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At least 73 records · Page 4

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DOE OSTI2024

Functionalization of Cathode–Electrolyte Interface with Ionic Liquids for High-Performance Quasi-Solid-State Lithium–Sulfur Batteries: A Low-Sulfur Loading Study

We introduce a quasi-solid-state electrolyte lithium-sulfur (Li–S) battery (QSSEB) based on a novel Li-argyrodite solid-state electrolyte (SSE), Super P–Sulfur cathode, and Li-anode. The cathode was prepared using a water-based carboxymethyl cellulose (CMC) solution and styrene butadiene rubber (SBR) as the binder while Li6PS5F0.5Cl0.5 SSE was synthesized using a solvent-based process, via the introduction of LiF into the argyrodite crystal structure, which enhances both the ionic conductivity and interface-stabilizing properties of the SSE. Ionic liquids (IL) were prepared using lithium bis(trifluoromethyl sulfonyl)imide (LiTFSI) as the salt, with pre-mixed pyrrolidinium bis(trifluoromethyl sulfonyl)imide (PYR) as solvent and 1,3-dioxolane (DOL) as diluent, and they were used to wet the SSE–electrode interfaces. The effect of IL dilution, the co-solvent amount, the LiTFSI concentration, the C rate at which the batteries are tested and the effect of the introduction of SSE in the cathode, were systematically studied and optimized to develop a QSSEB with higher capacity retention and cyclability. Interfacial reactions occurring at the cathode–SSE interface during cycling were also investigated using electrochemical impedance spectroscopy, cyclic voltammetry, and X-ray photoelectron spectroscopy supported by ab initio molecular dynamics simulations. This work offers a new insight into the intimate interfacial contacts between the SSE and carbon–sulfur cathodes, which are critical for improving the electrochemical performance of quasi-solid-state lithium–sulfur batteries.

25 ENERGY STORAGE↗

NASA NTRS1977

Toxicity of Pyrolysis Gases from Elastomers

The toxicity of the pyrolysis gases from six elastomers was investigated. The elastomers were polyisoprene (natural rubber), styrene-butadiene rubber (SBR), ethylene propylene diene terpolymer (EPDM), acrylonitrile rubber, chlorosulfonated polyethylene rubber, and polychloroprene. The rising temperature and fixed temperature programs produced exactly the same rank order of materials based on time to death. Acryltonitrile rubber exhibited the greatest toxicity under these test conditions; carbon monoxide was not found in sufficient concentrations to be the primary cause of death.

Hilado, Carlos J.↗

NASA NTRS1978

Development and evaluation of elastomeric materials for geothermal applications

A material for a casing packer for service for 24 hours in a geothermal environment was developed by synthesis of new elastomers and formulation of available materials. Formulation included use of commercial elastomer gumstocks and also crosslinking of plastic (high Tg) materials. Fibrous reinforcement of fluorocarbon rubbers was emphasized. Organic fiber reinforcement did not increase hot properties significantly. Glass fiber reinforcement gave significant increase in tensile properties. Elongation was reduced, and the glass-reinforced composition examined so far did not hold up well in the geothermal environment. Colloidal asbestos fibers were also investigated. A few experiments with polyphenyl ether gave material with low tensile and high compression set. Available high styrene SBR compositions were studied. Work to date suggests that new synthetic polymers will be required for service in geothermal environments.

Mueller, W. A.↗

NASA NTRS1977

Effect of heating rate on toxicity of pyrolysis gases from some elastomers

The effect of heating rate on the toxicity of the pyrolysis gases from six elastomers was investigated, using a screening test method. The elastomers were polyisoprene (natural rubber), styrene-butadiene rubber (SBR), ethylene propylene diene terpolymer (EPDM), acrylonitrile rubber, chlorosulfonated polyethylene rubber, and polychloroprene. The rising temperature and fixed temperature programs produced exactly the same rank order of materials based on time to death. Acrylonitrile rubber exhibited the greatest toxicity under these test conditions, and carbon monoxide was not found in sufficient concentrations to be the primary cause of death.

Hilado, C. J.↗

NASA NTRS1980

Low-thrust vehicles concept studies

Low thrust chemical (hydrogen-oxygen) propulsion systems configured specifically for low acceleration orbit transfer of large space systems were studied in order to provide the required additional data to better compare new, low thrust chemical propulsion systems with other propulsion approaches such as advanced electric systems. Study results indicate that it is cost-effective and least risk to combine the low thrust OTV and stowed spacecraft in a single 65 K shuttle. Mission analysis indicates that there are 25 such missions, starting in 1987. Multiple shuttles (LSS in one, OTV in another) result in a 20% increase in LSS (SBR) diameter over single shuttle launches. Synthesis and optimization of the LSS characteristics and OTV capability resulted in determination of the optimum thrust-to-weight and thrust level. For the space based radar with radial truss arms (center thrust application), the optimum thrust-to-weight (maximum) is 0.1, giving a thrust of 2000 lb. For the annular truss (edge-on thrust application) the structure is not as sensitive, and thrust of 1000 lb appears optimum. For the geoplatform, optimum T/W is .15 (3000 lb thrust). The effects of LSS structure material, weight distribution, and unit area density were evaluated, as were the OTV engine thrust transient and number of burns.

Ketchum, W. J.↗

NASA NTRS1986

Development of the Lens Antenna Deployment Demonstration (LADD) shuttle-attached flight experiment

The primary objective of the LADD Program is to develop a technology demonstration test article that can be used for both ground and flight tests to demonstrate the structural and mechanical feasibility and reliability of the single-axis roll-out space based radar (SBR) approach. As designed, the LADD will essentially be a generic strucutural experiment which incorporates all critical technology elements of the operational satellite and is applicable to a number of future antenna systems. However, to fully determine its design integrity for meeting the lens flatness and constant geometry requirements in a zero g environment under extreme thermal conditions, the LADD must be space flight tested. By accurately surveying the structure under varying conditions the membrane tolerance-holding capabilities of the structure will be demonstrated. The flight test will provide data to verify analytical tools used to predict thermal and structural behavior. Most important, the experiment will provide an initial indication of structural damping in a zero g vacuum environment. The recently completed Solar Array Flight Experiment (SAFE) showed orbital damping greater than that experienced during ground testing. From the experience and the information obtained from LADD it is hoped that designs can be confidently extrapolated to operational satellites with apertures in the 20 m by 60 m size range.

Hill, H.↗

NASA NTRS1987

Reduction of the radar cross section of arbitrarily shaped cavity structures

The problem of the reduction of the radar cross section (RCS) of open-ended cavities was studied. The issues investigated were reduction through lossy coating materials on the inner cavity wall and reduction through shaping of the cavity. A method was presented to calculate the RCS of any arbitrarily shaped structure in order to study the shaping problem. The limitations of this method were also addressed. The modal attenuation was studied in a multilayered coated waveguide. It was shown that by employing two layers of coating, it was possible to achieve an increase in both the magnitude of attenuation and the frequency band of effectiveness. The numerical method used in finding the roots of the characteristic equation breaks down when the coating thickness is very lossy and large in terms of wavelength. A new method of computing the RCS of an arbitrary cavity was applied to study the effects of longitudinal bending on RCS reduction. The ray and modal descriptions for the fields in a parallel plate waveguide were compared. To extend the range of validity of the Shooting and Bouncing Ray (SBR) method, the simple ray picture must be modified to account for the beam blurring.

Chou, R.↗

NASA NTRS1988

Moving belt radiator development status

Development of the Moving Belt Radiator (MBR) as an advanced space radiator concept is discussed. The ralative merits of Solid Belt (SBR), Liquid Belt (LBR), and Hybrid Belt (HBR) Radiators are described. Analytical and experimental efforts related to the dynamics of a rotating belt in microgravity are reviewed. The development of methods for transferring heat to the moving belt is discussed, and the results from several experimental investigations are summarized. Limited efforts related to the belt deployment and stowage, and to fabrication of a hybrid belt, are also discussed. Life limiting factors such as seal wear and micrometeroid resistance are identified. The results from various MBR point design studies for several power levels are compared with advanced Heat Pipe Radiator technology. MBR designs are shown to compare favorable at both 300 and 1000 K temperature levels. However, additional effort will be required to resolve critical technology issues and to demonstrate the advantage of MBR systems.

White, K. Alan↗

NASA NTRS1988

Moving Belt Radiator technology issues

Development of the Moving Belt Radiator (MBR) as an advanced space radiator concept is discussed. The relative merits of Solid Belt (SBR) Liquid Belt (LBR), and Hybrid Belt (HBR) Radiators are described. Analytical and experimental efforts related to the dynamics of a rotating belt in microgravity are reviewed. The development of methods for transferring heat to the moving belt is discussed, and the results from several experimental investigations are summarized. Limited efforts related to the belt deployment and stowage, and to fabrication of a hybrid belt, are also discussed. Life limiting factors such as seal wear and micrometeroid resistance are identified. The results from various MBR point design studies for several power levels are compared with advanced Heat Pipe Radiator technology. MBR designs are shown to compare favorable at both 300 and 1000 K temperature levels. However, additional effort will be required to resolve critical technology issues and to demonstrate the advantage of MBR systems.

White, K. Alan, III↗

NASA NTRS1989

Arrays for space applications

Concepts that were studied for application in space based radar (SBR) systems are presented. These antenna systems were for low earth orbit and require large fields of view (FOV). The systems included both space-fed and corporate-fed arrays.

Schuman, Harvey K.↗

NASA NTRS1991

Effects of space environment on space-based radar phased-array antenna: Status and preliminary observations

The overall objective is to evaluate the effect of the space environment on Kapton films considered for the Grumman space based radar (SBR) phased-array antenna. The most striking result is the overall good condition of the Kapton antenna planes and Kapton tensile specimens. This is largely attributable to the orientation of the Kapton (parallel and flush on the space end) and the stability of the LDEF in orbit. Results on elongation and mechanical properties of the plain and fiberglass reinforced Kapton will be described. Stress-dependent permanent deformation and some reductions in strain to failure were observed. Physical property testing of the materials is in progress. Electronic data acquisition and memory systems appeared to operate correctly, but functional tests were not yet performed. An evaluation of the high voltage-plasma interaction data is underway. Some minor systems anomalies (e.g., fastener sheared during removal, strong odor inside electronics container) were noted. Other observations such as radiation, contamination, impacts, and orientation features of atomic oxygen erosion are reported.

Whiteside, J. B.↗

NASA NTRS1992

Effects of the space environment on space-based radar phased-array antenna; status and preliminary observations (LDEF Experiment A0133)

The overall objective of the experiment was to evaluate the effect of the space environment on components considered for a Space-Based Radar (SBR) Phased-Array Antenna. Of primary interest was a study of the degradation of the polyimide film Kapton (DuPont trademark), the material considered for use in the antenna plane. The most striking result of the experiment was the overall good condition of the Kapton antenna planes and Kapton tensile specimens, despite nearly six years of exposure to the space environment. This was largely attributable to the orientation of the Kapton (parallel and flush on the space end) and the stability of the Long Duration Exposure Facility (LDEF) in orbit. However, weathering of exposed Kapton surfaces was not insignificant. Results on elongation and mechanical properties of the plain and the fiberglass-reinforced Kapton are presented. Reduction in strain to failure of flight-exposed Kapton is attributed to surface defects of these specimens. Physical property testing of the materials to date reveals no significant difference between flight-exposed and control material. The second objective was to investigate the interaction between high-voltage electrodes and typical spacecraft contaminants in simulation of discharge triggering across differentially charged dielectric surfaces (spacecraft charging conditions). Electronic data acquisition and memory systems appeared to operate correctly, but very few discharges were recorded. Induced radioactivity, contamination, impacts, and orientation features of atomic oxygen erosion were observed.

J B Whiteside↗

NASA NTRS1992

A space-based microwave radar concept

A space-based microwave radar (SBR) concept is defined using a tether trans-receive antenna supported between two gravity gradient low earth-orbiting satellites. A cluster of four tether antennas each of 6 km maximum length and 1.5 km separation between tethers constitutes a radar. A system of eight to eleven such clusters constitutes the overall radar scheme which will cover approximately one third of the earth surface for detecting sea-based targets. Issues identified are the array structure, coherence of tethered arrays, grating lobe energy clamping, clutter effects, communications, system requirements and the overall radar system concept including stability considerations. This paper presents the base-line definition of an alternate space-based radar scheme.

Chakraborty, D.↗

NASA NTRS1992

Electromagnetic scattering from an inhomogeneous object by ray tracing

A 'shooting and bouncing ray' (SBR) formulation is presented for treating the electromagnetic scattering from electrically large, inhomogeneous objects. A dense grid of rays representing the incident plane wave is shot toward the inhomogeneous object. At the scatterer boundary, reflected rays and refracted rays are generated due to discontinuity of the medium parameters. The trajectory, amplitude, phase and polarization of the rays inside the inhomogeneous object are traced based on geometrical optics. Whenever the rays cross the scatterer surface, additional reflected/refracted rays are generated and are tracked. This process is repeated until the intensities of the refracted/reflected rays become negligible. The contributions of the exiting rays to the total scattered field are calculated by using the equivalence principle in conjunction with a ray-tube integration scheme. The ray formulation is applied to calculate the backscattering from cylinders and spheres and good agreement with the exact series solutions is observed in the high frequency range. In addition, the backscattering mechanisms in penetrable objects are interpreted in terms of simple ray pictures.

Kim, Hyeongdong↗

NASA NTRS1993

The development and testing of the Lens Antenna Deployment Demonstration (LADD) test article

The USAF Rome Laboratory and NASA Marshall Space Flight Center, through contract to Grumman Corporation, have developed a space-qualifiable test article for the Strategic Defense Initiative Organization to demonstrate the critical structural and mechanical elements of single-axis roll-out membrane deployment for Space Based Radar (SBR) applications. The Lens Antenna Deployment Demonstration (LADD) test article, originally designed as a shuttle-attached flight experiment, is a large precision space structure which is representative of operational designs for space-fed lens antennas. Although the flight experiment was cancelled due to funding constraints and major revisions in the Strategic Defense System (SDS) architecture, development of this test article was completed in June 1989. To take full advantage of the existence of this unique structure, a series of ground tests are proposed which include static, dynamic, and thermal measurements in a simulated space environment. An equally important objective of these tests is the verification of the analytical tools used to design and develop large precision space structures.

Pugh, Mark L.↗

NASA NTRS1994

Experimental evaluation of battery cells for space-based radar application

A test program was conducted to characterize five space-quality nickel-hydrogen (NiH2) battery cells. A subset of those tests was also done on five commercial nickel-cadmium (NiCd) cells, for correlation to the characteristics of an Energy Storage Unit Simulator. The test program implemented the recommendations of a 1991 study, as reported to IECEC-92. The findings of the tests are summarized, and expected impacts on the performance of the electrical power system (EPS) of a large space-based radar (SBR) surveillance satellite are derived. The main characteristics examined and compared were terminal voltage (average and transient) and capacity through discharge, equivalent series resistance, derived inductance and capacitance, charge return efficiency, and inter-pulse charge effectiveness.

Maskell, Craig A.↗

NASA NTRS1994

Advanced studies of electromagnetic scattering

In radar signature applications it is often desirable to generate the range profiles and inverse synthetic aperture radar (ISAR) images of a target. They can be used either as identification tools to distinguish and classify the target from a collection of possible targets, or as diagnostic/design tools to pinpoint the key scattering centers on the target. The simulation of synthetic range profiles and ISAR images is usually a time intensive task and computation time is of prime importance. Our research has been focused on the development of fast simulation algorithms for range profiles and ISAR images using the shooting and bouncing ray (SBR) method, a high frequency electromagnetic simulation technique for predicting the radar returns from realistic aerospace vehicles and the scattering by complex media.

Ling, Hao↗

NASA NTRS1998

A Hybrid SBR/MoM Technique for Analysis of Scattering from Small Protrusions on a Large Conducting Body

For analysis of large-scale electromagnetic scattering problems, high-frequency asymptotic methods are fast but approximate, whereas low-frequency numerical methods are accurate but slow. Neither can produce an efficient and accurate solution to scattering by large bodies containing small structures. A promising approach is to combine the best features of both types of methods to produce a hybrid technique that is sufficiently fast, reasonably accurate, and applicable to a class of unsolvable problems such as the scatterers mentioned above. There are two extremes for this type of hybridization. One is simply to superimpose solutions from asymptotic and numerical methods. While this approach is most widely used in practical applications, it neglects the interactions between the two solutions, which can be significant in many problems. The other extreme is to combine an asymptotic and a numerical method in an exact manner. In this approach, the effect of a large body is included by incorporating its diffraction into the Green's function in the integral equation for the small structures, which accounts for all interactions. While this approach is accurate, it is difficult to be implemented in a general-purpose computer code because of its complex nature. A more practical approach is to develop a technique that can include all significant interactions and neglect all trivial interactions. The resulting hybrid technique can produce sufficient accuracy and can be implemented in a general-purpose computer code. In this paper, we develop a technique that combines the shooting and- bouncing-ray (SBR) method and the method of moments (MoM) to solve for the scattering by large conducting bodies with small structures mounted on their surfaces.

Jin, J. M.↗