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At least 73 records · Page 4

Design of a Subscale Propellant Slag Evaluation Motor Using Two-Phase Fluid Dynamic Analysis

Small pressure perturbations in the Space Shuttle Reusable Solid Rocket Motor (RSRM) are caused by the periodic expulsion of molten aluminum oxide slag from a pool that collects in the aft end of the motor around the submerged nozzle nose during the last half of motor operation. It is suspected that some motors produce more slag than others due to differences in aluminum oxide agglomerate particle sizes that may relate to subtle differences in propellant ingredient characteristics such as particle size distributions or processing variations. A subscale motor experiment was designed to determine the effect of propellant ingredient characteristics on the propensity for slag production. An existing 5 inch ballistic test motor was selected as the basic test vehicle. The standard converging/diverging nozzle was replaced with a submerged nose nozzle design to provide a positive trap for the slag that would increase the measured slag weights. Two-phase fluid dynamic analyses were performed to develop a nozzle nose design that maintained similitude in major flow field features with the full scale RSRM. The 5 inch motor was spun about its longitudinal axis to further enhance slag collection and retention. Two-phase flow analysis was used to select an appropriate spin rate along with other considerations, such as avoiding bum rate increases due to radial acceleration effects. Aluminum oxide particle distributions used in the flow analyses were measured in a quench bomb for RSRM type propellants with minor variations in ingredient characteristics. Detailed predictions for slag accumulation weights during motor bum compared favorably with slag weight data taken from defined zones in the subscale motor and nozzle. The use of two-phase flow analysis proved successful in gauging the viability of the experimental program during the planning phase and in guiding the design of the critical submerged nose nozzle.

Whitesides, R. Harold↗

The Effect of Solid Constituent Particle Size Distributions on TP-H1148 Propellant Slag

Special aluminum and ammonium perchlorate (AP) particle size distributions were prepared for a matrix of five-inch diameter, center-perforated (CP) motor tests to measure the aluminum oxide slag response in Space Shuttle Reusable Solid Rocket Motor (RSRM) propellant. Previous tests of TP-H1148 propellant in five-inch CP spin motors have shown a correlation between aluminum particle size and generated slag. The motors for this study were cast from thirteen five-gallon propellant mixes which used five particle size levels of aluminum powder, five of unground AP and three of ground AP. Aluminum had the greatest effect on slag formation, the more coarse fractions causing greater slag quantities and larger slag particles. Unground AP had about half the effect of aluminum with the coarser fractions again producing more and larger sized slag particles. The variation in ground AP did not have a significant effect on slag formation. Quench bomb tests showed the same trends as the spin motors, that is, larger aluminum and AP particle size distributions generated larger slag particles leaving the propellant surface. Cured propellant mechanical properties were also impacted by particle size variation.

May, Douglas H.↗

X-Ray Diffraction of Slag-Based Sodium Salt Waste Forms - 15513

Cementitious materials are used to solidify and stabilize aqueous based radioactive waste containing sodium salts. The types and proportions of cementitious ingredients used to treat aqueous radioactive waste streams containing sodium salts depend on the performance objectives for the waste forms and the compositions of the waste streams. This paper documents sample preparation and x-ray diffraction results for a series of materials made with water or highly alkaline sodium salt simulated waste water and cementitious binders. The objective of this study was to: 1) generate a base line for the evolution of the waste form as a function of time and conditions, 2) design new binders based on mineralogy of the binder, 3) understand and predict anion and cation leaching behavior of contaminants of concern, and 4) predict performance of the waste forms for which phase solubility and thermodynamic data are available. Characterization of the mineralogy is also important for understanding the buffering effects that the waste form has on infiltrating water / leachates. In summary, mixtures of Type II portland cement, Grade 100 ground granulated blast furnace slag (GGBFS) and carbon burn-out (CBO) Class F Fly ash which were hydrated with water contained hydrated phase assemblages typical of those reported in the literature. The calcium silicate hydrate phase assemblage in samples hydrated with the alkaline 4.4 M sodium salt simulated waste solution was found to be a function of the (CaO + MgO) / (SiO{sub 2} + Al{sub 2}O{sub 3}) ratio of the samples characterized. No significant differences were detected in samples cured 2 months and 14 months in sealed containers at ambient indoor temperatures. Slag and a blend of slag and cement hydrated with caustic 4.4 M Na salt solution resulted in the most crystalline matrix. In addition to poorly ordered C-S-H, these samples contained fairly well ordered C-S-H I (a precursor of 14A tobermorite) and 11 A Al-substituted tobermorite. These crystalline C-S-H phases did not form or were present in only trace amounts in slag blends containing about 45 to 62 mass percent fly ash. These slag-Class F fly ash blends had a higher silica plus alumina content relative to lime and magnesia than the blends that produced C-S-H I and Al-substituted tobermorite. The calcium silicate binder in the 10:45:45 mixture of cement: slag: fly ash was made up of poorly ordered C-S-H. The sample cured for 14 months may contain a small amount of the more crystalline calcium silicate hydrate phases. Layered double hydroxides in the hydrotalcite (magnesium-aluminum carbonate hydroxide) and hydrocalumite / AFm phases (calcium aluminum hydroxide) were present in mixtures containing slag. The specific phase(s) were not identified because these phases form solid solutions and have a considerable amount of overlap in their x-ray patterns. Sodium nitrate was the only sodium salt phase identified in x-ray diffraction patterns of the samples hydrated with salt solution. Drying during x-ray diffraction sample preparation may have resulted in precipitation of the sodium nitrate or it may have been present in the samples prior to x-ray sample preparation. Sodium sulfate, aluminate, and carbonate may have been incorporated in the structures of the layered double hydroxide (AFm) type phases. These mixed metal layered double hydroxides make up an important fraction of the matrix in the slag containing blends hydrated with caustic salt solution. They are among the few oxide-based phases that exhibit substantial, permanent anion exchange capacity [Kirkpatrick, et al. 1999, Plamer, et al., 2009, and Zhang and Reardon, 2003]. They also contribute to the structural properties of cementitious matrices [Taylor, 1997]. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Recycling Perspectives of Electric Arc Furnace Slag in the United States: A Review

This article presents a comprehensive review of electric arc furnace (EAF) slag recycling in the United States, examining its classification and the associated challenges and opportunities of its industrial use. The study affirms EAF slag's nonhazardous status. Here, the main challenges identified in EAF slag applications include substantial variations in composition and volume instability during/after hydration. Analysis of the U.S. recycling practices reveals that EAF slag is predominantly reused, with minimal landfill disposal. However, its prevalent use as a low value-added aggregate in construction applications underscores the industry's ongoing challenge to get additional value from EAF slag recycling. Despite these challenges, the study highlights a great potential for increased value extraction from EAF slag recycling. Beyond conventional applications as a clinker material for the cement industry, the review explores modern technologies for steelmaking slag recycling, revealing options for recovering valuable metals such as Cr, V, Mo, and Fe through methods such as leaching, reduction, and oxidation.

42 ENGINEERING↗

The Effect of Slag Heat Treatment on Ingot Quality during Cold Start Electroslag Remelting

Heat treatments of a commercial 40CaF 2 –30CaO–30Al 2 O 3 slag are explored to study their effect on quality of ingots produced using cold start electroslag remelting (ESR). Reducing heat treatment (or roasting) time or temperature for slag degassing can lead to energy savings as well as longer lifetimes for various components. Heat treatments in vacuum with pressure monitoring and air are investigated along with several temperatures, heating rates, and/or holding times. A research scale ESR furnace is used with steel electrodes. Significant differences in ingot quality, such as the occurrence of pores and a rough sidewall near the bottom of the ingot produced using slag heat treated in air at 580 °C, are observed. Further, adjustments in the heat treatment temperature for heat treatment in air eventually lead to an ingot quality comparable to that obtained using slag degassing in a controlled atmosphere at higher temperatures. Using differential thermal analysis, it is found that moisture is primarily removed from the slag at ≈460 °C and 700 °C. A safe slag roasting temperature is concluded to be 750 °C. Improper slag heat treatment leads to hydrogen concentrations from 8 to 15 ppm in about one‐quarter of the ingot volume.

36 MATERIALS SCIENCE↗

Effect of Initial FeO Content and CaO:SiO{sub 2} Ratio on the Reduction Smelting Kinetics of the CaO-SiO{sub 2}-MgO{sub satd.}-FeO Slag System

The effect of the initial FeO content and CaO:SiO{sub 2} ratio (CaO mass pct/SiO{sub 2} mass pct) on the reduction smelting of FeO with carbon flake addition is investigated in the CaO-MgO{sub satd.}-SiO{sub 2}-FeO slag system at 1823 K (1550 °C). Carbon rapidly reacted with FeO in the molten slag, causing both foaming and compositional changes in the slag. As FeO is reduced, the MgO saturation is modified, and solid precipitants, including MgO and other complex oxides, were observed, which significantly affected the slag properties, including the viscosity and foaming behavior. The solid-phase fraction and viscosity were estimated from changes in the measured FeO content over time using the thermochemical software FactSage. The iron recovery, which is distinguished from the amount of reduced Fe droplets, showed opposite behavior to the measured maximum foaming height and modified foaming index. According to the FeO mass transfer coefficient considering slag foaming at various initial FeO contents and CaO:SiO{sub 2} ratios, the reduction rate was optimal at higher initial FeO contents and a CaO:SiO{sub 2} ratio of 2.0, which did not correspond to the optimal iron recovery at an initial FeO content of 44 mass pct and above and a CaO:SiO{sub 2} ratio of 1.2. The results showed that slag foaming may increase the reduction kinetics, but the slag composition needs to be optimized for greater iron recovery.

36 MATERIALS SCIENCE↗

Distribution of P{sub 2}O{sub 5} and Na{sub 2}O Between Solid Solution and Liquid Phase in the CaO-SiO{sub 2}-Fe{sub 2}O{sub 3}-P{sub 2}O{sub 5}-Na{sub 2}O Slag System with High P{sub 2}O{sub 5} Content

The phosphorus content in hot metal will increase in future, because iron ores are steadily deteriorating in quality. Na{sub 2}O addition to slag is considered an effective method for increasing the efficiency of dephosphorization. In addition, Na{sub 2}O modification also facilitates phosphorus recovery from dephosphorization slag with high P{sub 2}O{sub 5} content by selective leaching. Therefore, it is necessary to investigate the distribution ratios of P{sub 2}O{sub 5} and Na{sub 2}O between solid solution and liquid phase in the CaO-SiO{sub 2}-Fe{sub 2}O{sub 3}-P{sub 2}O{sub 5}-Na{sub 2}O slag system. A linear relationship was found between the distribution ratio of P{sub 2}O{sub 5} and the Na{sub 2}O content in slag, and was independent of P{sub 2}O{sub 5} content. When the Na{sub 2}O content was high, the Na{sub 2}O content in the solid solution approached saturation and a new 2CaO·SiO{sub 2}-2CaO·Na{sub 2}O·P{sub 2}O{sub 5} solid solution formed. The addition of Na{sub 2}O decreased the P{sub 2}O{sub 5} content in solid solution, while it increased the mass fraction of solid solution in slag. The distribution ratio of P{sub 2}O{sub 5} increased with increase in the Fe{sub 2}O{sub 3} content and basicity of slag. An increase in P{sub 2}O{sub 5} content in slag results in an increase in the activity coefficient of P{sub 2}O{sub 5} both in the liquid phase and in the solid solution.

36 MATERIALS SCIENCE↗

Effects of the Cr{sub 2}O{sub 3} Content on the Viscosity of CaO-SiO{sub 2}-10 Pct Al{sub 2}O{sub 3}-Cr{sub 2}O{sub 3} Quaternary Slag

The present study experimentally investigates the effect of Cr{sub 2}O{sub 3} on the viscosity of molten slags. The viscosities of CaO-SiO{sub 2}-10 pct Al{sub 2}O{sub 3}-Cr{sub 2}O{sub 3} quaternary slags with two different binary basicities (R, basic slag with R = 1.2 and acidic slag with R = 0.8) were measured by the rotating cylindrical method from 1813 K to 1953 K (1540 °C to 1680 °C). The results showed that the viscosity of both types of slag decreased as the Cr{sub 2}O{sub 3} content increased, but the viscosity of acidic slags exhibited a greater decrease. The slags showed good Newtonian behavior at such high temperatures. Cr{sub 2}O{sub 3} could act as a network modifier to simplify the Si-O-Si tetrahedral structure, as verified by the Raman spectral analysis, which was consistent with the decreasing trend of viscosity. The activation energy of viscous flow decreased slightly with increasing Cr{sub 2}O{sub 3}, but increasing the basicity seemed to be more effective in decreasing the viscosity than adding Cr{sub 2}O{sub 3}.

36 MATERIALS SCIENCE↗

Characteristics of Calcium-Aluminate Slags and Pig Iron Produced from Smelting-Reduction of Low-Grade Bauxites

Low-grade bauxite ores are not favorable in the conventional Bayer process for alumina production, as they are producing more bauxite residue (red mud) and accompanying lower alumina yield than high-grade ores. In the current study, the thermodynamics and characterization of calcium-aluminate slags and pig iron produced from smelting reduction of high iron- and silica-containing bauxites are studied. Coke and limestone are used to reduce the iron oxide and adjust the basicity of slag during smelting. There is evidence that complete iron separation from bauxite is feasible through smelting-reduction process, and up to 99.9 pct of iron can be eliminated. Moreover, it is shown that the partial separation of silicon, titanium, and other elements from the Al{sub 2}O{sub 3}-containing slag occurs. The phase compositions and the distribution of elements between the metal and slag phases provide information about the high-temperature behavior of the bauxite components during smelting reduction. Employing electron microscopy analysis, it is indicated that the morphologies of CaO·Al{sub 2}O{sub 3}, 12CaO·7Al{sub 2}O{sub 3}, 2CaO·Al{sub 2}O{sub 3}·SiO{sub 2}, and CaO·Al{sub 2}O{sub 3}·SiO{sub 2} phases in the slag, as well as the complex oxides of Ca-Al-Si-Ti in the slag behave differently as the mass ratio of Al{sub 2}O{sub 3}/(Fe{sub 2}O{sub 3 }+ SiO{sub 2}) in the bauxite changes. It is also shown that the phases of slag produced from smelting-reduction below 5 K s{sup −1} of cooling rate are proper for further leaching process.

36 MATERIALS SCIENCE↗

Effect of B{sub 2}O{sub 3} Addition on Electrical Conductivity and Structural Roles of CaO-SiO{sub 2}-B{sub 2}O{sub 3} Slag

The effect of B{sub 2}O{sub 3} addition on electrical conductivity of CaO-SiO{sub 2}-B{sub 2}O{sub 3} slag was investigated using the four-electrode method. The slag structure was determined from Raman and nuclear magnetic resonance spectra. The experimental results show that the electrical conductivity, as the B{sub 2}O{sub 3} content in the slag increased from 0 to 10 pct, monotonously increases from 0.0769 to 0.2642 Ω{sup −1} cm{sup −1} at temperatures ranging from 1783 to 1873 K (1510 °C to 1600 °C). The effects of temperature on electrical conductivity obeyed the Arrhenius law, and the electrical conductivity increased as the temperature increased. The Raman spectra results indicated that addition of B{sub 2}O{sub 3} led to an increase of Q{sup 3}(Si) at the cost of Q{sup 2}(Si), which will increase the degree of polymerization of the slag. {sup 11}B nuclear magnetic resonance spectra showed that both BO{sub 3} trigonal and BO{sub 4} tetrahedral structures increased with the increasing B{sub 2}O{sub 3} content. There was a competitive effect between the presence of these structures and an enhanced degree of polymerization of slags in the networks, which resulted in the increased electrical conductivity of the slag. A structure–electrical conductivity model for CaO-SiO{sub 2}-B{sub 2}O{sub 3} slag was established.

36 MATERIALS SCIENCE↗

Identification of Rate, Extent, and Mechanisms of Hot Metal Resulfurization with CaO-SiO{sub 2}-Na{sub 2}O Slag Systems

The resulfurization of hot metal has not been comprehensively studied in literature. This study presents an experimental and mathematical modeling study of resulfurization in thermodynamic and kinetic point of view. The rate, extent, and mechanisms of resulfurization were evaluated by analyzing concurrently the physical properties and sulfur-extracting ability of the slag. Experiments were conducted in a chamber furnace in an argon atmosphere, and the hot metal was sampled with pre-defined basis. The experiments were continued until the metal–slag system reached an apparent thermodynamic equilibrium. To obtain a quantitative measure on the effect of system properties on the rate and extent of resulfurization, the results of this study were combined with previous studies handling the sulfide capacities of Na{sub 2}O-SiO{sub 2} and CaO-SiO{sub 2}-Na{sub 2}O slag systems. The sulfide capacities of the slag and corresponding metal–slag sulfur partition ratios were mathematically modeled with data-driven techniques such as multiple linear and non-linear regression and artificial neural networks. Finally, with the help of these, to study the kinetics of resulfurization, a simple mechanistic reaction model was derived. The results suggest that resulfurization of hot metal follows 1st-order kinetics and that the rate and extent can be regulated through the control of the associated thermodynamic driving force and by modifying the physical properties of the slag. The rate-limiting factor was found to be determined by the morphology of the slag phase.

36 MATERIALS SCIENCE↗

Electric Conductivity of TiO{sub 2}-Ti{sub 2}O{sub 3}-FeO-CaO-SiO{sub 2}-MgO-Al{sub 2}O{sub 3} for High-Titania Slag Smelting Process

The electric conductivity of high-titania slag of TiO{sub 2}-Ti{sub 2}O{sub 3}-FeO-CaO-SiO{sub 2}-Al{sub 2}O{sub 3}-MgO slag system was measured by means of four-electrode alternating current (AC) impedance method. The results show that high-titania slag exhibits a good electric conductivity, around 45 to 141 S cm{sup −1} with slight dependence on the temperature, which is of several orders of magnitude higher than that of the silicate slags. Further, electric conductivity of high-titania slag decreased with the increasing FeO content, whereas, the increasing Ti{sup 3+}/Ti{sup 4+} and TiO{sub 2} contents caused a significant increase in the electric conductivity. Based on the experimental results and the calculated results, the conductive mechanism of high-titania slag was discussed in detail. It can be concluded that the high-titania slag exhibits a characteristic of electronic–ionic mixed conductivity, but the effect of electronic conduction dominates above the liquidus temperature; however, with the decreasing temperature, the electronic conductivity was gradually weakened. The mechanism was postulated to be a random walk of electrons between tetravalent titanium and trivalent titanium dispersed in the melt.

36 MATERIALS SCIENCE↗

Influence of limestone on the hydration of ternary slag cements

The hydration kinetics, microstructure and pore solution composition of ternary slag-limestone cement have been investigated. Commercial CEM I 52.5 R was blended with slag and limestone; maintaining a clinker to SCM ratio of 50:50 with up to 20% slag replaced by limestone. The sulphate content was maintained at 3% in all composite systems. Hydration was followed by a combination of isothermal calorimetry, chemical shrinkage, scanning electron microscopy, and thermogravimetric analysis. The hydration of slag was also followed by SEM image analysis and the QXRD/PONKCS method. The accuracy of the calibrated PONKCS phase was assessed on slag and corundum mixes of varying ratios, at different water/solid ratios. Thus, the method was used to analyse hydrated cement without dehydrating the specimens. The results show that the presence of limestone enhanced both clinker and slag hydration. The pore volume and pore solution chemistry were further examined to clarify the synergistic effects. The nucleation effects account for enhanced clinker hydration while the space available for hydrate growth plus the lowering of the aluminium concentration in the pore solution led to the improved slag hydration.

36 MATERIALS SCIENCE↗

Inhibition mechanisms of steel slag on the early-age hydration of cement

Steel slag inhibits the early-age hydration of cement. However, its mechanism is still unclear. In this paper, the early-age hydration kinetics and the evolution of the solid phases, aqueous species and microstructures in a cement-steel slag composite binder are investigated to explore how steel slag inhibits the early-age hydration of cement. Two novel phenomena are found: (1) steel slag slows the depletion of gypsum and reduces the formation of ettringite, and (2) steel slag significantly inhibits the precipitation of CH and CSH. The results show that the addition of steel slag increases the Ca concentration in the pore solution, reduces the supersaturation of the pore solution with respect to CH and inhibits the nucleation and growth of CSH. Based on the above results, the retardation mechanisms of steel slag on the initial setting of cement paste are explained.

36 MATERIALS SCIENCE↗

Experimental study of dissolution of minerals and CO{sub 2} sequestration in steel slag

Highlights: • CO{sub 2} sequestration potential of steel slag under aqueous medium without the usage of any additive chemicals. • Formation of residue and product layers on the surface of slag particles. • Stabilization of steel slags by carbonation process. •Determining the impact of carbonation of slag on environment. - Abstract: This study strives to achieve a substantial amount of steel slag carbonation without using any harmful chemicals. For this purpose, experiments were performed in an aqueous medium, in a semi-batch reactor, to investigate the effect of varying reaction conditions during the steel slag CO{sub 2} sequestration process. Further, studying the effect of dissolution on carbonation reactions and the mineralogical changes that subsequently occur within the slag helps provide insight into the parameters that ultimately have an impact on the carbonation rate as well the magnitude of the impact.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Assessment of Physicochemical Properties of Electrical Arc Furnace Slag and Their Effects on Foamability

The composition of slags of an electric arc furnace (EAF) in a commercial melt shop was systematically analyzed with a focus on slag foaming. Basic behavior of FeO in an EAF slag was confirmed using fundamental thermodynamics. Monoxide ([Mg,Fe,Mn]O = M’O) and spinel ([Mg,Fe]Al{sub 2}O{sub 4}) phases in EAF slag were confirmed by X-ray diffraction analysis, and these results were interpreted in the context of equilibrium cooling calculation using FactSage™ software. Furthermore, the distribution of MgO with respect to the M’O-saturation limit at different basicity ratios (=CaO/SiO{sub 2}=C/S) and temperatures was evaluated. In particular, the relationship between MgO and FeO for C/S ratios ranging from 1.3 to 1.6 was considered with reference to phase equilibria. Foam height was affected by slag viscosity (η) and gas generation according to changes in C/S ratio and FeO content. Foaming index (Σ) decreased with the increasing C/S ratio and FeO content. The measured foam heights were relatively higher than the calculated values, and the result indicates that the effect of M’O on slag foaming in commercial process is remarkable. Therefore, slag chemistry should be optimized based on thermodynamic considerations and thermophysical properties to achieve good foaming characteristics.

36 MATERIALS SCIENCE↗

Effect of blast furnace slag on self-healing of microcracks in cementitious materials

The physico-chemical process of self-healing in blast furnace slag cement paste was investigated in this paper. With a high slag content i.e., 66% in cement paste and saturated Ca(OH)₂ solution as activator, it was found that the reaction products formed in cracks are composed of C-S-H, ettringite, hydrogarnet and OH–hydrotalcite. The fraction of C-S-H in the reaction products is much larger than the other minerals. Large amount of ettringite formed in cracks indicates the leaching of SO₄⁻² ions from the bulk paste and consequently the recrystallization. Self-healing proceeds fast within 50 h and then slows down. According to thermodynamic modeling, when the newly formed reaction products are carbonated, the filling fraction of crack increases first and then decreases. Low soluble minerals such as silica gel, gibbsite and calcite are formed. Compared to Portland cement paste, the potential of self-healing in slag cement paste is higher when the percentage of slag is high. Highlights: • Self-healing reaction products in slag cement paste were characterized. • Self-healing reaction products formed in time were quantified with image analysis. • Self-healing in slag cement paste was simulated with a reactive transport model. • Effect of carbonation on self-healing was investigated by thermodynamic modeling. • Effect of slag on self-healing was discussed based on experiments and simulation.

36 MATERIALS SCIENCE↗

A Slag Management Toolset for Determining Optimal Coal Gasification Temperatures

Abstract Gasifier operation is an intricate process because of the complex relationship between slag chemistry and temperature, limitations of feedstock materials, and operational preference. High gasification temperatures increase refractory degradation, while low gasification temperatures can lead to slag buildup on the gasifier sidewall or exit, either of which are problematic during operation. Maximizing refractory service life and gasifier performance require finding an optimized operating temperature range which is a function of the coal slag chemistry and viscosity. Gasifier operators typically use a slag’s viscosity-temperature relationship and/or ash-fusion fluid temperature to determine the gasification temperature range. NETL has built a slag management toolset to determine the optimal temperature range for gasification of a carbon feedstock. This toolset is based on a viscosity database containing experimental data, and a number of models used to predict slag viscosity as a function of composition and temperature. Gasifier users typically have no scientific basis for selecting an operational temperature range for gasification, instead using experience to select operational conditions. The use of the toolset presented in this paper provides a basis for estimating or modifying carbon feedstock slags generated from ash impurities in carbon feedstock.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗