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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Rotating Reverse Osmosis for Wastewater Reuse

Membrane filtration such as Reverse Osmosis (RO) removes ions, proteins, and organic chemicals which are generally very difficult to remove using conventional treatment. Moreover, membrane is an absolute filtration method, so its treatment efficiency and performance are stable and predictable. We are currently working on the development of rotating RO membrane system. Dynamic rotating membrane filtration, which can produce a high shear rate, may be helpful to obtain high rejection of organic pollutants.The goal of our current work is to improve the flux of the device by increasing pressure by a factor of 3 to 4. In addition, the rejections for a wider variety of inorganic and organic compounds typically found in space mission wastewater are measured.

Lueptow, Richard M.↗

Site Disorder Drives Cyanide Dynamics and Fast Ion Transport in Li 6 PS 5 CN

Halide argyrodite solid-state electrolytes of the general formula Li 6 PS 5 X exhibit complex static and dynamic disorder that plays a crucial role in ion transport processes. Here, we unravel the rich interplay between site disorder and dynamics in the plastic crystal argyrodite Li 6 PS 5 CN and the impact on ion diffusion processes through a suite of experimental and computational methodologies, including temperature-dependent synchrotron powder X-ray diffraction, AC electrochemical impedance spectroscopy, 7 Li solid-state NMR, and machine learning-assisted molecular dynamics simulations. Sulfide and (pseudo)halide site disorder between the two anion sublattices unilaterally improves long-range lithium diffusion irrespective of the (pseudo)halide identity, which demonstrates the importance of site disorder in dictating bulk ionic conductivity in the argyrodite family. Furthermore, we find that anion site disorder modulates the presence and time scales of cyanide rotational dynamics. Ordered configurations of anions enable fast, quasi-free rotations of cyanides that occur on time scales of 10 11 Hz at T = 300 K. In contrast, we find that cyanide dynamics are slow or frozen in Li 6 PS 5 CN when site disorder between the cyanide and sulfide sublattices is present at T = 300 K. We rationalize the observed differences in cyanide dynamics in the context of elastic dipole interactions between neighboring cyanide anions and local strain induced by the configurations of site disorder that may impact the energetic landscape for cyanide rotational dynamics. Through this study, we find that anion disorder plays a decisive role in dictating the extent and time scales of both lithium ion and cyanide dynamics in Li 6 PS 5 CN.

36 MATERIALS SCIENCE↗

Double Paddle‐Wheel Enhanced Sodium Ion Conduction in an Antiperovskite Solid Electrolyte

Abstract Antiperovskite structure compounds (X 3 AB, where X is an alkali cation and A and B are anions) have the potential for highly correlated motion between the cation and a cluster anion on the A or B site. This so‐called “paddle‐wheel” mechanism may be the basis for enhanced cation mobility in solid electrolytes. Through combined experiments and modeling, the first instance of a double paddle‐wheel mechanism, leading to fast sodium ion conduction in the antiperovskite Na 3− x O 1− x (NH 2 ) x (BH 4 ), is shown. As the concentration of amide (NH 2 − ) cluster anions is increased, large positive deviations in ionic conductivity above that predicted from a vacancy diffusion model are observed. Using electrochemical impedance spectroscopy, powder X‐ray diffraction, synchrotron X‐ray diffraction, neutron diffraction, ab initio molecular dynamics simulations, and NMR, the cluster anion rotational dynamics are characterized and it is found that cation mobility is influenced by the rotation of both NH 2 − and BH 4 − species, resulting in sodium ion conductivity a factor of 10 2 higher at x = 1 than expected for the vacancy mechanism alone. Generalization of this phenomenon to other compounds could accelerate fast ion conductor exploration and design.

25 ENERGY STORAGE↗

Passive Stabilization of Rotating Spacecraft Using Dynamic Fluid-Pressure Equilibrium

Rotating spacecraft can provide artificial gravity for long-term space missions, but the design of a Guidance and Control scheme for these vehicles is nuanced. For a three-segment vehicle with the propulsion element located at the center of mass, the vehicle must stabilize itself about this point even in the event of various off-nominal circumstances. Thus, a robust and passive spin stabilization system is needed. In this paper, the dynamics of this system are explored and constraints are placed on the performance and controllability. A controller is thus developed based on assumptions regarding the fluid transfer between elements, and the result is simulated. Generalized methodology is then extracted and extended applications are explored, such as a conceptual fluid ring and active mass displacement for attitude control.

Rotating↗

Complex Dynamics in Argyrodite Solid-State Ion Conductors

Argyrodites are a compositionally diverse family of materials that exhibit remarkable ion transport properties. While the average crystal structures of argyrodites have been extensively studied, ion transport in these materials is governed by a confluence of dynamic processes spanning the cation, anion, and polyanionic sublattices. This Perspective synthesizes recent advances in understanding the role of dynamics in structural behavior and ion transport properties. We examine the compositional and structural motifs that govern order−disorder transitions within the argyrodite family and further explore how ion hopping is facilitated by lattice dynamics, from long-range phonons to local rotational dynamics of polyanionic species. Through the lens of dynamics spanning multiple time and length scales, we establish guiding principles that govern transport phenomena and highlight avenues of future study for the argyrodite family of ion conductors.

36 MATERIALS SCIENCE↗

Climate-Rotation Feedback on Mars

It has long been appreciated that changes in the orbital and rotational geometry of Mars will influence the seasonal and latitudinal pattern of insolation [1-5], and this will likely dominate climatic fluctuations on time scales of 101 to 107 years [6-9]. Equally important, but less widely appreciated, is the influence climatic change can have on rotational dynamics. The primary means by which climate influences rotation is via its influence on transport of mass (volatiles and dust) into and out of the polar regions. Both the rate and direction of Mars rotation can be changed by these mass fluxes, but only the directional changes are climatically relevant.

Bils, Bruce G.↗

Climate-Rotation Feedback on Mars

It has long been understood that changes in the orbital and rotational geometry of Mars will influence the seasonal and latitudinal pattern of insolation, and this will likely dominate climatic fluctuations on timescales of 105 to 107 yr [6-91. Equally important, but less widely appreciated, is the influence climatic change can have on rotational dynamics. The primary means by which climate influences rotation is via its influence on transport of mass (volatiles and dust) into and out of the polar regions. Both the rate and direction of Mars rotation can be changed by these mass fluxes, but only the directional changes are climatically relevant.

Bills, B. G.↗

Climate Rotation Feedback on Mars

It has long been appreciated that changes in the orbital and rotational geometry of Mars will influence the seasonal and latitudinal pattern of insolation [1-5], and this will likely dominate climatic fluctuations on time scales of 101 to 107 years (6-9]. Equally important, but less widely appreciated, is the influence climatic change can have on rotational dynamics. The primary means by which climate influences rotation is via its influence on transport of mass (volatiles and dust) into and out of the polar regions. Both the rate and direction of Mars rotation can be changed by these mass fluxes, but only the directional changes are climatically relevant.

Bills, Bruce G.↗

Climate-Rotation Feedback on Mars

A new model is presented for the coupled evolution of climate and rotation, as applied to Mars. It has long been appreciated that changes in the orbital and rotational geometry of Mars will influence the seasonal and latitudinal pattern of insolation [1-5], and this will likely dominate climatic fluctuations on time scales of 10(exp 5) to 10(exp 7) years [6-9]. Equally important, but less widely appreciated, is the influence climatic change can have on rotational dynamics. The primary means by which climate influences rotation is via its influence on transport of mass (volatiles and dust) into and out of the polar regions. Many important issues remain unresolved: What are the ages of the polar caps? What climatic periods are recorded in the polar layered deposits? What is the long term obliquity history?

Bills, Bruce G.↗

Climate-Rotation Feedback on Mars

A new model is presented for the coupled evolution of climate and rotation, as applied to Mars. It has long been appreciated that changes in the orbital and rotational geometry of Mars will influence the seasonal and latitudinal pattern of insolation, and this will likely dominate climatic fluctuations on time scales of 10(exp 5) to 10(exp 7) years. Equally important, but less widely appreciated, is the influence climatic change can have on rotational dynamics. The primary means by which climate influences rotation is via its influence on transport of mass (volatiles and dust) into and out of the polar regions. Many important issues remain unresolved: What are the ages of the polar caps? What climatic periods are recorded in the polar layered deposits? What is the long term obliquity history? Additional information is contained in the original extended abstract.

Bills, Bruce G.↗

A Comparison of Three Algorithms for Orion Drogue Parachute Release

The Orion Multi-Purpose Crew Vehicle is susceptible to ipping apex forward between drogue parachute release and main parachute in ation. A smart drogue release algorithm is required to select a drogue release condition that will not result in an apex forward main parachute deployment. The baseline algorithm is simple and elegant, but does not perform as well as desired in drogue failure cases. A simple modi cation to the baseline algorithm can improve performance, but can also sometimes fail to identify a good release condition. A new algorithm employing simpli ed rotational dynamics and a numeric predictor to minimize a rotational energy metric is proposed. A Monte Carlo analysis of a drogue failure scenario is used to compare the performance of the algorithms. The numeric predictor prevents more of the cases from ipping apex forward, and also results in an improvement in the capsule attitude at main bag extraction. The sensitivity of the numeric predictor to aerodynamic dispersions, errors in the navigated state, and execution rate is investigated, showing little degradation in performance.

Matz, Daniel A.↗

Inversion Of Dynamical Equations For Control Of Attitude

Method of inverting nonlinear equations of rotational dynamics of rigid body used to design feedback control of orientation of body. Applicable to both direction-cosine and quaternion formulations suitable for large-angle maneuvers. Exploiting some apparently little-known properties of direction cosine and quaternion formulations, method leads to equations for model-follower control system that exhibits exactly linear attitude-error dynamics. Quarternion system more robust in responding to large roll-angle commands.

Bach, Ralph↗

Attitude control with realization of linear error dynamics

An attitude control law is derived to realize linear unforced error dynamics with the attitude error defined in terms of rotation group algebra (rather than vector algebra). Euler parameters are used in the rotational dynamics model because they are globally nonsingular, but only the minimal three Euler parameters are used in the error dynamics model because they have no nonlinear mathematical constraints to prevent the realization of linear error dynamics. The control law is singular only when the attitude error angle is exactly pi rad about any eigenaxis, and a simple intuitive modification at the singularity allows the control law to be used globally. The forced error dynamics are nonlinear but stable. Numerical simulation tests show that the control law performs robustly for both initial attitude acquisition and attitude control.

Paielli, Russell A.↗