. Uniform warming in the simple model produces ascent area contraction and precipitation intensification—similar to observations and climate models. Contributing effects include stronger water vapor radiative feedbacks, weaker cloud-radiative feedbacks, stronger convection-circulation feedbacks, and greater poleward moisture export. The simple model identifies parameters consequential for the inter-AMIP-model spread; an ensemble generated by perturbing parameters governing shortwave water vapor feedbacks and gross moist stability changes under warming tracks inter-AMIP-model variations with a correlation coefficient ~0.46. Here, the simple model also predicts the multimodel mean changes in tropical ascent area and precipitation with reasonable accuracy. Furthermore, the simple model reproduces relationships among ascent area precipitation, ascent strength, and ascent area fraction observed in AMIP models. A substantial portion of the inter-AMIP-model spread is traced to the spread in how moist static energy and vertical velocity profiles change under warming, which in turn impact the gross moist stability in deep convective regions—highlighting the need for observational constraints on these quantities.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Observation of a mixed close-packed structure in superionic water

The study of superionic (SI) water has been a highly active research area since its theoretical prediction. Despite significant experimental and computational efforts, its melting curve and the stability of different oxygen lattices remain debated, impacting our understanding of SI ice’s peculiar transport properties. Experimental results at lower pressures show disagreement, whereas data at higher pressures are scarce due to the extreme challenges of such experiments. In this work, we present ultrafast X-ray diffraction results of water compressed by multiple shocks to pressures up to ~ 180 GPa. At pressures exceeding 150 GPa and temperatures around 2500 K, our diffraction patterns challenge the pure FCC-SI phase model, providing experimental evidence of the mixed close-packed superionic phase predicted by advanced ab initio calculations. At lower pressures, we observe simultaneous signatures of BCC and FCC structures within a pressure-temperature range consistent with some static-compression experiments, helping to resolve contradictory results in literature. These insights offer new constraints on the stability domains of SI phases and reveal detailed structural features, such as stacking faults. Our results advance the structural understanding of high-pressure SI ice to a level approaching that of ice I polymorphs, with potential implications for water-rich interiors of giant planets.

Andriambariarijaona, Leon [Centre National de la R↗
DOE OSTI2024

Microwave-assisted synthesis of mixed-linker covalent organic frameworks enabling tunable and ultrahigh iodine capture

The use of covalent organic frameworks (COFs) for hazardous radioiodine capture has been highly sought after recently. However, the synthesis of high-performance COF adsorbents while circumventing the limitations of traditional solvothermal methods remains largely unexplored. Herein, we for the first time combine microwave-assisted synthesis and mixed-linker strategy to fabricate multivariate COF adsorbents (X% OMe-TFB-BD COFs, X% = 0, 33, 50, 67, and 100 mol%) with varying ratios of benzidine (BD) and 3,3'-dimethoxylbenzidine (BD-OMe) linkers in a rapid and facile manner. Adjusting the BD-OMe/BD mole ratios has led to distinct variations in density, crystallinity, porosity, morphology, and thermal/chemical stability of the resultant COFs, which empowered fine-tuning of the adsorption performance towards static iodine vapor. Remarkably, the 50% OMe-TFB-BD COF exhibited an ultrahigh iodine adsorption capability of 8.2 g g –1 , surpassing those of single-component COFs, mixed-linker COFs with other methoxy content, physically blended mixtures, and most existing COF adsorbents. Moreover, 50% OMe-TFB-BD COF was recyclable seven times without obvious loss in its adsorption capacity. Finally, this work underscores the substantial potential of microwave-assisted mixed-linker strategy as a viable approach for developing multivariate COFs with shortened reaction times, precisely tailored pore environment, and tunable sorption properties, which are of considerable promise for environmental remediation and other niche applications.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Machine learning assisted derivation of minimal low-energy models for metallic magnets

Abstract We consider the problem of extracting a low-energy spin Hamiltonian from a triangular Kondo Lattice Model (KLM). The non-analytic dependence of the effective spin-spin interactions on the Kondo exchange excludes the use of perturbation theory beyond the second order. We then introduce a Machine Learning (ML) assisted protocol to extract effective two- and four-spin interactions. The resulting spin model reproduces the phase diagram of the original KLM as a function of magnetic field and single-ion anisotropy and reveals the effective four-spin interactions that stabilize the field-induced skyrmion crystal phase. Moreover, this model enables the computation of static and dynamical properties with a much lower numerical cost relative to the original KLM. A comparison of the dynamical spin structure factor in the fully polarized phase computed with both models reveals a good agreement for the magnon dispersion even though this information was not included in the training data set.

Sharma, Vikram (ORCID:0000000189105519)↗
DOE OSTI2021

Room Return Path Sensitivity

Standard practice for HVAC return design has evolved from running a dedicated return to each room with a supply, to systems with returns in more centrally located areas of the home with jump ducts, transfer grilles, or simply door undercuts used as return air pathways from isolated rooms. In these latter systems, hallways and stairwells act as large open ducts for conveying air back to a single (or sometimes multiple) central return. When partition doors to an isolated room are closed, the return airflow resistance goes up, significantly impacting airflow balance if an adequate relief pathway is not installed. Airflow imbalances can lead to comfort and building durability issues and increased envelope leakage. To combat this, some jurisdictions have requirements for return air pathways. The supply system topology–or layout–impacts the airflow balance stability in response to adjustments of return pathway resistances. Branching supply topologies typically have reduced static pressure after each split. The static pressure at the final split will be lower than the primary supply plenum. Because of this, if there is a restriction in a room’s return path, supply airflow will tend to redistribute to adjacent ducts at the end of the branch. A properly designed trunk and branch supply system can effectively equalize static pressure by reducing the cross sectional area after each takeoff . Maintaining static pressure within the trunk will reduce the system’s sensitivity to changes in return paths. However, in practice, it is difficult to design and time consuming to install a complex supply plenum. Velocity effects and poor takeoff placement also impact airflow balance. This report considers return systems in three main categories: distributed, with a return duct to each room; multiple central, with one return grille on each floor of a home; and single central, with a single return grille located near the air handling unit. Three supply categories are also considered: radial splitter box, trunk and branch, and home-run with all ducts connecting directly to a central manifold.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2021

Designing for Supply and Return Air System Interaction in Residential Buildings

Standard practice for HVAC return design has evolved from running a dedicated return to each room with a supply, to systems with returns in more centrally located areas of the home with jump ducts, transfer grilles, or simply door undercuts used as return air pathways from isolated rooms . In these latter systems, hallways and stairwells act as large open ducts for conveying air back to a single (or sometimes multiple) central return. When partition doors to an isolated room are closed, the return airflow resistance goes up, significantly impacting airflow balance if an adequate relief pathway is not installed. Airflow imbalances can lead to comfort and building durability issues and increased envelope leakage. To combat this, some jurisdictions have requirements for return air pathways. The supply system topology – or layout - impacts the airflow balance stability in response to adjustments of return pathway resistances. Branching supply topologies typically have reduced static pressure after each split. The static pressure at the final split will be lower than the primary supply plenum. Because of this, if there is a restriction in a room’s return path, supply airflow will tend to redistribute to adjacent ducts at the end of the branch. A properly designed trunk and branch supply system can effectively equalize static pressure by reducing the cross sectional area after each takeoff . Maintaining static pressure within the trunk will reduce the system’s sensitivity to changes in return paths. However, in practice, it is difficult to design and time consuming to install a complex supply plenum. Velocity effects and poor takeoff placement also impact airflow balance. This fact sheet considers return systems in three main categories: distributed, with a return duct to each room; multiple central, with one return grille on each floor of a home; and single central, with a single return grille located near the air handling unit. Three supply categories are also considered: radial splitter box, trunk and branch, and home-run with all ducts connecting directly to a central manifold. A complete description of the modeling work and results can be found in the companion technical report.

buildings↗
DOE OSTI2020

Calcitonin Receptor N-Glycosylation Enhances Peptide Hormone Affinity by Controlling Receptor Dynamics

The class B G protein-coupled receptor (GPCR) calcitonin receptor (CTR) is a drug target for osteoporosis and diabetes. N-glycosylation of asparagine 130 in its extracellular domain (ECD) enhances calcitonin hormone affinity with the proximal GlcNAc residue mediating this effect through an unknown mechanism. Here, we present two crystal structures of salmon calcitonin-bound, GlcNAc-bearing CTR ECD at 1.78 and 2.85 Å resolutions and analyze the mechanism of the glycan effect. The N130 GlcNAc does not contact the hormone. Surprisingly, the structures are nearly identical to a structure of hormone-bound, N-glycan-free ECD, which suggested that the GlcNAc might affect CTR dynamics not observed in the static crystallographic snapshots. Hydrogen-deuterium exchange mass spectrometry and molecular dynamics simulations revealed that glycosylation stabilized a β-sheet adjacent to the N130 GlcNAc and the N-terminal α-helix near the peptide-binding site while increasing flexibility of the peptide-binding site turret loop. These changes due to N-glycosylation increased the ligand on-rate and decreased its off-rate. The glycan effect extended to RAMP-CTR amylin receptor complexes and was also conserved in the related CGRP receptor. These results reveal that N-glycosylation can modulate GPCR function by altering receptor dynamics.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Stability and Conservation properties of Hermite-based approximations of the Vlasov-Poisson System

Spectral approximation based on Hermite-Fourier expansion of the Vlasov-Poisson model for a collisionless plasma in the electro-static limit is provided by adding high-order artificial collision operators of Lenard-Bernstein type. These differential operators are suitably designed in order to preserve the physically-meaningful invariants (number of particles, momentum, energy). In view of time-discretization, stability results in appropriate norms are presented. In this study, necessary conditions link the magnitude of the artificial collision term, the number of spectral modes of the discretization, as well as the time-step. The analysis, carried out in full for the Hermite discretization of a simple linear problem in one-dimension, is then partly extended to cover the complete nonlinear Vlasov-Poisson model.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2025

Predictive numerical modeling of plasma-induced surface roughness and wettability evolution in LM-PAEK/CF tape

Plasma surface modification effectively enhances adhesion in thermoplastic composites, yet its impacts on high-performance polymers like low-melting polyaryletherketone (LM-PAEK) remain inadequately quantified. Here, this study integrates experimental analysis and numerical modeling to characterize surface roughness and wettability changes in LM-PAEK/carbon fiber composites treated with atmospheric plasma. Atomic Force Microscopy quantified surface topography (n = 10 per condition for contact angles), while static contact-angle assessments measured wettability. Roughness rapidly increased from ∼0.2 nm to 1.6 nm, and contact angle reduced from ∼90° to 24°, both stabilizing after 25–30 s of exposure. A semi-empirical, physics-informed framework was calibrated to these data, coupling surface chemistry via the Owens–Wendt decomposition with topography via the Wenzel roughness factor, and evaluated using out-of-sample (cross-validated) tests, while static contact angle assessments measured wettability. Numerical predictions matched experimental results closely (RMSE <5%, R 2 > 0.95). Incorporating material-specific parameters, the calibrated model supports plasma-treatment optimization and provides quantitative guidance for improving interfacial adhesion in thermoplastic composite manufacturing.

Atomic Force Microscopy↗
DOE OSTI2021

Adaptive Phenotypic Plasticity Stabilizes Evolution in Fluctuating Environments

Fluctuating environmental conditions are ubiquitous in natural systems, and populations have evolved various strategies to cope with such fluctuations. The particular mechanisms that evolve profoundly influence subsequent evolutionary dynamics. One such mechanism is phenotypic plasticity, which is the ability of a single genotype to produce alternate phenotypes in an environmentally dependent context. Here, we use digital organisms (self-replicating computer programs) to investigate how adaptive phenotypic plasticity alters evolutionary dynamics and influences evolutionary outcomes in cyclically changing environments. Specifically, we examined the evolutionary histories of both plastic populations and non-plastic populations to ask: (1) Does adaptive plasticity promote or constrain evolutionary change? (2) Are plastic populations better able to evolve and then maintain novel traits? And (3), how does adaptive plasticity affect the potential for maladaptive alleles to accumulate in evolving genomes? We find that populations with adaptive phenotypic plasticity undergo less evolutionary change than non-plastic populations, which must rely on genetic variation from de novo mutations to continuously readapt to environmental fluctuations. Indeed, the non-plastic populations undergo more frequent selective sweeps and accumulate many more genetic changes. We find that the repeated selective sweeps in non-plastic populations drive the loss of beneficial traits and accumulation of maladaptive alleles, whereas phenotypic plasticity can stabilize populations against environmental fluctuations. This stabilization allows plastic populations to more easily retain novel adaptive traits than their non-plastic counterparts. In general, the evolution of adaptive phenotypic plasticity shifted evolutionary dynamics to be more similar to that of populations evolving in a static environment than to non-plastic populations evolving in an identical fluctuating environment. All natural environments subject populations to some form of change; our findings suggest that the stabilizing effect of phenotypic plasticity plays an important role in subsequent adaptive evolution.

54 ENVIRONMENTAL SCIENCES↗